MATERIAL SAFETY DATA SHEET
Sika Primer 209N
HMIS
HEALTH *3
FLAMMABILITY 3
REACTIVITY 1
H
PERSONAL PROTECTION
1. Product And Company Identification
Supplier Manufacturer
Sika Corporation Sika Schweiz AG
30800 Stephenson Highway Tuffenwies 16
Madison Heights, MI 48071 U.S.A. Zurich, Schweiz CH-8048 Switzerland
Company Contact: EHS Department
Telephone Number: 201-933-8800 Telephone Number: +411 436 40 40
FAX Number: 201-933-9379 FAX Number: +411 436 4584
Web Site: www.sikaindustry.com
Supplier Emergency Contacts & Phone Number Manufacturer Emergency Contacts & Phone Number
CHEMTREC: 800-424-9300 CHEMTREC: 1-800-424-9300
INTERNATIONAL: 703-527-3887 International: 1-703-527-3887
Issue Date: 02/10/2005
Product Name: Sika Primer 209N
CAS Number: Not Established
Chemical Family: Polyisocyanates in organic solvents
MSDS Number: 3467
2. Composition/Information On Ingredients
Ingredient CAS Percent Of
Name Number Total Weight
CARBON BLACK 1333-86-4
ETHYL ACETATE 141-78-6
METHYL ETHYL KETONE 78-93-3 15 - 20
POLYISOCYANATE PREPOLYMER Trade Secret
3. Hazards Identification
Eye Hazards
Causes eye irritation.
Skin Hazards
Causes skin irritation. Prolonged and/or repeated contact with skin may cause an allergic reaction/sensitization.
Ingestion Hazards
Harmful if swallowed.
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MATERIAL SAFETY DATA SHEET
Sika Primer 209N
3. Hazards Identification - Continued
Inhalation Hazards
Causes respiratory tract irritation. Headaches and dizziness may result. Inhalation may cause Central Nervous
System effects.
4. First Aid Measures
Eye
In case of contact, hold eyelids apart and immediately flush eyes with plenty of tepid water for at least 15 minutes.
Get medical attention immediately if irritation develops and persists.
Skin
In case of contact, immediately flush skin with soap and plenty of tepid water for at least 15 minutes. Get medical
attention immediately if irritation (redness, rash, blistering) develops and persists.
Ingestion
Do not induce vomiting. Call a physician or a poison control center immediately.
Inhalation
Remove to fresh air. If not breathing, give artificial respiration, seek medical attention.
5. Fire Fighting Measures
Flash Point: 24.8 掳F -4 掳C
Autoignition Point: N/AV 掳F
Lower Explosive Limit: N/AV
Upper Explosive Limit: N/AV
Fire And Explosion Hazards
Protect against electrostatic discharge. Possible formation of explosive mixtures air/vapor. Vapors may flow
along surfaces to distant ignition sources and flash back.
Extinguishing Media
CO2, Dry Powder, Foam
Fire Fighting Instructions
Firefighters should wear self-contained breathing apparatus and full protective gear. Avoid breathing vapors,
gases and fumes. Cool exposed containers with water spray.
6. Accidental Release Measures
Eliminate all ignition sources. Use appropriate Personal Protective Equipment (PPE). Absorb and/or contain spill with
inert materials (e.g. sand, vermiculite) and then place in appropriate container. For large spills, use water spray to
disperse vapors. Prevent runoff from entering waterways or sewers.
7. Handling And Storage
Handling And Storage Precautions
Keep out of reach of children. Store containers tightly sealed and moisture-proof in a well ventilated area. Take
precautionary measures against electrostatic discharge. Explosion protection: Possible formation of explosive
mixtures air/vapors. Keep away from open flame. No smoking.
8. Exposure Controls/Personal Protection
Engineering Controls
Use of a system of local and/or general exhaust is recommended to keep employee below applicable expsoure
limits. Refer to the current edition of "Industrial Ventilation: A Manual of Recommended Practice" published by
the American Conference of Governmental Industrial Hygienists for information on the design, installation, use,
and maintenance of exhaust systems.
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MATERIAL SAFETY DATA SHEET
Sika Primer 209N
8. Exposure Controls/Personal Protection - Continued
Eye/Face Protection
Faceshield over safety glasses or goggles.
Skin Protection
Chemical-resistant gloves. Lab coat or other work clothing to prevent skin exposure. Launder before reuse.
Respiratory Protection
A respirator protection program that meets 29 CFR 1910.134 requirement must be followed whenever workplace
conditions warrant a respirator's use. In areas where the Permissible Expsosure Limits are exceeded, use a
properly fitted NIOSH-approved respirator.
Other/General Protection
Wash thoroughly after handling.
Ingredient(s) - Exposure Limits
CARBON BLACK
ACGIH TLV-TWA 3.5 mg/m3
OSHA PEL-TWA 3.5 mg/m3
ETHYL ACETATE
ACGIH TLV-TWA 400 ppm
OSHA PEL-TWA 400 ppm
METHYL ETHYL KETONE
ACGIH TLV-STEL 300 ppm
ACGIH TLV-TWA 200 ppm
OSHA PEL-TWA 200 ppm
9. Physical And Chemical Properties
Appearance
Black liquid
Odor
Ester like
Chemical Type: Mixture
Melting Point: N/AV 掳F
Boiling Point: 170.6 掳F
Specific Gravity: 1.0g/L
Percent VOCs: 37.8
Viscosity: 12 mPas at 10Hz
VOC Content: 383 grams / liter
10. Stability And Reactivity
Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid (Stability)
Do not mix with water, oxidizers, amines, or alcohols as they may cause gaseous decomposition products that
cause pressurization in closed containers.
Incompatible Materials
Water, Oxidizers, Amines, Alcohols
Hazardous Decomposition Products
None if used as directed
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MATERIAL SAFETY DATA SHEET
Sika Primer 209N
10. Stability And Reactivity - Continued
Conditions To Avoid (Polymerization)
None known
11. Toxicological Information
Ingredient(s) - Carginogenicity
CARBON BLACK
Listed In The IARC Monographs
12. Ecological Information
No Data Available...
13. Disposal Considerations
Dispose in accordance with applicable federal, state and local government regulations.Waste generators must
determine whether a discarded material is classified as a hazardous waste. USEPA guidelines for the classification
determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous
waste regulations to ensure complete and accurate classification.
RCRA Information
Waste solutions may meet the RCRA Ignitable characteristic.
14. Transport Information
Proper Shipping Name
Resin Solution
Hazard Class
3, PG II
DOT Identification Number
UN1866
DOT Shipping Label
Flammable
15. Regulatory Information
SARA Hazard Classes
Acute Health Hazard
Chronic Health Hazard
Fire Hazard
SARA Title III - Section 313 Supplier Notification
This product contains the following toxic chemicals that are subject to the reporting requirements of section 313 of
the Emergency Planning and Community Right-To-Know Act (EPCRA) of 1986 and of 40 CFR 372.
METHYL ETHYL KETONE (78-93-3) 15 - 20 %
This information must be included on all MSDSs that are copied and distributed for this material.
Ingredient(s) - U.S. Regulatory Information
METHYL ETHYL KETONE
SARA Title III - Section 313 Form "R"/TRI Reportable Chemical
SARA - Acute Health Hazard
SARA - Chronic Health Hazard
SARA - Fire Hazard
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MATERIAL SAFETY DATA SHEET
Sika Primer 209N
15. Regulatory Information - Continued
Ingredient(s) - State Regulations
CARBON BLACK
New Jersey - Workplace Hazard
Pennsylvania - Workplace Hazard
Massachusetts - Hazardous Substance
ETHYL ACETATE
New Jersey - Workplace Hazard
New Jersey - Special Hazard
Pennsylvania - Workplace Hazard
Massachusetts - Hazardous Substance
New York City - Hazardous Substance
METHYL ETHYL KETONE
New Jersey - Workplace Hazard
New Jersey - Environmental Hazard
New Jersey - Special Hazard
Pennsylvania - Workplace Hazard
Pennsylvania - Environmental Hazard
Massachusetts - Hazardous Substance
New York City - Hazardous Substance
16. Other Information
HMIS Rating
Health: *3
F i re : 3
Reactivity: 1
PP E: H
Revision/Preparer Information
MSDS Preparer: EHS Department
MSDS Preparer Phone Number: 201-933-8800
This MSDS Supercedes A Previous MSDS Dated: 02/07/2005
Disclaimer
The data in this Material Safety Data Sheet relates only to the specific material herein and does not relate to use
in combination with any other material or in any process. The information set forth herein is based on technical
data that Sika believes to be reliable as of the date hereof. Since conditions of use are outside our control, we
make no warranties, express or implied and assume no liability in connection with any use of this information.
Nothing herein is to be taken as a license to operate under or a recommendation to infringe any patents.
Sika Corporation
Printed Using MSDS Generator鈩? 2000
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