MATERIAL SAFETY DATA SHEET
Sikaflex Primer 429/202
HMIS
HEALTH *3
FLAMMABILITY 3
REACTIVITY 0
H
PERSONAL PROTECTION
1. Product And Company Identification
Supplier Manufacturer
Sika Corporation Sika Corporation
201 Polito Ave 201 Polito Ave
Lyndhurst, NJ 07071 Lyndhurst, NJ 07071
Company Contact: EHS Department Company Contact: EHS Department
Telephone Number: 201-933-8800 Telephone Number: 201-933-8800
FAX Number: 201-933-9379 FAX Number: 201-933-9379
Web Site: www.sikausa.com Web Site: www.sikausa.com
Supplier Emergency Contacts & Phone Number Manufacturer Emergency Contacts & Phone Number
CHEMTREC: 800-424-9300 CHEMTREC: 800-424-9300
INTERNATIONAL: 703-527-3887 INTERNATIONAL: 703-527-3887
Issue Date: 04/18/2005
Product Name: Sikaflex Primer 429/202
CAS Number: Not Established
Chemical Family: Polyurethane
MSDS Number: 3582
Product Code: 0429540
2. Composition/Information On Ingredients
Ingredient CAS Percent Of
Name Number Total Weight
AROMATIC POLYISOCYANATE Not Establis
PROPYLENE GLYCOL MONOMETHYL ETHER ACETATE 108-65-6
TOLUENE DIISOCYANATE (MIXED ISOMERS) 26471-62-5 <= 0.5
XYLENE (MIXED ISOMERS) 1330-20-7 20 - 30
3. Hazards Identification
Eye Hazards
LIQUID, AEROSOLS OR VAPORS ARE SEVERELY IRRITATING AND CAN CAUSE PAIN, TEARING,
REDDENING AND SWELLING. IF LEFT UNTREATED, CORNEAL DAMAGE CAN OCCUR AND INJURY IS
SLOW TO HEAL. HOWEVE, DAMAGE IS USUALLY REVERSIBLE.
Skin Hazards
MAY CAUSE A REVERSIBLE INFLAMMATORY EFFECT ON SKIN OR TISSUE AT THE SITE OF CONTACT.
CAUSES AN ALLERGIC SENSITIZATION IN A SUBSTANTIAL PROPORTION OF HUMANS OR ANIMALS IN
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3. Hazards Identification - Continued
Skin Hazards - Continued
NORMAL TISSUE AFTER REPEATED EXPOSURES. MAY CAUSE DERMATITIS(SKIN REDNESS, DRYNESS,
SCALING, ETC) FROM REPEATED OR PROLONGED CONTACT.
Ingestion Hazards
MAY CAUSE EFFECTS TO THE GI TRACT, USUALLY RESULTING FROM INGESTION OF THE MATERIALS,
SUCH AS IRRITATION, NAUSEA, GI DISORDERS, ULCERATION, DIARRHEA OR CONSTIPATION.
VOMITING MAY CAUSE ASPIRATION RESULTING IN CHEMICAL PNEUMONITIS.
Inhalation Hazards
MAY CAUSE EFFECTS ON MUCOUS MEMBRANE TISSUE, SUCH AS INFLAMMATION, IRRITATION,
HYPERPLASIA OR CHANGE IN CILIARY ACTIVITY.CAUSES AN ALLERGIC SENSITIZATIONIN A
SUBSTANTIAL PROPORTION OF HUMANS OR ANIMALS IN NORMAL TISSUE AFTER REPE ATED
EXPOSURES. MAY CAUSE A REVERSIBLE INFLAMMATORY EFFECT ON THE UPPER RESPIRATORY
SYSTEM. MAY CAUSE EFFECTS SUCH AS ANESTHETIC EFFECTS, DROWSINESS, DIZZINESS,
DECREASE IN MOTOR FUNCTIONS, CONVULSIONS, TREMORS, NARCOSIS OR BEHAVIORAL CHANGES.
4. First Aid Measures
Eye
In case of contact, hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes. Get
medical attention immediately if irritation develops and persists.
Skin
In case of contact, immediately flush skin with soap and plenty of water for at least 15 minutes. Get medical
attention immediately if irritation (redness, rash, blistering) develops and persists.
Ingestion
DO NOT INDUCE VOMITING. DILUTE WITH WATER. CONSULT PHYSICIAN.
Inhalation
REMOVE TO FRESH AIR. IF BREATHING HAS STOPPED, INSTITUTE ARTIFICIAL RESPIRATION.
ASTHMATIC-TYPE SYMPTOMS MAY DEVELOP AND MAY BE IMMEDIATE OR DELAYED UP TOSEVERAL
HOURS. CONSULT WITH PHYSICIAN.
5. Fire Fighting Measures
Flash Point: 86 掳F
Flash Point Method: ABEL-PENSKY CLOSED CUP
Autoignition Point: N/AV 掳F
Flammability Class: FLM
Lower Explosive Limit: 1.0
Upper Explosive Limit: 7.0
Fire And Explosion Hazards
IRRITATING AND/OR TOXIC GASES AND AEROSOLS FROM THE DECOMPOSITION/ COMBUSTION
PRODUCTS MAY BE PRESENT. CLOSED CONTAINER MAY EXPLODE WHEN EXPOSED TO EXTREME
HEAT OR BURST WHEN CONTAMINATED WITH WATER. SOLVENT VAPORS MAY BE HEAVIER THAN AIR.
UNDER CONDITIONS OF STAGNANT AIR, VAPORS MAY BUILD UP AND TRAVEL ALONG THE GROUND
TO AN IGNITION SOURCE WHICH MAY RESULT IN A FLASH BACK TO THESOURCE OF THE VAPORS.
Extinguishing Media
DRY CHEMICAL/CARBON DIOXIDE/WATER SPRAY. CAUTION: REACTION BETWEEN WATER AND HOT
TDI CAN BE VIGOROUS.
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5. Fire Fighting Measures - Continued
Fire Fighting Instructions
WEAR NIOSH/MSA APPROVED SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE
GEAR. NO SKIN SURFACE SHOULD BE EXPOSED.
6. Accidental Release Measures
WEAR APPROPRIATE PROTECTIVE EQUIPMENT. CONTAIN SPILL AND COLLECT WITH ABSORBENT
MATERIAL, POUR LIQUID DECONTAMINANT OVER SPILLAGE AND ALLOW TO REACT FOR AT LEAST 10
MINUTES. USE NON-SPARKING TOOLS TO SHOVEL INTO OPEN CONTAINERS ANDADD FURTHER AMOUNTS
OF DECONTAMINATION SOLUTION. REMOVE CONTAINERS TO SAFE PLACE AND COVER LOOSELY. WASH
DOWN AREA WITH LIQUID DECONTAMINANT AND FLUSH SPILL AREA WITH WATER. VENTILATE AREA.
ELIMINATE SOURCES OF IGNITION. AVOID CONTACT.
DECONTAMINATION SOLUTIONS: AMMONIUM HYDROXIDE (0-10%), DETERGENT (2-5%) AND BALANCE
WATER; OR SOLUTION OF UNION CARBIDE'S TERGITOL TMN-10 (20%) AND WATER (80%).
7. Handling And Storage
Handling And Storage Precautions
STORE IN A COOL DRY AREA AWAY FROM HEAT, SPARKS AND FLAMES. KEEP CONTAINERS TIGHTLY
CLOSED. GROUND CONTAINERS DURING STORAGE AND TRANSFER OPERATIONS. STORAGE
TEMPERATURE MIN. 32F - MAX 122F.
SPECIAL SENSITIVITY: HEAT, LIGHT, MOISTURE: IF CONTAINER IS EXPOSED TO HIGH HEAT
Work/Hygienic Practices
WASH THOROUGHLY AFTER USING PRODUCT.
8. Exposure Controls/Personal Protection
Engineering Controls
Use of a system of local and/or general exhaust is recommended to keep employee exposures below the
Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of
the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH
document, Industrial Ventilation, A Manual for Recommended Practices, most recent edition, for details. When
appropriate, use explosion-proof equipment.
Eye/Face Protection
Safety glasses with side shields or goggles.
Skin Protection
AVOID SKIN CONTACT. WEAR LONG SLEEVE SHIRT AND LONG PANTS. CHEMICAL RESISTANT RUBBER
OR PLASTIC GLOVES.
Respiratory Protection
A respirator protection program that meets 29 CFR 1910.134 requirement must be followed whenever workplace
conditions warrant a respirator's use. In areas where the Permissible Expsosure Limits are exceeded, use a
properly fitted NIOSH-approved respirator.
Other/General Protection
MEDICAL SUPERVISION OF ALL EMPLOYEES WHO HANDLE OR COME IN CONTACT WITH TDI IS
RECOMMENDED. THIS SHOULD INCLUDE PREEMPLOYMENT AND PERIODIC MEDICAL EXAMINATIONS
WITH RESPIRATORY FUNCTION TESTS.
MONITORING: TDI, POLYISOCYANATE AND SOLVENT EXPOSURE LEVELS MUST BE MONITORED BY
ACCEPTED MONITORING TECHNIQUES TOENSURE THAT THE TLVS ARE NOT EXCEEDED.
Ingredient(s) - Exposure Limits
TOLUENE DIISOCYANATE (MIXED ISOMERS)
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8. Exposure Controls/Personal Protection - Continued
Ingredient(s) - Exposure Limits - Continued
2, 4-Toluene Diisocyante (TDI) CAS # 584-84-9
OSHA CEILING: 0.02 ppm
ACGIH TLV-TWA: 0.005 ppm
ACGIH TLV-STEL: 0.02 ppm
2, 6-Toluene Diisocyante (TDI) CAS # 91-08-7
OSHA: Not Established
ACGIH: Not Established
XYLENE (MIXED ISOMERS)
OSHA TLV-TWA: 100 ppm
ACGIH TLV-TWA: 100 ppm
ACGIH TLV-STEL: 150 ppm
9. Physical And Chemical Properties
Appearance
CLEAR YELLOW LIQUID
Odor
SOLVENT ODOR
Chemical Type: Mixture
Physical State: Liquid
Melting Point: -22 掳F
Boiling Point: 280-300 掳F
Specific Gravity: 1.07
Percent VOCs: 46.0%
Packing Density: 8.9#/gal
Vapor Pressure: N/AV
Vapor Density: >AIR
Solubility: INSOLUBLE
Evaporation Rate: SLOWER THAN ETHER
VOC Content: 491.5 gram / liter
10. Stability And Reactivity
Stability: STABLE
Hazardous Polymerization: WILL NOT OCCUR
Conditions To Avoid (Stability)
NONE KNOWN
Incompatible Materials
WATER, ALCOHOLS, AMINES, STRONG BASES AND OXIDIZING MATERIALS
THIS PRODUCT CONTAINS TRIMETHYLOL PROPANE AND SHOULD NOT BE
COMBINED WITH PHOSPHORUS CONTAINING MATERIALS BECAUSE HIGHLY
TOXIC FUMES CAN BE EMITTED IN A FIRE SITUATION.
Hazardous Decomposition Products
BY FIRE: CO2, CO, OXIDES OF NITROGEN, HCN, TDI
Conditions To Avoid (Polymerization)
NONE KNOWN
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11. Toxicological Information
Miscellaneous Toxicological Information
NTP: THIS PRODUCT CONTAINS LESS THAN 0.5% TDI. BASED ON STUDY, NTP LISTS TDI AS A
SUBSTANCE THAT MAY REASONABLY BE ANTICIPATED TO BE A CARCINOGEN IN ITSFOURTH ANNUAL
REPORT ON CARCINOGENS.
IARC: IARC HAS ANNOUNCED THAT IT WILL LIST TDI AS A SUBSTANCE FOR WHICH THERE IS
SUFFICIENT EVIDENCE FOR ITS CARCINOGENICITY IN EXPERIMENTAL ANIMALS BUT INADEQUATE
EVIDENCE FOR THE CARCINOGENICY OF TDI TO HUMANS.
Conditions Aggravated By Exposure
ASTHMA TYPE CONDITIONS, CHRONIC BRONCHITIS AND OTHER CHRONIC RESPIRATORY
CONDITIONS. RECURRENT SKIN ECZEMA. PRESENSITIZATION TO PRODUCT.
MAY AFFECT THE RENAL SYSTEM,INCLUDING KIDNEY DAMAGE, EDEMA, PROTEINURIA, OR OTHER
NEPHROTOXICITY. MAY CAUSE EFFECTS TO THE HEPATIC SYSTEM, SUCH AS JAUNDICE, LIVER
ENLARGEMENT, LIVER DAMAGE, OR OTHER HEPATOXICITY.
Ingredient(s) - Carginogenicity
TOLUENE DIISOCYANATE (MIXED ISOMERS)
Listed In The IARC Monographs
12. Ecological Information
No Data Available...
13. Disposal Considerations
Dispose in accordance with applicable federal, state and local government regulations. Waste generators must
determine whether a discarded material is classified as a hazardous waste. USEPA guidelines for the classification
determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous
waste regulations to ensure complete and accurate classification.
RCRA Information
Waste solutions may meet the RCRA Ignitable characteristic.
14. Transport Information
Proper Shipping Name
Resin Solution, Flammable
Hazard Class
3, PG III
DOT Identification Number
UN1866
DOT Shipping Label
FLAMMABLE
15. Regulatory Information
U.S. Regulatory Information
All ingredients of this product are listed or are excluded from listing under the U.S. Toxic Substances Control Act
(TSCA) Chemical Substance Inventory.
SARA Hazard Classes
Acute Health Hazard
Chronic Health Hazard
Fire Hazard
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15. Regulatory Information - Continued
SARA Hazard Classes - Continued
SARA Title III - Section 313 Supplier Notification
This product contains the following toxic chemicals that are subject to the reporting requirements of section 313 of
the Emergency Planning and Community Right-To-Know Act (EPCRA) of 1986 and of 40 CFR 372.
TOLUENE DIISOCYANATE (MIXED ISOMERS) (26471-62-5) <=0.5 %
XYLENE (MIXED ISOMERS) (1330-20-7) 20 - 30 %
This information must be included on all MSDSs that are copied and distributed for this material.
Ingredient(s) - U.S. Regulatory Information
TOLUENE DIISOCYANATE (MIXED ISOMERS)
SARA Title III - EPA Part 355 Extremely Hazardous Substance
SARA Title III - Section 313 Form "R"/TRI Reportable Chemical
SARA - Acute Health Hazard
SARA - Chronic Health Hazard
XYLENE (MIXED ISOMERS)
SARA Title III - Section 313 Form "R"/TRI Reportable Chemical
SARA - Acute Health Hazard
SARA - Chronic Health Hazard
SARA - Fire Hazard
State Regulations
WARNING: This product contains a chemical known to the State of California to cause cancer, birth defects, or
other reproductive harm.
Ingredient(s) - State Regulations
TOLUENE DIISOCYANATE (MIXED ISOMERS)
New Jersey - Workplace Hazard
New Jersey - Environmental Hazard
New Jersey - TCPA Extraordinarily Hazardous Substance
XYLENE (MIXED ISOMERS)
New Jersey - Workplace Hazard
New Jersey - Environmental Hazard
New Jersey - Special Hazard
Pennsylvania - Workplace Hazard
Pennsylvania - Environmental Hazard
Massachusetts - Hazardous Substance
New York City - Hazardous Substance
16. Other Information
HMIS Rating
Health: *3
F i re : 3
Reactivity: 0
PP E: H
Revision/Preparer Information
MSDS Preparer: EHS Department
This MSDS Supercedes A Previous MSDS Dated: 08/28/2003
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Disclaimer
The data in this Material Safety Data Sheet relates only to the specific material herein and does not relate to use
in combination with any other material or in any process. The information set forth herein is based on technical
data that Sika believes to be reliable as of the date hereof. Since conditions of use are outside our control, we
make no warranties, express or implied and assume no liability in connection with any use of this information.
Nothing herein is to be taken as a license to operate under or a recommendation to infringe any patents.
SIKA CORPORATION
Printed Using MSDS Generator鈩? 2000
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