070995
DOD Hazardous Materials Information System
DoD 6050.5-L
AS OF July 1998
FSC: 8010
NIIN: 00N038742
Manufacturer's CAGE: 90227
Part No. Indicator: A
Part Number/Trade Name: 2-K URETHANE HARDENER, 483-15
===========================================================================
General Information
===========================================================================
Item Name:
Company's Name: E I DU PONT DE NEMOURS & CO INC
Company's Street: 1007 MARKET ST
Company's P. O. Box:
Company's City: WILMINGTON
Company's State: DE
Company's Country: US
Company's Zip Code: 19898
Company's Emerg Ph #: 800-441-3637;800-424-9300(CHEMTREC)
Company's Info Ph #: 800-441-7515
Distributor/Vendor # 1:
Distributor/Vendor # 1 Cage:
Distributor/Vendor # 2:
Distributor/Vendor # 2 Cage:
Distributor/Vendor # 3:
Distributor/Vendor # 3 Cage:
Distributor/Vendor # 4:
Distributor/Vendor # 4 Cage:
Safety Data Action Code:
Safety Focal Point: N
Record No. For Safety Entry: 001
Tot Safety Entries This Stk#: 001
Status: SMJ
Date MSDS Prepared: 19AUG92
Safety Data Review Date: 20JAN93
Supply Item Manager:
MSDS Preparer's Name:
Preparer's Company:
Preparer's St Or P. O. Box:
Preparer's City:
Preparer's State:
Preparer's Zip Code:
Other MSDS Number:
MSDS Serial Number: BRFJT
Specification Number:
Spec Type, Grade, Class:
Hazard Characteristic Code: NK
Unit Of Issue:
Unit Of Issue Container Qty:
Type Of Container:
Net Unit Weight:
Report for NIIN: 00N038742
NRC/State License Number:
Net Explosive Weight:
Net Propellant Weight-Ammo:
Coast Guard Ammunition Code:
===========================================================================
Ingredients/Identity Information
Page 1
070995
===========================================================================
Proprietary: NO
Ingredient: ISOCYANIC ACID, HEXAMETHYLENE ESTER, POLYMERS; (HOMOPOLYMER OF
HEXAMETHYLENE DIISOCYANATE (HDI))
Ingredient Sequence Number: 01
Percent: N/K
Ingredient Action Code:
Ingredient Focal Point: N
NIOSH (RTECS) Number: NQ9170000
CAS Number: 28182-81-2
OSHA PEL: NOT APPLICABLE
ACGIH TLV: NOT APPLICABLE
Other Recommended Limit: N/K
-------------------------------------
Proprietary: NO
Ingredient: ACETIC ACID, BUTYL ESTER; (N-BUTYL ACETATE). VP:8 @ 20C
Ingredient Sequence Number: 02
Percent: N/K
Ingredient Action Code:
Ingredient Focal Point: N
NIOSH (RTECS) Number: AF7350000
CAS Number: 123-86-4
OSHA PEL: 150 PPM;200 PPM STEL
ACGIH TLV: 150 PPM;200 PPM STEL
Other Recommended Limit: N/K
-------------------------------------
Proprietary: NO
Ingredient: AROMATIC HYDROCARBON. VP:10 @ 25C
Ingredient Sequence Number: 03
Percent: N/K
Ingredient Action Code:
Ingredient Focal Point: N
NIOSH (RTECS) Number: 1002782AH
CAS Number: 68333-88-0
OSHA PEL: NOT APPLICABLE
ACGIH TLV: NOT APPLICABLE
Other Recommended Limit: N/K
-------------------------------------
Proprietary: NO
Ingredient: VOLATILE ORGANIC COMPOUNDS (1.2)
Ingredient Sequence Number: 04
Percent: N/K
Ingredient Action Code:
Ingredient Focal Point: N
NIOSH (RTECS) Number: 9999999VO
CAS Number:
OSHA PEL: NOT APPLICABLE
Report for NIIN: 00N038742
ACGIH TLV: NOT APPLICABLE
Other Recommended Limit: N/K
-------------------------------------
Proprietary: NO
Ingredient: SUPP DATA:INCONCLUSIVE. HAS BEEN TOX TO FETUS IN LAB ANIMALS
AT DOSES THAT ARE TOX TO MOTHER. AROMATIC (ING 6)
Ingredient Sequence Number: 05
Percent: N/K
Ingredient Action Code:
Ingredient Focal Point: N
NIOSH (RTECS) Number: 9999999ZZ
Page 2
070995
CAS Number:
OSHA PEL: NOT APPLICABLE
ACGIH TLV: NOT APPLICABLE
Other Recommended Limit: N/K
-------------------------------------
Proprietary: NO
Ingredient: ING 5:HYDROCARBON:LAB STUDIES W/RATS HAVE SHOWN THAT PETROLEUM
DISTILLATES CAUSE KIDNEY DAM & KIDNEY OR LIVER (ING 7)
Ingredient Sequence Number: 06
Percent: N/K
Ingredient Action Code:
Ingredient Focal Point: N
NIOSH (RTECS) Number: 9999999ZZ
CAS Number:
OSHA PEL: NOT APPLICABLE
ACGIH TLV: NOT APPLICABLE
Other Recommended Limit: N/K
-------------------------------------
Proprietary: NO
Ingredient: ING 6:TUMORS. THESE EFTS WERE NOT SEEN IN SIMILAR STUDIES W/
GUINEA PIGS, DOGS OR MONKEYS. SEVERAL STUDIES (ING 8)
Ingredient Sequence Number: 07
Percent: N/K
Ingredient Action Code:
Ingredient Focal Point: N
NIOSH (RTECS) Number: 9999999ZZ
CAS Number:
OSHA PEL: NOT APPLICABLE
ACGIH TLV: NOT APPLICABLE
Other Recommended Limit: N/K
-------------------------------------
Proprietary: NO
Ingredient: ING 7:EVALUATING PETROLEUM WORKERS HAVE NOT SHOWN A
SIGNIFICANT INCR OF KIDNEY DAM OR AN INCR IN KIDNEY OR LIVER TUMORS.
Ingredient Sequence Number: 08
Percent: N/K
Ingredient Action Code:
Ingredient Focal Point: N
NIOSH (RTECS) Number: 9999999ZZ
CAS Number:
OSHA PEL: NOT APPLICABLE
ACGIH TLV: NOT APPLICABLE
Report for NIIN: 00N038742
Other Recommended Limit: N/K
-------------------------------------
Proprietary: NO
Ingredient: SPILL PROC:W/20% SURFACTANT (TERGITOL TMN-10 OR EQUIV), 80%
WATER OR 0-10% AMMONIA, 2-5% DETERGENT, BALANCE (ING 10)
Ingredient Sequence Number: 09
Percent: N/K
Ingredient Action Code:
Ingredient Focal Point: N
NIOSH (RTECS) Number: 9999999ZZ
CAS Number:
OSHA PEL: NOT APPLICABLE
ACGIH TLV: NOT APPLICABLE
Other Recommended Limit: N/K
-------------------------------------
Proprietary: NO
Page 3
070995
Ingredient: ING 9:WATER. POUR LIQ, DECONTAMINATE SOLN OVER SPILL & ALLOW
TO SIT 10 MINS, MINIMUM. DO NOT SEAL WASTE CONTRS (ING 11)
Ingredient Sequence Number: 10
Percent: N/K
Ingredient Action Code:
Ingredient Focal Point: N
NIOSH (RTECS) Number: 9999999ZZ
CAS Number:
OSHA PEL: NOT APPLICABLE
ACGIH TLV: NOT APPLICABLE
Other Recommended Limit: N/K
-------------------------------------
Proprietary: NO
Ingredient: ING 10:FOR 48 HOURS TO ALLOW CARBON DIOXIDE TO VENT.
Ingredient Sequence Number: 11
Percent: N/K
Ingredient Action Code:
Ingredient Focal Point: N
NIOSH (RTECS) Number: 9999999ZZ
CAS Number:
OSHA PEL: NOT APPLICABLE
ACGIH TLV: NOT APPLICABLE
Other Recommended Limit: N/K
-------------------------------------
Proprietary: NO
Ingredient: OTHER PROT EQUIP:OF CLEAN UP, NOT FOR PROT. DO NOT GET ON
AREAS THAT WILL INTERFERE W/PROPER SEAL OF RESPIRATOR.
Ingredient Sequence Number: 12
Percent: N/K
Ingredient Action Code:
Ingredient Focal Point: N
NIOSH (RTECS) Number: 9999999ZZ
CAS Number:
OSHA PEL: NOT APPLICABLE
ACGIH TLV: NOT APPLICABLE
Other Recommended Limit: N/K
Report for NIIN: 00N038742
===========================================================================
Physical/Chemical Characteristics
===========================================================================
Appearance And Odor: NONE SPECIFIED BY MANUFACTURER.
Boiling Point: >257F,>125C
Melting Point: N/K
Vapor Pressure (MM Hg/70 F): SEE INGRED
Vapor Density (Air=1): HVR/AIR
Specific Gravity: N/K
Decomposition Temperature: N/K
Evaporation Rate And Ref: SLOWER THAN ETHER
Solubility In Water: SLIGHT
Percent Volatiles By Volume: 17.3
Viscosity:
pH: N/K
Radioactivity:
Form (Radioactive Matl):
Magnetism (Milligauss):
Corrosion Rate (IPY): N/K
Autoignition Temperature:
===========================================================================
Fire and Explosion Hazard Data
Page 4
070995
===========================================================================
Flash Point: >20F,>-7C
Flash Point Method: CC
Lower Explosive Limit: 0.9%
Upper Explosive Limit: 7.6%
Extinguishing Media: FOAM, CARBON DIOXIDE & DRY CHEMICAL.
Special Fire Fighting Proc: WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT (FP N). WATER FROM FOG NOZZLES MAY BE USED TO PREVENT
PRESSURE BUILD-UP.
Unusual Fire And Expl Hazrds: WHEN HEATED ABOVE FLASH POINT, EMITS FLAMM
VAPORS WHICH, WHEN MIXED W/AIR, CAN BURN/BE EXPLOSIVE. FINE MIST/SPRAYS MAY
BE FLAMM AT TEMPS BELOW FLASH POINT.
===========================================================================
Reactivity Data
===========================================================================
Stability: YES
Cond To Avoid (Stability): STABLE IN SEALED CONTAINERS.
Materials To Avoid: WATER, ALCOHOLS & AMINES.
Hazardous Decomp Products: CARBON MONOXIDE, CARBON DIOXIDE, SMOKE, OXIDES
OF METALS REPORTED IN INGREDIENT SECTION.
Hazardous Poly Occur: NO
Conditions To Avoid (Poly): NOT RELEVANT.
===========================================================================
Health Hazard Data
===========================================================================
LD50-LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry - Inhalation: YES
Route Of Entry - Skin: YES
Route Of Entry - Ingestion: YES
Health Haz Acute And Chronic: INGEST:GI DISTRESS. INHAL:EXPOS TO
ISOCYANATES MAY CAUSE RESP SENSIT. THIS EFT MAY BE PERM. SYMPS INCL AN
Report for NIIN: 00N038742
ASTHMA-LIKE RXN W/SHORTNESS OF BREATH/WHEEZING/COUGHING, WHICH MAY BE PERM.
THIS EFTS MAY BE DELAYED FOR SEVERAL HRS AFTER EXPOS. RPTD OVEREXPOS TO
ISOCYANATES MAY CAUSE A DECR IN LUNG FUNCTION (EFTS OF OVEREXP)
Carcinogenicity - NTP: NO
Carcinogenicity - IARC: NO
Carcinogenicity - OSHA: NO
Explanation Carcinogenicity: NOT RELEVANT.
Signs/Symptoms Of Overexp: HTLH HAZ:WHICH MAY BE PERM. RPTD/PRLNGD
OVEREPXOS TO SOLV MAY LEAD TO PERM BRAIN & NERV SYS DAM. EYE WATERING/HDCH/
NAUS/DIZZ/LOSS OR COORD ARE SIGNS THAT SOLV LEVELS ARE TOO HIGH. MAY CAUSE
NOSE/THROAT IRRIT. EYES:MAY CAUSE IRRIT/BURNING. SKIN:RPTD/PRLNGD LIQ CONT
MAY CAUSE IRRIT W/DISCOMFORT & DERM. (SUPP DATA)
Med Cond Aggravated By Exp: INDIV W/PRE-EXISTING LUNG DISEASE, ASTHMA,
BRTHG DFCLTIES OR PRIOR RXN TO ISOCYANATES MAY HAVE INCRD SUSCEPTIBLITY TO
TOX OF EXCESSIVE EXPOS. DO NOT EXPOSE TO VAPORS/SPRAY MIST OF THIS PRODUCT.
Emergency/First Aid Proc: INHAL:REMOVE TO FRESH AIR. IF NOT BREATHING,
GIVE ARTF RESP, PREF MOUTH-TO-MOUTH. IF BREATHING DIFFICULTY PERSISTS/
OCCURS LATER, CONSULT MD. EYES:IMMEDIATELY FLUSH W/PLENTY OF WATER FOR AT
LEAST 15 MINS. CALL MD. SKIN:WASH W/SOAP & WATER. IF IRRITATION OCCURS,
CONTACT MD. INGEST:CALL MD IMEMDIATELY & HAVE NAMES OF INGREDIENTS
AVAILABLE.
===========================================================================
Precautions for Safe Handling and Use
===========================================================================
Steps If Matl Released/Spill: DO NOT BREATHE VAPS. DO NOT GET IN EYES/ON
SKIN. WEAR A NIOSH/MSHA APPRVD POS PRESS, SUPPLIED AIR RESP (TC-19C), EYE
PROT, GLOVES & PROT CLTHG. REMOVE SOURCES OF IGNIT. ABSORB W/INERT MATL.
Page 5
070995
VENT AREA. DEACTIVATE ISOCYANATE CONTAINING SPILLS (ING 9)
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Method: DO NOT ALLOW MATERIAL TO CONTAMINATE GROUND WATER
SYSTEMS. INCINERATE ABSORBED MATERIAL IN ACCORDANCE W/FEDERAL, STATE &
LOCAL REQUIREMENTS. DO NOT INCINERATE IN CLOSED CONTAINERS.
Precautions-Handling/Storing: DO NOT STORE >120F. KEEP AWAY FROM HEAT,
SPARKS & FLAME. CLOED CONTAINER AFTER EACH USE. OBSERVE LABEL PRECAUTIONS.
GROUND CONTAINERS WHEN POURING.
Other Precautions: DO NOT BREATHE VAPORS OR MISTS. DO NOT SAND, FLAME CUT,
BRAZE OR WELD DRY COATING W/OUT A NIOSH/MSHA APPROVED RESPIRATOR OR
APPROPRIATE VENTILATION. DO NOT PERMIT ANYONE W/OUT PROTECTION IN THE
PAINTING AREA.
===========================================================================
Control Measures
===========================================================================
Respiratory Protection: WEAR A NIOSH/MSHA APPROVED POS PRESSURE SUPPLIED
AIR RESPIRATOR (TC-19C) WHILE MIXING ACTIVATOR W/ANY PAINT/ENAMEL, DURING
APPLICATN & UNTIL ALL VAPORS/SPRAY MISTS ARE EXHAUSTED. FOLLOW THE RESP
MFR'S DIRECTIONS FOR RESPIRATOR USE.
Ventilation: PROVIDE SUFFICIENT VENTILATION IN VOLUME/PATTERN TO KEEP
CONTAMINANTS BELOW APPLICABLE OSHA REQUIREMENTS.
Protective Gloves: IMPERMEABLE NEOPRENE GLOVES.
Eye Protection: CHEMICAL WORKERS GOGGLES (FP N).
Other Protective Equipment: WEAR COVERALLS. DO NOT REUSE COVERALLS WHILE
SOLV ODOR IS RETAINED IN THEM. PROT CREAMS MAY BE USED FOR EASE (ING 12)
Work Hygienic Practices: WASH THOROUGHLY AFTER HANDLING & BEFORE EATING OR
Report for NIIN: 00N038742
SMOKING.
Suppl. Safety & Health Data: EFTS OF OVEREXP:ALIPHATIC POLYISOCYANATE
RESIN: RPTD EXPOS MAY CAUSE ALLERGIC SKIN RASH/ITCHING/ SWELLING. MAY CAUSE
EYE IRRIT W/DISCOMFORT/ TEARING/BLURRED VISION. EFTS MAY BE DELAYED FOR
SEVERAL HRS AFTER EXPOS. BUTYL ACETATE:MAY CAUSE ABNORM LIVER FUNCTION.
TESTS FOR EMBRYOTOXIC ACTIVITY IN ANIMALS HAS BEEN (ING 5)
===========================================================================
Transportation Data
===========================================================================
Transportation Action Code:
Transportation Focal Point:
Trans Data Review Date:
DOT PSN Code:
DOT Symbol:
DOT Proper Shipping Name:
DOT Class:
DOT ID Number:
DOT Pack Group:
DOT Label:
DOT/DoD Exemption Number:
IMO PSN Code:
IMO Proper Shipping Name:
IMO Regulations Page Number:
IMO UN Number:
IMO UN Class:
IMO Subsidiary Risk Label:
IATA PSN Code:
IATA UN ID Number:
IATA Proper Shipping Name:
IATA UN Class:
IATA Subsidiary Risk Class:
IATA Label:
Page 6
070995
AFI PSN Code:
AFI Symbols:
AFI Prop. Shipping Name:
AFI Class:
AFI ID Number:
AFI Pack Group:
AFI Label:
AFI Special Prov:
AFI Basic Pac Ref:
MMAC Code:
N.O.S. Shipping Name:
Additional Trans Data:
===========================================================================
Disposal Data
===========================================================================
Disposal Data Action Code:
Disposal Data Focal Point:
Disposal Data Review Date:
Rec # For This Disp Entry:
Tot Disp Entries Per NSN:
Landfill Ban Item:
Report for NIIN: 00N038742
Disposal Supplemental Data:
1st EPA Haz Wst Code New:
1st EPA Haz Wst Name New:
1st EPA Haz Wst Char New:
1st EPA Acute Hazard New:
2nd EPA Haz Wst Code New:
2nd EPA Haz Wst Name New:
2nd EPA Haz Wst Char New:
2nd EPA Acute Hazard New:
3rd EPA Haz Wst Code New:
3rd EPA Haz Wst Name New:
3rd EPA Haz Wst Char New:
3rd EPA Acute Hazard New:
===========================================================================
Label Data
===========================================================================
Label Required: YES
Technical Review Date: 15JAN93
Label Date:
MFR Label Number:
Label Status: G
Common Name: 2-K URETHANE HARDENER, 483-15
Chronic Hazard: YES
Signal Word: DANGER!
Acute Health Hazard-None:
Acute Health Hazard-Slight:
Acute Health Hazard-Moderate: X
Acute Health Hazard-Severe:
Contact Hazard-None:
Contact Hazard-Slight: X
Contact Hazard-Moderate:
Contact Hazard-Severe:
Fire Hazard-None:
Fire Hazard-Slight:
Fire Hazard-Moderate:
Fire Hazard-Severe: X
Reactivity Hazard-None: X
Page 7
070995
Reactivity Hazard-Slight:
Reactivity Hazard-Moderate:
Reactivity Hazard-Severe:
Special Hazard Precautions: FLAMMABLE. KEEP AWAY FROM HEAT, SPARKS AND
FLAME. ACUTE: SWALLOWING CAN CAUSE GASTROINTESTINAL DISTRESS. INHALATION
MAY CAUSE SHORTNESS OF BREATH, WHEEZING AND COUGHING. MAY CAUSE EYE AND
SKIN IRRITATION. CHRONIC: MAY CAUSE DECREASE IN LUNG FUNCTION. MAY CAUSE
PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. MAY CAUSE RESPIRATORY
SENSITIZATION AND ASTHMA-LIKE REACTION.
Protect Eye: Y
Protect Skin: Y
Protect Respiratory: Y
Label Name: E I DU PONT DE NEMOURS & CO
Label Street: 1007 MARKET ST
Label P.O. Box:
Label City: WILMINGTON
Report for NIIN: 00N038742
Label State: DE
Label Zip Code: 19898
Label Country: US
Label Emergency Number: 800-441-3637;800-424-9300(CHEMTREC)
Year Procured:
Page 8
|