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MSDS Material Safety Data Sheet
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87-90-1

File Name: hasaindustrial_com---202.asp
 
                                                                                                                    Material Safety Data Sheet MSDS No. 202

                                                                                                                    HASA SMALL CHLORINATING TABLETS

HASA SMALL CHLORINATING TABLETS

Material Safety Data Sheet

Emergency 24 Hour Telephone:       CHEMTREC 800.424.9300



Corporate Headquarters:            Hasa Inc.

                                   23119 Drayton Street

                                   Saugus, California 91350

                                   Telephone 鈥? 661.259.5848

                                             鈥? 661.259.1538

                                   Fax









                                     IDENTIFICATION OF PRODUCT

Product Name:                          HASA SMALL CHLORINATING TABLETS

Common Chemical Names:                  TRICHLOR Tabs, Small Tabs, 1鈥? Tabs, Feeder Tabs

Chemical Names of Ingredients:          Trichloro-s-triazinetrione; 1,3,5-trichloro-s-trizainetrione-2,4,6-trione

Chemical Family:                        Halogenated triazines

CAS Registry Number:                    87-90-1

Empirical Formula:                      C3N3O3 Cl3





                               PHYSICAL AND CHEMICAL PROPERTIES

Vapor Pressure:           Very small. Impossible to measure.          Flash Point:           Not Applicable.

Weight/Gallon:            Not Applicable.                             pH:                    2.7-2.9

Density [liquid]:         Not Applicable.                             Odor:                  Slight Chlorine

Bulk Density:             陆 ounce/tablet                              Boiling Point:         Not Applicable.

Melting Point:            225-250潞C                                   Freezing Point:        Not Applicable.

Physical State:           Tablet                                      Color:                 White

Solubility in Water:      1.2 g/100 g H2O at 25掳 C                    Stability:             Stable

Volatiles [% by vol]:     Not Applicable.





                                            PHYSICAL HAZARDS

Potential for Fire:             Small Chlorinating Tablets are nonflammable.

Potential for Explosion:        Unlikely.

Reactivity:                     Stable when dry.

Extinguishing Media:            Water in excess

Fire Fighting Procedures:       SCBA + protective clothing









      Major Update: 08/01/01                Minor Revision: 06/01/03                               Page 1 of 4

                                                                                                                      Material Safety Data Sheet MSDS No. 202

                                                                                                                      HASA SMALL CHLORINATING TABLETS

                                              HEALTH HAZARDS

Signs and Symptoms of Exposure:                        Eye and skin irritation.

Medical Conditions Aggravated by Exposure:             No data available.

Oral [ingestion] LD50:                                 1500 mg/kg

Dermal [skin absorption] LD50:                         >10.0 g/kg

Inhalation [breathing] LC50:                           Vaporization and respirable dust not expected.

Eye Irritation:                                        Very irritating.

Skin Irritation:                                       Mild irritation. Not a skin sensitizer.

OSHA PEL:                                              None Established.

ACGIH TLV/TWA:                                         None Established.





                                    POTENTIAL ROUTE [S] OF ENTRY

Inhalation [Breathing]:        Vaporization and respirable dust not expected.

Dermal [Skin]:                 Not Anticipated.

Eyes:                          Dust from tablets may irritate eyes.

Ingestion:                     Not anticipated. Bitter, chlorine taste.





                    CARCINOGENIC [CANCER POTENTIAL] INFORMATION

National Toxicological Program [NTP] Sixth Annual Report on Carcinogens:                                Not listed.

International Agency for Research on Cancer [IARC] Monographs, V. 1-53, Supps. 1-8:                     Not listed.

Listed by Federal OSHA as Carcinogens:                                                                 Not listed.

Safe Drinking Water and Toxic Enforcement Act of 1986 [Proposition 65, California only]:

        Small quantities 鈥? less than 100 ppm (parts per million) 鈥? of impurities, including bromates, may be

        found in all chlorinating products, including this product. Bromates are derived from bromides, which

        are present in sodium chloride (table salt) from which chlorine is manufactured. Additional small

        quantities of bromates may be generated during the disinfection process. Bromates are known by the

        State of California to cause cancer when administered by the oral (drinking or ingesting) route. Read

        and follow label directions and use care when handling or using this product. The US Environmental

        Protection Agency has established a maximum contaminant level (MCL) for bromates in drinking

        water at 10 ppb (parts per billion). Application of this product in accordance with label directions at

        use dilution will not exceed this level.



        This warning is provided pursuant to Proposition 65, the Safe Drinking Water and Toxic Enforcement

        act of 1986, Chapter 6.6 of the California Health and Safety Code, which requires the Governor of

        California to publish a list of chemicals 鈥渒nown to the state to cause cancer or reproductive toxicity.鈥?

        This list is compiled in accordance with the procedures established under the proposition, and can be

        obtained on the internet from California鈥檚 Office of Environmental Health Hazard Assessment at

        http://www.oehha.ca.gov. There are over 700 chemical substances on this list.







                    GENERAL PRECAUTIONS FOR SAFE USE AND HANDLING

Mix only with water. Do not mix with other chemicals. Use clean dry utensils when mixing. Do not add these

tablets to any dispensing device containing remnants of other products. A violent reaction or explosion may

result when chemicals are mixed. Do not contaminate with moisture other chemicals or human wastes.



                              PERSONAL PROTECTION AND HYGIENE

Wear goggles or face shield and rubber gloves when handling. Avoid breathing dust. Remove and wash

contaminated clothing before reuse. Wash hands after handling.









      Major Update: 08/01/01                  Minor Revision: 06/01/03                           Page 2 of 4

                                                                                                                   Material Safety Data Sheet MSDS No. 202

                                                                                                                   HASA SMALL CHLORINATING TABLETS

                                            CLEAN-UP OF SPILLS

SMALL Chlorinating Tablets should be kept in tightly closed container when not in use in a cool, dry,

ventilated area. Keep away from open flame and heat or heating devices. Tablets which have been spilled

from a container should be picked up with a clean brush or broom and dust pan and placed in a clean, dry

container. If SMALL Chlorinating Tablets is contaminated by water, other chemicals, or human waste, place

the tablets in a bucket with lots of clean water and dissolve. Dissolved material may be disposed of on site or

at an approved landfill. See direction on labeling. Contact HASA, Inc. for guidance.





                                                 FIRST AID

Eye Contact:     Flush with water. Remove contact lenses [if applicable]. Hold eyelids open. Continue

                 flushing with water for 15 minutes. Get prompt medical attention.

Skin Contact:    Brush off any residue. Wash affected area with water for 5 minutes. If irritation persists, get

                 medical attention.

Ingestion        Feed bread soaked in milk followed by olive oil or other cooking oil. Call a physician

[sw allowing]:   immediately.

Inhalation:      Remove to fresh air. Call a physician.





           FEDERAL/STATE LISTS/REGISTRATION/S/REPORTING REQUIREMENTS

CERCLA Hazardous Substance [Section 1010 [4], P.L. 96-510]:             Not listed.

Extremely Hazardous Substance [40 CFR 355, Appendix A]:                 Not listed.

Pesticide Product 7 U.S.C. 136 et seq.:                                 Registered as Pesticide Product by

                                                                        Federal EPA.

Toxic Substance under TSCA:                                             Not reported.

Pesticide Product [various State laws]:                                 Registered as Pesticide Product in

                                                                        States where marketed.





                                 MATERIAL CLASSIFICATION

OSHA Hazard Communication Standard, Department of Labor, Oxidizer

Occupational Safety and Health Division, 29 CFR 1910.1200:



                           Hazardous Materials Transportation Regulations,

                        Department of Transportation (Federal) 49 CFR 172.101

US DOT Shipping Description:        Trichloroisocyanuric acid, dry, 5.1, UN 2468, P.G. II, E.R. No. 25

Placard/Label:                      5.1

Note: Inner packages containing 2.2 pounds [1kg] or less are renamed 鈥淐onsumer Commodity鈥? and

reclassified as 鈥淥RM-D鈥?. Labeling and placarding are not required for these shipments.





National Fire Protection Association NFPA 704 [1990]:                                    2-0-1-OX

NFPA 49:                                                                                 3-0-2-OX

BOCA National Fire Prevention Code/National Building Code [1999 editions]:               Oxidizer Class 1

Standard Fire Prevention Code/Standard Building Code [1997 editions]:                    Oxidizer Class 1

Uniform Fire Code/Uniform Building Code [1997 editions]:                                 Oxidizer Class 1

Uniform Fire Code Standards 79-3, Uniform Fire Code, V. II [1997 edition]:               2-0-1-OX









      Major Update: 08/01/01                Minor Revision: 06/01/03                            Page 3 of 4

                                                                                                                 Material Safety Data Sheet MSDS No. 202

                                                                                                                 HASA SMALL CHLORINATING TABLETS

Please Note: The information contained herein, while not guaranteed, was prepared by competent technical

personnel and is true and accurate to the best of our knowledge and belief. NO WARRANTY OR

GUARANTEE, expressed or implied, is made regarding the product performance, product stability, or as to

any other condition of use, handling, transportation, and storage. Customer use, handling, transportation, and

storage may involve additional safety and/or performance considerations. Our technical personnel will be

happy to respond to questions regarding safe handling, storage, transportation and use procedures. The safe

handling, storage, transportation and use procedures remain the sole responsibility of the customer. No

suggestions for handling, storage, transportation or use are intended as or to be construed as

recommendations which may infringe on any existing patents or violate any Federal, State, and/or local law

and/or regulation, ordinance, standard, etc.. This Material Safety Data Sheet has been prepared by HASA,

Inc. staff from test reports and other information available in the public domain.









      Major Update: 08/01/01               Minor Revision: 06/01/03                          Page 4 of 4
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