Material Safety Data Sheet
MSDS No: 49
Domestic Emergency Phone 613-996-6666
Woodstream Canada Corporation International Emergency Phone 613-996-6666
3 Pullman Court 416-291-8150
Information Phone
Scarborough, ON M1X 1E4 416-291-8150
Intl Info Phone:
SECTION I: MATERIAL IDENTIFICATION
12-1603CAN 350 Milliliter
Product Number/Size:
350ML CRAWLING INSECT KILLER
Trade Name:
Insect Killer
Also Known As:
Insect Killer-Permethrin
Description:
Liquid
Chemical Composition:
P.C.P. Registration Number: 24370
Regulatory Licenses:
SECTION II: INGREDIENTS
Hazardous Ingredient (s)* % BY WT CAS # OSHA/TWA PEL/STEL ACGIH/TWA TLV/STEL
Permethrin 0.25 52645-53- 5 mg/m3 NE 5 mg/m3 NE
Mineral seal oil <5.0 64742-80- 5 mg/m3 NE 3 mg/m3 NE
* all ingredients in quantities > 1.0% (0.1% for carcinogens or teratogens) that are potentially hazardous per OSHA definitions.
SECTION III: PHYSICAL DATA
Boiling Point: Not Determined Not Available
Viscosity:
Vapor Pressure (mm Hg): Not Determined Slight Odor
Odor:
Vapor Density (AIR=1): Not Determined 1.0
Specific Gravity (Water=1):
Bulk Density: 8.33 PPG Not Determined
Percent, Volitile by Volume %:
Freezing Point: Not Determined Not Determined
Evaporation Rate (Xylene=1):
Solubility in Water: Soluble Liquid
Physical State:
Appearance: Milky White 6.0-8.0
pH:
SECTION IV: FIRE AND EXPLOSION HAZARD DATA
> 200掳F (TCC) 1
Flash Point (method): NFPA Health Rating:
Not Determined 1
Autoignition Temp.: NFPA Fire Rating:
Not Determined 0
Flammable Lel: NFPA Reactivity Rating:
Not Determined CO2, dry chemical, foam, water
Flammable Uel: Extinguishing Material:
Hazardous Products
Carbon Oxides
of Combustion:
SECTION V: HEALTH HAZARD DATA
General Statement: Material is not considered to be hazardous per 29 CFR 1910.1200.
Occupational Exposure Limit: See Section II
Effects of Over Exposure: None Expected
Carcinogenicity: None listed per OSHA, NTP, or IARC.
Chronic Effects: None Expected
Rec. Exp. Limits: See Section II
Potential Health Effects: None Expected
Acute Oral: > 5000 mg/kg
Acute Dermal: > 5000 mg/kg
Acute Inhalation: >2 mg/liter
Eye Irritation: Not An Irritant
Skin Irritation: Not An Irritant
Sensitization: Not A Sensitizer
Tuesday, May 27, 2003 Page 1 of 3
Route of Entry Symptoms/Effects of Overexposure First Aid
Skin None Expected Wash with plenty of soap and water. Get medical attention.
Inhalation None Expected Remove victim to fresh air. If not breathing, give artificial respiration,
preferably mouth to mouth. Get medical attention.
Eye None Expected Hold eyelids open and flush with a steady, gentle stream of water for 15
minutes. Get medical attention.
Ingestion None Expected If swallowed, promptly drink large amounts of water. Never give liquids to an
unconscious person. Get medical attention.
SECTION VI: REACTIVITY DATA
Stability: Stable
Conditions to avoid: Excessive heat
Materials to avoid: Concentrated mineral supplements (fertilizers), strong oxidizers, acids
Hazardous Decomposition: Will Not Occur
Conditions to avoid: Excessive heat
Hazardous Polymerization: Will Not Occur
Conditions to avoid: Excessive heat
SECTION VII: SPILL OR LEAK PROCEDURES
Steps to be taken if material Rinse with abundant water and mop up
is released or spilled:
Waste Disposal Method: Dispose in accordance with local, provincial and national regulations.
Product Disposal Method: PESTICIDE DISPOSAL: Wastes resulting from use of this product may be disposed of on site or at an approved
waste disposal facility.
CONTAINER DISPOSAL:
If Empty: Do not reuse this container. Place in trash or offer for recycling if available.
If Partly Filled: Call your local solid waste agency for disposal instructions. Never place unused product down any
indoor or outdoor drain.
SECTION VIII: SPECIAL PROTECTION INFORMATION
Respiratory Protection: In typical applications no engineering controls should be needed; if industrial hygiene surveys show that occupational
exposure limits may be exceeded, use NIOSH approved respirator with organic vapor/dust/mist cartridges.
Protective Gloves: Protective gloves (nitrile) recommended
Eye Protection: Recommended to avoid splashing of material directly into eyes
Protective Clothing: Not Needed
Ventilation: Not Needed
Other Protective Equipment: Not Needed
Protection Note: Personal protection information provided in this Section is based upon general information as to normal uses and
conditions. Where special or unusual uses or conditions exist, it is suggested that the expert assistance of an
industrial hygienist or other qualified professional be sought.
SECTION IX: SPECIAL PRECAUTIONS
Storage and Handling: PESTICIDE STORAGE: Store only in a cool, dry area inaccessible to children and pets. Protect from freezing and
heat. Keep container tightly closed to prevent evaporation. Do not contaminate water, food or feed by storage and
disposal.
Other Precautions: Store away from heat, out of reach of children. Do not contaminate water, food or feed by storage or disposal. Do
not reuse container.
Precaution Note: None
SECTION X: ECOLOGICAL INFORMATION
Ecotoxicity: Toxic to fish and aquatic invertebrates. Do not apply directly to water; do not contaminate water by cleaning of
equipment or disposal of wash waters.
Environmental Fate: Not persistent
Tuesday, May 27, 2003 Page 2 of 3
SECTION XI: TRANSPORTATION INFORMATION
DOT HAZARD DESCRIPTION
Not Hazardous
DOT Proper Shipping Name:
Not Regulated
Identification Number:
None
DOT Hazard Class/Division:
None
Packaging Group:
None
Packaging Instructions:
None
Special Instructions:
None Required
Placard:
None
Emergency Response Guide#:
See NMFTA Manual
US Surface Freight Class:
IATA CLASSIFICATION
IATA Proper Shipping Name:
Not Regulated
Identification Number:
IATA Hazard Class/Division:
None
Packaging Group:
None
IATA Bulk Packaging Inst:
None
IATA Shipping Notes:
IMO CLASSIFICATION
IMO Proper Shipping Name:
Not Regulated
Identification Number:
IMO Hazard Class/Division:
None
Packaging Group:
None
IMO Shipping Notes:
None
IMO Bulk Packaging Inst:
None
IMO Stowage Category:
SECTION XII: REGULATORY INFORMATION
Not Regulated
SARA Title III:
Reporting not required unless TPQ exceeded in inventory
SARA Product Classification:
N/A
Acute:
N/A
Chronic:
N/A
Fire:
N/A
Reactivity:
Not Pressure Generating
Pressure Generating:
Not Subject
311/312 Hazard Categories:
Not Subject
313 Reportable Ingredients:
None Listed
TSCA Regulatory:
In the U.S.A. states such as Pennsylvania, New Jersey, California, Vermont, Massachusetts and Rhode Island
State Regulations:
may all have components of this product listed; consult specific state regulatory requirements for additional
information.
Proposition 65 Statement: None Listed
SECTION XIII: OTHER INFORMATION
While this information and recommendations set forth are believed to be accurate as of the date hereof,
Memo:
Woodstream Corp. makes no warranty with respect hereto and disclaims all liability from reliance thereon.
10/24/2002 Nathan P. Ehresman
Date MSDS Prepared: Contact:
2/1/2001 Regulatory Affairs
Supercedes Date: Title:
Tuesday, May 27, 2003 Page 3 of 3
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