Eng
Material Safety Data Sheet
Conforms to 93/112/EC and ISO 11014-1
Responsible Name Pierce Administration
Section 1. Chemical Product and Company Identification
4M Imidazole Stock Solution
Product name
Product No. 1858602
Supplier In USA:In Europe: Manufacturer Pierce Biotechnology
Pierce Perbio Science P.O. Box 117
P.O. Box 117
Industriezone III Rockford, IL 61105
Rockford, IL 61105
Industrielaan 27 USA
USA 9320 Erembodegem-Aalst 815.968.0747 or
815.968.0747 or
Belgium 1.800.874.3723
1.800.874.3723
Tel:+32 53 83 44 04
Fax:+32 53 83 76 38
In Case of Emergency CALL CHEMTREC: Print Date 11/6/2002
800.424.9300 Validation Date 11/4/2002
OUTSIDE US:
MSDS# 3925
202.483.7616
Intended Use Refer to the instruction booklet for proper and intended use. Otherwise, contact supplier for specific applications.
Section 2. Composition, Information on Ingredients
Substance/Preparation : Preparation
CAS No. EC Number Symbol R-Phrases
Ingredient Name %
1) Imidazole 288-32-4 25-45 206-019-2 C R22, R34
Section 3. Hazards Identification
United States Review the most current and approved institutional guideline, protocol, standard operating procedure(s) and MSDS(s)
for the proper handling of institutional materials/equipment associated with the use of this product.
Emergency Overview No specific hazard.
Routes of Entry Absorbed through skin. Dermal contact. Eye contact. Inhalation. Ingestion.
Potential Acute Health Effects Hazardous in case of ingestion. Slightly hazardous in case of inhalation (lung sensitizer). Non-corrosive for skin.
Non-irritant for skin. Non-irritating to the eyes. Non-irritant for lungs. Non-corrosive to the eyes. Non-corrosive for
lungs.
Carcinogenic Effects Data CARCINOGENIC EFFECTS: Not available.
MUTAGENIC EFFECTS: Classified None. for human [4M Imidazole Stock Solution].
TERATOGENIC EFFECTS: Classified None. for human [4M Imidazole Stock Solution].
Medical Conditions Aggravated Repeated or prolonged exposure is not known to aggravate medical condition.
by Overexposure:
Overexposure /Signs/Symptoms Not available.
Europe
Classification Not controlled under dsd (Europe).
Physical/chemical hazards Not applicable.
Human health hazards Not applicable.
Environmental hazards Not applicable.
See Toxicological Information (section 11)
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4M Imidazole Stock Solution
Section 4. First Aid Measures
Notice to Reader Get immediate medical attention.
Effects and symptoms
Inhalation Slightly hazardous in case of inhalation (lung sensitizer). Non-irritant for lungs. Non-corrosive for lungs.
Ingestion Hazardous in case of ingestion.
Skin Contact Sensitization of the product: Not available.
Non-corrosive for skin. Non-irritant for skin.
Eye Contact Non-irritating to the eyes. Non-corrosive to the eyes.
Aggravating conditions Repeated or prolonged exposure is not known to aggravate medical condition.
First-Aid Measures
Inhalation If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention if symptoms appear.
Ingestion Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious
person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms appear.
Skin Contact Wash with soap and water. Get medical attention if irritation develops. Cold water may be used.
Eye Contact Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Cold water may be used. Get medical attention if irritation occurs.
Notes to Physician Not available.
Protection of first-aiders Not available.
Section 5. Fire Fighting Measures
Flammability of the Product Non-flammable.
Flash Points Not applicable.
Fire Hazards in Presence of Various Not applicable.
Substances
Fire Fighting Media Not applicable.
and Instructions
Protective Clothing (Fire) Not applicable.
Hazardous thermal (de)composition Not applicable.
products
Section 6. Accidental Release Measures
Personal precautions Safety glasses. Lab coat.
Environmental Precautions and Absorb with an inert material and put the spilled material in an appropriate waste disposal. Finish cleaning by spreading
Clean-up Methods water on the contaminated surface and allow to evacuate through the sanitary system.
Small Spill and Leak Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container.
Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority
requirements.
Section 7. Handling and Storage
Handling Avoid breathing vapors or spray mists.
Storage Keep container tightly closed. Keep container in a cool, well-ventilated area.
Intended Use Refer to the instruction booklet for proper and intended use. Otherwise, contact supplier for specific applications.
Packaging materials
Suitable / Not suitable Use original container.
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4M Imidazole Stock Solution
Section 8. Exposure Controls/Personal Protection
Engineering Controls Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their
respective threshold limit value.
Exposure Limit Values
Ingredient Name Occupational Exposure Limits
United States
1) Imidazole Not available.
Sweden
1) Imidazole Not available.
Denmark
1) Imidazole Not available.
Norway
1) Imidazole Not available.
France
1) Imidazole Not available.
Netherlands
1) Imidazole Not available.
Germany
1) Imidazole Not available.
Personal Protection
Eyes Safety glasses.
Body Lab coat.
Protective Clothing
(Pictograms)
Section 9. Physical and Chemical Properties
Physical State and Liquid. Odor Slight.
Appearance
Taste Not available.
Molecular Weight Not applicable.
Color Clear
pH (1% Soln/Water) 7.5 [Basic.]
Boiling/Condensation Point The lowest known value is 100掳C (212掳F) (Milli-Q Water).
Melting/Freezing Point May start to solidify at -0.1掳C (31.8掳F) based on data for: Milli-Q Water.
Specific Gravity Weighted average: 0.82 (Water = 1)
Vapor Pressure The highest known value is 2.3 kPa (@ 20掳C) (Milli-Q Water).
Vapor Density The highest known value is 0.62 (Air = 1) (Milli-Q Water).
Evaporation Rate 0.36 (Milli-Q Water) compared to Butyl acetate.
Dispersion Properties See solubility in water.
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4M Imidazole Stock Solution
Solubility Easily soluble in cold water.
Soluble in hot water.
Section 10. Stability and Reactivity
Stability and Reactivity The product is stable.
Conditions to avoid Not available.
Materials to avoid Slightly reactive to reactive with oxidizing agents, acids.
Hazardous Polymerization Will not occur.
Hazardous Decomposition Not applicable.
Products
Section 11. Toxicological Information
Toxicity to Animals Acute oral toxicity (LD50): 3235 mg/kg (Mouse) (Calculated value for the mixture).
Chronic Effects on Humans MUTAGENIC EFFECTS: Classified None. for human [4M Imidazole Stock Solution].
TERATOGENIC EFFECTS: Classified None. for human [4M Imidazole Stock Solution].
Other Toxic Effects on Humans Hazardous in case of ingestion.
Slightly hazardous in case of inhalation (lung sensitizer).
Non-irritating to the eyes. Non-hazardous in case of ingestion. Non-sensitizer for lungs. Non-corrosive for lungs.
Special Remarks on Toxicity to Not available.
Animals
Special Remarks on Chronic Not available.
Effects on Humans
Special Remarks on Other Toxic Not available.
Effects on Humans
Section 12. Ecological Information
Mobility Not available.
Persistence/degradability Not available.
Bioaccumulative potential Not available.
Ecotoxicity Not available.
Germany water class VCI WGK: No products were found.
Section 13. Disposal Considerations
Waste Information Type: Non-hazardous chemical waste.
Location: not available
Classification: not available
Disposal.: Waste must be disposed of in accordance with federal, state and local environmental control regulations.
Storage: not available
Recycling: not available
Waste Stream Not available.
Consult your local or regional authorities.
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4M Imidazole Stock Solution
Section 14. Transport Information
Contact the supplier for all information regarding the proper transportation method for this material.
1
Section 15. Regulatory Information
Label Requirements
This product is not classified according to the EU regulations.
(Europe)
HCS Classification --
U.S. Federal Regulations TSCA 8(b) inventory: Imidazole; Milli-Q Water
TSCA 8(d) H and S data reporting: Imidazole
SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: No products were found.
SARA 311/312 MSDS distribution - chemical inventory - hazard identification: No products were found.
SARA 313 toxic chemical notification and release reporting: No products were found.
Clean Water Act (CWA) 307: No products were found.
Clean Water Act (CWA) 311: No products were found.
Clean air act (CAA) 112 accidental release prevention: No products were found.
Clean air act (CAA) 112 regulated flammable substances: No products were found.
Clean air act (CAA) 112 regulated toxic substances: No products were found.
WHMIS (Canada) Not controlled under WHMIS (Canada).
No products were found.
International Regulations
EINECS Not available.
DSCL (EEC) This product is not classified according to the EU regulations.
International Lists Australia (NICNAS): Imidazole; Milli-Q Water
Germany water class: Imidazole
Korea (TCCL): Imidazole; Milli-Q Water
Philippines (RA6969): Imidazole; Milli-Q Water
State Regulations No products were found.
California prop. 65: No products were found.
Section 16. Other Information
Hazardous Material National Fire Protection
0
Health
Fire Hazard
0
Information System Association (U.S.A.)
0
Fire Hazard
(U.S.A.)
0 0
Health Reactivity
0
Reactivity
Specific Hazard
a
Personal Protection
References Not available.
History of Document Changes Any information changes since last document version are marked with a triangle symbol.
Full text of R-Phrases Harmful if ingested.
referenced under headings 2 and 3: Causes burns.
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4M Imidazole Stock Solution
Intended Use Refer to the instruction booklet for proper and intended use. Otherwise, contact supplier for specific applications.
Date of Previous Issue No Previous
Validated by Pierce Administration on 11/4/2002. Verified by Pierce Administration.
Validation
Printed 11/6/2002. Version 0.01
Notice to Reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any
liability whatsoever for the accuracy or completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution.
Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
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