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MSDS Material Safety Data Sheet
CAS

7681-38-1

File Name: hasaindustrial_com---207.asp
                                                                                                                    Material Safety Data Sheet MSDS No.207
HASA DRY ACID
HASA DRY ACID Material Safety Data Sheet

Emergency 24 Hour Telephone: CHEMTREC 800.424.9300


Corporate Headquarters: Hasa Inc.
23119 Drayton Street
Saugus, California 91350
Telephone 鈥? 661.259.5848
鈥? 661.259.1538
Fax




IDENTIFICATION OF PRODUCT
Product Name: HASA DRY ACID
Common Chemical Names: Sodium Bisulfate, Sodium Acid Sulfate, Nitre Cake
Chemical Names of Ingredients [>1.0% by weight]: Sodium Hydrogen Sulfate, Sodium Bisulfate
Chemical Family: Inorganic acid salt
CAS Registry Number: 7681-38-1
Empirical Formula: NaHSO4


PHYSICAL AND CHEMICAL PROPERTIES
Vapor Pressure: Not Applicable. Flash Point: Not Applicable.
Weight/Gallon: Not Applicable. pH: Not Applicable.
Density [liquid]: Not Applicable. Odor: None.
Bulk Density: 83 lbs/cubic foot Boiling Point: Not Applicable.
Melting Point: 350潞F Freezing Point: Not Applicable.
Physical State: Solid granules Color: Off-white
Solubility in Water: 100% Stability: Stable



PHYSICAL HAZARDS
Potential for Fire: Nonflammable.
Potential for Explosion: None. At temperatures above 570潞F, hazardous fumes of sulfur dioxide and
sulfur trioxide are evolved.
Reactivity: Will react with caustic materials in water solution. Forms dilute sulfuric acid
with water.
Extinguishing Media: Non-flammable.
Fire Fighting Procedures: Water, capture, runoff.




Major Update: 08/01/01 Minor Revision: 04/21/03 Page 1 of 3
Material Safety Data Sheet MSDS No.207
HASA DRY ACID
HEALTH HAZARDS
Signs and Symptoms of Exposure: Eye and skin irritation.
Medical Conditions Aggravated by Exposure: No data available.
Oral [ingestion] LD50: 2800 mg/kg
Dermal [skin absorption] LD50: No data available.
Inhalation [breathing] LC50: No data available.
Eye Irritation: No information available.
Skin Irritation: Mean primary irritation score = 1.66
OSHA PEL: None Established.
ACGIH TLV/TWA: None Established.


POTENTIAL ROUTE [S] OF ENTRY
Inhalation [Breathing]: Dust from product, irritant.
Dermal [Skin]: Dust from product, irritant.
Eyes: Dust from product, irritant.
Ingestion: Not anticipated.


CARCINOGENIC [CANCER POTENTIAL] INFORMATION
National Toxicological Program [NTP] Sixth Annual Report on Carcinogens: Not listed.
International Agency for Research on Cancer [IARC] Monographs, V. 1-53, Supps. 1-8: Not listed.
Listed by Federal OSHA as Carcinogens: Not listed.
Safe Drinking Water and Toxic Enforcement Act of 1986 [Proposition 65, California only]: Not listed.


GENERAL PRECAUTIONS FOR SAFE USE AND HANDLING
Store in cool, dry place. Do not mix with alkaline materials. Add this product only to swimming pool, spa, hot
tub, or therapeutic waters in accordance with label directions. Mixing with water will form sulfuric acid solution.


PERSONAL PROTECTION AND HYGIENE
Wear rubber gloves and eye protection when handling. Wash hands after handling. Self-contained breathing
apparatus required where temperature of material exceeds 570潞F.


CLEAN-UP OF SPILLS
Sweep up spilled material and place in a sanitary sewer. Material which cannot be swept up should be
dissolved with water, neutralized with soda ash, sodium sesquicarbonate, or sodium bicarbonate, and flushed
to a sanitary sewer.


FIRST AID
Eye Contact: Flush with water. Remove contact lenses [if applicable]. Hold eyelids open. Continue
flushing with water for 15 minutes. Get prompt medical attention.
Skin Contact: Brush off any residue. Wash affected area with water for 15 minutes. If irritation persists, get
medical attention.
Ingestion Drink large quantities of water. DO NOT induce vomiting. Follow with Milk of Magnesia,
[swallowing]: vegetable oil, or beaten egg. Call a physician or poison control center immediately.
Inhalation: Dust-Get medical attention if irritation persists.
Fumes-Move to a safe area. If not breathing give artificial respiration. Call a physician
immediately. Get medical attention for irritation, ingestion, or discomfort from inhalation.
Major Update: 08/01/01 Minor Revision: 04/21/03 Page 2 of 3
Material Safety Data Sheet MSDS No.207
HASA DRY ACID
FEDERAL/STATE LISTS/REGISTRATION/S/REPORTING REQUIREMENTS
CERCLA Hazardous Substance [Section 1010 [4], P.L. 96-510]: Not listed.
Extremely Hazardous Substance [40 CFR 355, Appendix A]: Not listed.
Pesticide Product 7 U.S.C. 136 et seq.: Not registered.
Toxic Substance under TSCA: Not reported.
Pesticide Product [various State Laws]: Not registered.


MATERIAL CLASSIFICATION
OSHA Hazard Communication Standard, Department of Labor, Irritant
Occupational Safety and Health Division, 29 CFR 1910.1200:
Hazardous Materials Transportation Regulations, Not listed.
Department of Transportation (Federal) 49 CFR 172.101:
National Fire Protection Association NFPA 704 [1990]: 1-0-1
NFPA 49: Irritant
BOCA National Fire Prevention Code/National Building Code [1999 editions]: Irritant
Standard Fire Prevention Code/Standard Building Code [1997 editions]: Irritant
Uniform Fire Code/Uniform Building Code [1997 editions]: Irritant
Uniform Fire Code Standards 79-3, Uniform Fire Code, V. II [1997 edition]: 1-0-1




Please Note: The information contained herein, while not guaranteed, was prepared by competent technical
personnel and is true and accurate to the best of our knowledge and belief. NO WARRANTY OR
GUARANTEE, expressed or implied, is made regarding the product performance, product stability, or as to
any other condition of use, handling, transportation, and storage. Customer use, handling, transportation,
and storage may involve additional safety and/or performance considerations. Our technical personnel will
be happy to respond to questions regarding safe handling, storage, transportation and use procedures. The
safe handling, storage, transportation and use procedures remain the sole responsibility of the customer. No
suggestions for handling, storage, transportation or use are intended as or to be construed as
recommendations which may infringe on any existing patents or violate any Federal, State, and/or local law
and/or regulation, ordinance, standard, etc.. This Material Safety Data Sheet has been prepared by HASA,
Inc. staff from test reports and other information available in the public domain.




Major Update: 08/01/01 Minor Revision: 04/21/03 Page 3 of 3

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