**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 573-58-0 |C.I. Direct Red 28 | 100 | 209-358-4 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 45 63
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
May cause cancer. Possible risk of harm to the unborn child.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
May cause skin irritation. May cause skin sensitization, an allergic
reaction, which becomes evident upon re-exposure to this material.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
May cause respiratory tract irritation.
Chronic:
This product is a chemical derivative of benzidine, a known human
carcinogen. This substance has caused adverse reproductive and fetal
effects in laboratory animals. The primary target organs for
carcinogenicity induced by benzidine vary with species. Rats, mice,
and hamsters develop liver and mammary tumors. Dogs and humans
develop increased incidences of urinary bladder cancer.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid.
Skin:
In case of contact, flush skin with plenty of water. Remove
contaminated clothing and shoes. Get medical aid if irritation
develops and persists. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by
medical personnel. Never give anything by mouth to an unconscious
person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. This
material in sufficient quantity and reduced particle size is capable
of creating a dust explosion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Avoid contact with eyes, skin, and
clothing. Keep container tightly closed. Avoid ingestion and
inhalation.
Storage:
Store in a cool, dry place. Keep containers tightly closed.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 573-58-0:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: dark red-brown
Odor: odorless
pH: 8-9.5 (aq soln)
Vapor Pressure: Negligible.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: > 360 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Soluble.
Specific Gravity/Density: Not available.
Molecular Formula: C32H22N6O6S2Na2
Molecular Weight: 696.67
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions. Materials containing similar functional
groups can decompose at elevated temperatures.
Conditions to Avoid:
Dust generation, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, oxides of sulfur, carbon
dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 573-58-0: QK1400000
LD50/LC50:
CAS# 573-58-0: Draize test, rabbit, eye: 100 mg Moderate; Oral, rat:
LD50 = 15200 mg/kg.
Carcinogenicity:
C.I. Direct Red 28 -
California: carcinogen, initial date 10/1/92 (listed as Benzidine base
NTP: Known carcinogen (listed as Benzidine based dyes).
IARC: Group 2A carcinogen (listed as Benzidine based dyes).
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 45 May cause cancer.
R 63 Possible risk of harm to the unborn child.
Safety Phrases:
S 53 Avoid exposure - obtain special instructions
before use.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 573-58-0: 1
Canada
CAS# 573-58-0 is listed on Canada's DSL List.
CAS# 573-58-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 573-58-0 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 5/20/1998 Revision #4 Date: 8/27/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
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| ALL MSDS PAGES IN THIS GROUP
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Water, Demineralized
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Polyethyleneglycol 200 Monooctylether
| 27252-75-1 |
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Cyclopropyl methyl ketone, 98%
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Aniline Blue, certified biological stain
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1,2,3,5-Tetrafluorobenzene, 99+%
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|
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| 2170-09-4 |
|
1-Bromo-3,4-Dichlorobenzene, 98+%
| 18282-59-2 |
|
L(-)-Malic Acid,30 Wt% Aqueous Solution
| 97-67-6 |
|
Bromothymol Blue
| 76-59-5 |
|
Thallium (I) Nitrate, 99.5%
| 10102-45-1 |
|
Bromophenol Blue
| 115-39-9 |
|
Diethylene glycol dibutyl ether, 98%
| 112-73-2 |
|
D-Glutamic Acid, 99+%
| 6893-26-1 |
|
Bromophenol Blue Sodium Salt, Reagent ACS
| 62625-28-9 |
|
Blue Tetrazolium, Recrystallized
| 1871-22-3 |
|
4-Nitrobenzenesulfonyl Fluoride, 99% (HPLC)
| 349-96-2 |
|
Bromocresol Green
| 76-60-8 |
|
Tetraphenylarsonium chloride hydro- chloride, 95% (titr.)
| 21006-73-5 |
|
Acetone Oxime, 98%
| 127-06-0 |
|
Cresyl Violet Acetate (Cert)
| 10510-54-0 |
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Hematein, 94% (uv-vis)
| 475-25-2 |
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| 9003-27-4 |
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Congo Red
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| 618-36-0 |
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Allyl Trifluoroacetate
| 383-67-5 |
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| 93-72-1 |
|
2,6-Dichloroindophenol Sodium Salt
| 620-45-1 |
|
Eosin Y
| 17372-87-1 |
|
4-Nitrobenzoyl Azide
| 2733-41-7 |
|
Eosin b, spirit soluble
| 56360-46-4 |
|
Acetone sodium bisulfite, 97%(titr.)
| 540-92-1 |
|
Eriochrome Black T, Indicator Grade
| 1787-61-7 |
|
2-Nitrophenylacetonitrile, 98%
| 610-66-2 |
|
Ir-132, laser grade, 99% (uv-vis)
| 51010-97-0 |
|
Evans Blue Certified
| 314-13-6 |
|
Fast Green FCF
| 2353-45-9 |
|
Giemsa Stain
| 51811-82-6 |
|
7-Hydroxyquinoline, 99%
| 580-20-1 |
|
|