P120-20-020
Issue: B
Rev Date: 01-02-05
MATERIAL SAFETY DATA SHEET Page: 1 of 14
PRODUCT NAME : Emarald Lacquer
1. Product and Company Identification
Product Name: Emarald Lacquer
Synonyms: None
Item Numbers : E48010000, E48010001
European Contact Details US Contact Details
BOC Edwards, Manor Royal, Crawley, BOC Edwards, 301 Ballardvale Street,
West Sussex, RH10 2LW, England Wilmington, MA 01887
General enquiries General enquiries
UK : +44 (0) 1293 528844 +(1) 978-658-5410
France : +(33) 1 47 98 24 01 Toll Free: 800-848-9800
Germany : +(49) 6420-82-410
Italy : +(39) 248-4471 24 Hr Emergency telephone number:
Chemtrec : 1-800-424-9300
2. Composition/Information on Ingredients
Ingredient % Weight Hazard Symbols Risk Phrases CAS No EINECS No
Methanol < 16 TF 11 23/24/25/39 67-56-1 200-659-6
n-butanol < 15 XN 10 20 71-36-3 200-751-6
PM Glycol Ether < 15 F 10 107-98-2 203-539-1
OSHA Regulatory Status: This product is classified as hazardous under OSHA regulations.
Additional Information :
PM Glycol Ether may also be known as 1-Methoxy-2-Propanol or Propyleneglycol Monomethylether.
3. Hazards Identification
EMERGENCY OVERVIEW
This product is a flammable liquid and cannot be made non poisonous. Harmful if inhaled or ingested.
Overexposure may cause skin irritation and severe eye irritation. May adversely affect the reproductive system and
developing child.
For short and long term exposure effects see Toxicological data section 11
705
DCC1 No :
BOC Edwards is part of BOC Limited.
The stripe symbol is a trade mark of the BOC Group.
Ref 2D01-010 form issue 1.2
P120-20-020
Issue: B
Rev Date: 01-02-05
MATERIAL SAFETY DATA SHEET Page: 2 of 14
PRODUCT NAME : Emarald Lacquer
Route of Entry
Skin Contact Skin Absorption Eye Contact Inhalation Ingestion
Yes Yes Yes Yes Yes
Health Effects
Exposure Limits Irritant Sensitisation
Yes Yes Yes
Teratogen Reproductive Hazard Mutagen
Yes Yes Yes
Synergistic: n-Butanol potentiates the acute inhalation toxicity of carbon tetrachloride. Chronic combined
exposure to methanol and carbon monoxide has been reported as a causative factor of cerebral atherosclerosis.
May cause severe eye irritation. May cause corneal edema and inflammation. May cause
Eye Effects:
lacrimation (tearing), blurred vision, and photophobia.
May cause skin irritation. Prolonged and/or frequent contact may cause drying, cracking or
Skin Effects:
folliculitis, defating of the skin and dermatitis.
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause
Ingestion Effects:
systemic toxicity with acidosis. May cause central nervous system depression,
characterized by excitement, followed by headache, dizziness, drowsiness, and nausea.
Advanced stages may cause collapse, unconsciousness, coma and possible death due to
respiratory failure. Aspiration may be fatal. May be absorbed from the gastrointestinal tract.
May cause blindness. May cause cardiopulmonary system effects.
May cause respiratory tract irritation. May cause cardiovascular disturbances, hearing
Inhalation Effects:
abnormalities, central nervous system depression, muscle weakness, and possible death
due to respiratory failure. May be absorbed through the lungs.
Medical Conditions Aggravated by Exposure:
Persons with liver, kidney, central nervous system, eye or skin disorders may be at
increased risk from exposure to this product.
NFPA Hazard codes HMIS Hazard codes Rating System
3 3 0 = No Hazard
Health Health
3 3 1 = Slight hazard
Flammability Flammability
0 0 2 = Moderate Hazard
Stability Physical Hazard
3 = Serious Hazard
4 = Severe hazard
705
DCC1 No :
BOC Edwards is part of BOC Limited.
The stripe symbol is a trade mark of the BOC Group.
Ref 2D01-010 form issue 1.2
P120-20-020
Issue: B
Rev Date: 01-02-05
MATERIAL SAFETY DATA SHEET Page: 3 of 14
PRODUCT NAME : Emarald Lacquer
Additional Information :
Chronic: There are reports associating repeated and prolonged occupational overexposure with
permanent brain and nervous system damage, sometimes referred to as solvents or painter
syndrome.
Methanol. Prolonged or repeated skin contact may cause dermatitis. Chronic inhalation and
ingestion may cause effects similar to those of acute inhalation and ingestion. Chronic exposure may
cause reproductive disorders and teratogenic effects. Laboratory experiments have resulted in
mutagenic effects. Prolonged exposure may cause liver, kidney, and heart damage.
n-butanol. Prolonged or repeated skin contact may cause defatting and dermatitis. May cause
reproductive and foetal effects. Laboratory experiments have resulted in mutagenic effects.
Prolonged exposure may cause liver, kidney, and heart damage. May cause damage to the auditory
nerve (some hearing loss) and vestibular injury.
PM Glycol Ether. Repeated or prolonged exposure may cause CNS stimulation.
4. First Aid Measures
Get medical aid immediately. Immediate irrigation with water for at least 15 minutes is
Eyes:
required, occasionally lifting the upper and lower eyelids.
Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least
Skin:
15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Get medical aid immediately. Remove from exposure to fresh air immediately. If breathing is
Inhalation:
difficult, give oxygen. Do not use mouth-to-mouth resuscitation. If breathing has ceased,
apply artificial respiration using oxygen and a suitable mechanical device such as a bag and
a mask.
DO NOT Induce vomiting. If victim is conscious and alert give 2-4 cupfuls of milk or water.
Ingestion:
Never give anything by mouth to an unconscious person. Possible aspiration hazard Get
medical aid immediately. Wash mouth out with water.
Notes to Physician.
Other Information:
Effects may be delayed. Ethanol may inhibit methanol metabolism. Alcoholic beverage
consumption may enhance the toxic effects of n-butanol. Butanol is especially toxic if
aspirated. Treat symptomatically and supportively.
5. Fire Fighting Measures
For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant
Extinguishing Media:
foam. For large fires, use water spray, fog, or alcohol-resistant foam. Use water
spray to cool fire-exposed containers. Water may be ineffective. Use agent most
appropriate to extinguish fire. Do NOT use straight streams of water. Cool
containers with flooding quantities of water until well after fire is out.
Flammable liquid. May be ignited by heat, sparks, and flames. Vapours may be
Fire and Explosion Hazard:
heavier than air. Vapours may form an explosive mixture with air.
Use self-contained breathing apparatus in pressure-demand, NIOSH (approved or
Special Protective
equivalent), and full protective gear with additional chemical protective clothing to
Equipment for Fire Fighters:
prevent exposure to methanol and toxic decomposition products.
Exposure to high temperatures will produce irritating, corrosive and/or toxic fumes
Hazardous Decomposition:
705
DCC1 No :
BOC Edwards is part of BOC Limited.
The stripe symbol is a trade mark of the BOC Group.
Ref 2D01-010 form issue 1.2
P120-20-020
Issue: B
Rev Date: 01-02-05
MATERIAL SAFETY DATA SHEET Page: 4 of 14
PRODUCT NAME : Emarald Lacquer
For Flammability Properties - see section 9
Additional Information : N/A
6. Accidental Release Measures
Evacuate area of spill and remove all sources of ignition. Wear appropriate protective equipment
Land Spill:
(See Section 8). No heat, sparks, or open flames in hazard area. Provide maximum explosion-
proof ventilation to prevent ignition and ventilate enclosed areas. Use spark-proof tools.
Immediately wipe up small spills. Absorb larger spills with inert material, (e.g., vermiculite, dry
sand or earth), then place into a chemical waste container. Absorbed materials may still be
flammable. Do not use combustible materials such as saw dust. Avoid runoff into storm sewers
and ditches that lead to waterways. A vapor suppressing foam may be used to reduce vapors.
Water spray may reduce vapor but may not prevent ignition in closed spaces.
Additional Information :
D.O.T. (49 CFR 171.8)/E.P.A.(40 CFR 117) Spill Reporting Information.
This product cannot be made non poisonous.
7. Handling and Storage
Store at 4掳C (40掳F) or less. Keep away from heat, sparks, flame, and other sources of ignition.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible substances in appropriate
flammables-area. Keep containers tightly closed. Do not store in aluminum or lead containers.
Wash thoroughly after handling. Remove contaminated clothing promptly and wash before reuse.
Handling:
Do not eat, drink, smoke, apply cosmetics, or store personal items in work and storage areas.
Ground and bond containers when transferring material. Do not breathe dust, vapor, mist, or gas.
Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or
vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and
flame. Do not ingest or inhale. Use only in a chemical fume hood. Do not pressurize, cut, weld,
braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Additional Information : N/A
8. Exposure Controls/Personal Protection
Exposure Limits
Ingredient ACGIH 鈥? TLV OSHA 鈥? PEL Occupational Exposure
Limits EH40 (UK)*
Methanol 200 ppm (skin) 200 ppm 100 ppm (skin)
250 ppm 鈥? STEL
n-Butanol 20 ppm 100 ppm 50 ppm 鈥? STEL
PM Glycol ether 100 ppm None Established 100 ppm
150 ppm 鈥? STEL 300 ppm 鈥? STEL
Additional Information : N/A
705
DCC1 No :
BOC Edwards is part of BOC Limited.
The stripe symbol is a trade mark of the BOC Group.
Ref 2D01-010 form issue 1.2
P120-20-020
Issue: B
Rev Date: 01-02-05
MATERIAL SAFETY DATA SHEET Page: 5 of 14
PRODUCT NAME : Emarald Lacquer
Personal Protection:
Use explosion proof ventilation equipment. Facilities storing or utilising this
Engineering Measures:
material should be equipped with an eyewash facility and a safety shower. Use
adequate ventilation to keep airborne concentrations at or below acceptable
exposure guidelines.
A respiratory protection program that meets OSHA鈥檚 29 CFR 1910.134 and ANSI
Respiratory Protection:
Z88.2 requirement or European Standard EN 149 must be followed whenever
workplace conditions warrant a respirator鈥檚 use.
Wear appropriate protective gloves and clothing to prevent skin exposure.
Hand/Skin Protection:
Wear appropriate protective eyeglasses or chemical safety goggles as described
Eye/Face Protection:
by OSHA鈥檚 eye and face protection regulations in 29 CFR 1910.133 or European
Standard EN166.
DO NOT eat or smoke whilst using the product. Wash hands before eating or
Hygiene Measures:
smoking.
Remove contaminated clothing promptly. Contaminated clothing may result in
Other/General Protection:
irritation, skin absorption or may catch fire. Launder before re-use. Discard
contaminated clothing that cannot be properly cleaned.
Additional Information : N/A
9. Physical and Chemical Properties
0 0
Liquid with slight >100 C >212 F
Appearance and Odour Boiling Point
colour. Solvent odour.
0 0
Unknown N/A C F
pH (as supplied) Melting Point
0 0
Less than 1%. Unknown C F
Solubility in Water Freezing Point
0 0
70% Unknown C F
Volatile Content by Auto Ignition
Volume
0 0
1.05 @ 25掳C/77掳F 32 C 90 F
Specific Gravity Flash Point
o
50mm 25掳C/77掳F Value range - @ F
Vapour Pressure Vapour Pressure (Torr)
Setaflash Closed Cup
Flash Point Method
N/A = Not Applicable
Additional Information :
Evaporation rate (Ether = 1)
Less than 1.
10. Stability and Reactivity
Stable.
Stability:
Oxidising agents. Avoid heat, sparks, and flames.
Material/Conditions to Avoid:
Unknown.
Hazardous Decomposition:
Will not occur
Hazardous Polymerisation:
Additional Information :
705
DCC1 No :
BOC Edwards is part of BOC Limited.
The stripe symbol is a trade mark of the BOC Group.
Ref 2D01-010 form issue 1.2
P120-20-020
Issue: B
Rev Date: 01-02-05
MATERIAL SAFETY DATA SHEET Page: 6 of 14
PRODUCT NAME : Emarald Lacquer
1-Methoxy-2-Propanol
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Isocyanates, perchloric acid, sulfuric acid, oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.
Methanol
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
High temperatures, incompatible materials, ignition sources, oxidizers.
Incompatibilities with Other Materials:
Acids (mineral, non-oxidizing, e.g. hydrochloric acid, hydrofluoric
acid, muriatic acid, phosphoric acid), acids (mineral, oxidizing,
e.g. chromic acid, hypochlorous acid, nitric acid, sulfuric acid),
acids (organic, e.g. acetic acid, benzoic acid, formic acid,
methanoic acid, oxalic acid), azo, diazo, and hydrazines (e.g.
dimethyl hydrazine, hydrazine, methyl hydrazine), isocyanates (e.g.
methyl isocyanate), nitrides (e.g. potassium nitride, sodium
nitride), peroxides and hydroperoxides (organic, e.g. acetyl
peroxide, benzoyl peroxide, butyl peroxide, methyl ethyl ketone
peroxide), epoxides (e.g. butyl glycidyl ether), Oxidants (such as
barium perchlorate, bromine, chlorine, hydrogen peroxide, lead
perchlorate, perchloric acid, sodium hypochlorite)., Active metals
(such as potassium and magnesium)., acetyl bromide, alkyl aluminum
salts, beryllium dihydride, carbontetrachloride, carbon
tetrachloride + metals, chloroform + heat, chloroform + sodium
hydroxide, cyanuric chloride, diethyl zinc, nitric acid,
potassium-tert-butoxide, chloroform + hydroxide, water reactive
substances (e.g. acetic anyhdride, alkyl aluminum chloride, calcium
carbide, ethyl dichlorosilane).
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide, formaldehyde.
Hazardous Polymerization: Will not occur.
n-Butanol
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents, reducing agents, acid chlorides, alkali metals,
aluminum, copper, copper alloys, halogens, organic peroxides, acid
anhydrides, chromium trioxide, mineral acids.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
705
DCC1 No :
BOC Edwards is part of BOC Limited.
The stripe symbol is a trade mark of the BOC Group.
Ref 2D01-010 form issue 1.2
P120-20-020
Issue: B
Rev Date: 01-02-05
MATERIAL SAFETY DATA SHEET Page: 7 of 14
PRODUCT NAME : Emarald Lacquer
Hazardous Polymerization: Will not occur.
11. Toxicological Information
For a comprehensive description for the various toxicological (health) effects, which may arise if the user comes
into contact with the substance or preparation, refer to Section 3 Hazards Identification.
Animal Data:
Test data was not available for mixture. See 鈥淎dditional Information鈥?.
LD50 value:
Test data was not available for mixture. See 鈥淎dditional Information鈥?.
LC50 value:
NAV
Tumorigenic :
Yes
Reproductive :
Yes
Mutagenic :
See 鈥淎dditional Information鈥?.
Others :
Not listed by ACGHIH, IARC, NIOSH, NTP, or OSHA.
Carcinogenicity :
Additional Information :
1-Methoxy-2-Propanol
RTECS#:
CAS# 107-98-2: UB7700000
LD50/LC50:
CAS# 107-98-2: Draize test, rabbit, eye: 500 mg/24H Mild;
Inhalation, rat: LC50 = 10000 ppm/5H; Oral, mouse: LD50 = 11700
mg/kg; Oral, rabbit: LD50 = 5700 mg/kg; Skin, rabbit: LD50 = 13
gm/kg.
Carcinogenicity:
1-Methoxy-2-propanol -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
See actual entry in RTECS for complete information.
705
DCC1 No :
BOC Edwards is part of BOC Limited.
The stripe symbol is a trade mark of the BOC Group.
Ref 2D01-010 form issue 1.2
P120-20-020
Issue: B
Rev Date: 01-02-05
MATERIAL SAFETY DATA SHEET Page: 8 of 14
PRODUCT NAME : Emarald Lacquer
Methanol
RTECS#:
CAS# 67-56-1: PC1400000
LD50/LC50:
CAS# 67-56-1: Draize test, rabbit, eye: 40 mg Moderate; Draize test,
rabbit, eye: 100 mg/24H Moderate; Draize test, rabbit, skin: 20
mg/24H Moderate; Inhalation, rat: LC50 = 64000 ppm/4H; Oral, mouse:
LD50 = 7300 mg/kg; Oral, rabbit: LD50 = 14200 mg/kg; Oral, rat: LD50
= 5628 mg/kg; Skin, rabbit: LD50 = 15800 mg/kg.
Carcinogenicity:
Methyl Alcohol -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Other:
See actual entry in RTECS for complete information.
n-Butanol
RTECS#:
CAS# 71-36-3: EO1400000
LD50/LC50:
CAS# 71-36-3: Draize test, rabbit, eye: 2 mg Severe; Draize test,
rabbit, eye: 2 mg/24H Severe; Draize test, rabbit, skin: 405 mg/24H
Moderate; Draize test, rabbit, skin: 20 mg/24H Moderate; Inhalation,
rat: LC50 = 8000 ppm/4H; Oral, mouse: LD50 = 2680 mg/kg; Oral,
rabbit: LD50 = 3484 mg/kg; Oral, rat: LD50 = 790 mg/kg; Skin,
rabbit: LD50 = 3400 mg/kg.
Carcinogenicity:
n-Butyl alcohol -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Other:
See actual entry in RTECS for complete information.
12. Ecological Information
Elimination
No data for mixture 鈥? Available ingredient information is listed below.
Persistence
No data for mixture 鈥? Available ingredient information is listed below.
Degradability
Behaviour in the Aquatic Compartment
No data for mixture 鈥? Available ingredient information is listed below.
Mobility
No data for mixture 鈥? Available ingredient information is listed below.
Bio accumulation
Ecotixicity
No data for mixture 鈥? Available ingredient information is listed below.
Aquatic
No data for mixture 鈥? Available ingredient information is listed below.
Terrestrial
705
DCC1 No :
BOC Edwards is part of BOC Limited.
The stripe symbol is a trade mark of the BOC Group.
Ref 2D01-010 form issue 1.2
P120-20-020
Issue: B
Rev Date: 01-02-05
MATERIAL SAFETY DATA SHEET Page: 9 of 14
PRODUCT NAME : Emarald Lacquer
Additional Information :
1-Methoxy-2-Propanol
Ecotoxicity:
Fish: Rainbow trout: LC50 = 19202 mg/L; 96 Hr.; UnspecifiedFish:
Fathead Minnow: LC50 = 15886 mg/L; 96 Hr.; UnspecifiedFish:
Bluegill/Sunfish: LC50 = 21742 mg/L; 96 Hr.; UnspecifiedWater flea
EC50 = 10457 mg/L; 96 Hr.; Unspecified
Methanol
Ecotoxicity:
Fish: Fathead Minnow: 29.4 g/L; 96 Hr; LC50 (unspecified)Fish:
Goldfish: 250 ppm; 11 Hr; resulted in deathFish: Rainbow trout: 8000
mg/L; 48 Hr; LC50 (unspecified)Fish: Rainbow trout: LC50 = 13-68
mg/L; 96 Hr.; 12 degrees CFish: Fathead Minnow: LC50 = 29400 mg/L;
96 Hr.; 25 degrees C, pH 7.63Fish: Rainbow trout: LC50 = 8000 mg/L;
48 Hr.; UnspecifiedBacteria: Phytobacterium phosphoreum: EC50 =
51,000-320,000 mg/L; 30 minutes; Microtox test
n-Butanol
Ecotoxicity:
Fish: Fathead Minnow: LC50 = 1510-1730 mg/L; 96 Hr; Static bioassay
at 24.7 C (pH 7.64)Water flea Daphnia: EC50 = 1980-1983 mg/L; 48 Hr;
UnspecifiedBacteria: Phytobacterium phosphoreum: EC50 = 2817-3710
mg/L; 5,30 min; Microtox testRelease of n-butanol to soil may result
in volatilization from the soil surface and biodegradation is
expected to be significant. n-Butanol should not bind strongly to
soil and so is expected to leach into groundwater. Release of
n-butanol to water is expected to result in biodegradation and in
volatilization from the water surface. Photooxidation by hydroxyl
radicals is expected to be slow.
13. Disposal Considerations
Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste and
act in accordance with local regulations. Products, which are considered hazardous for supply, are classified as
Special Waste and the disposal of such chemicals is covered by regulations that may vary according to location.
Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be
decontaminated before returning for recycling. Dispose of in accordance with applicable federal, state, provincial,
and local regulations.
Additional Information : N/A
14. Transport Information
PARAMETER EUROPEAN CANADIAN TDG UNITED STATES DOT
Proper Shipping Name
Resin solution, flammable Resin solution, flammable Resin solution, flammable
Hazard Class
3 3 3
Identification Number
UN 1866 UN 1866 UN 1866
Shipping Label
FLAMMABLE FLAMMABLE LIQUID FLAMMABLE LIQUID
LIQUID
705
DCC1 No :
BOC Edwards is part of BOC Limited.
The stripe symbol is a trade mark of the BOC Group.
Ref 2D01-010 form issue 1.2
P120-20-020
Issue: B
Rev Date: 01-02-05
MATERIAL SAFETY DATA SHEET Page: 10 of 14
PRODUCT NAME : Emarald Lacquer
Additional Information : Packing group III
U.S.: If net weight of methanol or butanol > 5,000 pounds (approximately 30,000 lbs. of product), the shipping
papers must be also marked with the letters 鈥淩Q鈥?.
IATA
Class 3
Packing Group: 3
15. Regulatory Information
European Regulatory Information
Dangerous to supply : Yes
Risk Phrases : R 10 Flammable
R 23/24/25/39 Toxic by inhalation in contact with skin and if swallowed. Danger of very
serious and irreversible effects.
R 20 Harmful if inhaled.
R 41 Risk of serious damage to eye.
Safety Phrases : S7 Keep container tightly closed
S9 Keep container in well-ventilated place.
S 16 Keep away from sources of ignition 鈥? No smoking.
S 24 Avoid contact with skin.
S 25 Avoid contact with eyes.
S 26 In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice.
S 33 Take precautionary measures against static discharges.
S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
S41 In case of fire and/or explosion do not breathe fumes.
S 45 In case of accident or if you feel unwell, seek medical advice immediately
(show the label where possible).
Hazard Symbols :
United States Regulatory Information
Methanol, n-butanol, and PM glycol ether are listed on the U.S. Toxic Substances Control Act (TSCA) inventory.
California Proposition 65: Methanol, n-butanol, and PM glycol ether are not ingredients known to the State of
California to cause cancer, birth defects, or other reproductive harm.
SARA TITLE III - SECTION 313 SUPPLIER NOTIFICATION:
This product contains the following toxic chemicals subject to reporting requirements of section 313 of the
Emergency Planning and Community Right-To-Know Act (EPCRA) of 1986 and of 40 CFR 372:
CHEMICAL CAS NUMBER % WEIGHT
Methanol 67-56-1 < 16
n-Butanol 71-36-3 < 15
Canadian Regulatory Information
705
DCC1 No :
BOC Edwards is part of BOC Limited.
The stripe symbol is a trade mark of the BOC Group.
Ref 2D01-010 form issue 1.2
P120-20-020
Issue: B
Rev Date: 01-02-05
MATERIAL SAFETY DATA SHEET Page: 11 of 14
PRODUCT NAME : Emarald Lacquer
Methanol, n-butanol and PM glycol ether are listed on the Canadian Domestic Substances List (DSL).
WHMIS Class: B2, D2A, D2B
705
DCC1 No :
BOC Edwards is part of BOC Limited.
The stripe symbol is a trade mark of the BOC Group.
Ref 2D01-010 form issue 1.2
P120-20-020
Issue: B
Rev Date: 01-02-05
MATERIAL SAFETY DATA SHEET Page: 12 of 14
PRODUCT NAME : Emarald Lacquer
Additional Information :
n-Butanol
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 10 Flammable.
R 20 Harmful by inhalation.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
WGK (Water Danger/Protection)
CAS# 71-36-3: 1
United Kingdom Occupational Exposure Limits
CAS# 71-36-3: OES-United Kingdom, STEL 50 ppm STEL; 154 mg/m3 STEL
Canada
CAS# 71-36-3 is listed on Canada's DSL List.
CAS# 71-36-3 is listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 71-36-3: OEL-AUSTRALIA:TWA 50 ppm (150 mg/m3);Skin
OEL-AUSTRIA:TWA 100 ppm (300 mg/m3)
OEL-BELGIUM:STEL 50 ppm (152 mg/m3);Skin
OEL-CZECHOSLOVAKIA:TWA 100 mg/m3;STEL 200 mg/m3
OEL-DENMARK:STEL 50 ppm (150 mg/m3);Skin
OEL-FINLAND:TWA 50 ppm (150 mg/m3);STEL 75 ppm (225 mg/m3);Skin
OEL-FRANCE:STEL 50 ppm (150 mg/m3)
OEL-GERMANY:TWA 100 ppm (300 mg/m3)
OEL-HUNGARY:TWA 100 mg/m3;STEL 200 mg/m3;Skin
OEL-INDIA:TWA 50 ppm (150 mg/m3);Skin
OEL-JAPAN:STEL 50 ppm (150 mg/m3);Skin
OEL-THE NETHERLANDS:TWA 50 ppm (150 mg/m3);Skin
OEL-THE PHILIPPINES:TWA 100 ppm (300 mg/m3)
OEL-RUSSIA:STEL 50 ppm (10 mg/m3)
OEL-SWEDEN:TWA 15 ppm (45 mg/m3);STEL 30 ppm (90 mg/m3);Skin
OEL-SWITZERLAND:TWA 50 ppm (150 mg/m3);STEL 100 ppm;Skin
OEL-TURKEY:TWA 100 ppm (300 mg/m3)
OEL-UNITED KINGDOM:TWA 50 ppm (150 mg/m3);STEL 50 ppm;Skin
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
US FEDERAL
TSCA
CAS# 71-36-3 is listed on the TSCA inventory.
Methanol
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T F
Risk Phrases:
R 11 Highly flammable.
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
R 39/23/24/25 Toxic : danger of very serious
705
DCC1 No :
BOC Edwards is part of BOC Limited.
The stripe symbol is a trade mark of the BOC Group.
Ref 2D01-010 form issue 1.2
P120-20-020
Issue: B
Rev Date: 01-02-05
MATERIAL SAFETY DATA SHEET Page: 13 of 14
PRODUCT NAME : Emarald Lacquer
irreversible effects through inhalation, in contact
with skin and if swallowed.
Safety Phrases:
S 7 Keep container tightly closed.
S 16 Keep away from sources of ignition - No
smoking.
S 36/37 Wear suitable protective clothing and
gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 67-56-1: 1
United Kingdom Occupational Exposure Limits
CAS# 67-56-1: OES-United Kingdom, TWA 200 ppm TWA; 266 mg/m3 TWA
CAS# 67-56-1: OES-United Kingdom, STEL 250 ppm STEL; 333 mg/m3 STEL
Canada
CAS# 67-56-1 is listed on Canada's DSL List.
CAS# 67-56-1 is listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 67-56-1: OEL-ARAB Republic of Egypt:TWA 200 ppm (260 mg/m3);Skin
US FEDERAL
TSCA
CAS# 67-56-1 is listed on the TSCA inventory.
1-Methoxy-2-Propanol
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F
Risk Phrases:
R 10 Flammable.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 24 Avoid contact with skin.
S 33 Take precautionary measures against static
discharges.
WGK (Water Danger/Protection)
CAS# 107-98-2: 1
United Kingdom Occupational Exposure Limits
CAS# 107-98-2: OES-United Kingdom, TWA 100 ppm TWA; 375 mg/m3 TWA
CAS# 107-98-2: OES-United Kingdom, STEL 300 ppm STEL; 1120 mg/m3
STEL
Canada
CAS# 107-98-2 is listed on Canada's DSL List.
CAS# 107-98-2 is listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 107-98-2: OEL-BELGIUM:TWA 100 ppm (369 mg/m3);STEL 150 ppm (553 m
g/m3)
OEL-DENMARK:TWA 100 ppm (360 mg/m3)
OEL-FINLAND:TWA 100 ppm (360 mg/m3);STEL 150 ppm;Skin
OEL-FRANCE:TWA 100 ppm (360 mg/m3)
OEL-GERMANY:TWA 100 ppm (375 mg/m3)
705
DCC1 No :
BOC Edwards is part of BOC Limited.
The stripe symbol is a trade mark of the BOC Group.
Ref 2D01-010 form issue 1.2
P120-20-020
Issue: B
Rev Date: 01-02-05
MATERIAL SAFETY DATA SHEET Page: 14 of 14
PRODUCT NAME : Emarald Lacquer
OEL-THE NETHERLANDS TWA 100 ppm (360 mg/m3)
OEL-SWITZERLAND:TWA 100 ppm (360 mg/m3);STEL 200 ppm (720 mg/m3)
OEL-UNITED KINGDOM:TWA 100 ppm (360 mg/m3);Skin
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
US FEDERAL
TSCA
CAS# 107-98-2 is listed on the TSCA inventory.
16. Other Information
Original Supplier Information:
Product classification under section 311 SARA.
Acute(Y) Chronic(Y) Fire(Y) Reactive(N) Pressure(N).
Reportable quantity of product 30,000lbs.
Glossary : CAS, Chemical Abstracts Service. TWA, Time-Weighted Average. STEL, Short Term Exposure Limit.
NFPA, National Fire Protection Association. HMIS, Hazardous Material Information Service. LD, Lethal Dose. LC,
Lethal Concentration. OSHA, Occupational Safety and Health Administration, US department of Labour. ACGIH,
American Conference of Governmental Industrial Hygienists. EINECS, European Inventory of Existing Commercial
Substances. MSHA, Mine Safety and Health Administration. NIOSH, National Institute for Occupational Safety and
Health. SCBA, Self-Contained Breathing Apparatus. CFR, Code of Federal Regulations. RTECS, Registry of Toxic
Effects of Chemical Substances. IARC, International Agency for Research in Cancer. NTP, National Toxicology
Program, OEL, Occupational Exposure Limit. TLV, Threshold Limit Value. TSCA, Toxic Substances Control Act.
Revisions
This document has been reformatted. Individual changes are not highlighted.
___________________________________________________________________________________________
_
Although the information and recommendations in this data sheet are to the best of our knowledge correct, it is recommended
that you make your own determination of the material鈥檚 suitability for your purpose before you use it. The information contained in
this data sheet has been reproduced from the manufacturers data, the accuracy of this information is the responsibility of the
manufacturer. BOC Edwards accept no responsibility for damage of any nature resulting from the use of, or the reliance upon this
data sheet.
705
DCC1 No :
BOC Edwards is part of BOC Limited.
The stripe symbol is a trade mark of the BOC Group.
Ref 2D01-010 form issue 1.2
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