**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 1461-25-2 |Tetra-n-butyltin | 96 | 215-960-8 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 23/24/25 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic by inhalation, in contact with skin and if swallowed.
Irritating to eyes, respiratory system and skin.The toxicological
properties of this material have not been fully investigated.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea. Ingested inorganic tin exhibits only moderate toxicity due
to poor absorption and rapid tissue turnover. Ingestion of large
amounts may cause gastrointestinal irritation, nausea, cramps,
vomiting and diarrhea. May interfere with various enzyme systems.
Inhalation:
Causes respiratory tract irritation. The toxicological properties of
this substance have not been fully investigated.
Chronic:
Adverse reproductive effects have been reported in animals. Repeated
or prolonged exposure may cause CNS stimulation.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Vapors may be heavier
than air. They can spread along the ground and collect in low or
confined areas. Containers may explode when heated.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog or
alcohol-resistant foam. Do NOT use straight streams of water. Cool
containers with flooding quantities of water until well after fire
is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Scoop up
with a nonsparking tool, then place into a suitable container for
disposal. Remove all sources of ignition. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Avoid contact with eyes, skin, and clothing. Keep container tightly
closed. Avoid ingestion and inhalation. Use with adequate
ventilation. Wash clothing before reuse.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 1461-25-2:
United Kingdom, WEL - TWA: (listed as tin organic compounds): 0.1
mg/m3 TWA (except cyhexatin, as Sn)
United Kingdom, WEL - STEL: (listed as tin organic compounds): 0.
mg/m3 STEL (except cyhexatin, as Sn)
United States OSHA: 0.1 mg/m3 TWA (as Sn) (listed under Tin orga
compounds).
Belgium - TWA: (listed as tin organic compounds): 0.1 mg/m3 VLE (
Sn)
Belgium - STEL: (listed as tin organic compounds): 0.2 mg/m3 VLE
Sn)
France - VME: (listed as tin organic compounds): 0.1 mg/m3 VME (a
Sn)
France - VLE: (listed as tin organic compounds): 0.2 mg/m3 VLE (a
Sn)
Germany: (listed as tin organic compounds): 0.1 mg/m3 VME (as Sn)
Germany: (listed as tin organic compounds): Skin absorber
Malaysia: (listed as tin organic compounds): 0.1 mg/m3 TWA (as Sn
Netherlands: (listed as tin organic compounds): 0.2 mg/m3 STEL (a
Sn)
Netherlands: (listed as tin organic compounds): 0.1 mg/m3 MAC (as
Spain: (listed as tin organic compounds): 0.1 mg/m3 VLA-ED (as Sn
Spain: (listed as tin organic compounds): 0.2 mg/m3 VLA-EC (as Sn
Personal Protective Equipment
Eyes:
Wear chemical goggles and a face shield. Wear
appropriate protective eyeglasses or chemical safety
goggles as described by OSHA's eye and face protection
regulations in 29 CFR 1910.133 or European Standard
EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless to slight yellow
Odor: characteristic odor
pH: Not available.
Vapor Pressure: .022 mm Hg @ 25C
Viscosity: Not available.
Boiling Point: 145 deg C @ 10.00mm Hg
Freezing/Melting Point: -97 deg C
Autoignition Temperature: 265 deg C ( 509.00 deg F)
Flash Point: 107 deg C ( 224.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 265 deg C
Solubility in water: soluble in most common organic solvents
Specific Gravity/Density: 1.0570g/cm3
Molecular Formula: C16H36Sn
Molecular Weight: 347.14
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, excess heat, oxidizers.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide, tin/tin oxides.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 1461-25-2: WH8605000
LD50/LC50:
CAS# 1461-25-2: Draize test, rabbit, eye: 500 mg/24H Mild;
Inhalation, mouse: LC50 = 142 mg/m3; Oral, mouse: LD50 = 6 gm/kg;
Oral, rat: LD50 = 1268 mg/kg.
Carcinogenicity:
Tetra-n-butyltin -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ORGANOTIN COMPOUND, LIQUID, N.O.S.
Hazard Class: 6.1
UN Number: 2788
Packing Group: III
IMO
Shipping Name: ORGANOTIN COMPOUND, LIQUID, N.O.S.
Hazard Class: 6.1
UN Number: 2788
Packing Group: III
RID/ADR
Shipping Name: ORGANOTIN COMPOUND, LIQUID, N.O.S.
Hazard Class: 6.1
UN Number: 2788
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 1461-25-2: 3
Canada
CAS# 1461-25-2 is listed on Canada's NDSL List.
CAS# 1461-25-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1461-25-2 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 1/07/1999 Revision #3 Date: 4/27/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
O,n-dimethylhydroxylamine hydrochloride, 98%
| 6638-79-5 |
|
Dl-mandelic acid, 99+%
| 611-72-3 |
|
Trans, Trans-2,4-Decadienal, Tech., 95%.
| 25152-84-5 |
|
Phenanthrene, 90%
| 85-01-8 |
|
N-(Propargyloxy)phthalimide, 98%
| 4616-63-1 |
|
Tetra-normal-butyltin, 96%
| 1461-25-2 |
|
Oxindole, 97+% (TLC)
| 59-48-3 |
|
Water, Demineralized
| 7732-18-5 |
|
Polyethyleneglycol 200 Monooctylether
| 27252-75-1 |
|
Cyclopropyl methyl ketone, 98%
| 765-43-5 |
|
Aniline Blue, certified biological stain
| 28631-66-5 |
|
Barbital Sodium
| 144-02-5 |
|
1,2,3,5-Tetrafluorobenzene, 99+%
| 2367-82-0 |
|
1-Chloro-9,10-bis(phenylethynyl)anthracene
| 41105-35-5 |
|
2-Chloroethyl isocyanate, 98%
| 1943-83-5 |
|
Brilliant Green
| 633-03-4 |
|
2-Methoxyphenylisocyanate, 99%
| 700-87-8 |
|
n-Methyl-o-toluamide, 99%
| 2170-09-4 |
|
1-Bromo-3,4-Dichlorobenzene, 98+%
| 18282-59-2 |
|
L(-)-Malic Acid,30 Wt% Aqueous Solution
| 97-67-6 |
|
Bromothymol Blue
| 76-59-5 |
|
Thallium (I) Nitrate, 99.5%
| 10102-45-1 |
|
Bromophenol Blue
| 115-39-9 |
|
Diethylene glycol dibutyl ether, 98%
| 112-73-2 |
|
D-Glutamic Acid, 99+%
| 6893-26-1 |
|
Bromophenol Blue Sodium Salt, Reagent ACS
| 62625-28-9 |
|
Blue Tetrazolium, Recrystallized
| 1871-22-3 |
|
4-Nitrobenzenesulfonyl Fluoride, 99% (HPLC)
| 349-96-2 |
|
Bromocresol Green
| 76-60-8 |
|
Tetraphenylarsonium chloride hydro- chloride, 95% (titr.)
| 21006-73-5 |
|
Acetone Oxime, 98%
| 127-06-0 |
|
Cresyl Violet Acetate (Cert)
| 10510-54-0 |
|
Hematein, 94% (uv-vis)
| 475-25-2 |
|
Poly(isobutylene), approximate MW 400,000
| 9003-27-4 |
|
Congo Red
| 573-58-0 |
|
DL-alpha-Methylbenzylamine, 99%
| 618-36-0 |
|
Allyl Trifluoroacetate
| 383-67-5 |
|
2-(2,4,5-Trichlorophenoxy)-propionic acid, 97%
| 93-72-1 |
|
2,6-Dichloroindophenol Sodium Salt
| 620-45-1 |
|
Eosin Y
| 17372-87-1 |
|
4-Nitrobenzoyl Azide
| 2733-41-7 |
|
Eosin b, spirit soluble
| 56360-46-4 |
|
Acetone sodium bisulfite, 97%(titr.)
| 540-92-1 |
|
Eriochrome Black T, Indicator Grade
| 1787-61-7 |
|
2-Nitrophenylacetonitrile, 98%
| 610-66-2 |
|
Ir-132, laser grade, 99% (uv-vis)
| 51010-97-0 |
|
Evans Blue Certified
| 314-13-6 |
|
Fast Green FCF
| 2353-45-9 |
|
Giemsa Stain
| 51811-82-6 |
|
7-Hydroxyquinoline, 99%
| 580-20-1 |
|
|