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7681-52-9

File Name: hasaindustrial_com---103.asp
 
                                                                                                             Material Safety Data Sheet MSDS No. 103

                                                                                                             HASA BLEACH SOLUTION

BLEACH SOLUTION                                               Material Safety Data Sheet



Emergency 24 Hour Telephone:       CHEMTREC 800.424.9300





Corporate Headquarters:            Hasa Inc.

                                   23119 Drayton Street

                                   Saugus, California 91350

                                   Telephone 鈥? 661.259.5848

                                             鈥? 661.259.1538

                                   Fax









                                    IDENTIFICATION OF PRODUCT

Product Name:                                              BLEACH SOLUTION

Common Chemical Names:                                     Hypochlorite solution sodium salt, sodium

                                                           hypochlorite

Chemical Names of Ingredients [>1.0% by weight]:           Sodium hypochlorite, 12.5% Active Ingredient

Chemical Family:                                           Inorganic halogen compound

CAS Registry Number:                                       7681-52-9

Empirical Formula:                                         NaOCl

Molecular Weight:                                          74.45





                              PHYSICAL AND CHEMICAL PROPERTIES

Vapor Pressure:        12.1 mm Hg at 20潞C               Flash Point:        Not Applicable.

Weight/Gallon:         10.0 lbs. (4.54 kg.)             pH:                 11.2 鈥? 11.4

Density [liquid]:      1.20 at 20潞C (68潞F)              Odor:               Slight Bleach

Bulk Density:          Not Applicable.                  Boiling Point:      Decomposes

Melting Point:         Not Applicable.                  Freezing Point:     -20掳 Fahrenheit

Physical State:        Liquid Solution                  Color:              Straw Yellow

Solubility in Water:   Not Applicable.                  Stability:          Stable







                                          PHYSICAL HAZARDS

Potential for Fire:           None. Nonflammable and combustible liquid.

Potential for Explosion:      None. Nonflammable and combustible liquid.

Reactivity:                   Do not mix acids, aqua ammonia, or other organic or inorganic chemicals with

                              this product.









     Major Update: 08/01/01                Minor Revision: 06/01/03                           Page 1 of 4

                                                                                                                    Material Safety Data Sheet MSDS No. 103

                                                                                                                    HASA BLEACH SOLUTION

                                            HEALTH HAZARDS

Signs and Symptoms of Exposure:                       Eyes and skin irritation. Chemical burns to broken skin.

Medical Conditions Aggravated by Exposure:            No data available.

Oral [ingestion] LD50:                                No data available.

Dermal [skin absorption] LD50:                        No data available.

Inhalation [breathing] LC50:                          No data available.

Eye Irritation:                                       Irritating. May cause eye damage.

Skin Irritation:                                      Mild irritation. Not considered to be a skin sensitizer.

OSHA PEL:                                             None established.

ACGIH TLV/TWA:                                        None established.





                                   POTENTIAL ROUTE [S] OF ENTRY

Inhalation [Breathing]:       Unlikely to occur. Vapor may cause irritation to upper respiratory tract.

Dermal [Skin]:                Contact with broken skin may cause burning, blistering, and tissue destruction if

                              not washed off immediately.

Ingestion [Swallowing]:       Not anticipated. May cause severe chemical burns to esophagus and to

                              stomach lining.





                     CARCINOGENIC [CANCER POTENTIAL] INFORMATION

National Toxicological Program [NTP] Sixth Annual Report on Carcinogens:                               Not listed

International Agency for Research on Cancer [IARC] Monographs, V. 1-53, Supps. 1-8:                    Not listed

Listed by Federal OSHA as Carcinogens:                                                               Not listed

Safe Drinking Water and Toxic Enforcement Act of 1986 [Proposition 65, California only]:

        Small quantities 鈥? less than 100 ppm (parts per million) 鈥? of impurities, including bromates, may be

        found in all chlorinating products, including this product. Bromates are derived from bromides,

        which are present in sodium chloride (table salt) from which chlorine is manufactured. Additional

        small quantities of bromates may be generated during the disinfection process. Bromates are

        known by the State of California to cause cancer when administered by the oral (drinking or

        ingesting) route. Read and follow label directions and use care when handling or using this

        product. The US Environmental Protection Agency has established a maximum contaminant level

        (MCL) for bromates in drinking water at 10 ppb (parts per billion). Application of this product in

        accordance with label directions at use dilution will not exceed this level.



        This warning is provided pursuant to Proposition 65, the Safe Drinking Water and Toxic

        Enforcement act of 1986, Chapter 6.6 of the California Health and Safety Code, which requires the

        Governor of California to publish a list of chemicals 鈥渒nown to the state to cause cancer or

        reproductive toxicity.鈥? This list is compiled in accordance with the procedures established under the

        proposition, and can be obtained on the internet from California鈥檚 Office of Environmental Health

        Hazard Assessment at http://www.oehha.ca.gov. There are over 700 chemical substances on this

        list.









     Major Update: 08/01/01                 Minor Revision: 06/01/03                             Page 2 of 4

                                                                                                                   Material Safety Data Sheet MSDS No. 103

                                                                                                                   HASA BLEACH SOLUTION

                    GENERAL PRECAUTIONS FOR SAFE USE AND HANDLING

Open containers carefully. Mix only with water. Do not mix with other chemicals. Use clean, dry utensils

when mixing. Do not discharge this product or mixtures of this product into lakes, streams, ponds, bays,

estuaries, or the ocean. Sodium hypochlorite is toxic to aquatic organisms at very low levels.





                            PERSONAL PROTECTION AND HYGIENE

Wash hands after handling. Remove and wash contaminated clothing before use.







                                          CLEAN-UP OF SPILLS

Store this product in a cool, dry area, away from sunlight and heat to avoid deterioration. In case of spill,

clean up area where spill has occurred with mop, rinse with water and flush residue to sanitary sewer.





                                                  FIRST AID

Eye Contact:      Flush with water. Remove contact lenses [if applicable]. Hold eyelids open. Continue

                  flushing with water for 15 minutes. Get prompt medical attention.

Skin Contact:     Wash affected area with water for 15 minutes. Get medical attention.

Ingestion         Drink large quantities of milk or gelatin solutions. If these are not available drink large

[swallowing]:     quantities of water. DO NOT induce vomiting. DO NOT give vinegar or other acids. Get

                  prompt medical attention.









          FEDERAL/STATE LISTS/REGISTRATION/S/REPORTING REQUIREMENTS

CERCLA Hazardous Substance [Section 1010 [4], P.L. 96-510]: RQ=100 lbs

                                                            [80 gallons for 12.5% solution]

Extremely Hazardous Substance [40 CFR 355, Appendix A]:     Not listed.

                                                            Registered as a pesticide product by

Pesticide Product 7 U.S.C. 136 et seq.:

                                                            Federal EPA.

Toxic Substance under TSCA:                                 Not reported.

Pesticide Product [various State Laws] :                    Registered as pesticide product in

                                                            states where marked.





                                MATERIAL CLASSIFICATION

OSHA Hazard Communication Standard, Department of Labor, Irritant.

Occupational Safety and Health Division, 29 CFR 1910.1200:



                         Hazardous Materials Transportation Regulations,

                     Department of Transportation (Federal) 49 CFR 172.101

Proper Shipping Description [1 gallon or less]:      Consumer Commodity, ORM -D

Proper Shipping Description [greater than 1 gallon]:          Hypochlorite Solutions, 8, UN1791, P.G. III



National Fire Protection Association NFPA 704 [1990]:                                     2-0-0

BOCA National Fire Prevention Code/National Building Code [1999 editions]:                Irritant

Standard Fire Prevention Code/Standard Building Code [1997 editions]:                     Irritant

Uniform Fire Code/Uniform Building Code [1997 editions]:                                  Irritant

Uniform Fire Code Standards 79-3, Uniform Fire Code, V. II [1997 edition]:                2-0-0







     Major Update: 08/01/01                 Minor Revision: 06/01/03                                 Page 3 of 4

                                                                                                              Material Safety Data Sheet MSDS No. 103

                                                                                                              HASA BLEACH SOLUTION

                                       RETURNABLE CONTAINERS

Returnable (deposit) containers must be resealed and the contents drained therefrom prior to return to the

distributor or manufacturer for credit. Do not offer leaking or damaged containers for transportation. Call

HASA, Inc. or your distributor for instructions.









Please Note: The information contained herein, while not guaranteed, was prepared by competent

technical personnel and is true and accurate to the best of our knowledge and belief. NO WARRANTY OR

GUARANTEE, expressed or implied, is made regarding the product performance, product stability, or as to

any other condition of use, handling, transportation, and storage. Customer use, handling, transportation,

and storage may involve additional safety and/or performance considerations. Our technical personnel will

be happy to respond to questions regarding safe handling, storage, transportation and use procedures. The

safe handling, storage, transportation and use procedures remain the sole responsibility of the customer.

No suggestions for handling, storage, transportation or use are intended as or to be construed as

recommendations which may infringe on any existing patents or violate any Federal, State, and/or local law

and/or regulation, ordinance, standard, etc.. This Material Safety Data Sheet has been prepared by HASA,

Inc. staff from test reports and other information available in the public domain.









     Major Update: 08/01/01                Minor Revision: 06/01/03                           Page 4 of 4
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