Sartomer Company, Inc.
MATERIAL SAFETY DATA SHEET
Product Name: Ricobond 1756HS
MSDS ID #: 1756HS
Section I - GENERAL
Manufacturer:
Sartomer Company, Inc.
Oaklands Corporate Center
502 Thomas Jones Way
Exton, Pennsylvania 19341
Emergency Phone Numbers
1-800-424-9300 (CHEMTREC)
610-692-8401
Product Information
610-363-4100
Product Identification
Ricobond庐 1756HS
Tradename:
CAS#: 25655-35-0
CAS# Hydrated
Amorphous Silica: 007631-86-9
Chemical Name &
Synonyms: Polybutadiene adducted with maleic anhydride dispersed on hydrated amorphous silica
Chemical Family: Aliphatic Polyanhydride
Formula: Complex Polymeric
DOT Hazardous Materials Proper Shipping Name: Not Regulated
DOT Hazard Class: Not Regulated
SECTION II SUMMARY OF HAZARDS
HMIS: Health 1 Flammability 1 Activity 1 Other None
Physical Hazards: Slightly combustible powder
Acute Health Effects: Inhalation respiratory irritant
(short term) Skin may be slight skin irritant
Ingestion hazard may be slight ingestion hazard
Eye irritant no data, mild eye irritant
Crystalline Silica has been determined to be a suspected carcinogen. No Crystalline Silica has
been detected in this product. Detection limit <0.01% by weight.
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Chronic Health Effects: No chronic hazards have been observed
(long term)
This product is NOT listed under: National Toxicology Program (NTP) Annual Report on Carcinogens
International Agency for Research on Cancer (IARC) Monographs.
Regulatory Information:
TSCA: All ingredients of this product appear on the TSCA inventory.
SARA Title III-Section 313: This product does not contain a toxic chemical in excess of 1% of the mixture (.1% if a listed
carcinogen).
International Status
Australia (AICS): included on inventory
Canada (DSL): included on inventory
China (CECS): included on inventory
Europe (EINECS): not included on inventory
Japan (ENCS): included on inventory
Korea (ECL): included on inventory
Philippines (PICCS): included on inventory
SECTION III PHYSICAL AND CHEMICAL DATA
Boiling Point ( F): No defined boiling point decomposes above 475 by polymerization. Cracks into
(long term) gaseous and liquid products above 800 .
Vapor Pressure: Very low
Vapor Density: Not determined
Solubility in Water: Nil
Appearance and Odor: Light gray powder, mild hydrocarbon odor.
Specific Gravity (H2O): > 1.0
% Volatile by Volume: < 3.0
Evaporation Rate: Not determined
Freezing Point: Not determined
Conditions to Avoid: Oxidizing conditions, extreme temperatures
Materials to Avoid: Strong oxidizers, strong acids
SECTION IV FIRE AND EXPLOSION HAZARD DATA
Flash Point: > 250 F (COC)
Extinguishing Media: Foam or water spray, CO2, dry chemical, water
Special Fire Fighting
Procedures: Keep drums cool with water from hose.
Unusual Fire & Explosion
Hazards: Will tend to polymerize thermally at temperatures above 400 F (200 C). Once initiated,
the reaction generates sufficient heat to continue spontaneously. Heat from fire can
generate flammable vapors. Such fires are very smoky. Closed drums can rupture in a
fire causing flame to spread, increasing risk of burns. Personal contact with hot liquid
after a fire can cause severe burns due to high temperature. Notify authorities if liquid
enters sewer or public waters.
SECTION V HEALTH HAZARDS
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Summary of Acute Hazards: Slight health hazards see below for route-specific details.
ROUTE OF EXPOSURE SIGNS AND SYMPTOMS
Inhalation: Excessive contact with powder can cause drying of mucous membranes of nose and
throat due to absorption of water and oil.
Eye Contact: May cause eye irritation.
Skin Contact: May produce skin irritation.
Ingestion: No significant signs or symptoms indicative of any adverse health hazards are expected
to occur as a result of ingestion.
Summary of Chronic
Hazards: No chronic health hazards have been found to be associated with this material.
Special Health Effects: No additional medical information found.
SECTION VI REACTIVITY DATA
Stability: Stable
Condition to Avoid: Keep away from excessive heat, avoid long exposure above 190 F.
Incompatibility: Incompatible with peroxides and many reactive materials.
Hazardous Decomposition
Products: Small quantities of butadiene and maleic anhydride, along with other lower molecular
weight hydrocarbons.
Hazardous Polymerization: May occur when heated above 400 F
SECTION VII PROECTIVE EQUIPMENT AND OTHER CONTROL MEASURES
Respiratory: Dust respirator and local exhaust are recommended
Eye: Eye protection such as chemical splash goggles and/or face shield should be used
due to particles. Contact lenses should not be worn.
Skin: Depending on the conditions of use, gloves, apron, boots, head and face protection is
recommended. Equipment should be cleaned thoroughly after each use.
Engineering Controls: Local exhaust ventilation and dust control may be needed under anticipated conditions
of normal use.
Other Hygienic and
Work Practices: Use good personal hygiene practices. Wash hands before eating, drinking, smoking,
or using toilet facilities. Promptly remove soiled clothing/wash thoroughly before
reuse. Shower after work using plenty of soap and water. No special work practices
are needed beyond the above recommended actions under anticipated condition of
normal use.
SECTION VIII OCCUPATIONAL EXPOSURE LIMITS
6mg/cuM OSHA 8 hr TWA for Silica
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SECTION IX EMERGENCY AND FIRST AID
Inhalation: If symptoms of discomfort of irritation occur due to this product, remove affected
person to fresh air. If irritation or discomfort persists, consult a physician.
Eye Contact: In case of eye contact, immediately rinse with clean water for 20-30 minutes. Retract
eyelids often. Obtain emergency medical attention if pain, blinking, tears or redness
persists.
Skin Contact: Remove contaminated clothing as needed. Wash skin thoroughly with mild
soap/water. Flush with lukewarm water for 15 minutes. Wipe off resin with dry or oily
rag. Baby oil will remove stickiness, as will waterless cleaner.
Ingestion: Not expected to present a significant ingestion hazard under anticipated conditions of
normal use.
Emergency Medical
Treatment Procedures: After adequate first aid, no further treatment is required unless symptoms reappear.
Treat symptomatically.
SECTION X SPILL AND DISPOSAL
Precautions if Material is
Spilled or Released: Stop release. Sweep into appropriate containers. On water, material may float or
sink, may biodegrade. Contain/minimize dispersion/collect. Disperse residue to
reduce aquatic harm. Report per Reg. Requirements.
Waste Disposal Methods: Landfill solids at permitted sites after appropriate test demonstrating material meets
treatment standards. Use registered transporters. May be incinerated at approved
incinerators. Follow all local, state and Federal regulations when disposing.
SECTION XI COMPONENTS
(This may not be a complete list of components.)
CAS # COMPOSITION AMT #
Polybutadiene adducted
with maleic anhydride: 25655-35-0 65-70%
Hydrated Amorphous Silica: 007631-86-9 30-35%
SECTION XII ADDITIONAL PRECAUTIONS
Handling, Storage & Decon-
tamination Procedures: Store away from heat, sparks, open flames and strong oxidizing agents. Avoid
overheating which may adversely affect quality or overpressure container(s). Follow
standard plant decontamination operations.
General Comments: Some of the information presented and conclusions drawn herein are from sources
other than direct test data on the product itself.
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DISCLAIMER OF LIABILITY
The information in this MSDS was obtained from sources which we believe are reliable. HOWEVER, THE
INFORMATION IS PROVIDED WITHOUT ANY WARRANTY, EXPRESSED OR IMPLIED, REGARDING ITS
CORRECTNESS.
The conditions or methods of handling, storage, use and disposal of the product are beyond our control and may be
beyond our knowledge. FOR THIS AND OTHER REASONS, WE DO NOT ASSUME RESPONSIBILITY AND
EXPRESSLY DISCLAIM LIABILITY FOR LOSS, DAMAGE OR EXPENSE ARISING OUT OF, OR IN ANY WAY
CONNECTED WITH THE HANDLING, STORAGE, USE OR DISPOSAL OF THE PRODUCT.
Create Date: 2000-12-10 16:43:31
Revision Date: 2005-01-18 09:32:14
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