**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 58966-93-1 |1,4,7-Triazacyclononane trihydrochlori| 97 | unlisted |
| |de | | |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Hygroscopic (absorbs moisture from the air).Corrosive.
Potential Health Effects
Eye:
Causes eye burns. May cause chemical conjunctivitis and corneal
damage.
Skin:
Causes skin burns. Substance is readily absorbed through the skin.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. May cause perforation of the digestive
tract. May cause systemic effects.
Inhalation:
Causes chemical burns to the respiratory tract. Inhalation may be
fatal as a result of spasm, inflammation, edema of the larynx and
bronchi, chemical pneumonitis and pulmonary edema. May cause burning
sensation, coughing, wheezing, laryngitis, shortness of breath,
headache, nausea, and vomiting.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do not use
mouth-to-mouth resuscitation if victim ingested or inhaled the
substance; induce artificial respiration with the aid of a pocket
mask equipped with a one-way valve or other proper respiratory
medical device.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Minimize dust generation and
accumulation. Do not get in eyes, on skin, or on clothing. Keep
container tightly closed. Use with adequate ventilation. Use only in
a chemical fume hood. Discard contaminated shoes. Keep from contact
with moist air and steam. Do not breathe dust or fumes.
Storage:
Keep container closed when not in use. Corrosives area. Store
protected from moisture. Store in a cool, dry area away from
incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 58966-93-1:
Belgium - TWA: (listed as nonane): 200 ppm VLE; 1065 mg/m3 VLE
France - VME: (listed as nonane): 200 ppm VME; 1050 mg/m3 VME
Germany: (listed as nonane): 200 ppm VME; 1050 mg/m3 VME
Japan: (listed as nonane): 200 ppm OEL; 1050 mg/m3 OEL
Malaysia: (listed as nonane): 200 ppm TWA; 1050 mg/m3 TWA
Netherlands: (listed as nonane): 200 ppm MAC; 1050 mg/m3 MAC
Spain: (listed as nonane): 200 ppm VLA-ED; 1065 mg/m3 VLA-ED
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves and clothing to
prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 286.00 - 300.00 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: > 300 deg C
Solubility in water: Not available.
Specific Gravity/Density: Not available.
Molecular Formula: C6H15N3.3HCl
Molecular Weight: 238.59
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. Moisture sensitive.
Conditions to Avoid:
Incompatible materials, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents, moisture.
Hazardous Decomposition Products:
Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 58966-93-1 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
1,4,7-Triazacyclononane trihydrochloride -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE SOLID, N.O.S.*
Hazard Class: 8
UN Number: 1759
Packing Group: III
IMO
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36 Wear suitable protective clothing.
WGK (Water Danger/Protection)
CAS# 58966-93-1: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 58966-93-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 58966-93-1 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 7/15/1999 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
1-Methoxynaphthalene, 95% (gc)
| 2216-69-5 |
|
2-Bromo-4'-Chloroacetophenone, 98+%
| 536-38-9 |
|
Methyl 3-bromopropionate, 97%
| 3395-91-3 |
|
1,4,7-Triazacyclononane trihydrochloride , 97%
| 58966-93-1 |
|
Ethylene/Methacrylic Acid Ionomer, Sodium Ion
| 25608-26-8 |
|
1-Fluoro-4-nitrobenzene, 99%
| 350-46-9 |
|
Bis(trimethylsilyl)telluride, 98%
| 4551-16-0 |
|
1-Acetoxy-1,3-butadiene, 97%, mixture of isomers
| 1515-76-0 |
|
Heneicosanol, 99%
| 15594-90-8 |
|
Amberlite ira-900 cl ion-exchange resin
| 9050-97-9 |
|
2-Ethyl-1,3-hexanediol, mixture of isomers, 99%
| 94-96-2 |
|
Poly(butadiene), cis and trans, average m. w. 420.000
| 9003-17-2 |
|
3-Bromo-o-xylene, 99%
| 576-23-8 |
|
Dichloroisocyanuric acid sodium salt
| 2893-78-9 |
|
Dimethyl 1,3-acetonedicarboxylate, 97%
| 1830-54-2 |
|
Octyl 4-Methoxycinnamate, 98%
| 5466-77-3 |
|
2-Cyclohexylethanol, 98%
| 4442-79-9 |
|
4-Morpholinecarbonitrile, 97+%
| 1530-89-8 |
|
2-Oxo-1-Cyclohexanepropionitrile, 99+%
| 4594-78-9 |
|
Azelaoyl Chloride, 98% (Titr.)
| 123-98-8 |
|
2-(4-Methoxyphenyl)malondialdehyde, 95+% (nmr)
| 53868-40-9 |
|
4,7-Dichloroquinoline, Tech., 95+%
| 86-98-6 |
|
Methyl azodicarboxylate, 97%
| 2446-84-6 |
|
D(+)-10-Camphorsulfonyl Chloride, 97%
| 21286-54-4 |
|
Thioisonicotinamide, 95%
| 2196-13-6 |
|
N-Methyl-4-nitroaniline, 99% (Titr.)
| 100-15-2 |
|
FLUORESCENT POLYMER SPHERES
| |
|
4-(2-Pyridylazo)resorcinol Disodium Salt, Dihydrate, 75% (UV-Vis)
| 52722-53-9 |
|
1,4-Diphenyl-1-butanone
| 5407-91-0 |
|
Amberlite ira-420, anion exchange resin
| 9002-24-8 |
|
Dibenzo-15-Crown-5, 98%
| 14262-60-3 |
|
Ammonium Hexachlororhodate(III)Trihydrate
| 81044-09-9 |
|
Methylmagnesium chloride, 22 wt% solution in tetrahydrofuran (THF)
| 109-99-9 |
|
3,3-Tetramethyleneglutaric Anhydride, 98%
| 5662-95-3 |
|
2-Chloro-6-Methylaniline, 98%
| 87-63-8 |
|
Aluminum Perchlorate Nonahydrate, 99%
| 81029-06-3 |
|
3,4-Dimercaptotoluene, zinc salt
| 26293-80-1 |
|
1-Phenyl-1-cyclohexanecarbonitrile 97%
| 2201-23-2 |
|
Allyl Mercaptan, Tech., 70+% Remainder Mainly Sulfide
| 870-23-5 |
|
4-Acetoxyacetophenone, 99%
| 13031-43-1 |
|
Lithiumtriethylborohydride, 1M solution in THF
| 109-99-9 |
|
Dimethyl Methoxymethylenemalonate, 98+%
| 22398-14-7 |
|
Methyl Oxalyl Chloride, 97%
| 5781-53-3 |
|
alpha-Hydroxy-heptafluoronaphthalene, 98%
| 5386-30-1 |
|
2-Chloro-5-fluoroanisole, 97%
| 450-89-5 |
|
Potassium selenocyanate, 99%
| 3425-46-5 |
|
2-Bromonaphtalene, 99% (GC)
| 580-13-2 |
|
Azobenzene, 99%
| 103-33-3 |
|
N-Carbobenzyloxy-DL-alanine
| 4132-86-9 |
|
Trimellitic Anhydride Acid Chloride, 99%
| 1204-28-0 |
|
|