Carolina Biological Supply Co. Catalog No.:841292
MATERIAL SAFETY DATA SHEET
EM SCIENCE
|1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
--------------------------------------------------------------------------------
Manufacturer.............: Preparation Date.: 7/21/00
EM SCIENCE
A Division of EM Industries Information Phone Number.: 856-423-6300
P.O. Box 70 Hours: Mon. to Fri. 8:30-5
480 Democrat Road Chemtrec Emergency Number: 800-424-9300
Gibbstown, N.J. 08027 Hours: 24 hrs a day
Catalog Number(s):
55 AX0072 AX0073 AX0073I AX0076 AX0071 AX0073Y
AX0073P 62 AX0073T AX0073TP AX0079 AX0073PS AX0074
0000567W 00005687 ACS003
Product Name:
Acetic Acid
Synonyms:
Ethanoic Acid; Glacial Acetic Acid
Chemical Family:
Organic Acid
Formula:
CH3COOH
Molecular Weight.:
60.05
2. COMPOSITION / INFORMATION ON INGREDIENTS
--------------------------------------------------------------------------------
Component CAS # Appr %
____________________________________________________________
Acetic Acid
64-19-7 100%
3. HAZARDS IDENTIFICATION
--------------------------------------------------------------------------------
EMERGENCY OVERVIEW
CAUSES SEVERE BURNS.
MAY BE FATAL IF SWALLOWED.
HARMFUL IF INHALED.
May Cause Damage To Respiratory Passages and Lungs.
FLAMMABLE LIQUID AND VAPOR.
Appearance:
Clear, colorless liquid, pungent odor
POTENTIAL HEALTH EFFECTS (ACUTE AND CHRONIC)
Symptoms of Exposure:
Contact causes severe burns, eye damage. Vapor inhalation causes
lachrymation, severe irritation of respiratory passages; bronchitis, pulmonary
edema and chemical pneumonitis may occur. May be fatal if swallowed.
Medical Cond. Aggravated by Exposure:
Respiratory conditions
Routes of Entry:
Inhalation, ingestion or skin contact.
Carcinogenicity:
The material is not listed (IARC, NTP, OSHA) as cancer causing
agent.
4. FIRST AID MEASURES
--------------------------------------------------------------------------------
Emergency First Aid:
GET MEDICAL ASSISTANCE FOR ALL CASES OF OVEREXPOSURE.
Skin: Immediately flush thoroughly with large amounts of water.
Eyes: Immediately flush thoroughly with water for at least 15
minutes.
Inhalation: Remove to fresh air; give artificial respiration if
breathing has stopped.
Ingestion: Do not induce vomiting; if conscious, give water
freely and get medical attention.
Remove contaminated clothing and wash before reuse.
5. FIRE FIGHTING MEASURES
--------------------------------------------------------------------------------
Flash Point (F): 109F (cc)
Flammable Limits LEL (%): 5.40
Flammable Limits UEL (%): 16.00
Extinguishing Media:
Use water spray, foam, dry chemical, or CO2.
Fire Fighting Procedures:
Wear self-contained, positive pressure, breathing apparatus.
Wear acid-resistant protective suit (full face shield) with
rubber boots and gloves.
Fire & Explosion Hazards:
Moderate fire and explosion hazard. Vapor can travel distances to ignition source
and flash back.
6. ACCIDENTAL RELEASE MEASURES
--------------------------------------------------------------------------------
Spill Response:
Evacuate the area of all unnecessary personnel. Wear suitable protective
equipment listed under Exposure / Personal Protection. Eliminate any ignition
sources until the area is determined to be free from explosion or fire hazards.
Contain the release and eliminate its source, if this can be done without risk.
Take up and containerize for proper disposal as described under Disposal.
Comply with Federal, State, and local regulations on reporting releases. Refer to
Regulatory Information for reportable quantity and other regulatory data.
EM SCIENCE recommends SPILL-X neutralizers and absorbent agents for
various types of spills. Additional information on the SPILL-X products can be
provided through the EM SCIENCE Technical Service Department (856) 423-
6300. The following EM SCIENCE SPILL-X neutralizer and absorbent is
recommended for this product:
SX0861 Spill-X-A Acid Spill Treatment Kit
7. HANDLING AND STORAGE
--------------------------------------------------------------------------------
Handling & Storage:
Keep container tightly closed. Store above 62F, but away from direct heat,
ignition sources and oxidizers. Do not breathe vapor. Retained residue may
make empty containers hazardous; use caution! Do not get in eyes, on skin, or
on clothing.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
--------------------------------------------------------------------------------
ENGINEERING CONTROLS AND PERSONAL PROTECTIVE EQUIPMENT:
Ventilation, Respiratory Protection, Protective Clothing, Eye Protection:
Respiratory Protection: If workplace exposure limit(s) of product or any
component is exceeded (see TLV/PEL), a NIOSH/MSHA approved air supplied
respirator is advised in absence of proper environmental control. OSHA
regulations also permit other NIOSH/MSHA respirators (negative pressure type)
under specified conditions (see your safety equipment supplier). Engineering
and/or administrative controls should be implemented to reduce exposure.
Material must be handled or transferred in an approved fume hood or with
equivalent ventilation. Protective gloves (Natural rubber, Neoprene, PVC or
equivalent) must be worn to prevent skin contact. Safety glasses with side
shields must be worn at all times. Impervious protective clothing should be worn
to prevent skin contact.
Work/Hygenic Practices:
Wash thoroughly after handling. Do not take internally. Eye wash and safety
equipment should be readily available.
EXPOSURE GUIDELINES
OSHA - PEL:
TWA STEL CL
Component PPM MG/M3 PPM MG/M3 PPM MG/M3 Skin
____________________________________________________________
Acetic Acid
10 25
ACGIH - TLV:
TWA STEL CL
Component PPM MG/M3 PPM MG/M3 PPM MG/M3 Skin
____________________________________________________________
Acetic Acid
10 25 15 37
If there are no exposure limit numbers listed in the Exposure Guidelines chart,
this indicates that no OSHA or ACGIH exposure limts have been established.
9. PHYSICAL AND CHEMCIAL PROPERTIES
--------------------------------------------------------------------------------
Boiling Point (C 760 mmHg) : 118.1C
Melting Point (C) : 16.7C
Specific Gravity (H20 = 1) : 1.049
Vapor Pressure (mm Hg) : 11.4 20C
Percent Volatile by vol (%): 100%
Vapor Density (Air = 1) : 2.07
Evaporation Rate (BuAc = 1): 0.97
Solubility in Water (%) : Miscible
Appearance :
Clear, colorless liquid, pungent odor
10. STABILITY AND REACTIVITY
--------------------------------------------------------------------------------
Stability: Yes
Hazardous Polymerization:
Does not occur
Hazardous Decomposition:
COx
Conditions to Avoid:
Heat; contact with ignition sources. Diluted acid reacts with metals to produce
flammable hydrogen gas.
Materials To Avoid:
( ) Water
( ) Acids
( ) Bases
( ) Corrosives
(X) Oxidizers
(X) Other: Strong alkalies, metals, amines, cyanides,
sulfides, chromic acid, nitric acid, hydrogen
peroxide, carbonates
11. TOXICOLOGICAL INFORMATION
--------------------------------------------------------------------------------
Toxicity Data
ihl-mus LC50: 5620 ppm/1H orl-rat LD50: 3310 mg/kg
skin-rbt LD50: 1060 mg/kg
Toxicological Findings:
Test on laboratory animals indicate material may produce adverse
mutagenic and reproductive effects.
Cited in Registry of Toxic Effects of Chemical Substances (RTECS)
12. DISPOSAL CONSIDERATIONS
--------------------------------------------------------------------------------
EPA Waste Numbers: D002 D001
Treatment:
Specified Technology - Neutralize to pH 6-9. Contact your local permitted waste
disposal site (TSD) for permissible treatment sites.
ALWAYS CONTACT A PERMITTED WASTE DISPOSER (TSD) TO ASSURE
COMPLIANCE WITH ALL CURRENT LOCAL, STATE AND FEDERAL
REGULATIONS.
13. TRANSPORT INFORMATION
--------------------------------------------------------------------------------
DOT Proper Shipping Name:
Acetic Acid, Glacial
DOT ID Number :
UN2789
14. REGULATORY INFORMATION
--------------------------------------------------------------------------------
TSCA Statement:
The CAS number of this product is listed on the TSCA Inventory.
SARA SARA CERCLA
Component EHS EHS TPQ RQ
(302) (lbs) (lbs)
____________________________________________________________
Acetic Acid
5000
OSHA SARA DeMinimis
Component Floor List 313 for SARA 313
(%)
____________________________________________________________
Acetic Acid
Y
If there is no information listed on the regulatory information chart, this indicates
that the chemical is not covered by the specific regulation listed.
15. OTHER INFORMATION
--------------------------------------------------------------------------------
Comments:
None
NFPA Hazard Ratings:
Health :3
Flammability : 2
Reactivity :0
Special Hazards :
Revision History: 3/20/00 8/1/81 9/1/83 9/12/86
1/29/87 10/27/87 11/28/88 1/10/89 2/13/89 3/1/91
11/26/91 12/3/92 3/3/94 10/13/95 1/13/97 10/23/97
1/29/98 8/26/98
| = Revised Section
N/A = Not Available
N/E = None Established
The statements contained herein are offered for informational purposes only and
are based upon technical data that EM Science believes to be accurate. It is
intended for use only by persons having the necessary technical skill and at their
own discretion and risk. Since conditions and manner of use are outside our
control, we make NO WARRANTY, EXPRESS OR IMPLIED, OR
MERCHANTABILITY, FITNESS OR OTHERWISE.
|