KUMIAI CHEMICAL INDUSTRY CO., LTD.
4-26, IKENOHATA 1-CHOME, TAITOH-KU
TOKYO 110-8782, JAPAN
MATERIAL SAFETY DATA SHEET
Date: November 1, 2001
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
NOMINEE庐 100 SC
Product Name:
KIH-2023 100 SC
Synonyms:
Manufacturer and Address: Kumiai Chemical Industry Co., Ltd.
Product Development & Technical Service Section
Overseas Department
1-4-26, Ikenohata, Taitoh-ku, Tokyo 110-8782, Japan
Person Responsible for MSD Takuro Shinohara
Telephone: (03) 3822-5065
Telefax: (03) 3828-6148
Transportation Emergency: Telephone Japan (03) 3822-5065
2. COMPOSITION INFORMATION ON INGREDIENTS
Substance/Mixture: Formulation
Chemical Name: Sodium 2,6-bis[(4,6-dimethoxypyrimidin-2-yl)oxy]
benzoate
Common Name: Bispyribac-sodium (proposed to ISO)
CAS No.: 125401-92-5
Ingredients and Composition: Active ingredient 10% (w/v) (9.7% w/w)
(Bispyribac-sodium)
Inert ingredient 90% (w/v) (90.3% w/w)
(Surfactant, water, etc.)
Chemical Family: Pyrimidinyl carboxy compounds
Formula: C19H17N4NaO8
OCH3
N
O
N
COONa OCH3
OCH3
N
O
N
OCH3
Usage: Herbicide for agricultural use
UN Class: Not classified to any hazardous chemical class
UN No.: Not applicable
EC No. (EINECS No.): Not established
3. HAZARDS IDENTIFICATION
Class Name of Hazardous Chemicals for SDS in Japan:
Not applicable
Adverse Human Health Effects:
Effect of over exposure: We have never faced the poisoning problem attributed to
Nominee 100 SC on laboratory researchers, factory workers and users, however,
over-exposure experiments on animals showed that the administration of an extra-ordinary
large quantity of Nominee 100 SC may cause hypoactivity, abnormal walking and
prostration.
4. FIRST AID MEASURES
Skin Contact: -----Wash material off the skin in flowing water or shower with soap. If irritation
persists, consult a physician immediately.
Eye Contact: ------Immediately flush with copious amount of water for at least 15 minutes. If
irritation persists, consult a physician.
Inhalation:-----------Remove the victime to fresh air and keep him warm and quiet. Get a
medical attention immediately. If not breathing, clear the airway and give
MSDS Nominee 100 SC 1/3
artifical respiration. If breathing is difficult, give oxgen.
Ingestion: -----------Induce vomiting by giving one or two glasses of water. Get a medical
attention immediately. If the victim is unconscious or having convulsions,
never give fluids nor induce vomiting.
5. FIRE FIGHTING MEASURES
Flash Point: Not available
Flammability: Not applicable
Extinguishing Media: Water, dry chemical powder, foam or carbon dioxide
Special Fire Fighting Procedure:
鈥? Use water, dry chemical powder or carbon dioxide in extinguishing.
鈥? For a fire in surrounding area, apply water to cool and protect surrounding equipments.
Remove containers, if feasible, from the fire area to safe place immediately.
鈥? Fire fighters should wear protective gears including a positive pressure self-contained
breathing apparatus (SCBA). Evacuate non essential personnel.
6. ACCIDENTAL RELEASE MEASURES
鈥? Evacuate non essential personnel by roping the area of leak or spill. Evacuate people to
upwind of the spilled area. Remove all sources of ignition; No flares, smoking, or flames in
the area immediately. Wear protective gears and never work downwind.
鈥? For small spills, adsorb with inert materials (e.g. dry sand or earth), then place in a waste
chemical container for disposal. Flush residual spill (area) with a plenty of water.
鈥? Prevent spills from entering sewers, watercourses or low areas.
7. HANDLING AND STORAGE
Handling Precaution: KEEP OUT OF REACH OF CHILDREN
鈥? When handling and spraying the product, wear duty working clothes, cap, gloves, glasses
and mask to avoid contact with skin, eyes and inhalation of dust, fog and vapours.
鈥? After work thoroughly wash hands, face and possible exposed areas of body and change
clothing.
Storage Precaution:
鈥? Keep containers tightly closed and store in a cool, dark and dry place.
8. EXPOSURE CONTROL/PERSONAL PROTECTION
Control Parameters:
ACGIH TLV (1992-93) Not established
Engineering Controls:
鈥? The use of local exhaust ventilations is recommended. Containers should be kept tightly
closed.
鈥? Make available emergency showers and eye washes in a work area.
Personal Protective Equipment:
鈥? Wear chemical cartridge respirator with an organic vapour cartridge, airline respirator,
positive pressure self-contained breathing apparatus, safety goggles, gloves and boots as
appropriate.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance, Physical state, Form, Colour, Odour:
Almost ordourless off-white viscous suspension concentrate
Specific Gravity: 1.059 鈥? 1.070 (20 )
Viscosity: 300 鈥? 600 mPa
Suspensibility: 102%
Dispersibility: Good
Compatibility: Compatible to almost all pesticides
Heat Stability: Stable
Cold Stability: Stable
pH: 9.12 (x1)
10. STABILITY AND REACTIVITY
Flash Point: Not applicable
Autoignition Temperature: Not applicable
Explosion Limit: Not applicable
Stability and Reactivity: Stable under normal conditions
Hazardous Polymerization: Not data available
Incompatibility: Compatible to almost all pesticides
Storage Stability: Stable for 3 years if stored in a cool, dark and dry
place.
11. TOXICOLOGICAL INFORMATION
Acute Toxicity:
Oral: LD50 (Rat) >5,000 mg/kg (male & female)
Dermal: LD50 (Rat) >4,000 mg/kg (male & female)
MSDS Nominee 100 SC 2/3
Inhalation: LC50 (Rat) >3.99 mg/L (4 hours exp.)
Irritant Properties:
Eye irritation: (Rabbit) Not irritant
Skin irritation: (Rabbit) Mild irritant
Allergenic and Sensitizing Effects:
(Guinea pig) Not sensitizing
Mutagenic effects: (Ames test) Negative (S-9 Mix + or-)
(Technical grade)
12. ECOLOGICAL INFORMATION
Fish Toxicity: Bluegill sunfish TLm96 >100 ppm
Common carp TLm96 >100 ppm
Daphniamagna TLm48 >100 ppm
Avian Toxicity: Bobwhite quail Acute LD50 (Oral) >2,000 mg/kg
Mallard duck Acute LD50 (Oral) >2,000 mg/kg
Earthworm Toxicity: Acute LC50 >1,000 ppm (14 days exp.)
Honey bee Toxicity: Topical LD50 >200 碌g/bee
13. DISPOSAL CONSIDERATIONS
鈥? Waste should be disposed of in a chemical incinerator equipped with afterburner and
scrubber.
鈥? Do not dump into sewers or into any body of water.
14. TRANSPORT INFORMATION
鈥? Shippers must give transporters a transport precautionary instruction at the time of shipping
the product.
鈥? Check the leakage of containers before loading. Make sure to load containers correctly to
prevent them from falling down.
鈥? Follow all regulations with regard to transporting chemicals in your country.
15. REGULATORY INFORMATION
Follow all regulations in your country.
16. OTHER INFORMATION
Reference: Proceedings, Brighton Crop Protection Conference, 1993
Original MSDS of Nominee100 SC was prepared on June 17, 1997
Revised: October 22, 1997 (Acute dermal toxicity)
November 1, 2001 (Change of Kumiai鈥檚 postal code)
To the best of our knowledge, the information contained herein is accurate. However, we cannot
assume any liability whatsoever for the accuracy or completeness of the information contained herein.
MSDS Nominee 100 SC 3/3
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