**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 3395-91-3 |Methyl 3-bromopropionate | 97.0 | 222-247-5 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed.The toxicological properties of this material
have not been fully investigated.
Potential Health Effects
Eye:
No information regarding eye irritation and other potential effects
was found.
Skin:
No information regarding skin irritation and other potential effects
was found.
Ingestion:
The toxicological properties of this substance have not been fully
investigated. May be harmful if swallowed. May cause central nervous
system effects.
Inhalation:
The toxicological properties of this substance have not been fully
investigated.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Combustible liquid.
Containers may explode when heated.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Avoid contact with
eyes, skin, and clothing. Empty containers retain product residue,
(liquid and/or vapor), and can be dangerous. Keep container tightly
closed. Keep away from heat, sparks and flame. Avoid ingestion and
inhalation. Do not pressurize, cut, weld, braze, solder, drill,
grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Keep container closed when not in use. Store in a tightly
closed container. Store in a cool, dry, well-ventilated area away
from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 3395-91-3:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: very slightly yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 64.0 - 66.0 deg C @ 18.00mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 75 deg C ( 167.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 58-60C
Solubility in water:
Specific Gravity/Density: 1.5300g/cm3
Molecular Formula: C4H7BrO2
Molecular Weight: 167.00
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents, acids, bases.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrogen bromide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 3395-91-3: UA2451790
LD50/LC50:
CAS# 3395-91-3: Oral, rat: LD50 = 1600 mg/kg.
Oral, rat: LD50 = 1796 mg/kg (male)
Carcinogenicity:
Methyl 3-bromopropionate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
WGK (Water Danger/Protection)
CAS# 3395-91-3: No information available.
Canada
CAS# 3395-91-3 is listed on Canada's DSL List.
CAS# 3395-91-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 3395-91-3 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/22/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
1-Methoxynaphthalene, 95% (gc)
| 2216-69-5 |
|
2-Bromo-4'-Chloroacetophenone, 98+%
| 536-38-9 |
|
Methyl 3-bromopropionate, 97%
| 3395-91-3 |
|
1,4,7-Triazacyclononane trihydrochloride , 97%
| 58966-93-1 |
|
Ethylene/Methacrylic Acid Ionomer, Sodium Ion
| 25608-26-8 |
|
1-Fluoro-4-nitrobenzene, 99%
| 350-46-9 |
|
Bis(trimethylsilyl)telluride, 98%
| 4551-16-0 |
|
1-Acetoxy-1,3-butadiene, 97%, mixture of isomers
| 1515-76-0 |
|
Heneicosanol, 99%
| 15594-90-8 |
|
Amberlite ira-900 cl ion-exchange resin
| 9050-97-9 |
|
2-Ethyl-1,3-hexanediol, mixture of isomers, 99%
| 94-96-2 |
|
Poly(butadiene), cis and trans, average m. w. 420.000
| 9003-17-2 |
|
3-Bromo-o-xylene, 99%
| 576-23-8 |
|
Dichloroisocyanuric acid sodium salt
| 2893-78-9 |
|
Dimethyl 1,3-acetonedicarboxylate, 97%
| 1830-54-2 |
|
Octyl 4-Methoxycinnamate, 98%
| 5466-77-3 |
|
2-Cyclohexylethanol, 98%
| 4442-79-9 |
|
4-Morpholinecarbonitrile, 97+%
| 1530-89-8 |
|
2-Oxo-1-Cyclohexanepropionitrile, 99+%
| 4594-78-9 |
|
Azelaoyl Chloride, 98% (Titr.)
| 123-98-8 |
|
2-(4-Methoxyphenyl)malondialdehyde, 95+% (nmr)
| 53868-40-9 |
|
4,7-Dichloroquinoline, Tech., 95+%
| 86-98-6 |
|
Methyl azodicarboxylate, 97%
| 2446-84-6 |
|
D(+)-10-Camphorsulfonyl Chloride, 97%
| 21286-54-4 |
|
Thioisonicotinamide, 95%
| 2196-13-6 |
|
N-Methyl-4-nitroaniline, 99% (Titr.)
| 100-15-2 |
|
FLUORESCENT POLYMER SPHERES
| |
|
4-(2-Pyridylazo)resorcinol Disodium Salt, Dihydrate, 75% (UV-Vis)
| 52722-53-9 |
|
1,4-Diphenyl-1-butanone
| 5407-91-0 |
|
Amberlite ira-420, anion exchange resin
| 9002-24-8 |
|
Dibenzo-15-Crown-5, 98%
| 14262-60-3 |
|
Ammonium Hexachlororhodate(III)Trihydrate
| 81044-09-9 |
|
Methylmagnesium chloride, 22 wt% solution in tetrahydrofuran (THF)
| 109-99-9 |
|
3,3-Tetramethyleneglutaric Anhydride, 98%
| 5662-95-3 |
|
2-Chloro-6-Methylaniline, 98%
| 87-63-8 |
|
Aluminum Perchlorate Nonahydrate, 99%
| 81029-06-3 |
|
3,4-Dimercaptotoluene, zinc salt
| 26293-80-1 |
|
1-Phenyl-1-cyclohexanecarbonitrile 97%
| 2201-23-2 |
|
Allyl Mercaptan, Tech., 70+% Remainder Mainly Sulfide
| 870-23-5 |
|
4-Acetoxyacetophenone, 99%
| 13031-43-1 |
|
Lithiumtriethylborohydride, 1M solution in THF
| 109-99-9 |
|
Dimethyl Methoxymethylenemalonate, 98+%
| 22398-14-7 |
|
Methyl Oxalyl Chloride, 97%
| 5781-53-3 |
|
alpha-Hydroxy-heptafluoronaphthalene, 98%
| 5386-30-1 |
|
2-Chloro-5-fluoroanisole, 97%
| 450-89-5 |
|
Potassium selenocyanate, 99%
| 3425-46-5 |
|
2-Bromonaphtalene, 99% (GC)
| 580-13-2 |
|
Azobenzene, 99%
| 103-33-3 |
|
N-Carbobenzyloxy-DL-alanine
| 4132-86-9 |
|
Trimellitic Anhydride Acid Chloride, 99%
| 1204-28-0 |
|
|