JANUARY 1, 2002
Material Safety Data Sheet
Product: No. 511-UBX
KEX/PERFICURE CHEMICAL ACTIVATOR CEMENT
1. CHEMICAL PRODUCT & COMPANY IDENTIFICATION7
Product Name: KEX/PERFICURE CHEMICAL ACTIVATOR CEMENT
Manufacturer: KEX Tire Repair, 119 Rockland Avenue, Northvale, NJ 07647
24-Hour Emergency Phone Number: 800-424-9300
2. PRODUCT INGREDIENTS
CHEMICAL NAME: CAS NUMBER: % RANGE: OSHA PEL:
Naphtha (Petroleum Distillate) 64742-89-8 >90% 400 ppm TWA
* Toluene 108-88-3 <5% 100 ppm TWA
Zinc Oxide 1314-13-2 <2% 15 mg/m3 TWA
N-Ethylcyclohexylamine 5459-93-8 <1% None
Zinc Di-n-butyldithiocarbamate 136-23-2 <1% NE
Zinc Dimethyldithiocarbamate 137-30-4 <1% NE
* Benzene 71-43-2 <10 ppm NA
Balance of ingredients not rated as hazardous as defined in 29 CFR 1910.1200
鈥? Denotes chemical subject to reporting requirements of Section 313 of Title III of the 1986 Superfund
Amendments and Reauthorization Act (SARA) and 40 CFR Part 372
3. HAZARDS IDENTIFICATION
POTENTIAL HEALTH EFFECTS:
EYE: Liquid in eyes produces pain and irritation
.
SKIN: Short single exposure not likely to cause significant skin irritation. Prolonged or repeated contact of liquid
can cause irritation, defatting of skin and dermatitis.
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JANUARY 1, 2002
Material Safety Data Sheet
Product: No. 511-UBX
KEX/PERFICURE CHEMICAL ACTIVATOR CEMENT
INGESTION: Harmful if swallowed. Swallowing or vomiting and subsequent aspiration into the lungs may lead to
chemical pneumonia and pulmonary edema which is a potentially fatal condition. Misuse or other massive exposure
to toluene may cause multiple organ damage and/or death.
INHALATION: Excessive exposure to airborne solvent vapors may cause nose, throat, mouth and digestive tract
irritation, nervous system depression (drowsiness, dizziness, loss of coordination) and irregular heart beat. Alcohol
consumed before or after exposure may increase adverse effects.
SYSTEMIC (OTHER TARGET ORGANS): Signs and symptoms of excessive exposure may be respiratory tract
irritation. High concentrations of vapor harmful; may affect the brain or nervous system causing dizziness, headache
or nausea.
CANCER INFORMATION: Benzene, an extremely small component of this product has been identified by NTP,
as a 鈥淜 鈥? substance know to be a human carcinogen鈥?.
TERATOLOGY (BIRTH DEFECTS): None known
MUTAGENICITY: None known.
4. FIRST AID
EYES: Irrigate with flowing water immediately and continuously for 15 minutes while frequently lifting the upper
and lower eyelids. If irritation persists, consult medical personnel.
INGESTION: Do not induce vomiting. Give victim one or two glasses of water or milk. Call a physician or poison
control center immediately for further instructions. Never give anything by mouth to an unconscious person.
SKIN: Wash off in flowing water or shower. Wash affected skin areas with soap and water. Wash contaminated
clothing before reuse. Get medical attention if symptoms occur.
INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, qualified
personnel should administer oxygen. Call a physician or transport to medical facility.
5. FIRE FIGHTING MEASURES
FLAMMABLE PROPERTIES: Flash Point = 5掳F Method used 鈥? SETAFLASH CLOSED CUP. Autoignition
Temperatures 鈥? none available.
FLAMMABLE LIMITS: LEL: 1.0% UEL: 8%
HAZARDOUS COMBUSTION PRODUCTS: During a fire, carbon monoxide, irritating and/or toxic gases and
particulate may be generated by thermal decomposition or combustion.
EXTINGUISHING MEDIA: Water fog or fine spray. Carbon dioxide chemical. Foam. Dry Chemical.
Continued on page 3)
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JANUARY 1, 2002
Material Safety Data Sheet
Product: No. 511-UBX
KEX/PERFICURE CHEMICAL ACTIVATOR CEMENT
FIRE FIGHTING INSTRUCTIONS: Flammable liquid and vapor. Keep containers tightly closed. Isolate from
heat, electrical equipment, sparks, open flame, and other sources of ignition. Closed containers may rupture when
exposed to extreme heat. Use water spray to keep fire-exposed containers cool. Water spray may be ineffective;
product will float and can be re-ignited on surface of water. If water is used, fog nozzles are preferable.
PROTECTIVE EQUIPMENT FOR FIREFIGHTERS: Wear positive-pressure self-contained breathing apparatus
(SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, pants, boots and gloves). If
protection equipment is not available or not used, fight fire from a protected location or safe distance.
6. ACCIDENTAL RELEASE MEASURES
Steps to be taken in case material is released or spilled: Keep non-essential personnel a safe distance away from the
spill area. Remove all sources of ignition (flame, hot surfaces, and electrical, static or frictional sparks). Avoid
breathing vapors. Use approved self-contained breathing equipment. Notify appropriate authorities if necessary.
Contain and remove with inert absorbent material and non-sparking tools. Avoid contact. Place in properly labeled
metal containers. Notify National Response Center (800-424-8802) of uncontained releases to the environment in
excess of the Reportable Quantity (RQ). For all transportation accidents, call CHEMTREC at 800-424-9300.
7. HANDLING & STORAGE
HANDLING: Keep closure tight and container upright to prevent leakage. Ground and bond containers when
transferring material. Avoid skin and eye contact. Wash thoroughly after handling. Avoid breathing of vapor or
spray mists. Do not handle until all safety precautions have been read and understood. Empty containers should not
be re-used. Use with adequate ventilation. Because empty containers may retain product residue and flammable
vapors, keep away from heat, sparks and flame; do not cut, puncture or weld on or near the empty container. Do not
smoke where this product is used or stored.
STORAGE: Keep packaged in original, labeled containers until use. Store in cool, dry place. Do not remove or
deface label. Do not store or use near heat, sparks, or open flame. Refer to OSHA 29 CFR Part 1910.106,
鈥淔lammable and Combustible Liquids鈥? for specific storage requirements. Store only in well-ventilated areas. Do not
puncture, drag, or slide container. Keep container closed when not in use.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS: Sufficient ventilation in pattern and volume should be provided in order to
maintain air contaminant levels below recommended exposure limits. Caution: Solvent vapors are heavier than air
and collect in lower levels of the work area. Sufficient ventilation (using explosion-proof equipment) should be
provided to prevent flammable vapor/air mixtures from accumulating.
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JANUARY 1, 2002
Material Safety Data Sheet
Product: No. 511-UBX
KEX/PERFICURE CHEMICAL ACTIVATOR CEMENT
PERSONAL PROTRECTIVE EQUIPMENT
EYE/FACE PROTECTION: Wear safety glasses. Contact lenses should not be exposed. Chemical goggles and/or
face shields should be worn when splashing is a possibility.
SKIN PROTECTION: Use neoprene, nitrile, or rubber gloves to prevent skin contact.
RESPIRATORY PROTECTION: Use a NIOSH/MSHA approved chemical/mechanical filter respirator designed
to remove a combination of particulate and organic vapor if occupational limits are exceeded. For emergencies in
confined or poorly ventilated areas, call for properly trained emergency personnel. Observe OSHA regulations
(29CFR 1910.134) for respirator use.
EXPOSURE GUIDELINE(s): REMA TIP/TOP USA recommends that its customers minimize employee exposure.
Toxicological data for this product mixture (Product LD50 and LC50) is not available. REMA therefore suggests
that its customers consider adopting the lower of the current OSHA PEL or the ACGIH TLV鈥檚 of the significant
ingredients (Naphtha) for the purpose of evaluating and controlling employee exposures. The TLV鈥檚 recommended
by the ACGIH have been updated on a continuing basis:
Ingredient name: ACGIH TWA/STEL: OSHA TWA/CEIL:
Naphtha 400/NE ppm 400/NE ppm
Toluene 50/NE ppm 100/150 ppm
Zinc Oxide 10 mg/m3/NE 15 mg/m3/NE
N-Ethylcyclohexylamine None None
Zinc Di-n-butyldithiocarbamate NE NE
Zinc Dimethyldithiocarbamate NE NE
Benzene 0.5/2.5 ppm NE
(Note: NE = Not established)
9. PHYSICAL & CHEMICAL PROPERTIES
APPEARANCE: Pale yellow liquid VAPOR DENSITY: 3.1 (Air=1.0)
ODOR: Rubber Solvent odor
BOILING RANGE: 195 鈥? 206 掳F
SOLUBILITY IN WATER: Negligible (less than 1%)
SPECIFIC GRAVITY: 0.70 @ 60掳F VAPOR PRESSURE: 119 @100掳F
% VOLATILE: 95% Minimum by weight (Max. VOC Content = 664 g/L)
10. STABILITY & REACTIVITY
INCOMPATIBILITY WITH OTHER MATERIALS: Product is stable under recommended storage conditions.
Materials to avoid are liquid oxygen and strong oxidizers. Avoid open flames and welding arcs, which can cause
thermal degradation.
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JANUARY 1, 2002
Material Safety Data Sheet
Product: No. 511-UBX
KEX/PERFICURE CHEMICAL ACTIVATOR CEMENT
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
DECOMPOSITION PRODUCTS: Hazardous decomposition products may include and are not limited to carbon
monoxide and unidentified organic compounds.
11. TOXICOLOGICAL INFORMATION
CHRONIC TOXICITY
Repeated or prolonged solvent overexposure may result in permanent central nervous system damage. May affect the
gastrointestinal system. May affect the blood and blood-forming organs. Chronic skin contact may cause dermatitis.
12. DISPOSAL CONSIDERATIONS
DISPOSAL: Do not dump into any sewers, on the ground, or into any body of water. Disposal should be done in
accordance with Federal (40CFR Part 261), State and Local environmental control regulations. If waste is
determined to be hazardous, use licensed hazardous waste transporter and disposal facility.
UNUSED & UNCONTAMINATED PRODUCT: The preferred options include sending to a licensed, permitted
recycler, reclaimer, incinerator or other thermal destruction device.
13. TRANSPORT INFORMATION
DOT SHIPPING DESCRIPTION (49 CRF 172.101):
鈥淎dhesives containing Flammable Liquid, 3, UN1133, PG II, Flammable Liquid鈥?
DOT PLACARD (WHEN REQUIRED): 鈥淔LAMMABLE LIQUID鈥?, 3, 1133
DOT SHIPPING LABEL (WHEN REQUIRED): 鈥淔LAMMABLE LIQUID鈥?
DOT EXCEPTIONS: DOT Paragraphs 172.150 & 172.202.
ALTERNATE SHIPPING ARRANGEMENTS: Based on package or shipping container size, this product may be
shipped as a, 鈥淟imited Quantity鈥?, or, renamed, 鈥淐onsumer Commodity鈥? and reclassed as, 鈥淥RM-D鈥? Material.
IMO REQUIREMENTS: EmS No. = 3-05 MFAG Table No. = 330 IMDG Class: 3.2
ICAO/IATA Class: 3
14. REGULATORY INFORMATION
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JANUARY 1, 2002
Material Safety Data Sheet
Product: No. 511-UBX
KEX/PERFICURE CHEMICAL ACTIVATOR CEMENT
NOTICE: The information herein is presented in good faith and believed to be accurate as of the effective date
shown above. However, no warranty, express or implied is given. Regulatory requirements are subject to change
and may differ from one location to another. It is the buyer鈥檚 responsibility to ensure that its activities comply with
Federal, State or provincial, and local laws. The following specific information is made for the purpose of complying
with numerous laws and regulations.
US FEDERAL REGULATIONS
SARA 313 INFORMATION: Components identified with an asterisk (*) in Section 2 are subject to the reporting
requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR
Part 372.
SARA HAZARD CATEGORY: This product has been reviewed according to the EPA 鈥淗azard Categories鈥?
promulgated under Sections 311 and 312 of SARA Title III and is considered, under applicable definitions, to meet
the following categories:
IMMEDIATE HEALTH HAZARD
FIRE HAZARD
COMPREHENSIVE ENVIRONMENTAL RESPONSE COMPENSATION AND LIABILITY ACT
(CIRCLA): This product contains the following substance listed as 鈥淗azardous Substances鈥? under CERCLA, which
may require reporting of releases:
CATEGORY CHEMICAL NAME: CAS NUMBER: RQ: % IN PRODUCT:
Toluene 108-88-3 1,000# <5%
Zinc Dimethyldithiocarbamate 137-30-4 1# <1%
Benzene 71-43-2 10# <1%
TOXIC SUBSTANCES CONTROL ACT (TSCA): All ingredients in this product are listed on the TSCA, section
8, inventory.
OSHA HAZARD COMMUNICATION STANDARD: This product is a 鈥淗azardous Chemical鈥? as defined by the
OSHA Hazard Communication Standard, 29 CFR 1910.1200
STATE RIGHT-TO-KNOW: The following product component(s) are cited on certain State lists as mentioned.
Non-listed components may be shown in the composition section of the MSDS.
CHEMICAL NAME: CAS NUMBER: LIST:
Toluene 108-88-3 NYC, NJ, PA
Benzene 71-43-2 NYC, NJ, PA
CALIFORNIA PROPOSITION 65: The following statement is made in order to comply with the California Safe
Drinking Water and Toxic Enforcement Act of 1986: 鈥淲ARNING 鈥? THIS PRODUCT CONTAINS CHEMICALS
KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER OR REPRODUCTIVE TOXICITY.鈥?
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JANUARY 1, 2002
Material Safety Data Sheet
Product: No. 511-UBX
KEX/PERFICURE CHEMICAL ACTIVATOR CEMENT
CANADIAN REGULATIONS
WHMIS INFORMATION: The Canadian Workplace Hazardous Materials Information System (WHMIS)
Classification for this product is:
D2B 鈥? Eye or skin irritant (Other Toxic Effects)
Class B, Division 2 鈥? Flammable Liquid
CPR STATEMENT: This product has been classified in accordance with the hazard criteria of the Canadian
Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR.
HAZARDOUS PRODUCTS ACT INFORMATION: This product contains the following ingredient(s) which are
Controlled Products and/or on the Ingredient Disclosure List (Canadian HPA section 13 & 14):
COMPONENTS: CAS # AMOUNT (%W/W)
Toluene 108-88-3 <5%
Zinc Oxide 1314-13-2 <2%
Benzene 71-43-2 <1%
15. OTHER INFORMATION
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) RATINGS:
Health = 3 Flammability = 4 Reactivity = 0
MEDICAL EMERGENCIES: FOR ANY OTHER INFORMATION:
Call CHEMTREC 24 hours a KEX TIRE REPAIR
Day for emergency information 119 ROCKLAND AVENUE
800-424-9300 NORTHVALE, NJ 07647
888-395-1539
NOTICE: KEX TIRE REPAIR believes that the information contained on this material safety
data sheet is accurate. The suggested procedures are based on experience as of the date of
publication. They are not necessarily all-inclusive or fully adequate in every circumstance. Also,
the suggestions should not be confused with nor followed in violation of applicable laws,
regulations, rules or insurance requirements.
NO WARRANTY IS MADE, EXPRESS OR IMPLIED, OF MERCHANTABILITY,
FITNESS FOR A PARTICULAR PURPOSE OR OTHERHWISE.
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