www.tra-con.com
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: Date Printed: 12/5/2002
TRA-BOND F253 Hardener
Revision Date: 11/18/2002
TRA-CON, INC.
Revision: C
45 Wiggins Avenue
Bedford, MA 01730
781-275-6363
1-800-872-2661
Emergency Telephone: 1-800-424-9300 (24 hours, CHEMTREC)
2. COMPOSITION/INFORMATION ON INGREDIENTS
TWA STEL Ceiling
Component CAS Number %
OSHA
ACGIH ppm mg/m3 ppm mg/m3 ppm mg/m3
Tetraethylenepentamine 000112-57-2 10 - 20
1-benzyl-2-methyl imidazole 013750-62-4 40 - 50
1,6-Hexanediamine, 2,2,4-trimethyl- 003236-53-1 <5
1,6-Hexanediamine, 2,4,4-trimethyl- 003236-54-2 <5
Proprietary Organic Diamines NJ 56705700001- 1 - 10
5195P
Proprietary Organic Diamines NJ 56705700001- 1 - 10
5196P
Proprietary Organic Diamines NJ 56705700001- 1 - 10
5197P
Proprietary Organic Diamines NJ 56705700001- 1 - 10
5198P
3. HAZARDS IDENTIFICATION
Effects of Overexposure Repeated contact or breathing of vapors may cause irritation; material is also a
strong sensitizer. Eye and skin contact may cause transient irritation.
4. FIRST AID MEASURES
Eyes Flush with water, get medical attention.
Skin Wash with soap and water; remove contaminated clothing.
Inhalation Remove to fresh air.
Ingestion No known antidote but give milk or water; do NOT induce vomitting if swallowed; get
medical attention.
5. FIREFIGHTING MEASURES
Flashpoint > 250掳F
Flashpoint Method PMCC
Extinguishing Media Dry chemicals, chemical foam, carbon dioxide, water.
Special Firefighting Measures Avoid breathing smoke. Addition of water may reduce flame intensity.
QAF-1058 Rev B Date Printed: 12/5/2002 Page 1 of 9 F253 Hardener
Fire and Explosion Hazards Toxic gases may be liberated; handle as combustible; store in a cool place.
Flammable Limits N/AV
LEL N/A
UEL N/A
6.ACCIDENTAL RELEASE MEASURES
Spill and Leak Procedures Prevent skin and eye contact. Soak up in absorbent material, or scrape up, and
transfer to disposal container. Wipe up remaining residue with solvents, observing
solvent flammability cautions, or use detergents.
7. HANDLING AND STORAGE
Special Sensitivity Store in cool place in closed containers.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Local Exhaust Recommended
Mechanical Exhaust Recommended
Eye Protection Requirements Safety glasses or goggles
Glove Requirements Rubber or plastic disposable.
Other Protection As required to prevent all body contact; eye bath and/or safety shower.
Respirator Requirements Air supplied or organic canister, mask in confined areas.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance and Odor Clear, amber-yellow, low viscosity liquid, ammoniacal odor.
Boiling Point (掳F) > 300
Solubility in Water negligible
Specific Gravity (H2O=1) 1.0
Evaporation Rate (BuAc=1) low
Vapor Pressure (mm Hg.) <1
Vapor Density (air = 1) >4
Percent Volatile low
10. STABILITY AND REACTIVITY
Stability Stable
Conditions to Avoid (Stability) Avoid contact with metals corroded by liquid amines; avoid high temperatures.
Incompatibility (Materials to Avoid) Strong acids and bases, strong oxidizing agents.
Hazardous Decomposition Carbon monoxide, carbon dioxide, aldehydes, phenol.
Products
Hazardous Polymerization Will Not Occur
Conditions to Avoid (Reactivity) Chlorinated compounds; exotherms when used to cure epoxy resins.
11. TOXICOLOGICAL INFORMATION
Primary Entry Route(s) Skin, eyes, inhalation.
Oral, LD50 Not determined, estimated based upon diethylene triamine. LD50 (rats) > 500
mg/kg ;
Dermal, LD50 > 1400 mg/kg
12. ECOLOGICAL INFORMATION
QAF-1058 Rev B Date Printed: 12/5/2002 Page 2 of 9 F253 Hardener
Not available
13. DISPOSAL CONSIDERATIONS
Waste Disposal Methods Dispose of as hazardous waste according to local, state and federal regulations.
Disposal method can be land burial or chemical incineration as regulated by all
governmental agencies.
14. TRANSPORTATION INFORMATION
Not Applicable
15. REGULATORY INFORMATION
TSCA: All components are on the TSCA inventory.
STATE LAWS:
The information given and the recommendations made herein apply to our product(s) alone and are not combined with other product(s). Such
are based on our research and on data from other reliable soruces and are believed to be accurate. no guaranty of accuracy is made. it is
the purchaser's responsibility before using any product to verify this data under their own operating conditions and to determine whether the
product is suitable for their purposes.
16. OTHER INFORMATION
H: 3 F: 1 R: 0
MSDS Date: 11/18/2002 Revision: C HMIS Coding:
QAF-1058 Rev B Date Printed: 12/5/2002 Page 3 of 9 F253 Hardener
www.tra-con.com
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: Date Printed: 12/5/2002
TRA-BOND F253 Pre-Mixed and Frozen
Revision Date: 11/18/2002
TRA-CON, INC.
Revision: C
45 Wiggins Avenue
Bedford, MA 01730
781-275-6363
1-800-872-2661
Emergency Telephone: 1-800-424-9300 (24 hours, CHEMTREC)
2. COMPOSITION/INFORMATION ON INGREDIENTS
TWA STEL Ceiling
Component CAS Number %
OSHA
ACGIH ppm mg/m3 ppm mg/m3 ppm mg/m3
Phenol,4,4'-(1-methylethylidene)bis-, 025068-38-6 75 - 95
polymer with (chloromethyl) oxirane
Oxirane,((2-methylphenoxy)methyl)- 002210-79-9 < 10
Alkaneaklyamines -- <5
3. HAZARDS IDENTIFICATION
Effects of Overexposure Repeated contact or breathing of vapors may cause irritation; material is also a
strong sensitizer. Eye and skin contact may cause transient irritation.
4. FIRST AID MEASURES
Eyes Flush with water, get medical attention.
Skin Wash with soap and water; remove contaminated clothing.
Inhalation Remove to fresh air.
Ingestion No known antidote but give milk or water; induce vomitting if large amount
swallowed.
5. FIREFIGHTING MEASURES
Flashpoint > 200掳F
Flashpoint Method setaflash
Extinguishing Media Dry chemicals, chemical foam, carbon dioxide, water.
Special Firefighting Measures Avoid breathing smoke. Use self-contained breathing apparatus.
Fire and Explosion Hazards Toxic gases may be liberated; handle as combustible; store in a cool place.
Flammable Limits N/AV
LEL N/A
UEL N/A
6.ACCIDENTAL RELEASE MEASURES
Spill and Leak Procedures Prevent skin and eye contact. Soak up in absorbent material or scrape up and
transfer to disposal container. Wipe up remaining residue with solvents, observing
solvent flammability cautions or use detergents.
7. HANDLING AND STORAGE
QAF-1058 Rev B Date Printed: 12/5/2002 Page 4 of 9 F253 Pre-Mixed and Frozen
Special Sensitivity Store in freezer at minium -40掳F. Thaw cartridges in upright position, dispensing tip
up, to release air in tip cap, if any.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Local Exhaust Recommended
Mechanical Exhaust Recommended
Eye Protection Requirements Safety glasses or goggles
Glove Requirements Rubber or plastic disposable.
Other Protection As required to prevent all body contact; eye bath and/or safety shower.
Respirator Requirements Air supplied or organic canister, mask in confined areas.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance and Odor Clear, amber-yellow liquid, ammoniacal odor.
Boiling Point (掳F) > 250
Solubility in Water partial
Specific Gravity (H2O=1) 1.1
Evaporation Rate (BuAc=1) ND
Vapor Pressure (mm Hg.) <1
Vapor Density (air = 1) ND
Percent Volatile ND
10. STABILITY AND REACTIVITY
Stability Unstable
Conditions to Avoid (Stability) Avoid uncontrolled excess heating over long periods; avoid uncontrolled amine reactions.
Will react at room temp. Keep frozen at all times.
Incompatibility (Materials to Avoid) Carbon monoxide, carbon dioxide, aldehydes, phenol.
Hazardous Decomposition Carbon monoxide, carbon dioxide, aldehydes, nitrogen oxides.
Products
Hazardous Polymerization May Occur
Conditions to Avoid (Reactivity) Moderate temperatures, strong acids; certain organics, metallic acids.
11. TOXICOLOGICAL INFORMATION
Primary Entry Route(s) Skin, eyes, inhalation
Oral, LD50 Ingestion LD50 2.5 g/kg. Dermal LD50 2.3 g/kg.
12. ECOLOGICAL INFORMATION
Not available
13. DISPOSAL CONSIDERATIONS
Waste Disposal Methods Dispose of as hazardous waste according to local, state and federal regulations.
Disposal method can be land burial or chemical incineration as regulated by all
governmental agencies.
14. TRANSPORTATION INFORMATION
Not Applicable
15. REGULATORY INFORMATION
TSCA: All components are on the TSCA inventory.
STATE LAWS:
QAF-1058 Rev B Date Printed: 12/5/2002 Page 5 of 9 F253 Pre-Mixed and Frozen
The information given and the recommendations made herein apply to our product(s) alone and are not combined with other product(s). Such
are based on our research and on data from other reliable soruces and are believed to be accurate. no guaranty of accuracy is made. it is
the purchaser's responsibility before using any product to verify this data under their own operating conditions and to determine whether the
product is suitable for their purposes.
16. OTHER INFORMATION
H: 2 F: 1 R: 1
MSDS Date: 11/18/2002 Revision: C HMIS Coding:
QAF-1058 Rev B Date Printed: 12/5/2002 Page 6 of 9 F253 Pre-Mixed and Frozen
www.tra-con.com
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: Date Printed: 12/5/2002
TRA-BOND F253 Resin
Revision Date: 11/18/2002
TRA-CON, INC.
Revision: C
45 Wiggins Avenue
Bedford, MA 01730
781-275-6363
1-800-872-2661
Emergency Telephone: 1-800-424-9300 (24 hours, CHEMTREC)
2. COMPOSITION/INFORMATION ON INGREDIENTS
TWA STEL Ceiling
Component CAS Number %
OSHA
ACGIH ppm mg/m3 ppm mg/m3 ppm mg/m3
Phenol,4,4'-(1-methylethylidene)bis-, 025068-38-6 80 - 100
polymer with (chloromethyl) oxirane
Oxirane[(methylphenoxy)methyl]- 026447-14-3 up to 20
3. HAZARDS IDENTIFICATION
Effects of Overexposure Repeated contact or breathing of vapors may cause irritation; material is also a
strong sensitizer. Eye and skin contact may cause transient irritation.
4. FIRST AID MEASURES
Eyes Flush with water, get medical attention.
Skin Wash with soap and water; remove contaminated clothing.
Inhalation Remove to fresh air.
Ingestion No known antidote but give milk or water; induce vomitting if large amount
swallowed.
5. FIREFIGHTING MEASURES
Flashpoint > 300掳F
Flashpoint Method TOC
Extinguishing Media Dry chemicals, chemical foam, carbon dioxide, water.
Special Firefighting Measures Avoid breathing smoke. Addition of water may reduce flame intensity.
Fire and Explosion Hazards Toxic gases may be liberated; handle as combustible; store in a cool place.
Flammable Limits N/AV
LEL N/A
UEL N/A
6.ACCIDENTAL RELEASE MEASURES
Spill and Leak Procedures Prevent skin and eye contact. Soak up in absorbent material or scrape up and
transfer to disposal container. Wipe up remaining residue with solvents, observing
solvent flammability cautions or use detergents.
7. HANDLING AND STORAGE
Special Sensitivity Store in cool place in closed containers.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
QAF-1058 Rev B Date Printed: 12/5/2002 Page 7 of 9 F253 Resin
Local Exhaust Recommended
Mechanical Exhaust Recommended
Eye Protection Requirements Safety glasses or goggles
Glove Requirements Rubber or plastic disposable.
Other Protection As required to prevent all body contact; eye bath and/or safety shower.
Respirator Requirements Air supplied or organic canister, mask in confined areas.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance and Odor Clear, light yellow, low viscosity liquid, aromatic odor.
Boiling Point (掳F) > 300
Solubility in Water nil
Specific Gravity (H2O=1) 1.2
Evaporation Rate (BuAc=1) low
Vapor Pressure (mm Hg.) <1
Vapor Density (air = 1) >1
Percent Volatile nil
10. STABILITY AND REACTIVITY
Stability Stable
Conditions to Avoid (Stability) Avoid uncontrolled excess heating over long periods; avoid uncontrolled amine reactions.
Incompatibility (Materials to Avoid) Strong acids and bases, strong oxidizing agents.
Hazardous Decomposition Carbon monoxide, carbon dioxide, aldehydes, phenol.
Products
Hazardous Polymerization Will Not Occur
Conditions to Avoid (Reactivity) High temperatures, strong acids; certain organics, metallic acids.
11. TOXICOLOGICAL INFORMATION
Primary Entry Route(s) Skin, eyes, inhalation.
Oral, LD50 LD50 (rats) > 8 grams/kg.
12. ECOLOGICAL INFORMATION
Not available
13. DISPOSAL CONSIDERATIONS
Waste Disposal Methods Dispose of as hazardous waste according to local, state and federal regulations.
Disposal method can be land burial or chemical incineration as regulated by all
governmental agencies.
14. TRANSPORTATION INFORMATION
Not Applicable
15. REGULATORY INFORMATION
TSCA: All components are on the TSCA inventory.
STATE LAWS:
The information given and the recommendations made herein apply to our product(s) alone and are not combined with other product(s). Such
are based on our research and on data from other reliable soruces and are believed to be accurate. no guaranty of accuracy is made. it is
QAF-1058 Rev B Date Printed: 12/5/2002 Page 8 of 9 F253 Resin
are based on our research and on data from other reliable soruces and are believed to be accurate. no guaranty of accuracy is made. it is
the purchaser's responsibility before using any product to verify this data under their own operating conditions and to determine whether the
product is suitable for their purposes.
16. OTHER INFORMATION
H: 2 F: 1 R: 1
MSDS Date: 11/18/2002 Revision: C HMIS Coding:
QAF-1058 Rev B Date Printed: 12/5/2002 Page 9 of 9 F253 Resin
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