Creation Date: 09-04-2007
Revision Date: 09-21-2007
Material Safety Data Sheet
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1. Chemical Product and Company Identification
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Material Name Semi-Volatile Cal STD, Method 8270C
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01
Version #
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Mixture
CAS #
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N9331030
Item #
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Methylene Chloride and Benzene solution containing trace calibration
Synonym(s)
elements.
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PerkinElmer Life and Analytical Sciences
Identification Of The
710 Bridgeport Avenue
Company/Undertaking
Shelton, CT 06484
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Technical Support 800-762-4000
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CHEMTREC 800-424-9300
Emergency Telephone
Emergency Phone 800-762-4000
Number
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2. Composition / Information on Ingredients
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Hazardous component(s) CAS # Percent PEL TLV
4-CHLOROANILINE, SUBLIMED, 99+% 106-47-8 0.1 - 1
ACENAPHTHENE 83-32-9 0.1 - 1
ACENAPHTHYLENE 208-96-8 0.1 - 1
ANTHRACENE 120-12-7 0.1 - 1 0.2 mg/m3 0.2
BENZ[A]ANTHRACENE 56-55-3 0.1 - 1
BENZO[A]PYRENE 50-32-8 0.1 - 1 0.2 mg/m3 0.2
DI(2-ETHYLHEXYL)PHTHALATE 117-81-7 0.1 - 1 5 mg/m3 5
HEXACHLOROBENZENE 118-74-1 0.1 - 1 0.002
HEXACHLOROBUTADIENE 87-68-3 0.1 - 1 0.02 ppm 0.02
P-DICHLOROBENZENE 106-46-7 0.1 - 1 75 ppm 10
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2,4-DINITROTOLUENE 121-14-2 0.1 - 1
2,6-DINITROTOLUENE 606-20-2 0.1 - 1
BENZO(B)FLUORANTHENE 205-99-2 0.1 - 1
BENZO(GHI)PERYLENE 191-24-2 0.1 - 1
BENZO(K)FLUORANTHENE 207-08-9 0.1 - 1
BIS(2-CHLOROETHYL) ETHER 111-44-4 0.1 - 1 5 ppm 5
DIBENZO(A,H)ANTHRACENE 53-70-3 0.1 - 1
FLUORANTHENE 206-44-0 0.1 - 1
FLUORENE 86-73-7 0.1 - 1
NITROBENZENE 98-95-3 0.1 - 1 1 ppm 1
Material ID 17652 Material Name Semi-Volatile Cal STD, Method 8270C
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MSDS US
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Benzene 71-43-2 40 - 60 10 ppm 0.5
DICHLOROMETHANE 75-09-2 40 - 60 500 ppm 50
HEXACHLOROETHANE 67-72-1 0.1 - 1 1 ppm 1
INDENO(1,2,3-CD)PYRENE 193-39-5 0.1 - 1
(2,3-O-PHENYLENEPYRENE)
ISOPHORONE 78-59-1 0.1 - 1 4 ppm
NAPHTHALENE 91-20-3 0.1 - 1 10 ppm 10
N-NITROSODI-N-PROPYLAMINE 621-64-7 0.1 - 1
PHENANTHRENE 85-01-8 0.1 - 1 0.2 mg/m3 0.2
PYRENE 129-00-0 0.1 - 1 0.2 mg/m3 0.2
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Non-hazardous component(s) CAS # Percent
1,2-DICHLOROBENZENE, ANHYDROUS, 95-50-1 0.1 - 1
99%
1,3-DICHLOROBENZENE 541-73-1 0.1 - 1
4-BROMODIPHENYL ETHER, 99% 101-55-3 0.1 - 1
BENZYL ALCOHOL, REAGENTPLUS, 100-51-6 0.1 - 1
>=99%
BIS(2-CHLOROETHOXY)METHANE 111-91-1 0.1 - 1
BIS(2-CHLOROISOPROPYL) ETHER 108-60-1 0.1 - 1
DIBUTYL PHTHALATE 84-74-2 0.1 - 1
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.BETA.-CHLORONAPHTHALENE 91-58-7 0.1 - 1
2-METHYLNAPHTHALENE 91-57-6 0.1 - 1
4-CHLOROPHENYL PHENYL ETHER 7005-72-3 0.1 - 1
BUTYL BENZYL PHTHALATE 85-68-7 0.1 - 1
DIBENZOFURAN 132-64-9 0.1 - 1
DIMETHYL PHTHALATE 131-11-3 0.1 - 1
DI-N-OCTYL PHTHALATE 117-84-0 0.1 - 1
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1,2,4-TRICHLOROBENZENE, ANHYDROUS, 120-82-1 0.1 - 1
99+%
DIPHENYLNITROSAMINE 86-30-6 0.1 - 1
Hexachlorocyclopentadiene 77-47-4 0.1 - 1
M-NITROANILINE 99-09-2 0.1 - 1
O-NITROANILINE 88-74-4 0.1 - 1
P-NITROANILINE 100-01-6 0.1 - 1
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3. Hazards Identification
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Health: 3
HMIS RATINGS
Flammability: 2
Physical hazard: 1
Personal protection: I
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Health: 3
NFPA RATINGS
Flammability: 2
Instability: 0
Material ID 17652 Material Name Semi-Volatile Cal STD, Method 8270C
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MSDS US
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4. First Aid Measures
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General advice
Consult a physician.
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First Aid
Skin contact
If skin irritation persists, call a physician. Wash off immediately with soap and plenty of water
removing all contaminated clothes and shoes.If skin irritation persists, call a physician and
Wash off immediately with soap and plenty of water removing all contaminated clothes and
shoes.
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Eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.Rinse
thoroughly with plenty of water for at least 15 minutes and consult a physician.
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Inhalation
Oxygen or artificial respiration if needed. Move to fresh air. Call a physician or Poison Control
Centre immediately.
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Ingestion
If swallowed, seek medical advice immediately and show this container or label. If a person
vomits when lying on his back, place him in the recovery position.
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5. Fire Fighting Measures
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Suitable extinguishing media
Do not use a solid water stream as it may scatter and spread fire. Use extinguishing measures that
are appropriate to local circumstances and the surrounding environment.
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Specific methods
In the event of fire, cool tanks with water spray.
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6. Accidental Release Measures
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Personal precautions
Use personal protective equipment. Keep people away from and upwind of spill/leak.
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Environmental precautions
Prevent further leakage or spillage if safe to do so.
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Methods for cleaning up
Dam up. Soak up with inert absorbent material. Shovel into suitable container for disposal.
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7. Handling and Storage
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Handling
Keep away from heat and sources of ignition.
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Material ID 17652 Material Name Semi-Volatile Cal STD, Method 8270C
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MSDS US
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8. Exposure Controls / Personal Protection
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Exposure Limit Values
Material TWA STEL
Semi-Volatile Cal STD, Method 8270C 0.5 ppm 2.5 ppm
ACGIH - Threshold Limits Values - Time Weighted Averages (TLV-TWA)
1,2-DICHLOROBENZENE, 95-50-1 25 ppm TWA
ANHYDROUS, 99%
ANTHRACENE 120-12-7 0.2 mg/m3 TWA (as benzene soluble aerosol)
Benzene 71-43-2 0.5 ppm TWA
BENZO[A]PYRENE 50-32-8 0.2 mg/m3 TWA (as benzene soluble aerosol)
BIS(2-CHLOROETHYL)111-44-4 5 ppm TWA
ETHER
DI(2-ETHYLHEXYL)PHTHALATE
117-81-7 5 mg/m3 TWA
HEXACHLOROBENZENE 118-74-1 0.002 mg/m3 TWA
HEXACHLOROBUTADIENE 87-68-3 0.02 ppm TWA
HEXACHLOROETHANE 67-72-1 1 ppm TWA
NAPHTHALENE 91-20-3 10 ppm TWA
NITROBENZENE 98-95-3 1 ppm TWA
P-DICHLOROBENZENE 106-46-7 10 ppm TWA
PHENANTHRENE 85-01-8 0.2 mg/m3 TWA (as benzene soluble aerosol)
PYRENE 129-00-0 0.2 mg/m3 TWA (as benzene soluble aerosol)
OSHA - Final PELs - Time Weighted Averages (TWAs)
ANTHRACENE 120-12-7 0.2 mg/m3 TWA (as benzene soluble fraction)
Benzene 71-43-2 10 ppm TWA (apply only to exempt industry
segments)
BENZO[A]PYRENE 50-32-8 0.2 mg/m3 TWA (as benzene soluble fraction)
DI(2-ETHYLHEXYL)PHTHALATE
117-81-7 5 mg/m3 TWA
HEXACHLOROETHANE 67-72-1 1 ppm TWA; 10 mg/m3 TWA
ISOPHORONE 78-59-1 25 ppm TWA; 140 mg/m3 TWA
NAPHTHALENE 91-20-3 10 ppm TWA; 50 mg/m3 TWA
NITROBENZENE 98-95-3 1 ppm TWA; 5 mg/m3 TWA
P-DICHLOROBENZENE 106-46-7 75 ppm TWA; 450 mg/m3 TWA
PHENANTHRENE 85-01-8 0.2 mg/m3 TWA (as benzene soluble fraction)
PYRENE 129-00-0 0.2 mg/m3 TWA (as benzene soluble fraction)
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Exposure Controls
Engineering measures to reduce exposure
Provide adequate ventilation.
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Respiratory protection
In the case of respirable dust and/or fumes, use self-contained breathing apparatus. Wear a
positive-pressure supplied-air respirator.
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Hand protection
gloves
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Eye protection
goggles If splashes are likely to occur, wear:
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9. Physical & Chemical Properties
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Important health, safety and environmental information
12.2 掳F (-11 掳C) estimated
Flash Point
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928.4 掳F (498 掳C) estimated
Auto Ignition
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Flammable IB
Flammability Class
Material ID 17652 Material Name Semi-Volatile Cal STD, Method 8270C
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MSDS US
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103.6 掳F (39.8 掳C) estimated
Boiling Point
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-142.1 掳F (-96.7 掳C) estimated
Melting Point
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1.83
Octanol Water
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1.8 mg/L
Solubility in Water
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212.7912 hPa estimated
Vapor Pressure
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92.6 % estimated
Volatile Organic
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10. Chemical Stability & Reactivity Information
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Further information
Stable at normal conditions
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11. Toxicological Information
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Dermal LD50 (Rabbit): 9400 l/kg
Other Toxicological
Inhalation LC50 (Rat): 10000 ppm/7h
Information
Oral LD50 (Mouse): 4700 mg/kg
Oral LD50 (Rat): 930 mg/kg
Occupational Carcinogen
Material ID 17652 Material Name Semi-Volatile Cal STD, Method 8270C
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MSDS US
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Acute Toxicity
NIOSH - Selected LD50s and LC50s
1,2-DICHLOROBENZENE, 95-50-1 Oral LD50 Rat: 500 mg/kg; Oral LD50 Mouse: 4386
ANHYDROUS, 99% mg/kg; Dermal LD50 Rabbit: >10 g/kg
2,4-DINITROTOLUENE121-14-2 Oral LD50 Rat: 268 mg/kg; Oral LD50 Mouse: 790
mg/kg
2,6-DINITROTOLUENE606-20-2 Inhalation LC50 Rat: 240 mg/m3/6H; Oral LD50 Rat:
177 mg/kg; Oral LD50 Mouse: 621 mg/kg
4-CHLOROANILINE, 106-47-8 Inhalation LC50 Rat: 2340 mg/m3/4H; Oral LD50 Rat:
SUBLIMED, 99+% 300 mg/kg; Oral LD50 Mouse: 100 mg/kg; Dermal
LD50 Rabbit: 360 mg/kg
Benzene 71-43-2 Inhalation LC50 Rat: 10000 ppm/7H; Oral LD50 Rat:
930 mg/kg; Oral LD50 Mouse: 4700 mg/kg; Dermal
LD50 Rabbit: >9400 L/kg
BIS(2-CHLOROETHOXY)METHANE
111-91-1 Oral LD50 Rat: 65 mg/kg
BIS(2-CHLOROETHYL)111-44-4 Inhalation LC50 Rat: 330 mg/m3/4H; Inhalation LC50
ETHER Mouse: 650 mg/m3/2H; Oral LD50 Rat: 75 mg/kg;
Oral LD50 Mouse: 209 mg/kg; Dermal LD50 Rabbit:
90 mg/kg
DI(2-ETHYLHEXYL)PHTHALATE
117-81-7 Oral LD50 Rat: 30 g/kg; Oral LD50 Mouse: 1500
mg/kg; Dermal LD50 Rabbit: 25 g/kg
FLUORANTHENE 206-44-0 Oral LD50 Rat: 2 g/kg; Dermal LD50 Rabbit: 3180
mg/kg
HEXACHLOROBENZENE
118-74-1 Oral LD50 Rat: 10 g/kg; Oral LD50 Mouse: 4 g/kg
HEXACHLOROBUTADIENE
87-68-3 Oral LD50 Rat: 82 mg/kg; Oral LD50 Mouse: 87
mg/kg; Dermal LD50 Rabbit: 100 mg/kg
HEXACHLOROETHANE
67-72-1 Oral LD50 Rat: 4460 mg/kg; Dermal LD50 Rabbit: 32
g/kg
ISOPHORONE 78-59-1 Oral LD50 Rat: 1870 mg/kg; Oral LD50 Mouse: 2690
mg/kg; Dermal LD50 Rabbit: 1500 L/kg
NAPHTHALENE 91-20-3 Inhalation LC50 Rat: >340 mg/m3/1H; Oral LD50
Rat: 490 mg/kg; Oral LD50 Mouse: 533 mg/kg;
Dermal LD50 Rabbit: >20 g/kg
NITROBENZENE 98-95-3 Inhalation LC50 Rat: 556 ppm/4H; Oral LD50 Mouse:
590 mg/kg
N-NITROSODI-N-PROPYLAMINE
621-64-7 Oral LD50 Rat: 480 mg/kg
P-DICHLOROBENZENE 106-46-7 Oral LD50 Rat: 500 mg/kg; Oral LD50 Mouse: 2950
mg/kg; Dermal LD50 Rabbit: >2 g/kg
PHENANTHRENE 85-01-8 Oral LD50 Mouse: 700 mg/kg
PYRENE 129-00-0 Oral LD50 Rat: 2700 mg/kg; Oral LD50 Mouse: 800
mg/kg
Material ID 17652 Material Name Semi-Volatile Cal STD, Method 8270C
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MSDS US
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Carcinogenicity
IARC - Group 1 (Carcinogenic to Humans)
ANTHRACENE 120-12-7 Supplement 7, 1987; Monograph 35, 1985
Benzene 71-43-2 Supplement 7, 1987; Monograph 29, 1982
BENZO[A]PYRENE 50-32-8 Supplement 7, 1987; Monograph 35, 1985
PHENANTHRENE 85-01-8 Supplement 7, 1987; Monograph 35, 1985
PYRENE 129-00-0 Supplement 7, 1987; Monograph 35, 1985
OSHA - Hazard Communication Carcinogens
2,4-DINITROTOLUENE 121-14-2 Present
2,6-DINITROTOLUENE606-20-2 Present
4-CHLOROANILINE, 106-47-8 Present
SUBLIMED, 99+%
ACENAPHTHENE 83-32-9 Present
ANTHRACENE 120-12-7 Present
BENZ[A]ANTHRACENE56-55-3 Present
Benzene 71-43-2 Present
BENZO(B)FLUORANTHENE 205-99-2 Present
BENZO(GHI)PERYLENE91-24-2
1 Present
BENZO(K)FLUORANTHENE 207-08-9 Present
BENZO[A]PYRENE 50-32-8 Present
DI(2-ETHYLHEXYL)PHTHALATE
117-81-7 Present
DIBENZO(A,H)ANTHRACENE
53-70-3 Present
FLUORANTHENE 206-44-0 Present
FLUORENE 86-73-7 Present
HEXACHLOROBENZENE 118-74-1 Present
HEXACHLOROETHANE 67-72-1 Present
INDENO(1,2,3-CD)PYRENE
193-39-5 Present
(2,3-O-PHENYLENEPYRENE)
NAPHTHALENE 91-20-3 Present
NITROBENZENE 98-95-3 Present
N-NITROSODI-N-PROPYLAMINE
621-64-7 Present
P-DICHLOROBENZENE 106-46-7 Present
PHENANTHRENE 85-01-8 Present
PYRENE 129-00-0 Present
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Carcinogenicity Data
OSHA Select Carcinogen
Material
ACGIH Confirmed Carcinogen
IARC Group 1 Carcinogen - Humans
NTP Known Carcinogen
Material ID 17652 Material Name Semi-Volatile Cal STD, Method 8270C
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MSDS US
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Material ID 17652 Material Name Semi-Volatile Cal STD, Method 8270C
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MSDS US
1,2-DICHLOROBENZENE, ANHYDROUS, 99%
Ingredient(s)
- ACGIH Not Classified Carcinogen
2,4-DINITROTOLUENE
- OSHA Select Carcinogen
2,6-DINITROTOLUENE
- OSHA Select Carcinogen
4-CHLOROANILINE, SUBLIMED, 99+%
- OSHA Select Carcinogen
ACENAPHTHENE
- OSHA Select Carcinogen
- NTP Suspected Carcinogen
ANTHRACENE
- OSHA Select Carcinogen
- OSHA Possible Select Carcinogen
- ACGIH Confirmed Carcinogen
- IARC Group 1 Carcinogen - Humans
- NTP Known Carcinogen
- NTP Suspected Carcinogen
BENZO(B)FLUORANTHENE
- OSHA Select Carcinogen
- ACGIH Suspected Carcinogen
- NTP Suspected Carcinogen
BENZO(GHI)PERYLENE
- OSHA Select Carcinogen
- NTP Suspected Carcinogen
BENZO(K)FLUORANTHENE
- OSHA Select Carcinogen
- NTP Suspected Carcinogen
BENZO[A]PYRENE
- OSHA Select Carcinogen
- ACGIH Suspected Carcinogen
- IARC Group 1 Carcinogen - Humans
- NTP Known Carcinogen
- NTP Suspected Carcinogen
BENZ[A]ANTHRACENE
- OSHA Select Carcinogen
- ACGIH Suspected Carcinogen
- NTP Suspected Carcinogen
BIS(2-CHLOROETHYL) ETHER
- ACGIH Not Classified Carcinogen
Benzene
- OSHA Select Carcinogen
- ACGIH Confirmed Carcinogen
- IARC Group 1 Carcinogen - Humans
- NTP Known Carcinogen
- NTP Suspected Carcinogen
DI(2-ETHYLHEXYL)PHTHALATE
- OSHA Select Carcinogen
- OSHA Possible Select Carcinogen
- ACGIH Animal Carcinogen
- NTP Suspected Carcinogen
DIBENZO(A,H)ANTHRACENE
- OSHA Select Carcinogen
- NTP Suspected Carcinogen
FLUORANTHENE
- OSHA Select Carcinogen
- NTP Suspected Carcinogen
FLUORENE
- OSHA Select Carcinogen
- NTP Suspected Carcinogen
Material ID 17652 Material Name Semi-Volatile Cal STD, Method 8270C
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MSDS US
- NTP Suspected Carcinogen
HEXACHLOROBENZENE
- OSHA Select Carcinogen
- OSHA Possible Select Carcinogen
- ACGIH Animal Carcinogen
- NTP Suspected Carcinogen
HEXACHLOROBUTADIENE
- ACGIH Animal Carcinogen
HEXACHLOROETHANE
- OSHA Select Carcinogen
- ACGIH Animal Carcinogen
- NTP Suspected Carcinogen
INDENO(1,2,3-CD)PYRENE (2,3-O-PHENYLENEPYRENE)
- OSHA Select Carcinogen
- NTP Suspected Carcinogen
ISOPHORONE
- ACGIH Animal Carcinogen
N-NITROSODI-N-PROPYLAMINE
- OSHA Select Carcinogen
- NTP Suspected Carcinogen
NAPHTHALENE
- OSHA Select Carcinogen
- OSHA Possible Select Carcinogen
- ACGIH Not Classified Carcinogen
- NTP Suspected Carcinogen
NITROBENZENE
- OSHA Select Carcinogen
- OSHA Possible Select Carcinogen
- ACGIH Animal Carcinogen
P-DICHLOROBENZENE
- OSHA Select Carcinogen
- ACGIH Animal Carcinogen
- NTP Suspected Carcinogen
PHENANTHRENE
- OSHA Select Carcinogen
- ACGIH Confirmed Carcinogen
- IARC Group 1 Carcinogen - Humans
- NTP Known Carcinogen
- NTP Suspected Carcinogen
PYRENE
- OSHA Select Carcinogen
- ACGIH Confirmed Carcinogen
- IARC Group 1 Carcinogen - Humans
- NTP Known Carcinogen
- NTP Suspected Carcinogen
Material ID 17652 Material Name Semi-Volatile Cal STD, Method 8270C
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MSDS US
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Symptoms and Target Organs
NIOSH - Pocket Guide - Target Organs
1,2-DICHLOROBENZENE, 95-50-1 liver, kidneys, skin, eyes, respiratory system
ANHYDROUS, 99%
ANTHRACENE 120-12-7 respiratory system, bladder, kidneys, skin
Benzene 71-43-2 eyes, skin, respiratory system, blood, CNS, bone
marrow (leukemia)
BENZO[A]PYRENE 50-32-8 respiratory system, bladder, kidneys, skin
BIS(2-CHLOROETHYL)111-44-4 eyes, respiratory system, liver (in animals: liver
ETHER tumors)
DI(2-ETHYLHEXYL)PHTHALATE
117-81-7 eyes, GI tract, respiratory system, CNS, liver,
reproductive system (in animals: liver tumors)
HEXACHLOROBUTADIENE
87-68-3 eyes, skin, respiratory system, kidneys (in animals:
kidney tumors)
HEXACHLOROETHANE
67-72-1 eyes, respiratory system, skin, kidneys (in animals:
liver cancer)
ISOPHORONE 78-59-1 skin, respiratory system, eyes, CNS, liver, kidneys
NAPHTHALENE 91-20-3 eyes, blood, liver, kidneys, skin, CNS
NITROBENZENE 98-95-3 blood, liver, kidneys, skin, CVS, eyes, reproductive
system
P-DICHLOROBENZENE
106-46-7 liver, respiratory system, eyes, kidneys, skin (in
animals: liver and kidney cancer)
PHENANTHRENE 85-01-8 respiratory system, bladder, kidneys, skin
PYRENE 129-00-0 respiratory system, bladder, kidneys, skin
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Material ID 17652 Material Name Semi-Volatile Cal STD, Method 8270C
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MSDS US
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12. Ecological Information
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Material ID 17652 Material Name Semi-Volatile Cal STD, Method 8270C
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MSDS US
Ecotoxicity
Ecotoxicity - Freshwater Algae Data
ACENAPHTHENE 83-32-9 96 Hr EC50 freshwater algae (Selenastrum
capricornutum and Skeletonema costatum): 0.50
mg/L
Ecotoxicity - Freshwater Fish Species Data
1,2-DICHLOROBENZENE, 95-50-1 96 Hr LC50 fathead minnow: 9.47 mg/L
ANHYDROUS, 99% (flow-through)
1,3-DICHLOROBENZENE 541-73-1 96 Hr LC50 fathead minnow: 8.03 mg/L
(flow-through)
2,4-DINITROTOLUENE121-14-2 96 Hr LC50 fathead minnow: 24.3 mg/L
(flow-through)
4-CHLOROANILINE, 106-47-8 96 Hr LC50 fathead minnow: 12 mg/L
SUBLIMED, 99+% (flow-through);96 Hr LC50 rainbow trout: 14 mg/L
(Static);96 Hr LC50 bluegill: 2 mg/L (Static)
ACENAPHTHENE 83-32-9 96 Hr LC50 fathead minnow (0.16 g):1.6 mg/L
(Flow-through);96 Hr LC50 rainbow trout (1.3 g):0.67
mg/L (Flow-through);96 Hr LC50 bluegill: 1.7 mg/L
(Static)
Benzene 71-43-2 96 Hr LC50 fathead minnow: 12.6 mg/L
(flow-through);96 Hr LC50 rainbow trout: 5.3 mg/L
(flow-through);96 Hr LC50 bluegill: 22 mg/L (Static)
BIS(2-CHLOROETHYL)111-44-4 96 Hr LC50 bluegill: 600 mg/L (Static)
ETHER
DI(2-ETHYLHEXYL)PHTHALATE
117-81-7 96 Hr LC50 fathead minnow: >10 mg/L
(Flow-through);96 Hr LC50 rainbow trout: >100 mg/L
(Static);96 Hr LC50 bluegill: >100 mg/L (Static)
HEXACHLOROBUTADIENE 87-68-3 96 Hr LC50 fathead minnow: 0.09 mg/L
(flow-through)
HEXACHLOROETHANE 67-72-1 96 Hr LC50 fathead minnow: 1.32 mg/L
(flow-through)
ISOPHORONE 78-59-1 96 Hr LC50 fathead minnow: 228 mg/L (flow-through)
NAPHTHALENE 91-20-3 96 Hr LC50 fathead minnow: 6.14 mg/L
(flow-through);96 Hr LC50 rainbow trout (juvenile):
1.60 mg/L (Flow-through);96 Hr LC50 pink salmon
(fry): 1.24 mg/L (Static)
NITROBENZENE 98-95-3 96 Hr LC50 fathead minnow: 119 mg/L (flow-through)
P-DICHLOROBENZENE 106-46-7 96 Hr LC50 fathead minnow: 18 mg/L (Static);96 Hr
LC50 fathead minnow (fry): 3.3 mg/L (Static);96 Hr
LC50 fathead minnow (juvenile):12.1 mg/L (Static);96
Hr LC50 fathead minnow (sub adult): 9.4 mg/L
(Static);96 Hr LC50 rainbow trout: 1.05 mg/L
(flow-through);96 Hr LC50 bluegill: 4.25 mg/L (Static)
Ecotoxicity - Microtox Data
1,2-DICHLOROBENZENE, 95-50-1 5 min EC50 Photobacterium phosphoreum: 4.76
ANHYDROUS, 99% mg/L; 15 min EC50 Photobacterium phosphoreum:
4.98 mg/L; 30 min EC50 Photobacterium
phosphoreum: 5.99 mg/L
1,3-DICHLOROBENZENE 541-73-1 5 min EC50 Photobacterium phosphoreum: 3.29
mg/L; 15 min EC50 Photobacterium phosphoreum:
3.96 mg/L; 30 min EC50 Photobacterium
phosphoreum: 5.10 mg/L
2,4-DINITROTOLUENE121-14-2 5 min EC50 Photobacterium phosphoreum: 33 mg/L;
30 min EC50 Photobacterium phosphoreum: 21 mg/L
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MSDS US
4-CHLOROANILINE, 106-47-8 5 min EC50 Photobacterium phosphoreum: 3.20
SUBLIMED, 99+% mg/L; 15 min EC50 Photobacterium phosphoreum:
3.77 mg/L; 30 min EC50 Photobacterium
phosphoreum: 5.08 mg/L
ACENAPHTHENE 83-32-9 15 min EC50 Photobacterium phosphoreum: 0.58
mg/L (15 掳C)
BENZ[A]ANTHRACENE56-55-3 15 min EC50 Photobacterium phosphoreum: 0.26
mg/L
DI(2-ETHYLHEXYL)PHTHALATE
117-81-7 5 min EC50 Photobacterium phosphoreum: 800
mg/L; 15 min EC50 Photobacterium phosphoreum:
800 mg/L; 30 min EC50 Photobacterium
phosphoreum: 800 mg/L
NAPHTHALENE 91-20-3 30 min EC50 Photobacterium phosphoreum: 0.93
mg/L
P-DICHLOROBENZENE
106-46-7 5 min EC50 Photobacterium phosphoreum: 4.34
mg/L; 15 min EC50 Photobacterium phosphoreum:
4.87 mg/L; 30 min EC50 Photobacterium
phosphoreum: 5.34 mg/L
Ecotoxicity - Water Flea Data
2,4-DINITROTOLUENE 121-14-2 48 Hr EC50 water flea: 24 mg/L
4-CHLOROANILINE, 106-47-8 48 Hr EC50 water flea: <10 mg/L
SUBLIMED, 99+%
ACENAPHTHENE 83-32-9 48 Hr EC50 water flea: 41.2 mg/L
BENZ[A]ANTHRACENE56-55-3 96 Hr EC50 water flea: 0.01 mg/L (Static)
Benzene 71-43-2 48 Hr EC50 water flea: 356 mg/L (Static)
BIS(2-CHLOROETHYL)111-44-4 48 Hr EC50 water flea: 238 mg/L (Static)
ETHER
DI(2-ETHYLHEXYL)PHTHALATE
117-81-7 48 Hr EC50 water flea:11.0 mg/L (24 hours old)
NAPHTHALENE 91-20-3 48 Hr EC50 water flea: 2.16 mg/L
P-DICHLOROBENZENE 106-46-7 48 Hr EC50 water flea:11.0 mg/L (Static, <=24 hours
old)
PYRENE 129-00-0 48 Hr EC50 water flea: 1.8 mg/L
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13. Disposal Considerations
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Disposal Instructions
In accordance with local and national regulations.
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Material ID 17652 Material Name Semi-Volatile Cal STD, Method 8270C
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14. Transportation Information
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US DOT
Flammable liquids, toxic, n.o.s.
Proper shipping name DOT
3
Hazard class
UN1992
UN number
II
Packaging group
IB2, T7, TP2, TP13
Special provisions
None
Packaging exceptions
202
Packaging non bulk
243
Packaging bulk
1L
Quantity limits
DOT
passenger
60 L
Quantity limits cargo
B
Vessel stowage
location
40
Vessel stowage other
3, 6.1
Labels required
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Other Information
According to IATA respectively ICAO exempt from regulations up to 1 per each inner packaging and
15 per each outer packaging. DOT regulated, small quantity provisions apply (see 49CFR173.4)
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15. Regulatory Information
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CERCLA/SARA Section 313
Semi-Volatile Cal STD, Method 8270C
Material
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Benzene
Ingredient(s)
Material ID 17652 Material Name Semi-Volatile Cal STD, Method 8270C
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Material ID 17652 Material Name Semi-Volatile Cal STD, Method 8270C
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US Federal Regulations
CERCLA/SARA - Hazardous Substances and their Reportable Quantities
1,2-DICHLOROBENZENE,95-50-1 100 lb final RQ; 45.4 kg final RQ
ANHYDROUS, 99%
1,3-DICHLOROBENZENE 541-73-1 100 lb final RQ; 45.4 kg final RQ
2,4-DINITROTOLUENE121-14-2 10 lb final RQ; 4.54 kg final RQ
2,6-DINITROTOLUENE606-20-2 100 lb final RQ; 45.4 kg final RQ
4-CHLOROANILINE, 106-47-8 1000 lb final RQ; 454 kg final RQ
SUBLIMED, 99+%
ACENAPHTHENE 83-32-9 100 lb final RQ; 45.4 kg final RQ
ANTHRACENE 120-12-7 5000 lb final RQ; 2270 kg final RQ
BENZ[A]ANTHRACENE56-55-3 10 lb final RQ; 4.54 kg final RQ
Benzene 71-43-2 10 lb final RQ (receives an adjustable RQ of 10 lbs
based on potential carcinogenicity in August 14, 1989
final rule); 4.54 kg final RQ (receives an adjustable
RQ of 10 lbs based on potential carcinogenicity in
August 14, 1989 final rule)
BENZO(B)FLUORANTHENE205-99-2 1 lb final RQ; 0.454 kg final RQ
BENZO(GHI)PERYLENE91-24-2
1 5000 lb final RQ; 2270 kg final RQ
BENZO(K)FLUORANTHENE207-08-9 1 lb final RQ; 0.454 kg final RQ
BENZO[A]PYRENE 50-32-8 1 lb final RQ; 0.454 kg final RQ
BIS(2-CHLOROETHOXY)METHANE
111-91-1 1000 lb final RQ; 454 kg final RQ
BIS(2-CHLOROETHYL)111-44-4 10 lb final RQ; 4.54 kg final RQ
ETHER
DI(2-ETHYLHEXYL)PHTHALATE
117-81-7 100 lb final RQ; 45.4 kg final RQ
DIBENZO(A,H)ANTHRACENE
53-70-3 1 lb final RQ; 0.454 kg final RQ
FLUORANTHENE 206-44-0 100 lb final RQ; 45.4 kg final RQ
FLUORENE 86-73-7 5000 lb final RQ; 2270 kg final RQ
HEXACHLOROBENZENE 118-74-1 10 lb final RQ; 4.54 kg final RQ
HEXACHLOROBUTADIENE 87-68-3 10 lb final RQ; 4.54 kg final RQ
HEXACHLOROETHANE 67-72-1 100 lb final RQ; 45.4 kg final RQ
INDENO(1,2,3-CD)PYRENE
193-39-5 100 lb final RQ; 45.4 kg final RQ
(2,3-O-PHENYLENEPYRENE)
ISOPHORONE 78-59-1 5000 lb final RQ; 2270 kg final RQ
NAPHTHALENE 91-20-3 100 lb final RQ; 45.4 kg final RQ
NITROBENZENE 98-95-3 1000 lb final RQ; 454 kg final RQ
N-NITROSODI-N-PROPYLAMINE
621-64-7 10 lb final RQ; 4.54 kg final RQ
P-DICHLOROBENZENE 106-46-7 100 lb final RQ; 45.4 kg final RQ
PHENANTHRENE 85-01-8 5000 lb final RQ; 2270 kg final RQ
PYRENE 129-00-0 5000 lb final RQ; 2270 kg final RQ
CERCLA/SARA - Section 302 Extremely Hazardous Substances TPQs
BIS(2-CHLOROETHYL)111-44-4 10000 lb TPQ
ETHER
NITROBENZENE 98-95-3 10000 lb TPQ
PYRENE 129-00-0 1000 lb TPQ (lower threshold); 10000 lb TPQ (upper
threshold)
CERCLA/SARA - Section 313 - Emission Reporting
1,2-DICHLOROBENZENE,95-50-1 1.0 % de minimis concentration
ANHYDROUS, 99%
1,3-DICHLOROBENZENE 541-73-1 1.0 % de minimis concentration
2,4-DINITROTOLUENE121-14-2 0.1 % de minimis concentration
2,6-DINITROTOLUENE606-20-2 0.1 % de minimis concentration
4-CHLOROANILINE, 106-47-8 0.1 % de minimis concentration
SUBLIMED, 99+%
ANTHRACENE 120-12-7 1.0 % de minimis concentration
Material ID 17652 Material Name Semi-Volatile Cal STD, Method 8270C
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BENZ[A]ANTHRACENE56-55-3 100 lb Reporting Threshold (Listed under 'Polycyclic
aromatic compounds', Chemical Category N590, PBT
Chemicals)
Benzene 71-43-2 0.1 % de minimis concentration
BENZO(B)FLUORANTHENE
205-99-2 100 lb Reporting Threshold (Listed under 'Polycyclic
aromatic compounds', Chemical Category N590, PBT
Chemicals)
BENZO(GHI)PERYLENE91-24-2
1 10 lb Reporting Threshold (PBT Chemical)
BENZO(K)FLUORANTHENE
207-08-9 100 lb Reporting Threshold (Listed under 'Polycyclic
aromatic compounds', Chemical Category N590, PBT
Chemicals)
BENZO[A]PYRENE 50-32-8 100 lb Reporting Threshold (Listed under 'Polycyclic
aromatic compounds', Chemical Category N590, PBT
Chemicals)
BIS(2-CHLOROETHOXY)METHANE
111-91-1 1.0 % de minimis concentration
BIS(2-CHLOROETHYL)111-44-4 1.0 % de minimis concentration
ETHER
DI(2-ETHYLHEXYL)PHTHALATE
117-81-7 0.1 % de minimis concentration
DIBENZO(A,H)ANTHRACENE
53-70-3 100 lb Reporting Threshold (Listed under 'Polycyclic
aromatic compounds', Chemical Category N590, PBT
Chemicals)
FLUORANTHENE 206-44-0 100 lb Reporting Threshold (Listed under 'Polycyclic
aromatic compounds', Chemical Category N590, PBT
Chemicals)
HEXACHLOROBENZENE 118-74-1 10 lb Reporting Threshold (PBT Chemical)
HEXACHLOROBUTADIENE87-68-3 1.0 % de minimis concentration
HEXACHLOROETHANE 67-72-1 0.1 % de minimis concentration
INDENO(1,2,3-CD)PYRENE
193-39-5 100 lb Reporting Threshold (Listed under 'Polycyclic
(2,3-O-PHENYLENEPYRENE) aromatic compounds', Chemical Category N590, PBT
Chemicals)
NAPHTHALENE 91-20-3 1.0 % de minimis concentration
NITROBENZENE 98-95-3 0.1 % de minimis concentration
N-NITROSODI-N-PROPYLAMINE
621-64-7 0.1 % de minimis concentration
P-DICHLOROBENZENE 106-46-7 0.1 % de minimis concentration
PHENANTHRENE 85-01-8 1.0 % de minimis concentration
OSHA - Specifically Regulated Chemicals
Benzene 71-43-2 1 ppm PEL; 5 ppm STEL; 0.5 ppm Action Level
(Cancer hazard, Flammable - see 29 CFR
1910.1028)
TSCA (Toxic Substances Control Act) - Section 12(b) - Export Notification
ISOPHORONE 78-59-1 Section 4
NAPHTHALENE 91-20-3 Section 4
P-DICHLOROBENZENE 106-46-7 Section 4
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Material ID 17652 Material Name Semi-Volatile Cal STD, Method 8270C
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State Regulations
California - Proposition 65 - Developmental Toxicity
Benzene 71-43-2 developmental toxicity, initial date 12/26/97
DI(2-ETHYLHEXYL)PHTHALATE
117-81-7 developmental toxicity, initial date 10/24/03
HEXACHLOROBENZENE 118-74-1 developmental toxicity, initial date 1/1/89
California - Proposition 65 - No Significant Risk Levels (NSRL)
2,4-DINITROTOLUENE 121-14-2 2 g/day NSRL
BENZ[A]ANTHRACENE56-55-3 0.033 g/day NSRL (oral)
Benzene 71-43-2 6.4 g/day NSRL (oral); 13 g/day NSRL (inhalation)
BENZO(B)FLUORANTHENE 205-99-2 0.096 g/day NSRL (oral)
BENZO[A]PYRENE 50-32-8 0.06 g/day NSRL
BIS(2-CHLOROETHYL)111-44-4 0.3 g/day NSRL
ETHER
DI(2-ETHYLHEXYL)PHTHALATE
117-81-7 310 g/day NSRL
DIBENZO(A,H)ANTHRACENE 53-70-3 0.2 g/day NSRL
HEXACHLOROBENZENE 118-74-1 0.4 g/day NSRL
HEXACHLOROETHANE 67-72-1 20 g/day NSRL
N-NITROSODI-N-PROPYLAMINE
621-64-7 0.1 g/day NSRL
P-DICHLOROBENZENE 106-46-7 20 g/day NSRL
Connecticut - Carcinogenic Substances
ANTHRACENE 120-12-7 Meets the definition of a carcinogen from the
Secretary of Labor.
Benzene 71-43-2 Present
BENZO[A]PYRENE 50-32-8 Meets the definition of a carcinogen from the
Secretary of Labor.
PHENANTHRENE 85-01-8 Meets the definition of a carcinogen from the
Secretary of Labor.
PYRENE 129-00-0 Meets the definition of a carcinogen from the
Secretary of Labor.
Massachusetts - Right To Know List
1,2-DICHLOROBENZENE, 95-50-1 Present
ANHYDROUS, 99%
1,3-DICHLOROBENZENE 541-73-1 Present
2,4-DINITROTOLUENE121-14-2 Carcinogen; Extraordinarily hazardous
2,6-DINITROTOLUENE606-20-2 Present
4-CHLOROANILINE, 106-47-8 Present
SUBLIMED, 99+%
ACENAPHTHENE 83-32-9 Present
ANTHRACENE 120-12-7 Present
BENZ[A]ANTHRACENE56-55-3 Carcinogen; Extraordinarily hazardous
Benzene 71-43-2 Carcinogen; Extraordinarily hazardous
BENZO(B)FLUORANTHENE 205-99-2 Carcinogen; Extraordinarily hazardous
BENZO(GHI)PERYLENE91-24-2
1 Present
BENZO(K)FLUORANTHENE 207-08-9 Carcinogen; Extraordinarily hazardous
BENZO[A]PYRENE 50-32-8 Carcinogen; Extraordinarily hazardous
BIS(2-CHLOROETHOXY)METHANE
111-91-1 Present
BIS(2-CHLOROETHYL)111-44-4 Carcinogen; Extraordinarily hazardous
ETHER
DI(2-ETHYLHEXYL)PHTHALATE
117-81-7 Carcinogen; Extraordinarily hazardous
DIBENZO(A,H)ANTHRACENE 53-70-3 Carcinogen; Extraordinarily hazardous
FLUORANTHENE 206-44-0 Present
FLUORENE 86-73-7 Present
HEXACHLOROBENZENE 118-74-1 Carcinogen; Extraordinarily hazardous; Teratogen
HEXACHLOROBUTADIENE 87-68-3 Carcinogen; Extraordinarily hazardous
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HEXACHLOROETHANE 67-72-1 Carcinogen; Extraordinarily hazardous
INDENO(1,2,3-CD)PYRENE193-39-5 Carcinogen; Extraordinarily hazardous
(2,3-O-PHENYLENEPYRENE)
ISOPHORONE 78-59-1 Present
NAPHTHALENE 91-20-3 Present
NITROBENZENE 98-95-3 Extraordinarily hazardous
N-NITROSODI-N-PROPYLAMINE
621-64-7 Carcinogen; Extraordinarily hazardous
P-DICHLOROBENZENE 106-46-7 Carcinogen; Extraordinarily hazardous
PHENANTHRENE 85-01-8 Present
PYRENE 129-00-0 Extraordinarily hazardous
Massachusetts - Toxics Use Reduction Act
1,2-DICHLOROBENZENE, 95-50-1 CERCLA and 313 chemical
ANHYDROUS, 99%
1,3-DICHLOROBENZENE 541-73-1 CERCLA and 313 chemical
2,4-DINITROTOLUENE121-14-2 CERCLA and 313 chemical
2,6-DINITROTOLUENE606-20-2 CERCLA and 313 chemical
4-CHLOROANILINE, 106-47-8 CERCLA and 313 chemical
SUBLIMED, 99+%
ACENAPHTHENE 83-32-9 CERCLA Only chemical
ANTHRACENE 120-12-7 CERCLA and 313 chemical
BENZ[A]ANTHRACENE56-55-3 CERCLA and 313 chemical
Benzene 71-43-2 CERCLA and 313 chemical
BENZO(B)FLUORANTHENE 205-99-2 CERCLA and 313 chemical
BENZO(GHI)PERYLENE91-24-2
1 CERCLA Only chemical
BENZO(K)FLUORANTHENE 207-08-9 CERCLA and 313 chemical
BENZO[A]PYRENE 50-32-8 CERCLA and 313 chemical
BIS(2-CHLOROETHOXY)METHANE
111-91-1 CERCLA and 313 chemical
BIS(2-CHLOROETHYL)111-44-4 CERCLA and 313 chemical
ETHER
DI(2-ETHYLHEXYL)PHTHALATE
117-81-7 CERCLA and 313 chemical
DIBENZO(A,H)ANTHRACENE53-70-3 CERCLA and 313 chemical
FLUORANTHENE 206-44-0 CERCLA Only chemical
FLUORENE 86-73-7 CERCLA Only chemical
HEXACHLOROBENZENE 118-74-1 CERCLA and 313 chemical
HEXACHLOROBUTADIENE 87-68-3 CERCLA and 313 chemical
HEXACHLOROETHANE 67-72-1 CERCLA and 313 chemical
INDENO(1,2,3-CD)PYRENE193-39-5 CERCLA and 313 chemical
(2,3-O-PHENYLENEPYRENE)
ISOPHORONE 78-59-1 CERCLA Only chemical
NAPHTHALENE 91-20-3 CERCLA and 313 chemical
NITROBENZENE 98-95-3 CERCLA and 313 chemical
N-NITROSODI-N-PROPYLAMINE
621-64-7 CERCLA and 313 chemical
P-DICHLOROBENZENE 106-46-7 CERCLA and 313 chemical
PHENANTHRENE 85-01-8 CERCLA and 313 chemical
PYRENE 129-00-0 CERCLA Only chemical
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International Regulations
Canada - WHMIS - Ingredient Disclosure List
1,2-DICHLOROBENZENE, 95-50-1 1 % (English Item 536, French Item 655)
ANHYDROUS, 99%
1,3-DICHLOROBENZENE 541-73-1 1 % (English Item 535, French Item 654)
2,4-DINITROTOLUENE121-14-2 1 % (English Item 652, French Item 766)
4-CHLOROANILINE, 106-47-8 1 % (English Item 344, French Item 412)
SUBLIMED, 99+%
ACENAPHTHENE 83-32-9 1 % (English Item 3, French Item 2)
ANTHRACENE 120-12-7 1 % (English Item 120, French Item 249)
BENZ[A]ANTHRACENE56-55-3 0.1 % (English Item 151, French Item 281)
Benzene 71-43-2 0.1 % (English Item 153, French Item 277)
BENZO(B)FLUORANTHENE 205-99-2 0.1 % (English Item 159, French Item 284)
BENZO[A]PYRENE 50-32-8 0.1 % (English Item 163, French Item 287)
BIS(2-CHLOROETHYL)111-44-4 1 % (English Item 547, French Item 838)
ETHER
DI(2-ETHYLHEXYL)PHTHALATE
117-81-7 0.1 % (English Item 590, French Item 1418)
DIBENZO(A,H)ANTHRACENE
53-70-3 0.1 % (English Item 501, French Item 636)
FLUORANTHENE 206-44-0 1 % (English Item 770, French Item 892)
HEXACHLOROBENZENE 118-74-1 1 % (English Item 811, French Item 945)
HEXACHLOROBUTADIENE 87-68-3 0.1 % (English Item 812, French Item 946)
HEXACHLOROETHANE 67-72-1 1 % (English Item 814, French Item 948)
INDENO(1,2,3-CD)PYRENE
193-39-5 0.1 % (English Item 871, French Item 1017)
(2,3-O-PHENYLENEPYRENE)
ISOPHORONE 78-59-1 1 % (English Item 898, French Item 1047)
NAPHTHALENE 91-20-3 1 % (English Item 1108, French Item 1181)
NITROBENZENE 98-95-3 1 % (English Item 1157, French Item 1227)
N-NITROSODI-N-PROPYLAMINE
621-64-7 0.1 % (English Item 1195, French Item 1256)
P-DICHLOROBENZENE 106-46-7 1 % (English Item 537, French Item 656)
PHENANTHRENE 85-01-8 1 % (English Item 1257, French Item 1371)
PYRENE 129-00-0 1 % (English Item 1373, French Item 1458)
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16. Other Information
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Disclaimer
The information provided in this Material Safety Data Sheet is based on our present knowledge,
and believed to be correct at the date of publication. However, no representation is made
concerning its accuracy and completeness. It is intended as guidance only, and is not to be
considered a warranty or quality specification. All materials may present unknown hazards, and
should be used with caution. Although certain hazards are described, we cannot guarantee that
these are the only hazards which exist. PerkinElmer Life and Analytical Sciences shall not be held
liable for any damage resulting from handling or from contact with the product.
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