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                                       TEREPHTHALIC ACID
Chemwatch Material Safety Data Sheet (REVIEW)
Issue Date: 17-Jun-2005 CHEMWATCH 32539
A317TC CD 2006/2 Page 1 of 10



Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION


PRODUCT NAME
TEREPHTHALIC ACID

SYNONYMS
C8-H6-O4, C6H4(COOH)2, "p-benzenedicarboxylic acid", "1, 4-benzenedicarboxylic
acid", "p-phthalic acid", "PTA purified terephthalic acid"

PRODUCT USE
In the manufacture of polyester film and sheet (following reaction with glycol);
reagent for alkali in wool; additve to poultry feeds; inhibits spontaneous
mammary tumorigenesis in mice.

SUPPLIER
Quantum Chemicals Pty Ltd
70 Quantum Close
Quantum Industrial Park
Dandenong South VIC 3175
Australia
Telephone: 1300 782 688
Emergency Tel: 1300 131 001
Fax: 1300 782 699


HAZARD RATINGS



Flammability
Toxicity
Body Contact
Reactivity
Chronic

SCALE: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4


Section 2 - HAZARDS IDENTIFICATION


STATEMENT OF HAZARDOUS NATURE
NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. According to
the Criteria of NOHSC, and the ADG Code.
TEREPHTHALIC ACID
Chemwatch Material Safety Data Sheet (REVIEW)
Issue Date: 17-Jun-2005 CHEMWATCH 32539
A317TC CD 2006/2 Page 2 of 10
Section 2 - HAZARDS IDENTIFICATION

POISONS SCHEDULE
None

RISK
Ingestion may produce health damage*.
Cumulative effects may result following exposure*.
May possibly affect fertility*.
* (limited evidence).

SAFETY
Avoid exposure - obtain special instructions before use.
Take off immediately all contaminated clothing.


Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS

NAME CAS RN %
terephthalic acid 100-21-0 >98


Section 4 - FIRST AID MEASURES


SWALLOWED
鈥? Immediately give a glass of water.
鈥? First aid is not generally required. If in doubt, contact a Poisons
Information Centre or a doctor.

EYE
If this product comes in contact with the eyes:
鈥? Immediately hold eyelids apart and flush the eye continuously with running
water.
鈥? Ensure complete irrigation of the eye by keeping eyelids apart and away from
eye and moving the eyelids by occasionally lifting the upper and lower lids.
鈥? Continue flushing until advised to stop by the Poisons Information Centre or a
doctor, or for at least 15 minutes.
鈥? Transport to hospital or doctor without delay.
鈥? Removal of contact lenses after an eye injury should only be undertaken by
skilled personnel.

SKIN
If skin contact occurs:
鈥? Immediately remove all contaminated clothing, including footwear
鈥? Flush skin and hair with running water (and soap if available).
鈥? Seek medical attention in event of irritation.

INHALED
鈥? If dust is inhaled, remove from contaminated area.
鈥? Encourage patient to blow nose to ensure clear passage of breathing.
鈥? If irritation or discomfort persists seek medical attention.

NOTES TO PHYSICIAN
Treat symptomatically.


Section 5 - FIRE FIGHTING MEASURES


EXTINGUISHING MEDIA
鈥? Foam.
鈥? Dry chemical powder.
TEREPHTHALIC ACID
Chemwatch Material Safety Data Sheet (REVIEW)
Issue Date: 17-Jun-2005 CHEMWATCH 32539
A317TC CD 2006/2 Page 3 of 10
Section 5 - FIRE FIGHTING MEASURES

鈥? BCF (where regulations permit).
鈥? Carbon dioxide.
鈥? Water spray or fog - Large fires only.

FIRE FIGHTING
鈥? Use water delivered as a fine spray to control fire and cool adjacent area.
鈥? Do not approach containers suspected to be hot.
鈥? Cool fire exposed containers with water spray from a protected location.
鈥? If safe to do so, remove containers from path of fire.
鈥? Equipment should be thoroughly decontaminated after use.

FIRE/EXPLOSION HAZARD
鈥? Solid which exhibits difficult combustion or is difficult to ignite.
鈥? Avoid generating dust, particularly clouds of dust in a confined or
unventilated space as dusts may form an explosive mixture with air, and any
source of ignition, i.e. flame or spark, will cause fire or explosion. Dust
clouds generated by the fine grinding of the solid are a particular hazard;
accumulations of fine dust may burn rapidly and fiercely if ignited
鈥? Dry dust can also be charged electrostatically by turbulence, pneumatic
transport, pouring, in exhaust ducts and during transport.
鈥? Build-up of electrostatic charge may be prevented by bonding and grounding.
鈥? Powder handling equipment such as dust collectors, dryers and mills may
require additional protection measures such as explosion venting.
鈥? All movable parts coming in contact with this material should have a speed of
less than 1-meter/sec.

FIRE INCOMPATIBILITY
Avoid contamination with oxidising agents i.e. nitrates, oxidising acids,
chlorine bleaches, pool chlorine etc. as ignition may result.

HAZCHEM
None


Section 6 - ACCIDENTAL RELEASE MEASURES


EMERGENCY PROCEDURES

MINOR SPILLS
鈥? Clean up all spills immediately.
鈥? Avoid contact with skin and eyes.
鈥? Wear impervious gloves and safety glasses.
鈥? Use dry clean up procedures and avoid generating dust.
鈥? Sweep up or
鈥? Vacuum up (consider explosion-proof machines designed to be grounded during
storage and use).
鈥? Place spilled material in clean, dry, sealable, labelled container.

MAJOR SPILLS
鈥? Clear area of personnel and move upwind.
鈥? Alert Fire Brigade and tell them location and nature of hazard.
鈥? Control personal contact by using protective equipment and dust respirator.
鈥? Prevent spillage from entering drains, sewers or water courses.
鈥? Avoid generating dust.
鈥? Sweep, shovel up. Recover product wherever possible.
鈥? Put residues in labelled plastic bags or other containers for disposal.
鈥? If contamination of drains or waterways occurs, advise emergency services.

EMERGENCY RESPONSE PLANNING GUIDELINES (ERPG)
The maximum airborne concentration below which it is believed that nearly all
TEREPHTHALIC ACID
Chemwatch Material Safety Data Sheet (REVIEW)
Issue Date: 17-Jun-2005 CHEMWATCH 32539
A317TC CD 2006/2 Page 4 of 10
Section 6 - ACCIDENTAL RELEASE MEASURES

individuals could be exposed for up to one hour WITHOUT experiencing or developing

life-threatening health effects is:
terephthalic acid 500 mg/m鲁

irreversible or other serious effects or symptoms which could
impair an individual's ability to take protective action is:
terephthalic acid 50 mg/m鲁

other than mild, transient adverse effects
without perceiving a clearly defined odour is:
terephthalic acid 30 mg/m鲁

The threshold concentration below which most people.
will experience no appreciable risk of health effects:
terephthalic acid 10 mg/m鲁

American Industrial Hygiene Association (AIHA)

Ingredients considered according to the following cutoffs
Very Toxic (T+) >= 0.1% Toxic (T) >= 3.0%
R50 >= 0.25% Corrosive (C) >= 5.0%
R51 >= 2.5%
else >= 10%
where percentage is percentage of ingredient found in the mixture

SAFE STORAGE WITH OTHER CLASSIFIED CHEMICALS
___________________________________________



+ + + + + +
___________________________________________
+: May be stored together
O: May be stored together with specific preventions
X: Must not be stored together


Personal Protective Equipment advice is contained in Section 8 of the MSDS.


Section 7 - HANDLING AND STORAGE


PROCEDURE FOR HANDLING
鈥? Limit all unnecessary personal contact.
鈥? Wear protective clothing when risk of exposure occurs.
鈥? Use in a well-ventilated area.
鈥? When handling DO NOT eat, drink or smoke.
鈥? Always wash hands with soap and water after handling.
鈥? Avoid physical damage to containers.
鈥? Use good occupational work practice.
鈥? Observe manufacturer's storing and handling recommendations.

SUITABLE CONTAINER
Multi ply paper bag with sealed plastic liner or heavy gauge plastic bag
NOTE: Bags should be stacked, blocked, interlocked, and limited in height so
that they are stable and secure against sliding or collapse. Check that all
containers are clearly labelled and free from leaks. Packing as recommended by
manufacturer.
TEREPHTHALIC ACID
Chemwatch Material Safety Data Sheet (REVIEW)
Issue Date: 17-Jun-2005 CHEMWATCH 32539
A317TC CD 2006/2 Page 5 of 10
Section 7 - HANDLING AND STORAGE

STORAGE INCOMPATIBILITY
Avoid reaction with oxidising agents.
Avoid strong bases.
Reaction with nitric acid may be explosive.

STORAGE REQUIREMENTS
鈥? Store in original containers.
鈥? Keep containers securely sealed.
鈥? Store in a cool, dry, well-ventilated area.
鈥? Store away from incompatible materials and foodstuff containers.
鈥? Protect containers against physical damage and check regularly for leaks.
鈥? Observe manufacturer's storing and handling recommendations.


Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION


EXPOSURE CONTROLS
The following materials had no OELs on our record under the following CAS or Chemwatch (CW) numbers
terephthalic acid: No data available for CAS:100-21-0


Not available. Refer to individual constituents.

PERSONAL PROTECTION




EYE
鈥? Safety glasses.
鈥? Safety glasses with side shields.
鈥? Chemical goggles.
鈥? Contact lenses may pose a special hazard; soft contact lenses may absorb and
concentrate irritants. A written policy document, describing the wearing of lens
or restrictions on use, should be created for each workplace or task. This
should include a review of lens absorption and adsorption for the class of
chemicals in use and an account of injury experience. Medical and first-aid
personnel should be trained in their removal and suitable equipment should be
readily available. In the event of chemical exposure, begin eye irrigation
immediately and remove contact lens as soon as practicable. Lens should be
removed at the first signs of eye redness or irritation - lens should be removed
in a clean environment only after workers have washed hands thoroughly. [CDC
NIOSH Current Intelligence Bulletin 59].

HANDS/FEET
Rubber gloves.
PVC gloves.
Safety footwear.
Rubber boots.

OTHER
Overalls.
PVC apron.
鈥? Barrier cream.
鈥? Eyewash unit.
TEREPHTHALIC ACID
Chemwatch Material Safety Data Sheet (REVIEW)
Issue Date: 17-Jun-2005 CHEMWATCH 32539
A317TC CD 2006/2 Page 6 of 10
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

Ensure there is ready access to a safety shower.

RESPIRATOR
Protection Factor Half-Face Full-Face Powered Air
Respirator Respirator Respirator
10 x ES P1 Air-line* -- PAPR-P1 -
50 x ES Air-line** P2 PAPR-P2
100 x ES - P3 -
Air-line* -
100+ x ES - Air-line** PAPR-P3

* - Negative pressure demand ** - Continuous flow.

The local concentration of material, quantity and
conditions of use determine the type of personal
protective equipment required.
For further information consult site specific
CHEMWATCH data (if available), or your
Occupational Health and Safety Advisor.

ENGINEERING CONTROLS
General exhaust is adequate under normal operating conditions. If risk of
overexposure exists, wear SAA approved respirator. Correct fit is essential to
obtain adequate protection. Provide adequate ventilation in warehouse or closed
storage areas. Air contaminants generated in the workplace possess varying
"escape" velocities which, in turn, determine the "capture velocities" of fresh
circulating air required to effectively remove the contaminant.

Type of Contaminant: Air Speed:
solvent " "vapours " degreasing "etc. 0.25-0.5 m/s (50-100 f/min)
" evaporating from tank (in still air)
aerosols " fumes from pouring 0.5-1 m/s (100-200 f/min.)
"operations " intermittent container
"filling " low speed conveyer
"transfers " "welding " spray "drift "
plating acid "fumes " pickling
(released at low velocity into zone of
active generation)
direct "spray " spray painting in 1-2.5 m/s (200-500 f/min)
shallow "booths " drum "filling "
conveyer "loading " crusher "dusts "
gas discharge (active generation into
zone of rapid air motion)
grinding " abrasive "blasting " 2.5-10 m/s (500-2000 f/min.)
"tumbling " high speed wheel generated
dusts (released at high initial
velocity into zone of very high rapid
air motion).

Within each range the appropriate value depends on:

Lower end of the range Upper end of the range
1: Room air currents minimal or 1: Disturbing room air currents
favourable to capture
2: Contaminants of low toxicity or of 2: Contaminants of high toxicity
nuisance value only
3: Intermittent, low production. 3: High production, heavy use
4: Large hood or large air mass in 4: Small hood - local control only
motion

Simple theory shows that air velocity falls rapidly with distance away from the
TEREPHTHALIC ACID
Chemwatch Material Safety Data Sheet (REVIEW)
Issue Date: 17-Jun-2005 CHEMWATCH 32539
A317TC CD 2006/2 Page 7 of 10
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

opening of a simple extraction pipe. Velocity generally decreases with the
square of distance from the extraction point (in simple cases). Therefore the
air speed at the extraction point should be adjusted, accordingly, after
reference to distance from the contaminating source. The air velocity at the
extraction fan, for example, should be a minimum of 1-2 m/s (200-400 f/min.) for
extraction of solvents generated in a tank 2 meters distant from the extraction
point. Other mechanical considerations, producing performance deficits within
the extraction apparatus, make it essential that theoretical air velocities are
multiplied by factors of 10 or more when extraction systems are installed or
used.


Section 9 - PHYSICAL AND CHEMICAL PROPERTIES


APPEARANCE
Off-white crystalline powder; does not mix well with water. Soluble
in alkalies, dimethyl sulfoxide.

PHYSICAL PROPERTIES
Solid.
Does not mix with water.
Sinks in water.

Molecular Weight: 166.13 Boiling Range (掳C): Not applicable
Melting Range (掳C): sublimes 402 C Specific Gravity (water=1): 1.5
Solubility in water (g/L): Partly miscible pH (as supplied): Not applicable
pH (1% solution): 2.16 (saturated) Vapour Pressure (kPa): <0.0013 @ 20 C
Volatile Component (%vol): Negligible Evaporation Rate: Not applicable
Relative Vapour Density (air=1): Not applicable Flash Point (掳C): 260 (OC)
Lower Explosive Limit (%): 0.05 g/l Upper Explosive Limit (%): Not available
Autoignition Temp (掳C): 496.11 Decomposition Temp (掳C): Not available
State: Divided solid Viscosity: Not available


Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION


CONDITIONS CONTRIBUTING TO INSTABILITY
鈥? Presence of incompatible materials.
鈥? Product is considered stable.
鈥? Hazardous polymerisation will not occur.


Section 11 - TOXICOLOGICAL INFORMATION


POTENTIAL HEALTH EFFECTS

ACUTE HEALTH EFFECTS

SWALLOWED
The material is moderately discomforting to the gastro-intestinal tract and may
be harmful if swallowed in large quantity Phthalates (aromatic dicarboxylic acid
esters), in general, exhibit low toxicity, partly because of poor absorption but
mainly as a result of rapid metabolism in which the esters are saponified to
phthalic acid (which is rapidly excreted) and the parent alcohol (which is
subsequently metabolised). The pathology of these compounds seems to be related
to the released alcohol and its biological effects. The rate of absorption of
ingested phthalate esters is influenced by the content of dietary fat. Ingested
phthalate esters may to a lesser degree be absorbed as the monoester derivatives
TEREPHTHALIC ACID
Chemwatch Material Safety Data Sheet (REVIEW)
Issue Date: 17-Jun-2005 CHEMWATCH 32539
A317TC CD 2006/2 Page 8 of 10
Section 11 - TOXICOLOGICAL INFORMATION

or in the case of di(2-ethylhexyl)phthalate, as the diester. Cumulative toxicity
of the phthalates has been observed on repeated administration. Both di-n-octyl
phthalate and di(2-ethylhexyl)phthalate were found to have 22-28 times greater
toxicity (based on LD50s) following repeated administration to animals. The
liver has been shown to be the target organ affected by the phthalates. In
general phthalates have induced liver enlargement; this increase in liver weight
has been attributed to rapid cell division (hyperplasia) along with the
detachment of cells (hypertrophy). The increase in liver weight caused by
phthalates has been found to reverse to normal or even below normal levels on
prolonged exposure.

Exposure to phthalates, in general, has been found to be associated with a
reduction in circulating cholesterol and serum triglyceride levels which
accounted for a reduction in liver steroidogenesis. The phthalates also effect
carbohydrate metabolism in the liver producing depleted glycogen electron
transport inhibitors following interaction with mitochondria. Testicular atrophy
produced in rats during feeding studies depends on the length and structure of
the alcohol; in general the lower molecular weight esters produce the more
severe effects. The toxicity of phthalic acid isomers decreases in the order
o-phthalic acid, isophthalic acid and terephthalic acid. Phthalic acid is not
metabolised but is excreted, unchanged, in the urine and faeces. Terephthalic
acid appears to potentiate the biological effects of substances such as
antibiotics, thiamine and sulfonamides.

EYE
The dust may produce eye discomfort causing smarting, pain and redness.
The material may be irritating to the eye, with prolonged contact causing
inflammation. Repeated or prolonged exposure to irritants may produce
conjunctivitis.

SKIN
The material is moderately discomforting to the skin.
Open cuts, abraded or irritated skin should not be exposed to this material.

INHALED
The dust may be discomforting to the upper respiratory tract.
Persons with impaired respiratory function, airway diseases and conditions such
as emphysema or chronic bronchitis, may incur further disability if excessive
concentrations of particulate are inhaled.

CHRONIC HEALTH EFFECTS
Principal routes of exposure are by accidental skin and eye contact and
inhalation of generated dusts. Exposure to phthalates over years leads to pain,
numbness and spasms in the hands and feet. Many people have developed multiple
disorders in the nervous system and the balancing system. Levels of sex hormones
are reduced in women, leading to missed ovulations and miscarriages. They also
reduce sperm counts and fertility in men. They mimic certain sex hormones and
can damage the foetus. Phthalates are found in paints, inks and glues.

TOXICITY AND IRRITATION
TOXICITY IRRITATION
Oral (rat) LD50: >6400 mg/kg Eye (rabbit): 500 mg/24h - Mild
Oral (mouse) LD50: 3200 mg/kg
Oral (mouse) LD50: >5000 mg/kg
Intraperitoneal (mouse) LD50: 1430 mg/kg
TEREPHTHALIC ACID
Chemwatch Material Safety Data Sheet (REVIEW)
Issue Date: 17-Jun-2005 CHEMWATCH 32539
A317TC CD 2006/2 Page 9 of 10


Section 12 - ECOLOGICAL INFORMATION

"Half-life Soil - High (hours):" 168
"Half-life Soil - Low (hours):" 24
"Half-life Air - High (hours):" 2326
"Half-life Air - Low (hours):" 232.6
"Half-life Surface water - High (hours):" 168
"Half-life Surface water - Low (hours):" 24
"Half-life Ground water - High (hours):" 336
"Half-life Ground water - Low (hours):" 48
"Aqueous biodegradation - Aerobic - High (hours):" 168
"Aqueous biodegradation - Aerobic - Low (hours):" 24
"Aqueous biodegradation - Anaerobic - High (hours):" 672
"Aqueous biodegradation - Anaerobic - Low (hours):" 96
"Aqueous biodegradation - Removal secondary treatment - High (hours):" 96%
"Photolysis maximum light absorption - High (nano-m):" 285.5
"Photolysis maximum light absorption - Low (nano-m):" 240.5
"Photooxidation half-life air - High (hours):" 2326
"Photooxidation half-life air - Low (hours):" 232.6

Koc: 292
Half-life (hr) air: 1392
BCF: 19
Toxicity Fish: LC50(96)1.1-1.9mg/L
Toxicity invertebrate: LC50(96)0.039mg/L
processes Abiotic: rapid hydrol. in water


Section 13 - DISPOSAL CONSIDERATIONS

鈥? Recycle wherever possible or consult manufacturer for recycling options.
鈥? Consult State Land Waste Authority for disposal.
鈥? Bury or incinerate residue at an approved site.
鈥? Recycle containers if possible, or dispose of in an authorised landfill.


Section 14 - TRANSPORTATION INFORMATION


HAZCHEM
None


NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS:UN,IATA,IMDG


Section 15 - REGULATORY INFORMATION


POISONS SCHEDULE
None

REGULATIONS

terephthalic acid (CAS: 100-21-0) is found on the following regulatory lists;
Australia High Volume Industrial Chemical List (HVICL)
Australia Inventory of Chemical Substances (AICS)
OECD Representative List of High Production Volume (HPV) Chemicals
TEREPHTHALIC ACID
Chemwatch Material Safety Data Sheet (REVIEW)
Issue Date: 17-Jun-2005 CHEMWATCH 32539
A317TC CD 2006/2 Page 10 of 10


Section 16 - OTHER INFORMATION


Denmark Advisory list for selfclassification of dangerous substances
Substance CAS Suggested codes
terephthalic acid 100-21-0 R43

This document is copyright. Apart from any fair dealing for the purposes of
private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from
CHEMWATCH. TEL (+61 3) 9572 4700.

Issue Date: 17-Jun-2005
Print Date: 29-Jun-2006

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