Material Safety Data Sheet
HMIS
NFPA Personal Protective Equipment
Health Hazard
2
1 Fire Hazard
1
2 0
Reactivity
0 See Section 15.
Section 1. Chemical Product and Company Identification Page Number: 1
Catalog
p-Anisidine A2095
Common Name/
Number(s).
Trade Name
104-94-9
CAS#
Manufacturer BZ5450000
RTECS
SPECTRUM QUALITY PRODUCTS INC.
14422 S. SAN PEDRO STREET TSCA 8(b) inventory:
TSCA
p-Anisidine
GARDENA, CA 90248
Not available.
Commercial Name(s) Not available.
CI#
1-Amino-4-Methoxybenzene
Synonym
IN CASE OF EMERGENCY
p-Anisidine
Chemical Name CHEMTREC (24hr) 800-424-9300
Not available. CALL (310) 516-8000
Chemical Family
C7-H9-N-O
Chemical Formula
SPECTRUM QUALITY PRODUCTS INC.
Supplier
14422 S. SAN PEDRO STREET
GARDENA, CA 90248
Section 2.Composition and Information on Ingredients
Exposure Limits
3
STEL (mg/m3) CEIL (mg/m3)
Name CAS # TWA (mg/m ) % by Weight
1) {p-}Anisidine 104-94-9 0.5 100
p-Anisidine:
Toxicological Data
ORAL (LD50): Acute: 1320 mg/kg [Rat]. 1410 mg/kg [Mouse]. 2900 mg/kg [Rabbit].
on Ingredients
DERMAL (LD50): Acute: 3200 mg/kg [Rat].
Section 3. Hazards Identification
Potential Acute Health Effects Hazardous in case of skin contact (irritant), . Slightly hazardous in case of eye contact (irritant), of inhalation (lung
irritant). Severe over-exposure can result in death.
CARCINOGENIC EFFECTS: A4 (Not classifiable for human or animal.) by ACGIH, 3 (Not classifiable for
Potential Chronic Health
human.) by IARC.
Effects
MUTAGENIC EFFECTS: Not available.
TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available.
The substance may be toxic to blood, kidneys, liver, cardiovascular system, central nervous system (CNS).
Repeated or prolonged exposure to the substance can produce target organs damage. Repeated exposure to a
highly toxic material may produce general deterioration of health by an accumulation in one or many human
organs.
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p-Anisidine
Section 4. First Aid Measures
Eye Contact Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at
least 15 minutes. Cold water may be used. WARM water MUST be used. Get medical attention.
Skin Contact In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated
clothing and shoes. Cover the irritated skin with an emollient. Wash clothing before reuse. Thoroughly clean
shoes before reuse. Get medical attention immediately.
Serious Skin Contact Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate
medical attention.
Inhalation If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get
medical attention immediately.
Serious Inhalation Not available.
Ingestion If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by
mouth to an unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical
attention immediately.
Serious Ingestion Not available.
Section 5. Fire and Explosion Data
May be combustible at high temperature.
Flammability of the Product
515掳C (959掳F)
Auto-Ignition Temperature
CLOSED CUP: 5掳C (41掳F).
Flash Points
Not available.
Flammable Limits
These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...).
Products of Combustion
Not available.
Fire Hazards in Presence of
Various Substances
Explosion Hazards in Presence Risks of explosion of the product in presence of mechanical impact: Not available.
Risks of explosion of the product in presence of static discharge: Not available.
of Various Substances
SMALL FIRE: Use DRY chemical powder.
Fire Fighting Media
LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
and Instructions
Not available.
Special Remarks on
Fire Hazards
Special Remarks on Explosion Not available.
Hazards
Section 6. Accidental Release Measures
Small Spill Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by
spreading water on the contaminated surface and dispose of according to local and regional authority
requirements.
Large Spill Poisonous solid.
Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray to
reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Eliminate all ignition
sources. Call for assistance on disposal. Finish cleaning by spreading water on the contaminated surface and
allow to evacuate through the sanitary system. Be careful that the product is not present at a concentration level
above TLV. Check TLV on the MSDS and with local authorities.
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p-Anisidine
Section 7. Handling and Storage
Keep locked up.. Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk,
Precautions
evaporate the residue under a fume hood. Ground all equipment containing material. Do not ingest. Do not
breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory
equipment. If ingested, seek medical advice immediately and show the container or the label. Keep away from
incompatibles such as oxidizing agents, acids.
Keep container tightly closed. Keep container in a cool, well-ventilated area.
Storage
Section 8. Exposure Controls/Personal Protection
Engineering Controls Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below
recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to
airborne contaminants below the exposure limit.
Personal Protection Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.
Personal Protection in Case of Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used
a Large Spill to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist
BEFORE handling this product.
Exposure Limits TWA: 0.1 (ppm) from ACGIH (TLV) [United States] [1999]
TWA: 0.5 (mg/m3) from NIOSH [United States] SKIN
Consult local authorities for acceptable exposure limits.
Section 9. Physical and Chemical Properties
Physical state and appearance Solid. (Crystalline solid.) Amine like. (Slight.)
Odor
Not available.
Taste
123.16 g/mole
Molecular Weight
Brown.
Color
Not available.
pH (1% soln/water)
246掳C (474.8掳F)
Boiling Point
57掳C (134.6掳F)
Melting Point
Not available.
Critical Temperature
Not available.
Specific Gravity
Not applicable.
Vapor Pressure
4.28 (Air = 1)
Vapor Density
Not available.
Volatility
Not available.
Odor Threshold
Not available.
Water/Oil Dist. Coeff.
Not available.
Ionicity (in Water)
Easily dispersed in methanol.
Dispersion Properties
Very slightly dispersed in cold water, hot water.
See solubility in methanol, acetone.
Easily soluble in methanol.
Solubility
Partially soluble in acetone.
Very slightly soluble in cold water, hot water.
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p-Anisidine
Section 10. Stability and Reactivity Data
The product is stable.
Stability
Not available.
Instability Temperature
Not available.
Conditions of Instability
Reactive with oxidizing agents, acids.
Incompatibility with various
substances
Not available.
Corrosivity
Not available.
Special Remarks on
Reactivity
Not available.
Special Remarks on
Corrosivity
Will not occur.
Polymerization
Section 11. Toxicological Information
Routes of Entry Eye contact. Inhalation. Ingestion.
Toxicity to Animals Acute oral toxicity (LD50): 1320 mg/kg [Rat].
Acute dermal toxicity (LD50): 3200 mg/kg [Rat].
Chronic Effects on Humans CARCINOGENIC EFFECTS: A4 (Not classifiable for human or animal.) by ACGIH, 3 (Not classifiable for
human.) by IARC.
May cause damage to the following organs: blood, kidneys, liver, cardiovascular system, central nervous system
(CNS).
Other Toxic Effects on Hazardous in case of skin contact (irritant), .
Humans Slightly hazardous in case of inhalation (lung irritant).
Special Remarks on Not available.
Toxicity to Animals
Special Remarks on Not available.
Chronic Effects on Humans
Special Remarks on other Not available.
Toxic Effects on Humans
Section 12. Ecological Information
Not available.
Ecotoxicity
Not available.
BOD5 and COD
Possibly hazardous short term degradation products are not likely. However, long term degradation products may
Products of Biodegradation
arise.
The products of degradation are less toxic than the product itself.
Toxicity of the Products
of Biodegradation
Not available.
Special Remarks on the
Products of Biodegradation
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p-Anisidine
Section 13. Disposal Considerations
Waste Disposal
Section 14. Transport Information
DOT Classification Not a DOT controlled material (United States).
Not applicable.
Identification
Not applicable.
Special Provisions for
Transport
DOT (Pictograms)
Section 15. Other Regulatory Information and Pictograms
Pennsylvania RTK: p-Anisidine
Federal and State
Florida: p-Anisidine
Regulations
Minnesota: p-Anisidine
Massachusetts RTK: p-Anisidine
New Jersey: p-Anisidine
TSCA 8(b) inventory: p-Anisidine
TSCA 8(d) H and S data reporting: p-Anisidine: June 1999
SARA 313 toxic chemical notification and release reporting: p-Anisidine
California
Proposition 65
Warnings
Other Regulations OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.
Not controlled under WHMIS (Canada).
Other Classifications WHMIS (Canada)
DSCL (EEC) R26/27/28- Very toxic by inhalation, in
contact with skin and if swallowed.
R33- Danger of cumulative effects.
R36/37/38- Irritating to eyes,
respiratory system and skin.
Health Hazard
HMIS (U.S.A.) 2 National Fire Protection Flammability
1
Association (U.S.A.)
Fire Hazard
1
0
2
Health Reactivity
Reactivity
0
Specific hazard
Personal Protection
E
WHMIS (Canada)
(Pictograms)
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p-Anisidine
DSCL (Europe)
(Pictograms)
TDG (Canada)
(Pictograms)
ADR (Europe)
(Pictograms)
Protective Equipment Gloves.
Lab coat.
Dust respirator. Be sure to use an
approved/certified respirator or
equivalent.
Safety glasses.
Section 16. Other Information
A5530
MSDS Code
Not available.
References
Other Special Not available.
Considerations
Validated by Sonia Owen on 8/11/2006. Verified by Sonia Owen.
Printed 9/11/2006.
CALL (310) 516-8000
Notice to Reader
All chemicals may pose unknown hazards and should be used with caution. This Material Safety Data Sheet (MSDS) applies only to the material as packaged. If this product is
combined with other materials, deteriorates, or becomes contaminated, it may pose hazards not mentioned in this MSDS. It shall be the user's responsibility to develop proper
methods of handling and personal protection based on the actual conditions of use. While this MSDS is based on technical data judged to be reliable, Spectrum Quality Products,
Inc. assumes no responsibility for the completeness or accuracy of the information contained herein.
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