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MSDS Material Safety Data Sheet
CAS

2173-38-3
2173-38-7
2133-51-4
24579-73-5
15845-66-6

File Name: bayercropscience_com_tr---previcur_energy.asp
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC


PREVICUR ENERGY SL840 20X300ML BOT TR 1/6
Version 1 / EU Revision Date: 27.07.2006
102000004473 Print Date: 15.05.2007


1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING

Product information
Trade name PREVICUR ENERGY SL840 20X300ML BOT TR
Product code (UVP) 06396712
Usage fungicide
Company Bayer CropScience AG
Alfred-Nobel-Stra脽e 50
40789 Monheim
Germany

Telephone +49(0)2173-38-3373
Telefax +49(0)2173-38-7394
Responsible Department Material and Transport Safety Management
+49(0)2173-38-3409/4566

Emergency telephone number +49(0)2133-51-4233 (Sicherheitszentrale Dormagen, Bayer AG)

2. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical nature
Soluble concentrate (SL)
75% Propamocarb-Fosetylate 840 g/l, adequate: 530 g/l Propamocarb (CAS-No. 24579-73-5) and
310 g/l Fosetyl (CAS-No. 15845-66-6)


3. HAZARDS IDENTIFICATION

Risk advice to man and the environment
May cause sensitization by skin contact.


4. FIRST AID MEASURES
General advice
Remove contaminated clothing immediately and dispose of safely.
Inhalation
If symptoms persist, call a physician. Move to fresh air.
Skin contact
Wash off with soap and water. If symptoms persist, call a physician.
Eye contact
In case of eye contact, remove contact lens and rinse immediately with plenty of water, also under
the eyelids, for at least 15 minutes. Get medical attention if irritation develops and persists.
Ingestion
When swallowed accidentally, do not induce vomiting, get medical help. Rinse out mouth and give
water in small sips to drink. Ingest activated charcoal.
Notes to Physician
Symptoms
The following symptoms may occur:, lethargy, ataxia, spasm, Local:, sensitising effects
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC


PREVICUR ENERGY SL840 20X300ML BOT TR 2/6
Version 1 / EU Revision Date: 27.07.2006
102000004473 Print Date: 15.05.2007

Risks
This product, although being a carbamate, is NOT a cholinesterase inhibitor.
Treatment
Treat symptomatically.


5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
Product itself is non-combustible; fire extinguishing measures to suit surroundings.
Special protective equipment for fire-fighters
In the event of fire, wear self-contained breathing apparatus.
Wear full protective suit.
Further information
Cool endangered containers with water spray jet.


6. ACCIDENTAL RELEASE MEASURES
Personal Precautions
Use personal protective equipment.
Environmental Precautions
Do not discharge into the drains/surface water/groundwater.
If the product contaminates rivers and lakes or drains inform respective authorities.
Methods for Cleaning Up
Take up with absorbent material (e.g. sand, diatomaceous earth or a proprietary absorbent
material).
Keep in suitable, closed containers for disposal.
Additional Advice
Information regarding personal protective equipment, see section 8.
Information regarding waste disposal, see section 13.


7. HANDLING AND STORAGE
Handling
Advice on safe handling
Keep container tightly closed.
Avoid subsoil penetration.
Advice on protection against fire and explosion
No special precautions required.

Storage
Requirements for storage areas and containers
Store in original container.
Keep away from direct sunlight.
Advice on common storage
Keep away from food, drink and animal feedingstuffs.
Storage stability
Storage period 24 Months
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC


PREVICUR ENERGY SL840 20X300ML BOT TR 3/6
Version 1 / EU Revision Date: 27.07.2006
102000004473 Print Date: 15.05.2007

Storage temperature < 28 掳C
Other data Stable under recommended storage conditions. Storage
temperature should ideally lie between 0 and 30 掳C, however,
storage for two weeks at 54 掳C has shown no adverse effects
regarding product safety or stability.
Suitable materials
HDPE (high density polyethylene)


8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering measures
See section 7; no measures exceeding those mentioned are necessary.

Personal protective equipment
Respiratory Protection No personal respiratory protective equipment normally required.
Respiratory protection should only be used to control residual risk of
short duration activities, when all reasonably practicable steps have
been taken to reduce exposure at source e.g. containment and/or
local extract ventilation. Always follow respirator manufacturer's
instructions regarding wearing and maintenance.

Hand Protection Wear CE Marked (or equivalent) nitrile rubber gloves (minimum
thickness 0,40 mm). Wash when contaminated. Dispose of when
contaminated inside, when perforated or when contamination outside
cannot be removed. Wash hands always before eating, drinking,
smoking or using the toilet.

Eye protection Wear goggles conforming to EN166 (Field of Use 5 or equivalent).

Skin and body protection Wear standard coverall and type 3 suit.
Wear two layers of clothing wherever possible. Polyester/cotton or
cotton overalls should be worn under chemical protection suit and
should be professionally laundered frequently.
AGRICULTURAL USES:
Applicators and other handlers must wear:
lightweight protective clothing
rubber apron
rubber gloves
Rubber or plastic boots.

Hygiene measures
Keep away from food, drink and animal feedingstuffs.
Avoid contact with the skin and the eyes.
Remove soiled and/or soaked clothing immediately and clean thoroughly before using again.
After worktime and during work intervals the affected skin areas must be thoroughly cleaned.


9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance
Form liquid
Colour colourless to yellowish
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC


PREVICUR ENERGY SL840 20X300ML BOT TR 4/6
Version 1 / EU Revision Date: 27.07.2006
102000004473 Print Date: 15.05.2007

Odour odourless
Safety data
pH 6 - 7,5 at 100 % (20 掳C)

Boiling point/ range from 100 掳C

Flash point > 120 掳C at 1.013 hPa
DIN EN ISO 2719 (2003-09)

Ignition temperature 300 掳C

Density ca. 1,121 g/cm鲁 at 20 掳C

Water solubility completely miscible

Viscosity, kinematic 36,9 mm2/s at 40 掳C

Surface tension 59 mN/m at 20 掳C

Explosivity Not explosive
92/69/EEC, A.14 / OECD 113



10. STABILITY AND REACTIVITY
Thermal decomposition No decomposition if used as directed.

Hazardous Reactions No hazardous reactions when stored and handled according to
prescribed instructions.



11. TOXICOLOGICAL INFORMATION
Acute Oral Toxicity LD50 (rat) > 2.000 mg/kg

Acute Dermal Toxicity LD50 (rat) > 2.000 mg/kg

Skin Irritation No skin irritation. (rabbit)

Eye Irritation Slight irritant effect - does not require labelling. (rabbit)

Sensitization Non-sensitizing. (guinea pig)
OECD Test Guideline 406, Buehler test

Sensitization sensitizing (mouse)
OECD Test Guideline 429, local lymph node assay (LLNA)
May cause sensitisation by skin contact.



12. ECOLOGICAL INFORMATION

Ecotoxicity effects
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC


PREVICUR ENERGY SL840 20X300ML BOT TR 5/6
Version 1 / EU Revision Date: 27.07.2006
102000004473 Print Date: 15.05.2007

Toxicity to Fish LC50 (Rainbow trout (Oncorhynchus mykiss)) > 98 mg/l
Exposure time: 96 h

Toxicity to daphnia EC50 (Water flea (Daphnia magna)) > 97 mg/l
Exposure time: 48 h

Toxicity to algae EC50 (Pseudokirchneriella subcapitata) > 97 mg/l
Exposure time: 72 h

Toxicity to algae NOEC (Pseudokirchneriella subcapitata) 2,2 mg/l



13. DISPOSAL CONSIDERATIONS
Product
Must not be disposed of together with household garbage. Do not allow product to reach sewage
system.
Dispose of as hazardous waste.
Contaminated packaging
Do not use containers for other products.
Dispose of as unused product.
Waste key for the unused product
020108 agrochemical waste containing dangerous substances


14. TRANSPORT INFORMATION

Not dangerous goods
ADNR
Not dangerous goods
ADR
Not dangerous goods
GGVE
Not dangerous goods
GGVS
Not dangerous goods
IATA_C
Not dangerous goods
IATA_P
Not dangerous goods
IMDG
Not dangerous goods
RID


15. REGULATORY INFORMATION
Classification and labelling in accordance with the EC Directive on dangerous preparations
1999/45/EC as amended.
Classification:
Hazard warning labelling compulsory

Symbol(s)
Xi Irritant
R-phrase(s)
R43 May cause sensitization by skin contact.
S-phrase(s)
S24 Avoid contact with skin.
S37 Wear suitable gloves.
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC


PREVICUR ENERGY SL840 20X300ML BOT TR 6/6
Version 1 / EU Revision Date: 27.07.2006
102000004473 Print Date: 15.05.2007

Exceptional labelling
To avoid risks to man and the environment, comply with the instructions for use.
Further information
WHO-classification: III (Slightly hazardous)


16. OTHER INFORMATION

Further information

The information given in this Data Sheet has been included in accordance with the guidelines
established by EC Directive 1991/155/EC as amended. This data sheet complements the user's
instructions, but does not replace them. The information it contains is based on the knowledge
available about the product concerned at the time it was compiled. Users are further reminded of the
possible risks of using a product for purposes other than those for which it was intended. The required
information complies with current EEC legislation. Addressees are requested to observe any
additional national requirements.
Changes since the last version are highlighted in the margin. This version replaces all previous versions.

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