Material Safety Data Sheet
HMIS
NFPA Personal Protective Equipment
Health Hazard
2
3 Fire Hazard
3
2 0
Reactivity
0 See Section 15.
Section 1. Chemical Product and Company Identification Page Number: 1
Catalog
1-Iodobutane I1029, I2039
Common Name/
Number(s).
Trade Name
542-69-8
CAS#
Manufacturer EK4400000
RTECS
SPECTRUM LABORATORY PRODUCTS INC.
14422 S. SAN PEDRO STREET TSCA 8(b) inventory:
TSCA
1-Iodobutane
GARDENA, CA 90248
Not available.
Commercial Name(s) Not available.
CI#
Butyl Iodide; n-Butyl Iodide; 1-Iodobutane, 98%, stabililzed over
Synonym
IN CASE OF EMERGENCY
copper
CHEMTREC (24hr) 800-424-9300
1-Iodobutane
Chemical Name
Not available. CALL (310) 516-8000
Chemical Family
C4-H9-I
Chemical Formula
SPECTRUM LABORATORY PRODUCTS INC.
Supplier
14422 S. SAN PEDRO STREET
GARDENA, CA 90248
Section 2.Composition and Information on Ingredients
Exposure Limits
3
STEL (mg/m3) CEIL (mg/m3)
Name CAS # TWA (mg/m ) % by Weight
1) {1}-Iodobutane 542-69-8 100
1-Iodobutane:
Toxicological Data
Acute: 6100 mg/m3 4 hours [Rat].
VAPOR (LC50):
on Ingredients
Section 3. Hazards Identification
Potential Acute Health Effects Hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation (lung irritant).
CARCINOGENIC EFFECTS: Not available.
Potential Chronic Health
MUTAGENIC EFFECTS: Not available.
Effects
TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available.
Repeated or prolonged exposure is not known to aggravate medical condition.
Continued on Next Page
Page Number: 2
1-Iodobutane
Section 4. First Aid Measures
Eye Contact Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at
least 15 minutes. Get medical attention.
Skin Contact In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove
contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get
medical attention.
Serious Skin Contact Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate
medical attention.
Inhalation If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get
medical attention.
Serious Inhalation Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or
waistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth
resuscitation. WARNING: It may be hazardous to the person providing aid to give mouth-to-mouth resuscitation
when the inhaled material is toxic, infectious or corrosive. Seek medical attention.
Ingestion Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight
clothing such as a collar, tie, belt or waistband.
Serious Ingestion Not available.
Section 5. Fire and Explosion Data
Flammable.
Flammability of the Product
Not available.
Auto-Ignition Temperature
CLOSED CUP: 33掳C (91.4掳F).
Flash Points
Not available.
Flammable Limits
These products are carbon oxides (CO, CO2), hydrogen iodide, iodine.
Products of Combustion
Highly flammable in presence of open flames and sparks, of heat.
Fire Hazards in Presence of
Various Substances
Explosion Hazards in Presence Risks of explosion of the product in presence of mechanical impact: Not available.
Risks of explosion of the product in presence of static discharge: Not available.
of Various Substances
Flammable liquid, insoluble in water.
Fire Fighting Media
SMALL FIRE: Use DRY chemical powder.
and Instructions
LARGE FIRE: Use water spray or fog. Never direct a water jet in the container in order to prevent any splashing
of the product which could cause spreading of the fire. Cool containing vessels with water jet in order to prevent
pressure build-up, autoignition or explosion.
Not available.
Special Remarks on
Fire Hazards
Special Remarks on Explosion Not available.
Hazards
Section 6. Accidental Release Measures
Small Spill Absorb with an inert material and put the spilled material in an appropriate waste disposal.
Large Spill Toxic flammable liquid, insoluble or very slightly soluble in water.
Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. Absorb with DRY earth,
sand or other non-combustible material. Do not get water inside container. Do not touch spilled material. Prevent
entry into sewers, basements or confined areas; dike if needed. Call for assistance on disposal.
Continued on Next Page
Page Number: 3
1-Iodobutane
Section 7. Handling and Storage
Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not
Precautions
ingest. Do not breathe gas/fumes/ vapor/spray. Wear suitable protective clothing. In case of insufficient
ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the
container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as oxidizing agents,
alkalis.
Light Sensitive. Store in light-resistant container. Store in a segregated and approved area. Keep container in a
Storage
cool, well-ventilated area. Keep container tightly closed and sealed until ready for use. Avoid all possible sources
of ignition (spark or flame). Do not store above 23掳C (73.4掳F).
Section 8. Exposure Controls/Personal Protection
Engineering Controls Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their
respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the
work-station location.
Personal Protection Splash goggles. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent.
Gloves.
Personal Protection in Case of Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be
a Large Spill used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist
BEFORE handling this product.
Exposure Limits Not available.
Section 9. Physical and Chemical Properties
Physical state and appearance Liquid. Not available.
Odor
Not available.
Taste
184.03 g/mole
Molecular Weight
Colorless.
Color
Not applicable.
pH (1% soln/water)
130.5掳C (266.9掳F)
Boiling Point
-103掳C (-153.4掳F)
Melting Point
Not available.
Critical Temperature
1.67 (Water = 1)
Specific Gravity
Not available.
Vapor Pressure
Not available.
Vapor Density
Not available.
Volatility
Not available.
Odor Threshold
Not available.
Water/Oil Dist. Coeff.
Not available.
Ionicity (in Water)
Not available.
Dispersion Properties
Insoluble in cold water, hot water.
Solubility
Continued on Next Page
Page Number: 4
1-Iodobutane
Section 10. Stability and Reactivity Data
The product is stable.
Stability
Not available.
Instability Temperature
Incompatible materials (strong oxidizing agents, strong bases), light, ignition sources, excess heat
Conditions of Instability
Reactive with oxidizing agents, alkalis.
Incompatibility with various
substances
Not available.
Corrosivity
Light Sensitive. Also incompatible with strong oxiders, and strong bases
Special Remarks on
Reactivity
Not available.
Special Remarks on
Corrosivity
Will not occur.
Polymerization
Section 11. Toxicological Information
Routes of Entry Absorbed through skin. Eye contact.
Toxicity to Animals WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE.
Acute toxicity of the vapor (LC50): 6100 mg/m3 4 hours [Rat].
Chronic Effects on Humans Not available.
Other Toxic Effects on Hazardous in case of skin contact (irritant), of ingestion, of inhalation (lung irritant).
Humans
Special Remarks on Not available.
Toxicity to Animals
Special Remarks on Not available.
Chronic Effects on Humans
Special Remarks on other Acute Potential Health Effects:
Toxic Effects on Humans Skin: May cause skin irritation.
Eye: May cause eye irritation.
Ingestion: May cause irritation of the digestive tract. The toxicological properties of the substance have not been
fully investigated.
Inhalation: May cause respiratory tract irritation. The toxicological properties of this substance have not been fully
investigated. May be harmful if inhaled.
May cause tumorogenic effects (tumors) of the thorax or respiratory tract (lungs) based on animal data.
Chronic Potential Health Effects: no information found.
Section 12. Ecological Information
Not available.
Ecotoxicity
Not available.
BOD5 and COD
Possibly hazardous short term degradation products are not likely. However, long term degradation products may
Products of Biodegradation
arise.
The products of degradation are less toxic than the product itself.
Toxicity of the Products
of Biodegradation
Not available.
Special Remarks on the
Products of Biodegradation
Continued on Next Page
Page Number: 5
1-Iodobutane
Section 13. Disposal Considerations
Waste Disposal
Section 14. Transport Information
DOT Classification CLASS 3: Flammable liquid.
: Flammable Liquid, n.o.s. (1-Iodobutane) UNNA: 1993 PG: III
Identification
Not available.
Special Provisions for
Transport
DOT (Pictograms)
Section 15. Other Regulatory Information and Pictograms
TSCA 8(b) inventory: 1-Iodobutane
Federal and State
Regulations
California
Proposition 65
Warnings
Other Regulations OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.
CLASS B-2: Flammable liquid with a flash point lower than 37.8掳C (100掳F).
Other Classifications WHMIS (Canada)
CLASS D-2B: Material causing other toxic effects (TOXIC).
DSCL (EEC) R10- Flammable. S9- Keep container in a well-ventilated place.
R20- Harmful by inhalation. S16- Keep away from sources of ignition - No
R36/37/38- Irritating to eyes, smoking.
respiratory system and skin. S29- Do not empty into drains.
Health Hazard
HMIS (U.S.A.) 2 National Fire Protection Flammability
3
Association (U.S.A.)
Fire Hazard
3
0
2
Health Reactivity
Reactivity
0
Specific hazard
Personal Protection
h
WHMIS (Canada)
(Pictograms)
DSCL (Europe)
(Pictograms)
TDG (Canada)
(Pictograms)
3
Continued on Next Page
Page Number: 6
1-Iodobutane
ADR (Europe)
(Pictograms)
Protective Equipment Gloves.
Lab coat.
Vapor respirator. Be sure to use an
approved/certified respirator or
equivalent. Wear appropriate respirator
when ventilation is inadequate.
Splash goggles.
Section 16. Other Information
3410I
MSDS Code
Not available.
References
Other Special Not available.
Considerations
Validated by Sonia Owen on 8/11/2006. Verified by Sonia Owen.
Printed 9/12/2006.
CALL (310) 516-8000
Notice to Reader
All chemicals may pose unknown hazards and should be used with caution. This Material Safety Data Sheet (MSDS) applies only to the material as packaged. If this product is
combined with other materials, deteriorates, or becomes contaminated, it may pose hazards not mentioned in this MSDS. It shall be the user's responsibility to develop proper
methods of handling and personal protection based on the actual conditions of use. While this MSDS is based on technical data judged to be reliable, Spectrum Quality Products,
Inc. assumes no responsibility for the completeness or accuracy of the information contained herein.
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