SUPERCOOL AEROSOL LEAK STOP
MATERIAL SAFETY DATA SHEET
Emergency Phone Number: 561-582-2245 Date: February 7, 2002
SECTION 1 COMPANY IDENTIFICATION AND CHEMICAL PRODUCT
Company Name: TSI, Inc.
Address: 932 South Dixie Highway, Lake Worth, Florida 33460
Phone/Fax: 561-582-2245 / 561-582-1499
Trade Name: Supercool Leak Stop
Chemical Name: R134A & Synthetic Esters
Chemical Family: R134A & Synthetic Esters
Formula: NA Mixture
CAS#: NA Mixture
Applications: Supercool Leak Stop is used to seal leaks in AC seals.
SECTION 2 HAZARDOUS INGREDIENTS
Ingredient: OSHA PEL / ACGIH TLV: CAS Number: Percent:
1,1,1,2-Tetrafluoroethane 1000PPM : TWA 811-97-2 50%
Synthetic Esters (POE) Non-Hazardous NA 50%
SECTION 3 Physical Characteristics
Appearance: Clear liquid & gas, yellow/green tint.
SECTION 4 FIRST AID MEASURES
Eyes: Flush with clean, lukewarm water (low pressure) occasionally lifting eyelids. Have
eyes examined and treated by medical personnel. R134A liquid splashes or
vapor may cause freeze burns.
Skin: R134A in the liquid form in this product may cause freeze burns (Frostbite-like
lesions). Thaw affected area with warm water. Remove oil from skin by washing
affected areas thoroughly with soap and water. Wash contaminated clothing
before reuse. If symptoms (irritations or blistering) develop, get medical attention.
Inhalation: Exposure to very high vapor concentrations can induce anesthetic effects
progressing from dizziness, weakness, nausea, to unconsciousness. It can act
as an asphyxiant by limiting available oxygen, at very high doses, cardiac
sensitization to the circulating epinephrine-like compounds can result in fatal
cardiac arrhythmias. Avoid breathing oil mists. Remove victim to fresh air. Give
artificial respiration if not breathing. Oxygen may be given by qualified personnel
if breathing is difficult. In the event of cardiac arrest, apply external cardiac
massage. Do not administer adrenaline or similar sympathomimetic drugs as
cardiac arrhythmias may result. Get immediate medical attention.
Ingestion: Do not induce vomiting. Force fluids. Has laxative effect. R134A liquid mixed with
lubricant most unlikely to ingest.
SECTION 5 FIRE FIGHTING MEASURES
Flash Point: 425 潞F min
Flammable Limits: N/A
Auto Ignition Temp: N/A
Fire & Explosion Hazards: LOW FIRE HAZARD - Do not cut, drill, or weld empty containers.
Extinguishing Media: Dry chemical foam, water spray, carbon dioxide for small fires.
Fire Fighting Procedures: Contain liquid, cover with extinguishing agent, use water spray to cool fire
exposed containers and as protective screen. Do not point solid water stream
directly into burning fluid to avoid spreading.
SECTION 6 ACCIDENTAL RELEASE MEASURES
Spill or Leak: Contain Spill, absorb with inert absorbent such as dry clay, sand, diatomaceous
earth, commercial sorbents or recover using pumps. Scoop up used absorbents
into approved receptacles.
Waste Disposal: Dispose in approved, secure landfill site or through a licensed waste reclaimer.
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SECTION 7 HANDLING AND STORAGE
Storage Temp - min / max: None / 104潞F recommended
Shelf Life: Indefinite in original container
Precautions: Not for internal use. Avoid contact with skin, eyes, clothing.
SECTION 8 EXPOSURE CONTROL / PERSONAL PROTECTION
Eye Protection: Chemical Goggles if splashing is likely or high pressure systems are used.
Skin Protection: PVC or Nitrile gloves are recommended if prolonged contact with skin is to occur.
Respiratory Protection: Normally not necessary. If mist is generated, wear approved organic respirator
suitable for oil mist areas with sufficient oxygen.
Ventilation: General ventilation.
Exposure Limits: Acute LD50 > 5000 mg/Kg (rat : oral)
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Clear liquid & gas, yellow/green tint.
Boiling Point: -40潞F (R134A), >570潞F Synthetic Esters
Vapor Pressure: 79 PSIG @ 25潞C (R134A), <0.001 kPa @ 25潞C
Specific Gravity: 0.85-.097 Synthetic Esters
Volatiles, % Volume: 0%
Odor: Very Slight hydrocarbon odor
Solubility in Water: Negligible
Evaporation Rate: Nil
Viscosity: @40潞C Varies depending on grade
SECTION 10 REACTIVITY
Stability: Product is STABLE
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizers.
Decomposition Products: R134A 鈥? Highly Toxic decomposition products occur when burned. Lubricant --
Analogous compounds evolve, carbon monoxide, carbon dioxide, and other
undefined fragments when burned.
SECTION 11 TOXICOLOGICAL INFORMATION
General: Acute LD50 > 2000 mg/Kg (rat : oral)
SECTION 12 ECOLOGICAL INFORMATION
General: Biodegradable CEC L33A93 > 80% @ 45 Days.
SECTION 13 DISPOSAL CONSIDERATIONS
Waste Disposal: Used product must be disposed of in accordance with Federal, State, and Local
environmental control regulations. Incineration is preferred. DO NOT HEAT OR
CUT EMPTY CONTAINERS WITH ELECTRIC OR GAS TORCH.
SECTION 14 TRANSPORTATION INFORMATION
DOT Ship Name: 1,1,1,2-Tetrafluoroethane & Synthetic Esters Mix
D.O.T. Hazard Class: 2.2
U.N. / N.A. #: UN3159
Product Label: Supercool Leak Stop Aerosol
SECTION 15 REGULATORY INFORMATION
OSHA STATUS: Non-Hazardous under 29 CFR 1910.1200
TSCA STATUS: N/A
RCRA STATUS: If discarded in its purchased form this product would not be a hazardous waste
either by listing or characteristic. However, it is the responsibility of the product
user to determine at the time of disposal, whether the material being disposed of
is a hazardous waste (40 CFR 261.20-24).
SECTION 16 OTHER INFORMATION
General: This information is furnished without warranty, expressed or implied, except that
is accurate to the best knowledge of TSI, Inc. The data on this sheet related only
to the specific material designed herein. TSI, Inc. assumes no legal responsibility
for the use or reliance upon these data.
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