MATERIAL SAFETY DATA SHEET
SikaSil庐 GP
HMIS
HEALTH 2
FLAMMABILITY 1
REACTIVITY 0
C
PERSONAL PROTECTION
1. Product And Company Identification
Supplier Manufacturer
Sika Corporation Accumetric, LLC
30800 Stephenson Highway 350 Ring Road
Madison Heights, MI 48071 U.S.A. Elizabethtown, KY 42701 USA
Company Contact: EHS Department
Telephone Number: 201-933-8800 Telephone Number: 270-769-3385
FAX Number: 201-933-9379
Web Site: www.sikaindustry.com
Supplier Emergency Contacts & Phone Number Manufacturer Emergency Contacts & Phone Number
CHEMTREC: 800-424-9300 CHEMTREC: 800-424-9300
INTERNATIONAL: 703-527-3887
Issue Date: 08/08/2006
Product Name: SikaSil庐 GP
CAS Number: Not Established
MSDS Number: 3962
Product/Material Uses
Sealant & Caulk
2. Composition/Information On Ingredients
Ingredient CAS Percent Of
Name Number Total Weight
ETHYLTRIACETOXYSILANE 17689-77-9 1-5
HYDROTREATED HEAVY PETROLEUM NAPTHA 64742-48-9 15 - 40
HYDROTREATED MIDDLE PETROLEUM DISTILLATES 64742-46-7 15 - 40
METHYLTRIACETOXYSILANE 4253-34-3 1-5
3. Hazards Identification
Primary Routes(s) Of Entry
Eye contact, ingestion, inhalation, skin contact
Eye Hazards
Direct contact may cause moderate irritation.
Skin Hazards
Limited exposure may cause moderate irritation. Repeated or prolonged contact may cause defatting and drying
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3. Hazards Identification - Continued
Skin Hazards - Continued
of skin which may result in skin irritation and dermatitis.May cause slight skin irritation.
Ingestion Hazards
May cause vomiting. Aspiration of liquid while vomiting may injure lungs seriously. No known effects associated
with repeated or prolonged exposure.
Inhalation Hazards
Vapor may irritate nose and throat. Overexposure by inhalation may cause drowsiness, dizziness, confusion or
loss of coordination. Repeated or prolonged exposure may cause injury to the nervous system.
Signs And Symptoms
No known applicable infomration.
Conditions Aggravated By Exposure
No known applicable information.
4. First Aid Measures
Eye
In case of contact, hold eyelids apart and immediately flush eyes with plenty of tepid water for at least 15 minutes.
Get medical attention immediately if irritation develops and persists. Remove contact lenses, if worn.
Skin
In case of contact, immediately flush skin with soap and plenty of tepid water for at least 15 minutes. Get medical
attention immediately if irritation (redness, rash, blistering) develops and persists.
Ingestion
Seek medical attention immediately. Induce vomiting if directed to do so by medical personnel. Never give
anything by mouth to an unconscious victim.
Inhalation
If inhaled, remove to fresh air. If symptoms persist, obtain appropriate medial attention.
Note To Physician
Treat according to person's condition and specifics of exposure.
5. Fire Fighting Measures
Flash Point: Not Applicable 掳F
Lower Explosive Limit: Not Determined
Upper Explosive Limit: Not Determined
Extinguishing Media
On large fires use dry chemical, foam, or water spray. On small fires use carbon dioxide, dry chemical, or water
spray. Water can be used to cool fire exposed containers.
Fire Fighting Instructions
In the event of a fire, firefighters should wear full protective clothing and NIOSH-approved self-contained
breathing apparatus with a full facepiece operated in the pressure demand or other positive pressure mode.
Determine the need to evacuate or isolate area according to your local emergency plan. Use water spray to keep
fire exposed containers cool.
6. Accidental Release Measures
Determine whether to evacuate or isolate the area according to your local emergency plan. Observe all personal
protection equipment recommendations described in Sections 5 and 8.
For large spills, provide diking or other appropriate containment to keep material from spreading. If diked material can
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6. Accidental Release Measures - Continued
be pumped, store recovered material in appropriate container. For small spills, wipe up or scrape up and contain for
salvage or disposal. Clean area as appropriate since spilled material, even in small quantities, may present a slip
hazard. Final cleaning may require the use of steam, solvents or detergent. Dispose of saturated absorbent or cleaning
material appropriately, since spontaneous heating may occur.
Local, state and federal laws and regulations may apply to releases and disposal of this material, as well as those
materials and items employed in the cleanup of releases. You will need to determine which federal, state and local laws
and regulations are applicable. Sections 13 and 15 of this MSDS provide information regarding certain federal and state
requirements.
7. Handling And Storage
Handling And Storage Precautions
Keep out of reach of children. Not for internal consumption.
Handling Precautions
Use adequate ventilation. Product evolves acetic acid when exposed to water or humid air. Provide ventilation
during use to control acetic acid within exposure guidelines or use respiratory protection. Avoid eye contact.
Avoid skin contact. Avoid breathing vapors, mist, dust or fumes. Keep container closed. Do not take internally.
Storage Precautions
Use reasonable care and store away from oxidizing materials. Keep containers closed and store away from
water and moisture.
Work/Hygienic Practices
Wash thoroughly after handling.
8. Exposure Controls/Personal Protection
Engineering Controls
Acetic Acid is formed upon contact with water or humid air. Provide adequate ventilation to control exposures
within guidelines of OSHA PEL: TWA 10 ppm and ACGIH TLV: TWA 10ppm, STEL 15ppm.
Eye/Face Protection
Safety goggles or glasses with side shields are recommended.
Skin Protection
Chemical-resistant butyl rubber protective gloves. Lab coat or other work clothing to prevent skin exposure (Long
sleeve shirt and long pants). Launder before reuse.
Respiratory Protection
General and local exhaust is recommended to maintain vapor exposures below recommended limits. Where
concentrations are above recommended limits as determined by air sampling or are unknown, appropriate
respiratory protection should be worn. Follow OSHA Respirator Regulations (28 CFR 1910.134) and use
NIOSH/MSHA approved respirators.
Special precautions to be taken in the event of a spill: Protection provided by air purifying respirators against
exposure to any hazardous chemical is limited. Use a positive pressure air supplied respirator if there is any
potential for uncontrolled release, exposure levels are unknown or any other circumstance where air purifying
respirators may not provide adequate protection.
Other/General Protection
Avoid contact with eyes and skin. Avoid breathing vapor, mist, dust or fumes. Keep container closed. Do not
take internally. Use reasonable care.
Ingredient(s) - Exposure Limits
HYDROTREATED MIDDLE PETROLEUM DISTILLATES
(Mineral Oil, Mist)
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8. Exposure Controls/Personal Protection - Continued
Ingredient(s) - Exposure Limits - Continued
ACGIH TLV-STEL 10 mg/m3
ACGIH TLV-TWA 5 mg/m3
OSHA PEL-TWA 5 mg/m3
ACETIC ACID
ACGIH TLV-TWA: 10 ppm
ACGIH TLV-STEL: 15 ppm
OSHA PEL-TWA: 10 ppm
Note: These precautions are for room temperature handling. Use at elevated temperatures or aerosol/spray
applications may require added precautions. For further information regarding aerosol inhalation toxicity, please refer to
the guidance document regarding the use of silicone-based materials in aerosol application that has been developed by
the silicone industry (www.SEHSC.com).
9. Physical And Chemical Properties
Appearance
Paste, various colors
Odor
Acetic acid odor
Chemical Type: Mixture
Physical State: Solid
Melting Point: Not Determined 掳F
Boiling Point: Not Determined 掳F
Specific Gravity: 0.96
Percent VOCs: Not Determined
Vapor Density: Not Determined
Solubility: Not Determined
Viscosity: Not Determined
10. Stability And Reactivity
Stability: Stable
Hazardous Polymerization: Will not occur
Conditions To Avoid (Stability)
None known
Incompatible Materials
Oxidizing material can cause a reaction. Water, moisture or humid air can cause hazardous vapors to form.
Hazardous Decomposition Products
Thermal breakdown of this product during fire or very high heat conditions may evolve the following hazardous
decomposition products: Carbon oxides and traces of incompletely burned carbon compounds. Formaldehyde.
Silicon Dioxide.
11. Toxicological Information
No known applicable information.
12. Ecological Information
Complete information is not yet available.
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13. Disposal Considerations
We make no guarantee or warranty of any kind that the use or disposal of this product complies with all local, state, or
federal laws. It is also the obligation of each user of the product mentioned herein to determine and comply with the
requirements of all applicable statutes.
This product is not known to be regulated under RCRA regulations. Disposal of unused portions of this product are
process waste containing this product should be done only after a careful evaluation and in complianc with all federal,
local and state laws.
14. Transport Information
Proper Shipping Name
Not regulated by the USDOT
15. Regulatory Information
U.S. Regulatory Information
All ingredients of this product are listed or are excluded from listing under the U.S. Toxic Substances Control Act
(TSCA) Chemical Substance Inventory.
SARA Hazard Classes
Acute Health Hazard
Chronic Health Hazard
SARA Section 313 Notification
This product does not contain any ingredients regulated under Section 313 of the Emergency Planning and
Community Right-To-Know Act of 1986 or 40 CFR 372.
16. Other Information
HMIS Rating
H eal th: 2
F i re : 1
Reactivity: 0
Personal Protection: C
Revision/Preparer Information
MSDS Preparer: EHS Department
MSDS Preparer Phone Number: 201-933-8800
Disclaimer
The information contained in this Material Safety Data Sheet applies only to the actual Sika Corporation ("Sika")
product identified and described herein. This information is not intended to address, nor does it address the use
or application of the identified Sika product in combination with any other material, product or process. All of the
information set forth herein is based on technical data regarding the identified product that Sika believes to be
reliable as of the date hereof. Prior to each use of any Sika product, the user must always read and follow the
warnings and instructions on the product's current Technical Data Sheet, product label and Material Safety Data
Sheet for each Sika product, which are available at web site and/or telephone number listed in Section 1 of this
MSDS.
SIKA MAKES NO WARRANTIES EXPRESS OR IMPLIED AND ASSUMES NO LIABILITY ARISING FROM THIS
INFORMATION OR ITS USE. SIKA SHALL NOT BE LIABLE UNDER ANY LEGAL THEORY FOR SPECIAL OR
CONSEQUENTIAL DAMAGES AND SHALL NOT BE RESPONSIBLE FOR THE USE OF THIS PRODUCT IN A
MANNER TO INFRINGE ON ANY PATENT OR ANY OTHER INTELLECTUAL PROPERTY RIGHTS HELD BY
OTHERS.
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Disclaimer - Continued
All sales of Sika products are subject to its current terms and conditions of sale available at www.sikacorp.com or
201-933-8800.
Sika Corporation
Printed Using MSDS Generator鈩? 2000
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