LOCTITE CORPORATION 09/11/96
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 01 of 07
82191 PX SUPRGL GEL 2 GR TB/CG
82191
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: 82191 PX SUPRGL GEL 2 GR TB/CG
Item No.: 82191
Part No.: 82191
Product Type: Cyanoacrylate ester
2. COMPOSITION, INFORMATION ON INGREDIENTS
Ingredients CAS No. %
Ethyl cyanoacrylate 7085-85-0 85-90
Poly (methyl methacrylate) 9011-14-7 5-10
SILICA, AMORPHOUS TREATED 112945-52-5 5-10
HYDROQUINONE 123-31-9 0.1-0.5
Ingredients which have exposure limits
Exposure Limits (TWA) ACGIH OSHA OTHER
Ingredients (TLV) (PEL)
Ethyl cyanoacrylate None None 2 ppm TWA
9.1 mg/m3
SILICA, AMORPHOUS TREATED 10 mg/m3 TWA 6 mg/m3 TWA 3 mg/m3 TWA
resp. dust
HYDROQUINONE 2 mg/m3 TWA 2 mg/m3 TWA 2 mg/m3 TWA
4 mg/m3 STEL
Exposure Limits (STEL) ACGIH OSHA
Ingredients (TLV) (PEL)
Ethyl cyanoacrylate (4 ppm) (4 ppm)
(18 mg/m3) (16 mg/m3)
3. HAZARDS IDENTIFICATION
Toxicity: Skin contact may cause burns.
Bonds skin rapidly and strongly.
Skin and eye irritant.
Estimated oral LD50 more than 5000 mg per kg.
Estimated dermal LD50 more than 2000 mg per kg.
Primary Routes of Entry: None known
Signs and symptoms
of Exposure: Vapor is irritating to eyes and mucous membranes
above TLV. Prolonged and repeated overexposure to
vapors may produce symptoms of non-allergic
asthma in sensitive individuals.
LOCTITE CORPORATION 09/11/96
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 02 of 07
Product Name: 82191 PX SUPRGL GEL 2 GR TB/CG
Item No.: 82191
3. HAZARDS IDENTIFICATION (continued)
Existing Conditions
Aggravated by Exposure: None known
Literature Referenced Carcinogen
Ingredients Target Organ and Other Health Effects NTP IARC OSHA
Ethyl cyanoacrylate ALG IRR RES NO NO NO
Poly (methyl methacrylate) IRR NO N/A NO
SILICA, AMORPHOUS TREATED NUI NO N/A NO
HYDROQUINONE BLO BNM CNS EYE IMM IRR MUT SKI NO N/A NO
-------------------------------------------------------------------------------
Abbreviations
N/A Not Applicable ALG Allergen
BLO Blood BNM Bone Marrow
CNS Central nervous system EYE Eyes
IMM Immune system IRR Irritant
MUT Mutagen NUI Nuisance dust
RES Respiratory SKI Skin
4. FIRST AID MEASURES
Ingestion: Ingestion is not likely. See supplemental page for
emergency procedures.
Inhalation: Remove to fresh air. If symptoms persist,
obtain medical attention.
Skin Contact: Soak in warm water. See supplemental page for
emergency procedures.
Eye Contact: Flush with water. See supplemental page for
emergency procedures.
5. FIRE FIGHTING MEASURES
Flash Point: 150 - 200掳F Method: Tag Closed Cup
Recommended
Extinguishing Agents: Carbon dioxide, foam, dry chemical
Hazardous Products formed
by Fire or Thermal Decomp Irritating organic vapors
Unusual Fire or
Explosion Hazards: None
Explosive Limits:
(% by volume in air)Lower Not available
(% by volume in air)Upper Not available
LOCTITE CORPORATION 09/11/96
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 03 of 07
Product Name: 82191 PX SUPRGL GEL 2 GR TB/CG
Item No.: 82191
6. ACCIDENTAL RELEASE MEASURES
Steps to be taken in case
of spill or leak: Flood with water to polymerize. Soak up with an
inert absorbent.
7. HANDLING AND STORAGE
Safe Storage: Store at or below 75 deg. F
(Contact Loctite Customer Service 1-800-243-4874 for shelf Life information)
Handling: Avoid contact with skin and eyes. Avoid breathing
vapor.
8. EXPOSURE CONTROLS, PERSONAL PROTECTION
Eyes: Safety glasses or goggles.
Skin: Nitrile or polyethylene gloves and aprons.
Do not use cotton.
See supplemental page for additional information.
Ventilation: Positive down-draft exhaust ventilation should be
provided to maintain vapor concentration below TLV
See Section 2 for Exposure Limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Water white gel
Odor: Sharp, irritating
Boiling Point: More than 300掳F
pH: Does not apply
Solubility in Water: Polymerized by water
Specific Gravity 1.05
Volatile Organic Compound
(EPA Method 24) 85.4%; 897 grams per liter
Vapor Pressure: Less than 0.2 mm
Vapor Density: Approximately 3
Evaporation Rate
(Ether = 1) Not available
10. STABILITY AND REACTIVITY
Stability: Stable
Hazardous Polymerization: Will not occur
Incompatibility: Polymerized by contact with water, alcohols,
amines, alkalies.
Hazardous Decomposition
Products (non-thermal): None
LOCTITE CORPORATION 09/11/96
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 04 of 07
Product Name: 82191 PX SUPRGL GEL 2 GR TB/CG
Item No.: 82191
11. TOXICOLOGICAL INFORMATION
See Section 3.
12. ECOLOGICAL INFORMATION
No data available
13. DISPOSAL CONSIDERATIONS
Recommended methods of
disposal: Polymerize as above. Incinerate following EPA
and local regulations.
EPA Hazardous Waste
Number NH - Not a RCRA Hazardous Waste Material
14. TRANSPORT INFORMATION
DOT (49 CFR 172)
Domestic Ground Transport
Proper Shipping Name: Unrestricted (Not more than 450 liters);
Combustible liquids, n.o.s. (Cyanoacrylate ester)
(More than 450 liters)
Hazard Class or
Division: Unrestricted (Not more than 450 liters)
Combustible liquid (More than 450 liters)
Identification Number: None (Not more than 450 liters);
NA 1993 (More than 450 liters)
Marine Pollutant: None
IATA
Proper Shipping Name: Unrestricted (Not more than one pint);
Other regulated substances (More than one pint)
Class or Division: Unrestricted (Not more than one pint);
Class 9 (More than one pint)
UN or ID Number: None (Not more than one pint)
ID 8027 (More than one pint)
15. REGULATORY INFORMATION
CA Proposition 65: No Prop65 chemicals are known to be present.
16. OTHER INFORMATION
Estimated NFPA(R) Code:
Health Hazard: 2
Fire Hazard: 2
Reactivity Hazard: 2
Specific Hazard: No water
Estimated HMIS(R) Code:
LOCTITE CORPORATION 09/11/96
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 05 of 07
Product Name: 82191 PX SUPRGL GEL 2 GR TB/CG
Item No.: 82191
16. OTHER INFORMATION (continued)
Health Hazard: 2
Flammability Hazard: 2
Reactivity Hazards: 2
Personal Protection: See Section 8.
NFPA is a registered trademark of the National Fire Protection Assn.
HMIS is a registered trademark of the National Paint and Coatings Assn.
Prepared By: Stephen Repetto
Title: Research Chemist, Environmental Health & Safety
Company: Loctite Corp., 1001 Tr Br Cr, Rocky Hill CT 06067
(24hr.) Phone: (860) 571-5100
Revision Date: January 22, 1996 Revision: 0028
LOCTITE CORPORATION 09/11/96
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 06 of 07
Product Name: 82191 PX SUPRGL GEL 2 GR TB/CG
Item No.: 82191
Supplement
INFORMATION FOR FIRST AID AND CASUALTY ON TREATMENT FOR ADHESION OF
HUMAN SKIN TO ITSELF IF CAUSED BY CYANOACRYLATE ADHESIVES
Cyanoacrylate adhesive is a very fast setting and strong adhesive. It
bonds human tissue including skin in seconds. Experience has shown
that accidents due to cyanoacrylates are handled best by passive,
nonsurgical first aid. Treatment of specific types of accidents are
given below.
SKIN CONTACT
Remove excess adhesive. Soak in warm, soapy water. The adhesive will
come loose from the skin in several hours. Cured adhesive does not
present a health hazard even when bonded to the skin.
Avoid contact with clothes, fabrics, rags, or tissue. Contact with
these materials may cause polymerization. The polymerization of large
amounts of adhesive will generate heat causing smoke, skin burns,
and strong, irritating vapors. Wear nitrile or polyethylene gloves and
apron when handling large amounts of adhesive.
SKIN ADHESION
First immerse the bonded surfaces in warm, soapy water. Peel or roll
the surfaces apart with the aid of a blunt edge, e.g. a spatula or a
teaspoon handle; then remove adhesive from the skin with soap and
water. Do not try to pull surfaces apart with a direct opposing
action.
EYELID TO EYELID OR EYEBALL ADHESION
In the event that eyelids are stuck together or bonded to the eyeball,
wash thoroughly with warm water and apply a gauze patch. The eye will
open without further action, typically in 1-4 days. There will be no
residual damage. Do not try to open the eyes by manipulation.
ADHESIVE ON THE EYEBALL
Cyanoacrylate introduced into the eyes will attach itself to the
eye protein and will disassociate from it over intermittent periods,
generally covering several hours. This will cause periods of weeping
until clearance is achieved. During the period of contamination,
double vision may be experienced together with a lachrymatory effect,
and it is important to understand the cause and realize that
disassociation will normally occur within a matter of hours, even with
gross contamination.
MOUTH
If lips are accidentally stuck together, apply lots of warm water to
the lips and encourage maximum wetting and pressure from saliva inside
the mouth. Peel or roll lips apart. Do not try to pull the lips
LOCTITE CORPORATION 09/11/96
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 07 of 07
Product Name: 82191 PX SUPRGL GEL 2 GR TB/CG
Item No.: 82191
Supplement
with direct opposing action.
It is almost impossible to swallow cyanoacrylate. The adhesive
solidifies and adheres in the mouth. Saliva will lift the adhesive in
one half to two days. In case a lump forms in the mouth, position the
patient to prevent ingestion of the lump when it detaches.
BURNS
Cyanoacrylates give off heat on solidification. In rare cases a large
drop will increase in temperature enough to cause a burn.
Burns should be treated normally after the lump of cyanoacrylate is
released from the tissue as described above.
SURGERY
It should never be necessary to use such a drastic method to separate
accidentally bonded skin.
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