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MSDS Material Safety Data Sheet
CAS

96-09-3
084-00-2
45-21-3

File Name: ilo_org---icsc1201.asp
STYRENE OXIDE                                                                                                                                    1201
April 2006
CAS No: 96-09-3 (Epoxyethyl)benzene
RTECS No: CZ9625000 1,2-Epoxyethylbenzene
EC No: 603-084-00-2 Styrene-7,8-oxide
Phenylethylene oxide
Phenyl oxirane
Styrene epoxide
Styryl oxide
C8H8O / C6H5CHCH2O
Molecular mass: 120.2


TYPES OF
ACUTE HAZARDS/SYMPTOMS PREVENTION FIRST AID/FIRE FIGHTING
HAZARD/
EXPOSURE

FIRE Combustible. NO open flames. NO contact with acid(s), Powder, foam, carbon dioxide
base(s).

EXPLOSION Above 76/C explosive vapour/air Above 76/C use a closed system, In case of fire: cool drums, etc., by
mixtures may be formed. ventilation. spraying with water but avoid contact of
the substance with water.



EXPOSURE AVOID ALL CONTACT!

Inhalation Dizziness. Drowsiness. Local exhaust or breathing protection. Fresh air, rest.
Unconsciousness. Vomiting.

Skin Redness. Pain. Protective clothing. Protective gloves. Remove contaminated clothes. Rinse and
then wash skin with water and soap.

Eyes Redness. Pain. Safety goggles or eye protection in First rinse with plenty of water for several
combination with breathing protection. minutes (remove contact lenses if easily
possible), then take to a doctor.

Ingestion Abdominal pain. (Further see Inhalation). Do not eat, drink, or smoke during work. Rinse mouth. Refer for medical attention.
Wash hands before eating.


SPILLAGE DISPOSAL PACKAGING & LABELLING

Personal protection: chemical protection suit including EU classification Do not transport with food and feedstuffs.
self-contained breathing apparatus. Collect leaking liquid in T Symbol
covered containers. Absorb remaining liquid in sand or inert R: 45-21-36
absorbent and remove to safe place. S: 53-45
GHS classification
Signal: Danger
Excl mark-Health haz
Combustible liquid
Harmful if swallowed
Causes skin irritation
Causes eye irritation
Suspected of causing genetic defects
May cause
Note: E cancer


EMERGENCY RESPONSE SAFE STORAGE

NFPA Code: H2; F2; R0 Separated from acids, bases, food and feedstuffs. Ventilation along the floor.




Prepared in the context of cooperation between the International
IPCS Programme on Chemical Safety and the European Commission 漏
IPCS 2006
International
Programme on
SEE IMPORTANT INFORMATION ON THE BACK.
Chemical Safety
1201 STYRENE OXIDE


IMPORTANT DATA
Physical State; Appearance Routes of exposure
COLOURLESS TO PALE YELLOW LIQUID. The substance can be absorbed into the body by inhalation, through the
skin and by ingestion.
Chemical dangers
The substance may polymerize due to heating above the flash point, Inhalation risk
under the influence of acid(s) and base(s). No indication can be given about the rate in which a harmful concentration
in the air is reached on evaporation of this substance at 20/C.
Occupational exposure limits
TLV not established. Effects of short-term exposure
MAK not established. The substance irritates the eyes and the skin. The substance may cause
effects on the central nervous system. Exposure could cause lowering of
consciousness.

Effects of long-term or repeated exposure
This substance is probably carcinogenic to humans.



PHYSICAL PROPERTIES
Boiling point: 194/C Relative density of the vapour/air-mixture at 20/C (air = 1): 1.001
Melting point: -36.7/C Flash point: 76/C c.c.
Relative density (water = 1): 1.05 Auto-ignition temperature: 498/C
Solubility in water, g/100 ml at 25/C: 0.3 (poor) Explosive limits, vol% in air: 1.1-22
Vapour pressure, Pa at 20/C: 40 Octanol/water partition coefficient as log Pow: 1.61
Relative vapour density (air = 1): 4.30



ENVIRONMENTAL DATA



NOTES
Do NOT take working clothes home.
Card has been partially updated in January 2008: see Fire fighting.



ADDITIONAL INFORMATION




Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible
LEGAL NOTICE for the use which might be made of this information

漏IPCS 2006

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