**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 349-96-2 |4-Nitrobenzenesulfonyl Fluoride | 99% | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Corrosive.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns.
Inhalation:
May cause severe irritation of the upper respiratory tract with
pain, burns, and inflammation. Causes chemical burns to the
respiratory tract. Inhalation may be fatal as a result of spasm,
inflammation, edema of the larynx and bronchi, chemical pneumonitis
and pulmonary edema.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide. DO NOT USE WATER! Do NOT
get water inside containers.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Avoid runoff into storm sewers and ditches which lead to
waterways. Clean up spills immediately, observing precautions in the
Protective Equipment section. Provide ventilation. Do not get water
inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Minimize dust generation and accumulation. Do not breathe dust,
vapor, mist, or gas. Do not get in eyes, on skin, or on clothing.
Keep container tightly closed. Do not ingest or inhale. Use with
adequate ventilation. Do not allow contact with water. Use only in a
chemical fume hood. Discard contaminated shoes. Keep from contact
with moist air and steam.
Storage:
Store in a cool, dry place. Keep container closed when not in use.
Store in a tightly closed container. Corrosives area. Store protected
from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 349-96-2:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: yellow
Odor: sulfurous odor
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 55 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C6H4FNO4S
Molecular Weight: 205.17
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, dust generation, moisture, excess heat,
exposure to moist air or water.
Incompatibilities with Other Materials:
Strong acids, strong bases, strong oxidizing agents, strong reducing
agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, oxides of sulfur, carbon dioxide,
hydrogen fluoride gas.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 349-96-2 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
4-Nitrobenzenesulfonyl Fluoride -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE SOLID, N.O.S.*
Hazard Class: 8
UN Number: 1759
Packing Group: II
IMO
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 25 Avoid contact with eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 349-96-2: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 349-96-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 349-96-2 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 2/19/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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Dl-mandelic acid, 99+%
| 611-72-3 |
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Trans, Trans-2,4-Decadienal, Tech., 95%.
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Phenanthrene, 90%
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Water, Demineralized
| 7732-18-5 |
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Polyethyleneglycol 200 Monooctylether
| 27252-75-1 |
|
Cyclopropyl methyl ketone, 98%
| 765-43-5 |
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Aniline Blue, certified biological stain
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|
Barbital Sodium
| 144-02-5 |
|
1,2,3,5-Tetrafluorobenzene, 99+%
| 2367-82-0 |
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| 41105-35-5 |
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| 1943-83-5 |
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Brilliant Green
| 633-03-4 |
|
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| 700-87-8 |
|
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| 2170-09-4 |
|
1-Bromo-3,4-Dichlorobenzene, 98+%
| 18282-59-2 |
|
L(-)-Malic Acid,30 Wt% Aqueous Solution
| 97-67-6 |
|
Bromothymol Blue
| 76-59-5 |
|
Thallium (I) Nitrate, 99.5%
| 10102-45-1 |
|
Bromophenol Blue
| 115-39-9 |
|
Diethylene glycol dibutyl ether, 98%
| 112-73-2 |
|
D-Glutamic Acid, 99+%
| 6893-26-1 |
|
Bromophenol Blue Sodium Salt, Reagent ACS
| 62625-28-9 |
|
Blue Tetrazolium, Recrystallized
| 1871-22-3 |
|
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| 349-96-2 |
|
Bromocresol Green
| 76-60-8 |
|
Tetraphenylarsonium chloride hydro- chloride, 95% (titr.)
| 21006-73-5 |
|
Acetone Oxime, 98%
| 127-06-0 |
|
Cresyl Violet Acetate (Cert)
| 10510-54-0 |
|
Hematein, 94% (uv-vis)
| 475-25-2 |
|
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| 9003-27-4 |
|
Congo Red
| 573-58-0 |
|
DL-alpha-Methylbenzylamine, 99%
| 618-36-0 |
|
Allyl Trifluoroacetate
| 383-67-5 |
|
2-(2,4,5-Trichlorophenoxy)-propionic acid, 97%
| 93-72-1 |
|
2,6-Dichloroindophenol Sodium Salt
| 620-45-1 |
|
Eosin Y
| 17372-87-1 |
|
4-Nitrobenzoyl Azide
| 2733-41-7 |
|
Eosin b, spirit soluble
| 56360-46-4 |
|
Acetone sodium bisulfite, 97%(titr.)
| 540-92-1 |
|
Eriochrome Black T, Indicator Grade
| 1787-61-7 |
|
2-Nitrophenylacetonitrile, 98%
| 610-66-2 |
|
Ir-132, laser grade, 99% (uv-vis)
| 51010-97-0 |
|
Evans Blue Certified
| 314-13-6 |
|
Fast Green FCF
| 2353-45-9 |
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Giemsa Stain
| 51811-82-6 |
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| 580-20-1 |
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