MATERIAL SAFETY DATA SHEET
Prepared to U.S. OSHA, CMA, ANSI, Canadian WHMIS Standards and European EC Directives
PART I What is the material and what do I need to know in an emergency?
1. PRODUCT IDENTIFICATION
DRAFTLINE BEER LINE CLEANER
TRADE NAME (AS LABELED):
CHEMICAL NAME/CLASS: Chelated Sodium Hydroxide Solution (30%)
PRODUCT USE: Draft Line Cleaner
U.S. SUPPLIER/MANUFACTURER'S NAME: BDP INNOVATIVE CHEMICALS
U.S. ADDRESS: 4393 Virginia Drive
Orlando, FL 32814 USA
U.S. BUSINESS PHONE: 1-800-574-6080
EMERGENCY PHONE: 1-800-424-9300 (CHEMTREC) [Within U.S. and Canada]
DATE OF PREPARATION: August 6, 2003
2. COMPOSITION and INFORMATION ON INGREDIENTS
CHEMICAL NAME CAS # EINECS # % w/w EXPOSURE LIMITS IN AIR
ACGIH-TLV OSHA-PEL NIOSH OTHER
TWA STEL TWA STEL IDLH
3 3 3 3 3 3
mg/m mg/m mg/m mg/m mg/m mg/m
Sodium Hydroxide 1310-73-2 215-185-5 30 NE 2 2 NE 10 NIOSH REL:
(ceiling) STEL = 2
2 [ceiling]
(ceiling)
(1989
Vacated
PEL)
Sodium Gluconate 527-07-1 208-407-7 1-10 NE NE NE NE NE NE
Amphoteric-Anionic Surfactant Proprietary 1-10 NE NE NE NE NE NE
Organic Phosphonate Proprietary 1-10 NE NE NE NE NE NE
Surfactant Mixture Proprietary <1 NE NE NE NE NE NE
Water 7732-18-5 231-791-2 Balance NE NE NE NE NE NE
NE = Not Established. See Section 16 for Definitions of Terms Used.
NOTE: ALL WHMIS required information is included in appropriate sections based on the ANSI Z400.1-1998 format. This product has been classified in
accordance with the hazard criteria of the CPR, and the MSDS contains all the information required by the CPR and EC Directives.
3. HAZARD IDENTIFICATION
EMERGENCY OVERVIEW: This product is a clear, corrosive solution with no distinct odor. Health Hazards: This
solution is corrosive, and can be damaging to contaminated tissue. Ingestion of large quantities can be fatal. Fire
Hazards: This product is not flammable. If involved in a fire, this product may decompose to produce sodium oxides and
a variety of other compounds (i.e. carbon monoxide and carbon dioxide, oxides of sodium). Reactivity Hazards: This
solution reacts with water to generate heat. Environmental Hazards: This product may damage plants and animals if
released to a terrestrial or aquatic environment. The product presents no bioaccumulation hazard. Emergency
Considerations: In the event of fire or spill, adequate precautions must be taken. Emergency responders must wear the
proper personal protective equipment suitable for the situation to which they are responding.
DRAFTLINE BEER LINE CLEANER MSDS
PAGE 1 OF 11
3. HAZARD IDENTIFICATION (Continued)
SYMPTOMS OF OVEREXPOSURE BY ROUTE OF EXPOSURE: The
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM
most significant routes of occupational overexposure are inhalation and
contact with skin and eyes. The symptoms of overexposure to this
product, via route of exposure, are as follows:
(BLUE) 3
INHALATION: Inhalation of vapors, mists, or sprays of this solution HEALTH HAZARD
may cause pulmonary irritation, irritation of the mucus membranes,
coughing, and a sore throat. Severe overexposure may damage the
tissues of the respiratory system and cause potentially fatal lung
conditions (e.g., chemical pneumonitis and pulmonary edema).
FLAMMABILITY HAZARD (RED) 0
Chronic low-level inhalation of vapors, mists or sprays of this product
may result in permanent damage to lung tissue and reduction of lung
capacity, including development of emphysema and other lung
conditions.
PHYSICAL HAZARD (YELLOW) 1
CONTACT WITH SKIN or EYES: Eye contact will cause irritation, pain,
reddening, and blindness. Depending on the duration of skin contact,
skin overexposures may cause reddening, discomfort, irritation, and
chemical burns. Skin contact may result in a “soapy� feel and cause
PROTECTIVE EQUIPMENT
reddening, discomfort, and irritation. Prolonged exposure may result in
ulcerating burns which could leave scars. Repeated skin overexposure
to low levels can cause dermatitis (dry, red skin). EYES HANDS BODY
RESPIRATORY
SKIN ABSORPTION: The components of this product are not known
to be absorbed through intact skin.
INGESTION: Ingestion is not anticipated to be a significant route of SEE SECTION 8 SEE SECTION 8
occupational exposure. If this product is swallowed, it can burn and
irritate the mouth, throat, esophagus, and other tissues of the digestive
For Routine Industrial Use and Handling Applications
system. Symptoms of such overexposure can include nausea,
vomiting, diarrhea, and ulceration of the gastrointestinal tract. Ingestion See Section 16 for Definition of Ratings
of large volumes of this product may be fatal.
INJECTION: Accidental injection of this product, via laceration or puncture by a contaminated object, may cause pain and
irritation in addition to the wound.
HEALTH EFFECTS OR RISKS FROM EXPOSURE: An Explanation in Lay Terms. In the event of exposure, the following
symptoms may be observed:
ACUTE: This solution is corrosive. Depending on the duration of contact, overexposures can irritate or burn the eyes, skin,
mucous membranes, and any other exposed tissue. Inhalation may cause coughing and difficulty breathing. Skin contact
can cause blisters and scars. Eye contact can cause blindness. Severe inhalation and ingestion overexposures may be
fatal.
CHRONIC: Repeated skin overexposures can cause dermatitis (dry, red skin). Repeated low-level inhalation exposure may
result in permanent tissue damage and development of adverse lung conditions.
TARGET ORGANS: ACUTE: Respiratory system, skin, eyes. CHRONIC: Skin, respiratory system.
PART II What should I do if a hazardous situation occurs?
4. FIRST-AID MEASURES
Victims of chemical exposure must be taken for medical attention. Remove or cover gross contamination to avoid exposure
to rescuers. Rescuers should be taken for medical attention, if necessary. Take copy of label and MSDS to physician or
health professional with victim.
SKIN EXPOSURE: If the product contaminates the skin, immediately begin decontamination with running water. Minimum
flushing is for 15 minutes. Do NOT interrupt flushing. Remove exposed or contaminated clothing, taking care not to
contaminate eyes. Victim must seek immediate medical attention.
EYE EXPOSURE: If this product's liquid or vapors enter the eyes, open victim's eyes while under gently running water. Use
sufficient force to open eyelids. Have victim "roll" eyes. Minimum flushing is for 15 minutes. Do NOT interrupt flushing.
INHALATION: If vapors, mists, or sprays of this product are inhaled, remove victim to fresh air. If necessary, use artificial
respiration to support vital functions. Seek medical attention if any adverse effect occurs.
INGESTION: If this product is swallowed, CALL PHYSICIAN OR POISON CONTROL CENTER FOR MOST CURRENT
INFORMATION. If professional advice is not available, do not induce vomiting. Rinse mouth with water immediately, if
conscious. Victim should drink milk, egg whites, or large quantities of water to dilute chemical. Never induce vomiting or give
diluents (milk or water) to someone who is unconscious, having convulsions, or unable to swallow. If vomiting occurs, lean
patient forward or place on left side (head-down position, if possible) to maintain an open airway and prevent aspiration.
If contaminated individual is convulsing, maintain an open airway and obtain immediate medical attention.
RECOMMENDATIONS TO PHYSICIANS: Treat symptoms and eliminate overexposure.
DRAFTLINE BEER LINE CLEANER MSDS
PAGE 2 OF 11
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Pre-existing dermatitis and respiratory problems may be
aggravated by overexposure to this product.
DRAFTLINE BEER LINE CLEANER MSDS
PAGE 3 OF 11
5. FIRE-FIGHTING MEASURES
FLASH POINT: Not flammable. NFPA RATING
AUTOIGNITION TEMPERATURE: Not flammable.
FLAMMABILITY
FLAMMABLE LIMITS (in air by volume, %):
Lower (LEL): Not applicable.
0
Upper (UEL): Not applicable.
FIRE EXTINGUISHING MATERIALS: 1
3
HEALTH REACTIVITY
Water Spray: YES Carbon Dioxide: YES
Foam: YES Dry Chemical: YES
Halon: YES Other: Any "ABC� Class.
UNUSUAL FIRE AND EXPLOSION HAZARDS: This product is corrosive and
presents a significant contact hazard to firefighters. Though the product is not OTHER
flammable, this product can react with water, creating an exothermic reaction which
See Section 16 for
result in severe spattering of the product. When involved in a fire, this material may
Definition of Ratings
decompose and produce caustic vapors and toxic gases (e.g., oxides of sodium and
carbon).
Explosion Sensitivity to Mechanical Impact: Not sensitive.
Explosion Sensitivity to Static Discharge: Not sensitive.
SPECIAL FIRE-FIGHTING PROCEDURES: Prevent the spread of any released product to combustible objects. Incipient
fire responders should wear eye protection. Structural firefighters must wear Self-Contained Breathing Apparatus and full
protective equipment. Chemical resistant clothing may be necessary. Move fire-exposed containers of this product out of
area, if it can be done without risk to firefighters. If this product is involved in a fire, fire runoff water should be contained to
prevent possible environmental damage.
6. ACCIDENTAL RELEASE MEASURES
SPILL AND LEAK RESPONSE: Uncontrolled releases should be responded to by trained personnel using pre-planned
procedures. Proper protective equipment should be used. In case of a large spill, clear the affected area, protect people,
and respond with trained personnel. Minimum Personal Protective Equipment for non-incidental releases should be Level B:
triple-gloves (rubber gloves and nitrile gloves over latex gloves), chemical resistant suit and boots, hard hat, and
Self Contained Breathing Apparatus). Absorb spilled liquid with suitable absorbent material. Neutralize residue with citric
acid or other neutralizing agent for basic materials. Decontaminate the area thoroughly. Test area with litmus paper to
ensure neutralization is complete. Place all spill residue in an appropriate container and seal. Dispose of in accordance with
U.S. Federal, State, and local hazardous waste disposal regulations and those of Canada and its Provinces and EC Member
States (see Section 13, Disposal Considerations).
PART III How can I prevent hazardous situations from occurring?
7. HANDLING and STORAGE
WORK AND HYGIENE PRACTICES: As with all chemicals, avoid getting this product ON YOU or IN YOU. Wash
thoroughly after handling this product. Do not eat, drink, smoke, or apply cosmetics while handling this product. Avoid
breathing vapors or mists generated by this product. Use in a well-ventilated location. Remove contaminated clothing
immediately.
STORAGE AND HANDLING PRACTICES: All employees who handle this material should be trained to handle it safely.
Keep container tightly closed when not in use. If this product is transferred into another container, only use portable
containers and dispensing equipment (faucet, pump, drip can) approved for corrosive, basic liquids. Never add water to this
product, always add product, with constant stirring, slowly to surface of lukewarm [27-38°C (80-100°F)] water, to assure
product is being completely dissolved as it is added. Never add more product than can be absorbed by solution while
maintaining temperatures below 93°C (200°F) to prevent boiling and spattering of caustic solution.
For Non-Bulk Containers: Store containers in a cool, dry location, away from direct sunlight, sources of intense heat, or
where freezing is possible. Material should be stored in secondary containers or in a diked area, as appropriate. Store
containers away from incompatible chemicals (see Section 10, Stability and Reactivity). When using this product, open
valves on pipelines and other production equipment that contains this product slowly. Periodically inspect totes or tanks of
this product for leaks or damage. Perform routine maintenance on all process equipment. Storage areas should be made of
corrosion resistant materials. Post warning and “NO SMOKING� signs in storage and use areas, as appropriate. Empty
containers may contain residual liquid or vapors; therefore, empty containers should be handled with care. Never store food,
feed, or drinking water in containers that held this product.
Bulk Containers: All tanks and pipelines which contain this material must be labeled. Perform routine maintenance on tanks
or pipelines which contain this product. Report all leaks promptly.
Tank Car Shipments: Tank cars carrying this product should be loaded and unloaded in strict accordance with tank-car
manufacturer’s recommendation and all established on-site safety procedures. Appropriate personal protective
equipment must be used (see Section 8, Engineering Controls and Personal Protective Equipment.). [continued on
following page]
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7. HANDLING and STORAGE (Continued)
Tank Car Shipments (continued): All loading and unloading equipment must be inspected, prior to each use. Loading and
unloading operations must be attended, at all times. Tank cars must be level and wheels must be locked or blocked prior to
loading or unloading. Tank car (for loading) or storage tank (for unloading) must be verified to be correct for receiving this
product and be properly prepared, prior to starting the transfer operations. Hoses must be verified to be clean and free of
incompatible chemicals, prior to connection to the tank car or vessel. Valves and hoses must be verified to be in the correct
positions, before starting transfer operations. A sample (if required) must be taken and verified (if required) prior to starting
transfer operations. All lines must be blown-down and purged before disconnecting them from the tank car or vessel.
PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT: Follow practices indicated in
Section 6 (Accidental Release Measures). Make certain that application equipment is locked and tagged-out safely. Always
use this product in areas where adequate ventilation is provided. Before maintenance begins, decontaminate equipment
with neutralizing agent appropriate for basic materials and follow with a triple-rinse with water. Test equipment with litmus
paper to ensure neutralization is complete. Collect all rinsates and dispose of according to applicable Federal, State, or local
procedures.
8. EXPOSURE CONTROLS - PERSONAL PROTECTION
VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation. If necessary, vent material to outside,
taking appropriate precautions to prevent environmental contamination. Ensure eyewash/safety shower stations are
available near where this product is used.
INTERNATIONAL EXPOSURE LIMITS: The following international exposure limits are currently available for the Sodium
Hydroxide component of this product, as follows:
SODIUM HYDROXIDE: SODIUM HYDROXIDE (continued): SODIUM HYDROXIDE (continued):
3 3 3
Australia :TWA = 2 mg/m , JAN 1993 Japan: OEL(C) = 2 mg/m , JAN1999 Sweden: TGV = 2 mg/m , JAN 1999
3 3 3
Austria: MAK = 2 mg/m , JAN 1999 The Netherlands: MAC-TGG = 2 mg/m , JAN Thailand: TWA = 2 mg/m , JAN 1993
3 3
Belgium: STEL = 2 mg/m , JAN1993 1999 Turkey: TWA = 2 mg/m , JAN 1993
3 3 3
Denmark: TWA = 2 mg/m , JAN 1999 Norway: TWA = 2 mg/m , JAN 1999 United Kingdom: STEL = 2 mg/m , SEP 2000
3 3
Finland: TWA = 2 mg/m , JAN 1999 The Philippines: TWA = 2 mg/m , JAN 1993 In Argentina, Bulgaria, Colombia, Jordan,
3 3
France: VME = 2 mg/m , JAN1 999 Poland: MAC (TWA) = 0.5 mg/m , MAC(STEL) Korea, New Zealand, Singapore, Vietnam
3 3
Germany: MAK = 2 mg/m , JAN1999 = 1 mg/m , JAN 1999 check ACGIH TLV
RESPIRATORY PROTECTION: Maintain airborne contaminant concentrations below exposure limits listed in Section 2
(Composition and Information on Ingredients). For operations in which mists or sprays of this product will be generated,
use only respiratory protection authorized in the U.S. Federal OSHA Respiratory Protection Standard (29 CFR 1910.134), or
equivalent U.S. State standards, Canadian CSA Standard Z94.4-93, and the European Standard EN149, and EC member
states. Oxygen levels below 19.5% are considered IDLH by OSHA. In such atmospheres, use of a full-facepiece
pressure/demand SCBA or a full facepiece, supplied air respirator with auxiliary self-contained air supply is required under
OSHA’s Respiratory Protection Standard (1910.134-1998). The following NIOSH guidelines for Sodium Hydroxide (the main
component of this product) are provided for further information.
SODIUM HYDROXIDE
CONCENTRATION RESPIRATORY PROTECTION
Up to 10 mg/m3: Any Supplied-Air Respirator (SAR) operated in a continuous-flow mode, or any Air-Purifying, Full-
Facepiece respirator with a high-efficiency particulate filter, or any Powered, Air-Purifying
Respirator (PAPR) with a dust and mist filter, or any Self-Contained Breathing Apparatus (SCBA)
with a full facepiece, or any SAR with a full facepiece.
Emergency or Planned Entry into Unknown Concentrations or IDLH Conditions: Any SCBA that has a full facepiece and
is operated in a pressure-demand or other positive-pressure mode, or any SAR that has a full
facepiece and is operated in a pressure-demand or other positive-pressure mode in combination
with an auxiliary SCBA operated in pressure-demand or other positive-pressure mode.
Escape: Any Air-Purifying, Full-Facepiece Respirator with a high-efficiency particulate filter, or any
appropriate escape-type, SCBA.
EYE PROTECTION: Splash goggles or safety glasses. Face shields recommended when using quantities of this solution in
excess of 1 gallon. If necessary, refer to U.S. OSHA 29 CFR 1910.133, the European Standard EN166, or appropriate
Canadian Standards.
HAND PROTECTION: Wear neoprene or vinyl gloves for routine industrial use. Use triple gloves for spill response, as
stated in Section 6 (Accidental Release Measures) of this MSDS. If necessary, refer to U.S. OSHA 29 CFR 1910.138,
appropriate Standards of Canada and those of EC Member States.
BODY PROTECTION: Use body protection appropriate for task. During handling of containers of 15 gallons or larger, an
apron or other impermeable body protection is suggested. For 40 oz bottles or other container less than 15 gallons an apron
is not necessary. Wear clothing appropriate for situation of handling. Full-body chemical protective clothing is recommended
for emergency response procedures. If a hazard of injury to the feet exists due to falling objects, rolling objects, where
objects may pierce the soles of the feet or where employee’s feet may be exposed to electrical hazards, use foot protection,
as described in U.S. OSHA 29 CFR 1910.136. If necessary, refer appropriate Standards of Canada, the European
Economic Community.
DRAFTLINE BEER LINE CLEANER MSDS
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9. PHYSICAL and CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid BOILING POINT @ 760 mm Hg: 119°C (246.2°F)
FREEZING POINT: 0°C (32°F) SPECIFIC GRAVITY @ 15.6°C: 1.33
VAPOR PRESSURE mm Hg @ 60°C: 76 pH: 13.5
DENSITY -- lb-gal @ 15.6°C: 11.11 VAPOR DENSITY: Not determined
EVAPORATION RATE (water = 1): Similar to water. ODOR THRESHOLD: Not established.
LOG WATER/OIL DISTRIBUTION COEFFICIENT: Not established.
APPEARANCE, ODOR AND COLOR: This product is a blue liquid with no distinct odor.
HOW TO DETECT THIS SUBSTANCE (warning properties): Litmus paper will turn purple/blue upon contact with this
solution.
10. STABILITY and REACTIVITY
STABILITY: Stable under conditions of normal temperature and pressure. This solution may react with water to generate
heat.
DECOMPOSITION PRODUCTS: Thermal decomposition will generate sodium oxides, carbon oxides, and caustic vapors.
MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: This product reacts with water and strong acids.
Additionally, it is incompatible with organic halogen compounds, organic nitro compounds, aluminum, zinc, tin, and other
metals. Avoid contact with leather and wool.
HAZARDOUS POLYMERIZATION: Will not occur.
CONDITIONS TO AVOID: Contact with or exposure to incompatible materials, extreme temperatures.
PART IV Is there any other useful information about this material?
11. TOXICOLOGICAL INFORMATION
TOXICITY DATA: Additional toxicology information for components greater than 1 percent in concentration is provided below:
ORGANIC PHOSPHONATE: SODIUM HYDROXIDE (continued): SODIUM HYDROXIDE (continued):
Standard Draize Test (Eye-Rabbit) 50 μg/24
LD50 (rabbit) = >2000 mg/kg Cytogenetic Analysis (Parenteral-Grasshopper)
LD50 (rat) = >5000 mg/kg 20 mg
hours: Severe
Cytogenetic Analysis (Hamster-Ovary) 16 mmol/L
SODIUM HYDROXIDE: Standard Draize Test (Eye-Rabbit) 1 mg/24
Standard Draize Test (Eye-Monkey) 1%/24 hours: SODIUM GLUCONATE:
hours: Severe
Severe LDLo (intravenous, rabbit) = 7630 mg/kg
Rinsed with water (Eye-Rabbit) 1 mg/30 seconds:
Standard Draize Test (Skin-Rabbit) 500 mg/24 AMPHOTERIC-ANIONIC SURFACTANT:
Severe
hours: Severe Currently, there are no toxicological data available
LD50 (Intraperitoneal-Mouse) 40 mg/kg
Standard Draize Test (Eye-Rabbit) 400 μg: Mild for this compound.
LDLo (Oral-Rabbit) 500 mg/kg
.
Cytogenetic Analysis (Hamster-Lung) 10 mmol/L
Standard Draize Test (Eye-Rabbit) 1%: Severe
SUSPECTED CANCER AGENT: None of the components of this product are found on the following lists: FEDERAL OSHA
Z LIST, NTP, IARC, CAL/OSHA, and therefore are not considered to be, nor suspected to be, cancer causing agents by
these agencies.
IRRITANCY OF PRODUCT: This product is extremely irritating and corrosive to contaminated tissue.
SENSITIZATION OF PRODUCT: No component of this product is known to be a skin or respiratory sensitizer.
REPRODUCTIVE TOXICITY INFORMATION: Listed below is information concerning the effects of this product and its
components on the human reproductive system.
Mutagenicity: The components of this product are not reported to produce mutagenic effects in humans. Mutation data
are available for the Sodium Chlorate and Sodium Hydroxide components of this product, obtained during clinical studies
on animal tissues exposed to high doses of this compound.
Embryotoxicity: The components of this product are not reported to produce embryotoxic effects in humans.
Teratogenicity: The components of this product are not reported to cause teratogenic effects in humans.
Reproductive Toxicity: The components of this product are not reported to cause reproductive effects in humans.
A mutagen is a chemical which causes permanent changes to genetic material (DNA) such that the changes will propagate
through generational lines. An embryotoxin is a chemical which causes damage to a developing embryo (i.e. within the first
eight weeks of pregnancy in humans), but the damage does not propagate across generational lines. A teratogen is a
chemical which causes damage to a developing fetus, but the damage does not propagate across generational lines. A
reproductive toxin is any substance which interferes in any way with the reproductive process.
BIOLOGICAL EXPOSURE INDICES: Currently there are no Biological Exposure Indices (BEIs) determined for the
components of this product.
DRAFTLINE BEER LINE CLEANER MSDS
PAGE 6 OF 11
12. ECOLOGICAL INFORMATION
ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.
ENVIRONMENTAL STABILITY: This product will decompose over time in ambient environmental conditions. Additional
environmental data are available for some components, and are provided below.
SODIUM HYDROXIDE: SODIUM HYDROXIDE (continued):
Water Solubility = 9 g/0.9 ml water BOD: None.
Octanol/Water Partition Coefficient: SRP4: Too low to be measured Persistence: Can persist for extended periods of time.
(or possibly virtually 0) ORGANIC PHOSPHONATE:
KOW = -3.53
EFFECT OF MATERIAL ON PLANTS or ANIMALS: Due to the corrosivity of this solution, this product can be harmful or
fatal to plant and animal life, if this product is released into the environment.
EFFECT OF CHEMICAL ON AQUATIC LIFE: This solution can substantially lower the pH of an aquatic environment and
can be extremely toxic to fish and aquatic plants. Additional aquatic toxicity data are available for some components, as
follows:
SODIUM HYDROXIDE: SODIUM HYDROXIDE (continued):
LC100 (Cyprimus carpio) 24 hours = 180 ppm/ 25°C
Acute Hazard Level:
TLm (mosquito fish) 96 hours = 125 ppm/ fresh water
Lethal pH (goldfish) = 10.9
TLm (bluegill) 48 hours = 99 mg/L/ tap water
Lethal pH (bluegill) = 10.5
13. DISPOSAL CONSIDERATIONS
PREPARING WASTES FOR DISPOSAL: Waste disposal must be in accordance with appropriate U.S. Federal, State, and
local regulations and those of Canada and EC Member States. This solution, if unaltered by use, may be disposed of by
treatment at a permitted facility or as advised by your local hazardous waste regulatory authority.
U.S. EPA WASTE NUMBER: D002 (Characteristic, Corrosive) applicable to wastes consisting only of this solution.
14. TRANSPORTATION INFORMATION
THIS PRODUCT IS HAZARDOUS AS DEFINED BY 49 CFR 172.101 BY THE U.S. DEPARTMENT OF
TRANSPORTATION.
PROPER SHIPPING NAME: Sodium hydroxide solution
HAZARD CLASS NUMBER and DESCRIPTION: 8 (Corrosive)
UN IDENTIFICATION NUMBER: UN 1824
PACKING GROUP: II
DOT LABEL(S) REQUIRED: Corrosive
NORTH AMERICAN EMERGENCY RESPONSE GUIDEBOOK NUMBER (2000): 154
MARINE POLLUTANT: No component of this product is designated by the Department of Transportation to be a Marine
Pollutant as per 49 CFR 172.101, Appendix B.
NOTE: Shipments of this product may be shipped under small quantity and limited quantity exceptions as indicated under 49
CFR §173.4 and 49 CFR §173.150, if all requirements are met.
Small Quantity Exception (49 CFR 173.4): Small quantities of Class 8 material are not subjected to other
requirements of the Hazardous Materials Regulations (Subchapter C) when the maximum quantity per inner
receptacle is limited to 30 mL (liquids). Refer to 49 CFR 173.4 for specific information in packaging small quantity
materials.
Limited Quantity Exceptions [49 CFR 173.154(b)]: Limited quantities for Class 8, Packing Group III materials have
inner packagings not over 1.0 L [0.3 gal] (liquids) net capacity each, packed in strong outer packaging.
TRANSPORT CANADA TRANSPORTATION OF DANGEROUS GOODS REGULATIONS: This material is considered as
Dangerous Goods, per regulations of Transport Canada. The use of the above U.S. DOT information from the U.S. 49
CFR regulations is allowed for shipments that originate in the U.S. For shipments via ground vehicle or rail that originate
in Canada, the following information is applicable.
UN IDENTIFICATION NUMBER: UN 1824
PROPER SHIPPING NAME: Sodium hydroxide solution
HAZARD CLASS NUMBER and DESCRIPTION: 8 (Corrosive)
PACKING GROUP: II
HAZARD LABEL(S) REQUIRED: Class 8 (Corrosive)
SPECIAL PROVISIONS: None
EXPLOSIVE LIMIT & LIMITED QUANTITY INDEX: 1
ERAP INDEX: None
PASSENGER CARRYING SHIP INDEX: None
PASSENGER CARRYING ROAD OR RAIL VEHICLE INDEX: 15
MARINE POLLUTANT: Not applicable.
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PAGE 7 OF 11
14. TRANSPORTATION INFORMATION (Continued)
INTERNATIONAL AIR TRANSPORT ASSOCIATION (IATA) DESIGNATION: This product is considered as dangerous
goods under the International Air Transport Association rules. As applicable, use the following information for the
preparation of shipments of this product.
PROPER SHIPPING NAME: Sodium hydroxide solution
HAZARD CLASS NUMBER and DESCRIPTION: 8 (Corrosive Material)
UN IDENTIFICATION NUMBER: UN 1824
PACKING GROUP: II
HAZARD LABEL(S) REQUIRED: 8 (Corrosive
EMERGENCY RESPONSE DRILL CODE DESIGNATION: 8L
The following Packaging Information is applicable to this product:
PASSENGER AND CARGO AIRCRAFT CARGO AIRCRAFT ONLY
Limited Quantity
Packing Instruction Max. Qty per Pkg Packing Instruction Max. Qty per Pkg Packing Instruction Max. Qty per Pkg
Y809 0.5 L 809 1L 813 30 L
INTERNATIONAL MARITIME ORGANIZATION SHIPPING INFORMATION (IMO): This product is considered as dangerous
goods, per the International Maritime Organization.
UN IDENTIFICATION NUMBER: UN 1824
PROPER SHIPPING NAME: Sodium hydroxide solution
CLASS or DIVISION: 8 (Corrosive)
PACKING GROUP: II
SPECIAL PROVISIONS: 223
LIMITED QUANTITIES: 1L
PACKING INSTRUCTION: P001
HAZARD LABEL(S) REQUIRED: Class 8 (Corrosive)
EmS: F-A, S-B
STOWAGE and SEGREGATION: Category A. “Away from Acids�
EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY ROAD
(ADR): This product is considered by the UN Economic Commission for Europe to be dangerous goods.
UN IDENTIFICATION NUMBER: UN 1824
NAME and DESCRIPTION: Sodium hydroxide solution.
CLASS: 8 (Corrosive)
CLASSIFICATION CODE: C5
PACKING GROUP: II
HAZARD LABEL(S) REQUIRED: Class 8 (Corrosive)
SPECIAL PROVISIONS: None
LIMITED QUANTITIES: LQ22
PACKING INSTRUCTIONS: P001, IBC02
VEHICLE FOR TANK CARRIAGE: AT
TRANSPORT CATEGORY: 2
HAZARD IDENTIFICATION: 80
15. REGULATORY INFORMATION
ADDITIONAL UNITED STATES REGULATIONS:
SARA REPORTING REQUIREMENTS: The components of this product are subject to the reporting requirements of
Sections 302, 304 and 313 of Title III of the Superfund Amendments and Reauthorization Act as follows:
CHEMICAL NAME SARA 302 SARA 304 SARA 313
(40 CFR 355, Appendix A) (40 CFR Table 302.4) (40 CFR 372.65)
Sodium Hydroxide No Yes No
U.S. SARA THRESHOLD PLANNING QUANTITY: There are no specific Threshold Planning Quantities for the components
of this product. The default Federal MSDS submission and inventory requirement filing threshold of 10,000 lb (4,540 kg) may
apply, per 40 CFR 370.20.
U.S. TSCA INVENTORY STATUS: The components of this product are listed on the TSCA Inventory.
U.S. CERCLA REPORTABLE QUANTITY (RQ): Sodium Hydroxide = 1000 lb (454 kg)
OTHER U.S. FEDERAL REGULATIONS: Not applicable.
DRAFTLINE BEER LINE CLEANER MSDS
PAGE 8 OF 11
15. REGULATORY INFORMATION (Continued)
ADDITIONAL UNITED STATES REGULATIONS (continued):
U.S. STATE REGULATORY INFORMATION: The components of this product are covered under specific State regulations,
as denoted below:
Alaska - Designated Toxic and Hazardous Massachusetts - Substance List: Sodium Pennsylvania - Hazardous Substance List:
Hydroxide. Sodium Hydroxide.
Substances: Sodium Hydroxide.
Michigan - Critical Materials Register: No. Rhode Island - Hazardous Substance List:
California - Permissible Exposure Limits for
Sodium Hydroxide.
Minnesota - List of Hazardous Substances:
Chemical Contaminants: Sodium
Sodium Hydroxide. Texas - Hazardous Substance List: Sodium
Hydroxide.
Hydroxide.
Missouri - Employer Information/Toxic
Florida - Substance List: Sodium Hydroxide.
West Virginia - Hazardous Substance List:
Substance List: Sodium Hydroxide.
Illinois - Toxic Substance List: Sodium
Sodium Hydroxide.
Hydroxide. New Jersey - Right to Know Hazardous
Wisconsin - Toxic and Hazardous Sodium
Kansas - Section 302/313 List: Sodium Substance List: Sodium Hydroxide.
Hydroxide.
Hydroxide. North Dakota - List of Hazardous Chemicals,
Reportable Quantities: Sodium Hydroxide.
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65): No component of this
product is listed on the California Proposition 65 lists.
ANSI LABELING (Z129.1): DANGER! CORROSIVE MATERIAL! LIQUID AND MIST CAUSE SEVERE BURNS TO ALL
BODY TISSUE. MAY BE FATAL IF SWALLOWED. HARMFUL IF INHALED. MAY CAUSE LUNG DAMAGE. REACTS
VIOLENTLY WITH WATER AND ACIDS. AVOID SPATTERING BY SLOWLY ADDING TO SOLUTION. Do not get into
eyes, on skin, or on clothing. Do not breathe spray or mist. Do not take internally. Use with adequate ventilation and employ
respiratory protection when exposed to the mist or spray. When handling, wear chemical splash goggles, face shield, rubber
gloves and protective clothing, and NIOSH/MSHA-approved respiratory protection, as appropriate. Do not transfer to
unlabeled containers. Wash thoroughly after handling. Keep container closed when not in use. FIRST-AID: In case of
contact, immediately flush skin or eyes for at least 15 minutes. If inhaled, move to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. If ingested, do not induce vomiting. Get medical attention. IN CASE OF
FIRE: Use dry chemical, CO2 , or alcohol foam. IN CASE OF SPILL: Absorb spill with neutralizing agent for basic materials
and place in suitable container. Refer to MSDS for additional information.
ADDITIONAL CANADIAN REGULATIONS:
CANADIAN DSL/NDSL INVENTORY STATUS: The components of this product are listed on the DSL Inventory.
OTHER CANADIAN REGULATIONS: Not applicable.
CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) PRIORITY SUBSTANCES LISTS: The components of this
product are not on the CEPA Priority Substances Lists.
CANADIAN WHMIS SYMBOLS: Class E: Corrosive Material (pH = 13.5)
ADDITIONAL EUROPEAN COMMUNITY REGULATIONS:
PRODUCT: Based on the information of the product’s components described above and an assessment of the physical
and health hazards associated with this material, the following assignments have been made (per Council Directive
67/548/EEC and subsequent regulations, to current date).
CODE LETTER AND HAZARD DESIGNATION OF PRODUCT: C (Corrosive)
RISK PHRASES: [R: 35]: Causes severe burns.
SAFETY PHRASES: Keep locked up and out of reach of children. (*This safety phrase can be omitted from the label
when the substance or preparation is sold for industrial use only.) In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice. In case of accident, or if you feel unwell, seek medical advice
immediately (show label where possible). [S: (1/2�), 26, 45]
EUROPEAN COMMUNITY ANNEX II HAZARD SYMBOL:
DRAFTLINE BEER LINE CLEANER MSDS
PAGE 9 OF 11
16. OTHER INFORMATION
PREPARED BY: CHEMICAL SAFETY ASSOCIATES, Inc.
PO Box 3519, La Mesa, CA 91944-3519
(619) 670-0609
DATE OF PRINTING: November 29, 2007
All statements, technical information and recommendations herein are based on tests we believe to be reliable, but the accuracy or completeness thereof is
not guaranteed. THE FOLLOWING IS MADE IN LIEU OF ALL WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING THE IMPLIED WARRANTIES
OF MERCHANTABILITY AND FITNESS FOR PURPOSE. Seller’s and manufacturer’s only obligation shall be to replace such quantity of the product
proved to be defective. Before using, user shall determine the suitability of the product for its intended use, and user assumes all risks and liability
whatsoever in connection therewith.
NEITHER SELLER NOR MANUFACTURER SHALL BE LIABLE EITHER IN TORT OR IN CONTRACT FOR ANY LOSS OR DAMAGE, DIRECT,
INCIDENTAL OR CONSEQUENTIAL, ARISING OUT OF THE USE OR THE INABILITY TO USE THE PRODUCT.
DEFINITIONS OF TERMS
A large number of abbreviations and acronyms appear on a MSDS. Some of these which are commonly used include the following:
CAS #: This is the Chemical Abstract Service Number that uniquely HAZARDOUS MATERIALS IDENTIFICATION SYSTEM HAZARD
identifies each constituent. RATINGS (continued):
HEALTH HAZARD (continued):
EXPOSURE LIMITS IN AIR:
3 (continued): PII or Draize > 0, < 5. Eye Irritation: Moderately to severely
CEILING LEVEL: The concentration that shall not be exceeded during any
irritating and/or corrosive; reversible corneal opacity; corneal involvement or
part of the working exposure.
irritation clearing in 8-21 days. Draize > 0, < 25. Oral Toxicity LD50 Rat: >
LOQ: Limit of Quantitation.
50-500 mg/kg. Dermal Toxicity LD50Rat or Rabbit: > 200-1000 mg/kg.
MAK: Federal Republic of Germany Maximum Concentration Values in the
Inhalation Toxicity LC50 4-hrs Rat: > 0.5-2 mg/L.); 3 (Serious Hazard: Major
workplace.
injury likely unless prompt action is taken and medical treatment is given;
NE: Not Established. When no exposure guidelines are established, an
high level of toxicity; corrosive. Skin Irritation: Severely irritating and/or
entry of NE is made for reference.
corrosive; may destroy dermal tissue, cause skin burns, dermal necrosis. PII
NIC: Notice of Intended Change.
or Draize > 5-8 with destruction of tissue. Eye Irritation: Corrosive,
NIOSH CEILING: The exposure that shall not be exceeded during any part
irreversible destruction of ocular tissue; corneal involvement or irritation
of the workday. If instantaneous monitoring is not feasible, the ceiling shall
persisting for more than 21 days. Draize > 80 with effects irreversible in 21
be assumed as a 15-minute TWA exposure (unless otherwise specified) that
days. Oral Toxicity LD50 Rat: > 1-50 mg/kg. Dermal Toxicity LD50Rat or
shall not be exceeded at any time during a workday.
Rabbit: > 20-200 mg/kg. Inhalation Toxicity LC50 4-hrs Rat: > 0.05-0.5
NIOSH RELs: NIOSH’s Recommended Exposure Limits.
mg/L.); 4 (Severe Hazard: Life-threatening; major or permanent damage
PEL-Permissible Exposure Limit: OSHA’s Permissible Exposure Limits.
may result from single or repeated exposure. Skin Irritation: Not
This exposure value means exactly the same as a TLV, except that it is
appropriate. Do not rate as a �4�, based on skin irritation alone. Eye
enforceable by OSHA. The OSHA Permissible Exposure Limits are based
Irritation: Not appropriate. Do not rate as a �4�, based on eye irritation
in the 1989 PELs and the June, 1993 Air Contaminants Rule (Federal
alone. Oral Toxicity LD50 Rat: < 1 mg/kg. Dermal Toxicity LD50Rat or
Register: 58: 35338-35351 and 58: 40191). Both the current PELs and the
Rabbit: < 20 mg/kg. Inhalation Toxicity LC50 4-hrs Rat: < 0.05 mg/L).
vacated PELs are indicated. The phrase, “Vacated 1989 PEL,� is placed
FLAMMABILITY HAZARD:
next to the PEL that was vacated by Court Order.
0 (Minimal Hazard-Materials that will not burn in air when exposure to a
SKIN: Used when a there is a danger of cutaneous absorption.
temperature of 815.5°C [1500°F] for a period of 5 minutes.); 1 (Slight
STEL-Short Term Exposure Limit: Short Term Exposure Limit, usually a
Hazard-Materials that must be pre-heated before ignition can occur.
15-minute time-weighted average (TWA) exposure that should not be
Material requires considerable pre-heating, under all ambient temperature
exceeded at any time during a workday, even if the 8-hr TWA is within the
conditions before ignition and combustion can occur, Including: Materials
TLV-TWA, PEL-TWA or REL-TWA.
that will burn in air when exposed to a temperature of 815.5°C (1500°F) for a
TLV-Threshold Limit Value: An airborne concentration of a substance that
period of 5 minutes or less; Liquids, solids and semisolids having a flash
represents conditions under which it is generally believed that nearly all
point at or above 93.3°C [200°F] (e.g. OSHA Class IIIB, or; Most ordinary
workers may be repeatedly exposed without adverse effect. The duration
combustible materials [e.g. wood, paper, etc.]; 2 (Moderate Hazard-Materials
must be considered, including the 8-hour.
that must be moderately heated or exposed to relatively high ambient
TWA-Time Weighted Average: Time Weighted Average exposure
temperatures before ignition can occur. Materials in this degree would not,
concentration for a conventional 8-hr (TLV, PEL) or up to a 10-hr (REL)
under normal conditions, form hazardous atmospheres in air, but under high
workday and a 40-hr workweek.
ambient temperatures or moderate heating may release vapor in sufficient
IDLH-Immediately Dangerous to Life and Health: This level represents a
quantities to produce hazardous atmospheres in air, Including: Liquids
concentration from which one can escape within 30-minutes without
having a flash-point at or above 37.8°C [100°F]; Solid materials in the form of
suffering escape-preventing or permanent injury.
coarse dusts that may burn rapidly but that generally do not form explosive
HAZARDOUS MATERIALS IDENTIFICATION SYSTEM HAZARD
atmospheres; Solid materials in a fibrous or shredded form that may burn
RATINGS: This rating system was developed by the National Paint and
rapidly and create flash fire hazards (e.g. cotton, sisal, hemp; Solids and
Coating Association and has been adopted by industry to identify the degree
semisolids that readily give off flammable vapors.); 3 (Serious Hazard-
of chemical hazards.
Liquids and solids that can be ignited under almost all ambient temperature
HEALTH HAZARD:
conditions. Materials in this degree produce hazardous atmospheres with air
0 (Minimal Hazard: No significant health risk, irritation of skin or eyes not
under almost all ambient temperatures, or, unaffected by ambient
anticipated. Skin Irritation: Essentially non-irritating. PII or Draize = �0�.
temperature, are readily ignited under almost all conditions, including:
Eye Irritation: Essentially non-irritating, or minimal effects which clear in < 24
Liquids having a flash point below 22.8°C [73°F] and having a boiling point at
hours [e.g. mechanical irritation]. Draize = �0�. Oral Toxicity LD50 Rat: <
or above 38°C [100°F] and below 37.8°C [100°F] [e.g. OSHA Class IB and
5000 mg/kg. Dermal Toxicity LD50Rat or Rabbit: < 2000 mg/kg. Inhalation
IC]; Materials that on account of their physical form or environmental
Toxicity 4-hrs LC50 Rat: < 20 mg/L.); 1 (Slight Hazard: Minor reversible Injury
conditions can form explosive mixtures with air and are readily dispersed in
may occur; slightly or mildly irritating. Skin Irritation: Slightly or mildly
air [e.g., dusts of combustible solids, mists or droplets of flammable liquids];
irritating. Eye Irritation: Slightly or mildly irritating. Oral Toxicity LD50 Rat: >
Materials that burn extremely rapidly, usually by reason of self-contained
500-5000 mg/kg. Dermal Toxicity LD50Rat or Rabbit: > 1000-2000 mg/kg.
oxygen [e.g. dry nitrocellulose and many organic peroxides]); (continued on
Inhalation Toxicity LC50 4-hrs Rat: > 2-20 mg/L); 2 (Moderate Hazard:
following page)
Temporary or transitory injury may occur. Skin Irritation: Moderately
irritating; primary irritant; sensitizer. (continued in following column)
DRAFTLINE BEER LINE CLEANER MSDS
PAGE 10 OF 11
DEFINITIONS OF TERMS (Continued)
HAZARDOUS MATERIALS IDENTIFICATION SYSTEM HAZARD HAZARDOUS MATERIALS IDENTIFICATION SYSTEM HAZARD
RATINGS (continued): RATINGS (continued):
HEALTH HAZARD (continued): PHYSICAL HAZARD (continued):
4 (Severe Hazard-Materials that will rapidly or completely vaporize at 4 (Water Reactivity: Materials that react explosively with water without
atmospheric pressure and normal ambient temperature or that are readily requiring heat or confinement. Organic Peroxides: Materials that are readily
dispersed in air, and which will burn readily, including: Flammable gases; capable of detonation or explosive decomposition at normal temperature and
Flammable cryogenic materials; Any liquid or gaseous material that is liquid pressures. Explosives: Division 1.1 & 1.2-explosive substances that have a
mass explosion hazard or have a projection hazard. A mass explosion is
while under pressure and has a flash point below 22.8°C [73°F] and a boiling
one that affects almost the entire load instantaneously. Compressed Gases:
point below 37.8°C [100°F] [e.g. OSHA Class IA; Material that ignite
No Rating. Pyrophorics: Add to the definition of Flammability �4�.
spontaneously when exposed to air at a temperature of 54.4°C [130°F] or
Oxidizers: No �4� rating. Unstable Reactives: Substances that may
below [e.g. pyrophoric]).
polymerize, decompose, condense or self-react at ambient temperature
PHYSICAL HAZARD:
and/or pressure and have a high potential to cause significant heat
0 (Water Reactivity: Materials that do not react with water. Organic
generation or explosion.).
Peroxides: Materials that are normally stable, even under fire conditions and
NATIONAL FIRE PROTECTION ASSOCIATION HAZARD
will not react with water. Explosives: Substances that are Non-Explosive.
RATINGS:
Unstable Compressed Gases: No Rating. Pyrophorics: No Rating.
Oxidizers: No �0� rating allowed. Unstable Reactives: Substances that will HEALTH HAZARD: 0 (material that on exposure under fire conditions would
not polymerize, decompose, condense or self-react.); 1 (Water Reactivity: offer no hazard beyond that of ordinary combustible materials); 1 (materials
Materials that change or decompose upon exposure to moisture. Organic that on exposure under fire conditions could cause irritation or minor residual
Peroxides: Materials that are normally stable, but can become unstable at injury); 2 (materials that on intense or continued exposure under fire
high temperatures and pressures. These materials may react with water, but conditions could cause temporary incapacitation or possible residual injury);
will not release energy. Explosives: Division 1.5 & 1.6 substances that are 3 (materials that can on short exposure cause serious temporary or residual
very insensitive explosives or that do not have a mass explosion hazard. injury); 4 (materials that under very short exposure could cause death or
Compressed Gases: Pressure below OSHA definition. Pyrophorics: No major residual injury).
Rating. Oxidizers: Packaging Group III; Solids: any material that in either FLAMMABILITY HAZARD: 0 Materials that will not burn under typical fire
concentration tested, exhibits a mean burning time less than or equal to the conditions, including intrinsically noncombustible materials such as
mean burning time of a 3:7 potassium bromate/cellulose mixture and the concrete, stone, and sand. 1 Materials that must be preheated before
criteria for Packing Group I and II are not met. Liquids: any material that ignition can occur. Materials in this degree require considerable
exhibits a mean pressure rise time less than or equal to the pressure rise preheating, under all ambient temperature conditions, before ignition and
time of a 1:1 nitric acid (65%)/cellulose mixture and the criteria for Packing combustion can occur 2 Materials that must be moderately heated or
Group I and II are not met. Unstable Reactives: Substances that may exposed to relatively high ambient temperatures before ignition can occur.
decompose, condense or self-react, but only under conditions of high Materials in this degree would not under normal conditions form
temperature and/or pressure and have little or no potential to cause hazardous atmospheres with air, but under high ambient temperatures or
significant heat generation or explosive hazard. Substances that readily under moderate heating could release vapor in sufficient quantities to
undergo hazardous polymerization in the absence of inhibitors.); 2 (Water produce hazardous atmospheres with air. 3 Liquids and solids that can
Reactivity: Materials that may react violently with water. Organic Peroxides: be ignited under almost all ambient temperature conditions. Materials in
Materials that, in themselves, are normally unstable and will readily undergo this degree produce hazardous atmospheres with air under almost all
violent chemical change, but will not detonate. These materials may also ambient temperatures or, though unaffected by ambient temperatures, are
react violently with water. Explosives: Division 1.4 � Explosive substances readily ignited under almost all conditions. 4 Materials that will rapidly or
where the explosive effect is largely confined to the package and no completely vaporize at atmospheric pressure and normal ambient
projection of fragments of appreciable size or range are expected. An temperature or that are readily dispersed in air and will burn readily.
external fire must not cause virtually instantaneous explosion of almost the INSTABILITY HAZARD: 0 Materials that in themselves are normally
entire contents of the package. Compressed Gases: Pressurized and meet stable, even under fire conditions. 1 Materials that in themselves are
OSHA definition but < 514.7 psi absolute at 21.1°C (70°F) [500 psig]. normally stable, but that can become unstable at elevated temperatures
Pyrophorics: No Rating. Oxidizers: Packing Group II Solids: any material and pressures. 2 Materials that readily undergo violent chemical change
that, either in concentration tested, exhibits a mean burning time of less than at elevated temperatures and pressures. 3 Materials that in themselves
or equal to the mean burning time of a 2:3 potassium bromate/cellulose are capable of detonation or explosive decomposition or explosive
mixture and the criteria for Packing Group I are not met. Liquids: any reaction, but that require a strong initiating source or that must be heated
material that exhibits a mean pressure rise time less than or equal to the under confinement before initiation. 4 Materials that in themselves are
pressure rise of a 1:1 aqueous sodium chlorate solution (40%)/cellulose readily capable of detonation or explosive decomposition or explosive
mixture and the criteria for Packing Group I are not met. Unstable Reactives: reaction at normal temperatures and pressures.
Substances that may polymerize, decompose, condense, or self-react at
FLAMMABILITY LIMITS IN AIR:
ambient temperature and/or pressure, but have a low potential for significant
Much of the information related to fire and explosion is derived from the
heat generation or explosion. Substances that readily form peroxides upon
National Fire Protection Association (NFPA). Flash Point - Minimum
exposure to air or oxygen at room temperature); 3 (Water Reactivity:
temperature at which a liquid gives off sufficient vapors to form an ignitable
Materials that may form explosive reactions with water. Organic Peroxides:
mixture with air. Autoignition Temperature: The minimum temperature
Materials that are capable of detonation or explosive reaction, but require a
required to initiate combustion in air with no other source of ignition. LEL -
strong initiating source, or must be heated under confinement before
the lowest percent of vapor in air, by volume, that will explode or ignite in the
initiation; or materials that react explosively with water. Explosives: Division
presence of an ignition source. UEL - the highest percent of vapor in air, by
1.2 � Explosive substances that have a fire hazard and either a minor blast
volume, that will explode or ignite in the presence of an ignition source.
hazard or a minor projection hazard or both, but do not have a mass
explosion hazard. Compressed Gases: Pressure > 514.7 psi absolute at
21.1°C (70°F) [500 psig]. Pyrophorics: No Rating. Oxidizers: Packing
Group I Solids: any material that, in either concentration tested, exhibits a
mean burning time less than the mean burning time of a 3.:2 potassium
bromate/cellulose mixture. Liquids: Any material that spontaneously ignites
when mixed with cellulose in a 1:1 ratio, or which exhibits a mean pressure
rise time less than the pressure rise time of a 1:1 perchloric acid
(50%)/cellulose mixture. Unstable Reactives: Substances that may
polymerize, decompose, condense or self-react at ambient temperature
and/or pressure and have a moderate potential to cause significant heat
generation or explosion.);
DRAFTLINE BEER LINE CLEANER MSDS
PAGE 11 OF 11
DEFINITIONS OF TERMS (Continued)
TOXICOLOGICAL INFORMATION: REGULATORY INFORMATION:
Human and Animal Toxicology: Possible health hazards as derived from U.S. and CANADA:
human data, animal studies, or from the results of studies with similar This section explains the impact of various laws and regulations on the
compounds are presented. Definitions of some terms used in this section material. ACGIH: American Conference of Governmental Industrial
are: LD50 - Lethal Dose (solids & liquids) which kills 50% of the exposed Hygienists, a professional association which establishes exposure limits.
animals; LC50 - Lethal Concentration (gases) which kills 50% of the exposed EPA is the U.S. Environmental Protection Agency. NIOSH is the National
animals; ppm concentration expressed in parts of material per million parts Institute of Occupational Safety and Health, which is the research arm of the
3
of air or water; mg/m concentration expressed in weight of substance per U.S. Occupational Safety and Health Administration (OSHA). WHMIS is the
volume of air; mg/kg quantity of material, by weight, administered to a test Canadian Workplace Hazardous Materials Information System. DOT and
subject, based on their body weight in kg. Other measures of toxicity include TC are the U.S. Department of Transportation and the Transport Canada,
TDLo, the lowest dose to cause a symptom and TCLo the lowest respectively. Superfund Amendments and Reauthorization Act (SARA); the
concentration to cause a symptom; TDo, LDLo, and LDo, or TC, TCo, Canadian Domestic/Non-Domestic Substances List (DSL/NDSL); the U.S.
LCLo, and LCo, the lowest dose (or concentration) to cause lethal or toxic Toxic Substance Control Act (TSCA); Marine Pollutant status according to
effects. Cancer Information: The sources are: IARC - the International the DOT; the Comprehensive Environmental Response, Compensation, and
Agency for Research on Cancer; NTP - the National Toxicology Program, Liability Act (CERCLA or Superfund); and various state regulations. This
RTECS - the Registry of Toxic Effects of Chemical Substances, OSHA and section also includes information on the precautionary warnings which
CAL/OSHA. IARC and NTP rate chemicals on a scale of decreasing appear on the material’s package label. OSHA - U.S. Occupational Safety
potential to cause human cancer with rankings from 1 to 4. Subrankings and Health Administration.
(2A, 2B, etc.) are also used. Other Information: BEI - ACGIH Biological
EUROPE:
Exposure Indices, represent the levels of determinants which are most likely
EC is the European Community (formerly known as the EEC, European
to be observed in specimens collected from a healthy worker who has been
Economic Community). EINECS: This the European Inventory of Now-
exposed to chemicals to the same extent as a worker with inhalation
Existing Chemical Substances. The ARD is the European Agreement
exposure to the TLV.
Concerning the International Carriage of Dangerous Goods by Road and the
ECOLOGICAL INFORMATION:
RID are the International Regulations Concerning the Carriage of Dangerous
EC is the effect concentration in water. BCF = Bioconcentration Factor,
Goods by Rail.
which is used to determine if a substance will concentrate in lifeforms which
consume contaminated plant or animal matter. TLm = median threshold limit;
Coefficient of Oil/Water Distribution is represented by log Kow or log Koc
and is used to assess a substance’s behavior in the environment.
DRAFTLINE BEER LINE CLEANER MSDS
PAGE 12 OF 11
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