Material Safety Data Sheet
HMIS
NFPA Personal Protective Equipment
Health Hazard
3
3 Fire Hazard
3
3 1
Reactivity
0 See Section 15.
Section 1. Chemical Product and Company Identification Page Number: 1
Catalog
3-Bromopropene B1159
Common Name/
Number(s).
Trade Name
106-95-6
CAS#
Manufacturer UC7090000
RTECS
SPECTRUM QUALITY PRODUCTS INC.
14422 S. SAN PEDRO STREET TSCA 8(b) inventory:
TSCA
3-Bromopropene
GARDENA, CA 90248
Not available.
Commercial Name(s) Not applicable.
CI#
Bromoallylene
Synonym
IN CASE OF EMERGENCY
3-Bromopropene
Chemical Name CHEMTREC (24hr) 800-424-9300
Aliphatic halogenated. (F,Cl,Br,I or At) (Aliphatic.) CALL (310) 516-8000
Chemical Family
H2C=CHCH2Br
Chemical Formula
SPECTRUM QUALITY PRODUCTS INC.
Supplier
14422 S. SAN PEDRO STREET
GARDENA, CA 90248
Section 2.Composition and Information on Ingredients
Exposure Limits
3
STEL (mg/m3) CEIL (mg/m3)
Name CAS # TWA (mg/m ) % by Weight
1) {3-}Bromopropene 106-95-6 100
3-Bromopropene:
Toxicological Data
ORAL (LD50): Acute: 120 mg/kg [Rat].
on Ingredients
Section 3. Hazards Identification
Potential Acute Health Effects Very hazardous in case of eye contact (irritant), of ingestion. Hazardous in case of skin contact (irritant). Slightly
hazardous in case of inhalation. Severe over-exposure can result in death. Inflammation of the eye is
characterized by redness, watering, and itching.
Very hazardous in case of eye contact (irritant), of ingestion.
Potential Chronic Health
Hazardous in case of skin contact (irritant).
Effects
Slightly hazardous in case of inhalation.
CARCINOGENIC EFFECTS: Not available.
MUTAGENIC EFFECTS: Not available.
TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available.
The substance is toxic to kidneys, liver.
Repeated or prolonged exposure to the substance can produce target organs damage. Repeated exposure to a
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3-Bromopropene
highly toxic material may produce general deterioration of health by an accumulation in one or many human
organs.
Section 4. First Aid Measures
Eye Contact Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at
least 15 minutes. Get medical attention immediately.
Skin Contact In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove
contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get
medical attention.
Serious Skin Contact Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate
medical attention.
Inhalation If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get
medical attention.
Serious Inhalation Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or
waistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth
resuscitation. WARNING: It may be hazardous to the person providing aid to give mouth-to-mouth resuscitation
when the inhaled material is toxic, infectious or corrosive. Seek medical attention.
Ingestion If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by
mouth to an unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical
attention immediately.
Serious Ingestion Not available.
Section 5. Fire and Explosion Data
Flammable.
Flammability of the Product
295掳C (563掳F)
Auto-Ignition Temperature
CLOSED CUP: -1.1掳C (30掳F).
Flash Points
LOWER: 4.4% UPPER: 7.3%
Flammable Limits
These products are carbon oxides (CO, CO2).
Products of Combustion
Highly flammable in presence of open flames and sparks, of heat, of oxidizing materials.
Fire Hazards in Presence of
Various Substances
Explosion Hazards in Presence Risks of explosion of the product in presence of mechanical impact: Not available.
Risks of explosion of the product in presence of static discharge: Not available.
of Various Substances
Flammable liquid, insoluble in water.
Fire Fighting Media
SMALL FIRE: Use DRY chemical powder.
and Instructions
LARGE FIRE: Use water spray or fog. Never direct a water jet in the container in order to prevent any splashing
of the product which could cause spreading of the fire.
Vapor may travel considerable distance to source of ignition and flash back. When heated to decomposition it
Special Remarks on
emits toxic fumes.
Fire Hazards
Special Remarks on Explosion Not available.
Hazards
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3-Bromopropene
Section 6. Accidental Release Measures
Small Spill Absorb with an inert material and put the spilled material in an appropriate waste disposal.
Large Spill Toxic flammable liquid, insoluble or very slightly soluble in water. Poisonous liquid.
Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. Absorb with DRY earth,
sand or other non-combustible material. Do not get water inside container. Do not touch spilled material. Use
water spray to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Call for
assistance on disposal.
Section 7. Handling and Storage
Keep locked up.. Keep away from heat. Keep away from sources of ignition. Ground all equipment containing
Precautions
material. Do not ingest. Do not breathe gas/fumes/ vapor/spray. If ingested, seek medical advice immediately
and show the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as
alkalis.
Store in a segregated and approved area. Keep container in a cool, well-ventilated area. Keep container tightly
Storage
closed and sealed until ready for use. Avoid all possible sources of ignition (spark or flame).
Section 8. Exposure Controls/Personal Protection
Engineering Controls Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their
respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the
work-station location.
Personal Protection Splash goggles. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent.
Gloves.
Personal Protection in Case of Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be
a Large Spill used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist
BEFORE handling this product.
Exposure Limits Not available.
Section 9. Physical and Chemical Properties
Physical state and appearance Liquid. (Liquid.) Irritant. Unpleasant.
Odor
Not available.
Taste
120.98 g/mole
Molecular Weight
Colorless to light yellow.
Color
Not applicable.
pH (1% soln/water)
70.5掳C (158.9掳F)
Boiling Point
-119掳C (-182.2掳F)
Melting Point
Not available.
Critical Temperature
1.4 (Water = 1)
Specific Gravity
14 kPa (@ 20掳C)
Vapor Pressure
4.17 (Air = 1)
Vapor Density
Not available.
Volatility
Not available.
Odor Threshold
Not available.
Water/Oil Dist. Coeff.
Not available.
Ionicity (in Water)
See solubility in water, methanol, diethyl ether.
Dispersion Properties
Soluble in methanol, diethyl ether.
Solubility
Partially soluble in cold water.
Insoluble in hot water.
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3-Bromopropene
Section 10. Stability and Reactivity Data
The product is stable.
Stability
Not available.
Instability Temperature
Not available.
Conditions of Instability
Reactive with alkalis.
Incompatibility with various
Slightly reactive to reactive with oxidizing agents.
substances
Non-corrosive in presence of glass.
Corrosivity
Not available.
Special Remarks on
Reactivity
Not available.
Special Remarks on
Corrosivity
Will not occur.
Polymerization
Section 11. Toxicological Information
Routes of Entry Eye contact. Ingestion.
Toxicity to Animals WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE.
Acute oral toxicity (LD50): 120 mg/kg [Rat].
Acute toxicity of the vapor (LC50): 5000 1 hours [Rat].
Chronic Effects on Humans Causes damage to the following organs: kidneys, liver.
Other Toxic Effects on Very hazardous in case of ingestion.
Humans Hazardous in case of skin contact (irritant).
Slightly hazardous in case of inhalation.
Special Remarks on Not available.
Toxicity to Animals
Special Remarks on Not available.
Chronic Effects on Humans
Special Remarks on other Material is irritating to mucous membranes and upper respiratory tract.
Toxic Effects on Humans
Section 12. Ecological Information
Not available.
Ecotoxicity
Not available.
BOD5 and COD
Possibly hazardous short term degradation products are not likely. However, long term degradation products may
Products of Biodegradation
arise.
The products of degradation are as toxic as the original product.
Toxicity of the Products
of Biodegradation
Not available.
Special Remarks on the
Products of Biodegradation
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3-Bromopropene
Section 13. Disposal Considerations
Waste Disposal
Section 14. Transport Information
DOT Classification CLASS 3: Flammable liquid.
: Allyl bromide UNNA: UN1099 PG: I
Identification
Marine Pollutant
Special Provisions for
Transport
DOT (Pictograms)
Section 15. Other Regulatory Information and Pictograms
Pennsylvania RTK: 3-Bromopropene
Federal and State
Massachusetts RTK: 3-Bromopropene
Regulations
TSCA 8(b) inventory: 3-Bromopropene
California
Proposition 65
Warnings
Other Regulations OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
CLASS B-2: Flammable liquid with a flash point lower than 37.8掳C (100掳F).
Other Classifications WHMIS (Canada)
CLASS D-1A: Material causing immediate and serious toxic effects (VERY TOXIC).
CLASS D-2B: Material causing other toxic effects (TOXIC).
DSCL (EEC) R11- Highly flammable.
R20- Harmful by inhalation.
R25- Toxic if swallowed.
R38- Irritating to skin.
R41- Risk of serious damage to eyes.
Health Hazard
HMIS (U.S.A.) 3 National Fire Protection Flammability
3
Association (U.S.A.)
Fire Hazard
3
1
3
Health Reactivity
Reactivity
0
Specific hazard
Personal Protection
h
WHMIS (Canada)
(Pictograms)
DSCL (Europe)
(Pictograms)
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Page Number: 6
3-Bromopropene
TDG (Canada)
(Pictograms)
ADR (Europe)
(Pictograms)
Protective Equipment Gloves.
Lab coat.
Vapor respirator. Be sure to use an
approved/certified respirator or
equivalent. Wear appropriate respirator
when ventilation is inadequate.
Splash goggles.
Section 16. Other Information
B4000
MSDS Code
-Hawley, G.G.. The Condensed Chemical Dictionary, 11e ed., New York N.Y., Van Nostrand Reinold, 1987.
References
-SAX, N.I. Dangerous Properties of Indutrial Materials. Toronto, Van Nostrand Reinold, 6e ed. 1984.
-The Sigma-Aldrich Library of Chemical Safety Data, Edition II.
-Guide de la loi et du r猫glement sur le transport des marchandises dangeureuses au canada. Centre de conformit茅
internatinal Lt茅e. 1986.
Other Special Not available.
Considerations
Validated by Sonia Owen on 8/11/2006. Verified by Sonia Owen.
Printed 9/11/2006.
CALL (310) 516-8000
Notice to Reader
All chemicals may pose unknown hazards and should be used with caution. This Material Safety Data Sheet (MSDS) applies only to the material as packaged. If this product is
combined with other materials, deteriorates, or becomes contaminated, it may pose hazards not mentioned in this MSDS. It shall be the user's responsibility to develop proper
methods of handling and personal protection based on the actual conditions of use. While this MSDS is based on technical data judged to be reliable, Spectrum Quality Products,
Inc. assumes no responsibility for the completeness or accuracy of the information contained herein.
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