MATERIAL SAFETY DATA SHEET
SECTION 1: CHEMICAL PRODUCT IDENTIFICATION
Manufacturer/Distributor : Kobo Products, Inc.
Address : 690 Montrose Avenue
South Plainfield, NJ 07080
Emergency Telephone # : (908) 757-0033
Facsimile Number : (908) 757-0905
Trade Name : BTD-SW
INCI : Titanium Dioxide (And) PEG-8 Methyl Ether Triethoxysilane
Chemical Name : Titanium Dioxide (And) PEG-8 Methyl Ether Triethoxysilane
Material Uses : Pigment, component in personal care products.
Chemical Family : Inorganic Pigment
SECTION 2: COMPOSITION / INFORMATION ON INGREDIENTS
Ingredient CAS # EINECS # Symbol(s) EU Phrases
Titanium Dioxide 13463-67-7 236-675-5 S22/25/36/37
PEG-8 Methyl Ether Triethoxysilane
SECTION 3: HAZARD IDENTIFICATION
Physical State and Appearance: Solid. (odorless, white powder)
Emergency Overview: May cause respiratory tract, eye and skin irritation.
Routes of Entry: Eye contact. Inhalation. Ingestion (not anticipated).
Potential Acute Health Effects
Eyes:May cause eye irritation. Symptoms include itching and redness after contact.
Skin: May cause mild skin irritation. Symptoms include itching and redness after contact.
Inhalation: May cause respiratory tract irritation. Symptoms include: coughing, wheezing or shortness
of breath when inhaled.
Ingestion:Not an intended route of exposure. May be hazardous in case of ingestion. Symptoms include
gastrointestinal tract upset and diarrhea.
Potential Chronic Health Effects
Additional information See Toxicological information (section 11)
Medical Conditions Overexposure: Aggravated by Repeated or prolonged inhalation of any dust particulate may aggravate
respiratory medical conditions.
SECTION 4: FIRST AID MEASURES
Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. If symptoms persist, seek medical attention.
Skin Contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing
contaminated clothing and shoes. Wash contaminated clothing before reusing. Thoroughly clean shoes
before reuse. If symptoms develop, seek medical attention.
Inhalation: If inhaled, remove to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial
respiration. If symptoms persist, seek medical attention.
Ingestion: Do not ingest. If this material is swallowed, call a physician immediately. Do NOT induce vomiting unless
directed to do so by medical personnel. Never give anything by mouth to an unconscious person.
SECTION 5: FIRE FIGHTING MEASURES
Flammability: Non-flammable
Fire Fighting Media And Instructions: In case of fire, use water spray (fog), foam, dry chemical, or CO2
Protective Clothing (fire): Wear self-contained breathing apparatus and full protective clothing.
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KOBO Products, Inc.
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SECTION 6: ACCIDENTAL RELEASE MEASURES
Small Spill and Leak Use a tool to scoop up solid or absorbed material and place into appropriate labeled waste
container. Finish cleaning by spreading water on the contaminated surface and dispose of
according to local and regional regulatory requirements.
Large Spill and Leak Use appropriate tools to put the spill material into a labeled waste disposal container. Finish
cleaning by spreading water on the contaminated surface and dispose of according to local and
regional regulatory requirements. Check TLV in section 8 of MSDS and with local authorities.
Spill Kit information No specific spill kit required for this product.
SECTION 7: HANDLING AND STORAGE
Handling : Avoid generating dust. Avoid breathing dust. Use only with adequate ventilation. Avoid prolonged or
repeated contact with skin. Avoid contact with eyes. Keep container closed. Wash thoroughly after
handling.
Storage : Keep container dry. Keep containers sealed until ready for use.
SECTION 8: EXPOSURE CONTROL / PERSONAL PROTECTION
Exposure Levels: OSHA ACGIH
Component TWA PEL TWA TLV
15 mg/m3 10 mg/m3
TiO2
Personal Protection:
Eye: Safety glasses with side shields or goggles
Body: Lab coat
Respiratory: Use NIOSH/MSHA approved air-purifying respirator as needed to control exposure.
Hand: Recommended: Gloves
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Boiling Point (掳C) : N/A Percent Volatile By Vol. (%) : N/A
Freezing Point (掳C) : N/A Vapor Density (Air=1) : N/A
Melting Point (掳C) : > 1000 Evaporation Rate (Buac=1) : N/A
Vapor Pressure (mm hg) : N/A Solubility In Water : Insoluble
Bulk Density (g/cbi.) : N/A Appearance & Odor : Free Flowing white Powder. No Odor
SECTION 10: STABILITY AND REACTIVITY
Stable: Stable
Hazardous Polymerization: None
Incompatibility: Strong acids and strong oxidizing agents.
Hazardous Decomposition Products: Incomplete combustion can produce carbon monoxide, carbon dioxide and nitrous dioxide.
SECTION 11: TOXICOLOGICAL INFORMATION
Titanium Dioxide*
Skin Irritation : Dermal LD50 > 10 g/kg (Rabbit)
Eye Irritation : No data
Acute Oral Toxicity : Non-toxic, LD 50 > 25 g/kg (rat)
Inhalation LC 50 : >6.82 mg/L (4 hour)
*: Trochimowicz. et. Al., J. Appl. Tox. 8, 383-385 (1998)
Chronic Effects on CARCINOGENIC EFFECTS: Classified None. By NIOSH [Titanium Dioxide]. Classified A4 (not
Humans classifiable for human or animal.) by ACGIH, 3 (not classifiable for human.) by IARC [Titanium
Dioxide]. Classified None.
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MUTAGENIC EFFECTS: Not available.
TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available.
Repeated or prolonged exposure to the substance at concentrations above exposure limits may cause
respiratory damage.
Target Organs: eyes, lungs, skin.
Acute Effects on Humans May cause skin, eye, and respiratory irritation.
Sensitization Repeated or prolonged exposure to the substance at concentrations above the exposure limits may cause
respiratory tract and lung sensitization.
Carcinogenic Effects This material is not known to cause cancer in animals or humans.
SECTION 12: ECOLOGICAL INFORMATION
Toxicity of the Products of Biodegradation: N/A
German Regulations:
Water pollutant class: nwg (own classification)
SECTION 13: DISPOSAL CONSIDERATIONS
EPA Waste Number Non-hazardous waste
Treatment Dispose of according to all federal, state and local regulations.
SECTION 14: TRANSPORT INFORMATION
DOT Classification Not regulated.
TDG Classification Not regulated.
IMO/IMDG Classification Not regulated.
ICAO/IATA Not regulated.
Classification
SECTION 15: REGULATORY INFORMATION
U.S. Federal Regulations Clean Water Act (CWA) 307: No products were found.
Clean Water Act (CWA) 311: No products were found.
Clean Air Act (CAA) 112 accidental release prevention: No products were found.
Clean Air Act (CAA) 112 regulated flammable substances: No products were found.
Clean Air Act (CAA) 112 regulated toxic substances: No products were found.
WHMIS (Canada) Not controlled under WHMIS (Canada)
International Regulations
Labeling according to EC Directives
Symbol(s) ---
R-Phrases ---
S-Phrases S22 Do not breathe dust
S25 Avoid contact with eyes
S36/37 Wear suitable protective clothing and gloves.
CEE Norms-Information on warning label.
Symbol : ---
Risk Phrase : ---
Safety advice :
Avoid unnecessary release to the environment. Refer to local and federal regulations if
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KOBO Products, Inc.
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accidental released..
International List
Australia (NICNAS): TITANIUM DIOXIDE
JAPAN (MITI): TITANIUM DIOXIDE
Korea (TCCL): TITANIUM DIOXIDE
Philippines (RA6969): TITANIUM DIOXIDE
State Regulations Pennsylvania RTK: TITANIUM DIOXIDE: (generic environmental hazard)
Massachusetts RTK: TITANIUM DIOXIDE
New Jersey: TITANIUM DIOXIDE
SECTION 16: OTHER INFORMATION
Hazardous Material Information System [Ratings Key: 4= Highest hazard, 0= Lowest hazard]
(U.S.A.)
Health 0
Fire Hazard 0
Reactivity 0
Personal Protection E
EU S phrases : S22/25/36/37- Do not breathe dust, avoid contact with eyes, wear suitable protective clothing and gloves.
Date Prepared : November 7, 2003
Last Revised : September 27, 2004
By : Eric Smith
Note:
The statements made here are based upon technical data that Kobo Products Inc. believes to be reliable, are intended to describe the
product with regard to necessary safety precautions. They do not guarantee special characteristics. This information is furnished
without warranty, expressed or implied, except that it is accurate to the best of our current knowledge.
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