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MSDS Material Safety Data Sheet
CAS

68855-54-9
14464-46-1
14808-60-7

File Name: hasaindustrial_com---114.asp
                                                                                                                     Material Safety Data Sheet MSDS No. 114
HASA DIATOMACEOUS EARTH (D.E.)
DIATOMACEOUS EARTH (D.E.)
Material Safety Data Sheet

Emergency 24 Hour Telephone: CHEMTREC 800.424.9300


Corporate Headquarters: 23119 Drayton Street
Saugus, California 91350
Telephone 鈥? 661.259.5848
鈥? 661.259.1538
Fax

* See Below


IDENTIFICATION OF PRODUCT
TRADE NAME (S): (CELITE漏 = C) AQUA-CEL漏, C503(ALL), C535, C545, C552, C560, C566, C578P,
C580, X-6, X-7, DICALITE
GENERIC NAME: FLUX CALCINED DIATOMACEOUS EARTH
CHEMICAL NAME: SILICA
CAS: 68855-54-9
EINECS: 272-489-0
FORMULA: SIO2


COMPOSITION/INFORMATION ON INGREDIENTS
INGREDIENT NAME: CAS NUMBER % PEL AND TLV
FLUX CALCINED DIATOMACEOUS EARTH (DE) 68855-54-9 100 See below.
This product may contain up to 54% crystalline silica:
Cristobalite 14464-46-1 <50 0.05mg/M鲁 Respirable
Christobalite, OSHA
Quartz 14808-60-7 <4 0.1mg/M鲁 Respirable
Quartz, OSHA


PHYSICAL AND CHEMICAL PROPERTIES
Appearance and Odor: Fine white powder. No Odor.
Boiling Point: NA Evaporation Rate (=1): NA Specific Gravity (water=1): 2.3
Vapor Pressure: NA Melting Point: ND %Volatile by Volume: NIL
Water Solubility (%): Negligible Vapor Density (Air=1): NA pH: 9 鈥? 10.5


NFPA FIRE HAZARD SYMBOL CODES
* SEE HAZARD IDENTIFICATION SECTION
- SEE NFPA 704.


Major Update: 08/01/01 Minor Revision: 08/01/01 Page 1 of 4
HAZARD IDENTIFICATION




Material Safety Data Sheet MSDS No. 114
HASA DIATOMACEOUS EARTH (D.E.)
Summary: This product contains Crystalline Silica (CS), which is considered a hazard by inhalation. IARC
has classified inhalation of CS as carcinogenic for humans (group 1). CS is listed by NTP as known human
carcinogen. Inhalation of CS is also a known cause of silicosis, a noncancerous lung disease.
Medical conditions which Pre-existing upper respiratory and lung disease such as but not limited to
may be aggravated: bronchitis, emphysema and asthma.
Target Organ(s): Lungs, Eyes
Acute Health Effects: Transitory upper respiratory or eye irritation.
Chronic Health Effects: Inhalation of Crystalline Silica has been classified by IARC as carcinogenic
for humans (group 1). Inhalation of Crystalline Silica is also a known cause of
silicosis, a noncancerous lung disease caused by excessive exposure to
Crystalline Silica.
Primary Entry Route(s): Inhalation. Dust contact with eyes.


FIRST AID MEASURES
Inhalation: Remove to fresh air. Drink water to clear throat and blow nose to evacuate dust.
Eyes: Flush eyes with large quantities of water. If irritation persists consult a physician.
Skin Contact: NA
Skin Absorption: NA
Ingestion: Not hazardous when ingested.


FIRE FIGHTING MEASURES
Flash Point (Method): Nonflammable
NFPA Flammable/Combustible Liquid Classification: NA
Flammable Limits: LEL: NA UEL: NA
Auto-ignition Temperature: NA
Extinguishing Media: NA
Unusual Fire or Explosion Hazards: None
Special Fire-Fighting Procedures: None


ACCIDENTAL RELEASE MEASURES
Procedure for Spill/Leak: Vacuum clean dust with equipment fitted with HEPA filter. Use a Dust
Suppressant such as water if sweeping is necessary.

HANDLING AND STORAGE
Minimize dust generation and accumulation. Avoid breathing dust. Avoid contact with eyes. Seal broken
bags immediately. Continue to follow all MSDS/LABEL warnings when handling empty containers.


EXPOSURE CONTROLS/PERSONAL PROTECTION
Goggles: Goggles or Safety Glasses with Sideshields are recommended.
Gloves: Not normally required.
Respirator: < 10X PEL, Use an N95 Quarter or Half Mask Respirator;
< 50X PEL, Use a full face Respirator equipped with N95 Filters;
< 200X PEL, Use a powered air purifying Respirator (positive pressure) with N95 Filters;
< 200X PEL, Use a full face, Type C supplied air Respirator (continuous flow mode).
Ventilation: Use sufficient natural or mechanical ventilation to keep dust level below PEL.
Other: Special Considerations for repair/maintenance of contaminated equipment:
Insure proper respiratory protection.

Major Update: 08/01/01 Minor Revision: 08/01/01 Page 2 of 4
Material Safety Data Sheet MSDS No. 114
HASA DIATOMACEOUS EARTH (D.E.)
STABILITY AND REACTIVITY
Material is stable.
Chemical Incompatibilities: HYDROFLUORIC ACID
HAZARDOUS POLYMERIZATION CANNOT OCCUR.
Conditions to avoid: None in designed use.


TOXICOLOGICAL INFORMATION
Summary: This product contains CYSTALLINE SILICA (CS), which is considered hazard by inhalation.
IARC has classified CS as carcinogenic for humans (GROUP 1). CS is listed by NTP as a known human
carcinogen. CS is also a known cause of Silicosis, a noncancerous ling disease.


ECOLOGICAL INFORMATION
Generally considered chemically inert in the environment. Used material which has become contaminated
may have significantly different characteristics based on the contaminant and should be evaluated
accordingly.


DISPOSAL CONSIDERATIONS
Waste is not hazardous as defined by RCRA (40 CFR 261). Other state and local regulations may vary.
Consult local agencies as needed. Used material which has become contaminated may have significantly
different characteristics based on the contaminants and should be evaluated accordingly.


TRANSPORTATION INFORMATION
D.O.T. Proper Shipping Name: Earth, Diatomaceous, crude or ground
Hazard Classification: Not Classified.
Reportable Quantities: Not Applicable.
UN (United Nations), NA (North America) Number: Not Applicable.


REGULATORY INFORMATION
OSHA Hazard Communications Material is considered hazardous. See HAZARD IDENTIFICATION
Standard, 29 CFR 1910.1200: SECTION of this MSDS.
RCRA: This material is not defined as hazardous waste per 40 CFR 261.
TSCA: This material is listed in the TSCA inventory, and is not otherwise
regulated by TSCA SEC. 4,5,6,7 or 12.
CERCLA: Material is not reportable under CERCLA. Local requirements may
vary.
SARA: 311/312 Hazard categories 鈥? immediate and delayed health. 313
reportable ingredients 鈥? none.
California Proposition 65: This product contains chemicals known to the state of California to
cause cancer.


OTHER INFORMATION
Storage Segregation Hazard Classes: NA
Special Handling/Storage: Repair all broken bags immediately.
Special Workplace Engineering Controls: Adequate ventilation to keep dust level below PEL.


Major Update: 08/01/01 Minor Revision: 08/01/01 Page 3 of 4
Material Safety Data Sheet MSDS No. 114
HASA DIATOMACEOUS EARTH (D.E.)
Please Note: The information contained herein, while not guaranteed, was prepared by competent technical
personnel and is true and accurate to the best of our knowledge and belief. NO WARRANTY OR
GUARANTEE, expressed or implied, is made regarding the product performance, product stability, or as to
any other condition of use, handling, transportation, and storage. Customer use, handling, transportation,
and storage may involve additional safety and/or performance considerations. Our technical personnel will
be happy to respond to questions regarding safe handling, storage, transportation and use procedures. The
safe handling, storage, transportation and use procedures remain the sole responsibility of the customer.
No suggestions for handling, storage, transportation or use are intended as or to be construed as
recommendations which may infringe on any existing patents or violate any Federal, State, and/or local law
and/or regulation, ordinance, standard, etc.. This Material Safety Data Sheet has been prepared by HASA,
Inc. staff from test reports and other information available in the public domain.




Major Update: 08/01/01 Minor Revision: 08/01/01 Page 4 of 4

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