**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 4594-78-9 |2-Oxo-1-Cyclohexanepropionitrile | 99+% | 224-991-6 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 20/21
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation and in contact with skin.The toxicological
properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. May cause cardiac
disturbances. The toxicological properties of this substance have not
been fully investigated. May cause central nervous system depression.
Metabolism may release cyanide, which may result in headache,
dizziness, weakness, collapse, unconsciousness and possible death.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated. May cause cardiac
abnormalities. May be metabolized to cyanide which in turns act by
inhibiting cytochrome oxidase impairing cellular respiration.
Inhalation at high concentrations may cause CNS depression and
asphixiation.
Chronic:
May be metabolized to cyanide which in turn acts by inhibiting
cytochrome oxidase impairing cellular respiration. Effects may be
delayed. Chronic exposure to cyanide solutions may lead to the
development of a "cyanide" rash, characterized by itching, and by
macular, papular, and vesicular eruptions, and may be accompanied by
secondary infections.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing
is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
May be partially metabolized to cyanide in the body.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Vapors may
be heavier than air. They can spread along the ground and collect
in low or confined areas. Vapors may form an explosive mixture with
air. Containers may explode when heated. Runoff from fire control or
dilution water may cause pollution.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Do NOT get water
inside containers. For small fires, use dry chemical, carbon
dioxide, or water spray. For large fires, use dry chemical, carbon
dioxide, alcohol-resistant foam, or water spray.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid
contact with eyes, skin, and clothing. Keep container tightly closed.
Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 4594-78-9:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear light yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 138 - 142 deg C @ 10.00mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.0060g/cm3
Molecular Formula: C9H13NO
Molecular Weight: 151.21
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents, reducing agents, strong acids, strong bases.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 4594-78-9 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
2-Oxo-1-Cyclohexanepropionitrile -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
IMO
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
RID/ADR
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21 Harmful by inhalation and in contact with
skin.
Safety Phrases:
S 23 Do not inhale gas/fumes/vapour/spray.
WGK (Water Danger/Protection)
CAS# 4594-78-9: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 4594-78-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 4594-78-9 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #4 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
1-Methoxynaphthalene, 95% (gc)
| 2216-69-5 |
|
2-Bromo-4'-Chloroacetophenone, 98+%
| 536-38-9 |
|
Methyl 3-bromopropionate, 97%
| 3395-91-3 |
|
1,4,7-Triazacyclononane trihydrochloride , 97%
| 58966-93-1 |
|
Ethylene/Methacrylic Acid Ionomer, Sodium Ion
| 25608-26-8 |
|
1-Fluoro-4-nitrobenzene, 99%
| 350-46-9 |
|
Bis(trimethylsilyl)telluride, 98%
| 4551-16-0 |
|
1-Acetoxy-1,3-butadiene, 97%, mixture of isomers
| 1515-76-0 |
|
Heneicosanol, 99%
| 15594-90-8 |
|
Amberlite ira-900 cl ion-exchange resin
| 9050-97-9 |
|
2-Ethyl-1,3-hexanediol, mixture of isomers, 99%
| 94-96-2 |
|
Poly(butadiene), cis and trans, average m. w. 420.000
| 9003-17-2 |
|
3-Bromo-o-xylene, 99%
| 576-23-8 |
|
Dichloroisocyanuric acid sodium salt
| 2893-78-9 |
|
Dimethyl 1,3-acetonedicarboxylate, 97%
| 1830-54-2 |
|
Octyl 4-Methoxycinnamate, 98%
| 5466-77-3 |
|
2-Cyclohexylethanol, 98%
| 4442-79-9 |
|
4-Morpholinecarbonitrile, 97+%
| 1530-89-8 |
|
2-Oxo-1-Cyclohexanepropionitrile, 99+%
| 4594-78-9 |
|
Azelaoyl Chloride, 98% (Titr.)
| 123-98-8 |
|
2-(4-Methoxyphenyl)malondialdehyde, 95+% (nmr)
| 53868-40-9 |
|
4,7-Dichloroquinoline, Tech., 95+%
| 86-98-6 |
|
Methyl azodicarboxylate, 97%
| 2446-84-6 |
|
D(+)-10-Camphorsulfonyl Chloride, 97%
| 21286-54-4 |
|
Thioisonicotinamide, 95%
| 2196-13-6 |
|
N-Methyl-4-nitroaniline, 99% (Titr.)
| 100-15-2 |
|
FLUORESCENT POLYMER SPHERES
| |
|
4-(2-Pyridylazo)resorcinol Disodium Salt, Dihydrate, 75% (UV-Vis)
| 52722-53-9 |
|
1,4-Diphenyl-1-butanone
| 5407-91-0 |
|
Amberlite ira-420, anion exchange resin
| 9002-24-8 |
|
Dibenzo-15-Crown-5, 98%
| 14262-60-3 |
|
Ammonium Hexachlororhodate(III)Trihydrate
| 81044-09-9 |
|
Methylmagnesium chloride, 22 wt% solution in tetrahydrofuran (THF)
| 109-99-9 |
|
3,3-Tetramethyleneglutaric Anhydride, 98%
| 5662-95-3 |
|
2-Chloro-6-Methylaniline, 98%
| 87-63-8 |
|
Aluminum Perchlorate Nonahydrate, 99%
| 81029-06-3 |
|
3,4-Dimercaptotoluene, zinc salt
| 26293-80-1 |
|
1-Phenyl-1-cyclohexanecarbonitrile 97%
| 2201-23-2 |
|
Allyl Mercaptan, Tech., 70+% Remainder Mainly Sulfide
| 870-23-5 |
|
4-Acetoxyacetophenone, 99%
| 13031-43-1 |
|
Lithiumtriethylborohydride, 1M solution in THF
| 109-99-9 |
|
Dimethyl Methoxymethylenemalonate, 98+%
| 22398-14-7 |
|
Methyl Oxalyl Chloride, 97%
| 5781-53-3 |
|
alpha-Hydroxy-heptafluoronaphthalene, 98%
| 5386-30-1 |
|
2-Chloro-5-fluoroanisole, 97%
| 450-89-5 |
|
Potassium selenocyanate, 99%
| 3425-46-5 |
|
2-Bromonaphtalene, 99% (GC)
| 580-13-2 |
|
Azobenzene, 99%
| 103-33-3 |
|
N-Carbobenzyloxy-DL-alanine
| 4132-86-9 |
|
Trimellitic Anhydride Acid Chloride, 99%
| 1204-28-0 |
|
|