LAKELAND
CHEMICAL SPECIALTIES, INC.
W140 N5090 LILLY ROAD
MENOMONEE FALLS, WI 53051
24 Hour Emergency: (800) 424-9300 (CHEMTREC) Phone: (262) 781-1350
MATERIAL SAFETY DATA SHEET
DATE ISSUED 06/06
SECTION 1: PRODUCT IDENTIFICATION
PRODUCT NAME: A-5000 WATER TREATMENT BIOCIDE
DATE ISSUED: 05/26/94-REV.
DOT HAZARDOUS CLASSIFICATION: 5.1, PGII
DOT SHIPPING NAME: OXIDIZING SUBSTANCES, SOLID, N.O.S.
DOT LABEL: OXIDIZER
FORMULA: MIXTURE
25
CHEMICAL FAMILY: MIXTURE
SECTION 2: HAZARDOUS INGREDIENTS
APPROXIMATE TWA/TLV
WEIGHT %
BROMOCHLORO-5
5-DIMETHYLHYDANOIN 60.0 0.2 MG/M3(LONZA
(CAS #126-06-7) INTERNAL STANDARD)
1,3-DICHLORO-5 0.2 MG/M3 (OSHA-PEL)
5-DIMETHYLHDANTOIN 27.4 0.4 MG/M3 (OSHA-Stel)
(CAS #118-52-5) 0.2 mg/m3 (ACGIH-TLV)
1,3-DICHLORO-5-ETHYL-
5-METHYLHYDANTOIN 10.6 0.2 MG/M3 (LONZA
(CAS #89415-87-2) INTERNAL STANDARD)
SODIUM CHLORIDE 1 NONE ESTABLISHED
(CAS #7647-14-5)
SECTION 3: PHYSICAL/CHEMICAL PROPERTIES
BOILING POINT: NOT APPLICABLE MELTING POINT: 120-148掳
SOLUBILITY IN WATER: 0.54 GRAM/100 GRAMS @25掳C VAPOR PRESSURE (mm Hg): NA
pH: NOT KNOWN VAPOR DENSITY (AIR = 1): NA
SPECIFIC GRAVITY(WATER=1): NOT APPLICABLE VISCOSITY: NOT APPLICABLE
APPEARANCE/ODOR BRIQUETTES EVAPORATION RATE (BUTYL ACETATE) <1
ODOR: VERY SLIGHT PUNGENT PERCENT VOLATILE (BY VOLUME): <0.5
SECTION 4 : FIRE AND EXPLOSION HAZARD DATA
FLASH POINT (METHOD USED): >200掳F
AUTO IGNITION TEMPERATURE: NOT KNOWN
LOWER EXPLOSION LIMIT (%): NOT APPLICABLE
UPPER EXPLOSION LIMIT (%): NOT APPLICABLE
EXTINGUISHER MEDIA: FOAM X
DRY CHEMICAL X
ALCOHOL
WATER X
CO2
OTHER
SPECIAL FIRE FIGHTING PROCEDURES
TO MINIMIZE THE PROGRESSIVE GENERATION OF NOXIOUS GASES, FLOOD BURNING MATERIAL WITH LARGE QUANTITIES OF WATER.
MUST WEAR NIOSH/MSHA APPROVED SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. COOL FIRE-EXPOSED
CONTAINERS WITH WATER SPRAY.
UNUSUAL FIRE AND EXPLOSION HAZARDS: MATERIAL IS A STRONG OXIDIZER AND CORROSIVE.
MAY IGNITE COMBUSTIBLE MATERIALS AND MAY PRODUCE NOXIOUS GASES.
PRODUCTS OF COMBUSTION ARE TOXIC.
AIRBORNE DUSTS OF THIS PRODUCT IN AN ENCLOSED SPACE AND IN THE PRESENCE OF AN IGNITION SOURCE MAY CONSTITUTE
AN EXPLOSION HAZARD. USE ADEQUATE EXPLOSION-PROOF VENTILATION SYSTEMS TO CONTROL DUST AT THE SOURCE.
AVOID GENERATING PRODUCT DUST NEAR SOURCES OF IGNITION, INCLUDING STATIC ELECTRICITY. USE SAFETY MEASURES
IN ACCORDANCE WITH THE 1988 EDITION OF NFPA 654 (STANDARD FOR THE PREVENTION OF DUST EXPLOSIONS IN THE
CHEMICAL, DYE, PHARMACEUTICAL AND PLASTIC INDUSTRIES).
SECTION 5: HEALTH EFFECTS INFORMATION
ROUTES OF ENTRY: SKIN CONTACT X EYE CONTACT X
INHALATION X INGESTION
EFFECTS OF OVEREXPOSURE:
DIRECT SKIN AND EYE CONTACT CAN RESULT IN SEVERE SKIN AND EYE IRRITATION. PROLONGED CONTACT MAY PRODUCE
IRREVERSIBLE DAMAGE. INHALATION OF HIGH CONCENTRATIONS CAN BE SEVERELY IRRITATING TO THE LUNG WITH
POTENTIAL SYSTEMIC ABSORPTION AND TISSUE DAMAGE. REPEATED SKIN EXPOSURE MAY INDUCE SENSITIZATION.
OVEREXPOSURE MAY AGGRAVATE EXISTING CONDITIONS: NO EFFECTS INDICATED.
EMERGENCY AND FIRST AID PROCEDURES:
EYES: FLUSH EYES WITH LARGE AMOUNTS OF RUNNING WATER FOR AT LEAST 15 MINUTES.
HOLD EYELID APART TO ENSURE RINSING OF THE ENTIRE SURFACE OF THE EYE AND LIDS WITH WATER.
GET IMMEDIATE MEDICAL ATTENTION. IF PHYSICIAN NOT AVAILABLE, FLUSH FOR ADDITIONAL 15 MINUTES
AND THEN TRANSPORT VICTIM TO MEDICAL CARE.
SKIN: IMMEDIATELY WIPE AWAY EXCESS MATERIAL WITH DRY CLOTH WHILE REMOVING CONTAMINATED CLOTHING
AND SHOES. UNDER SAFETY SHOWER, WASH AFFECTED AREAS THOROUGHLY WITH LARGE AMOUNTS OF
WATER, AND SOAP IF AVAILABLE, FOR AT LEAST 15 MINUTES. GET IMMEDIATE MEDICAL ATTENTION.
DISCARD OR DECONTAMINATE CLOTHING AND SHOES.
INHALATION: REMOVE FROM AREA TO FRESH AIR. IF NOT BREATHING, CLEAR AIRWAY AND START ARTIFICIAL RESPIRATION.
IF VICTIM IS HAVING TROUBLE BREATHING, GIVE SUPPLEMENTAL OXYGEN, IF AVAILABLE. GET IMMEDIATE MEDICAL ATTENTION.
INGESTION: IF SWALLOWED, IMMEDIAITELY GIVE 3-4 GLASSES OF WATER. DO NOT INDUCE VOMITING.
IF VOMITING OCCURS, GIVE FLUIDS AGAIN. GET IMMEDIATE MEDICAL ATTENTION. HAVE PHYSICIAN
DETERMINE IF PATIENT'S CONDITION ALLOWS INDUCTION OF VOMITING OR EVACUATION OF STOMACH.
DO NOT GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSING PERSON.
CHEMICAL LISTED AS CARCINOGEN BY:
NATIONAL TOXICOLOGY PROGRAM: NO
I.A.R.C. MONOGRAPHS: NO
OSHA NO
SECTION 6: REACTIVITY INFORMATION
STABLE X UNSTABLE
CONDITIONS TO AVOID: NONE KNOWN (DECOMPOSES AT 165掳C)
HAZARDOUS DECOMPOSITION PRODUCTS
THERMAL DECOMPOSITION MAY PRODUCE TOXIC VAPORS/FUMES OF CHLORINE, BROMINE, ORGANIC MATERIALS
AND OXIDES OF CARBON AND NITROGEN.
HAZARDOUS POLYMERIZATION
MAY OCCUR WILL NOT OCCUR X
CONDITIONS TO AVOID: NONE KNOWN
INCOMPATIBILITY (MATERIALS TO AVOID)
WATER
OTHER X
STRONG ACIDS AND ALKALIS, HIGH STORAGE TEMPERATURES, MOISURE AND READILY OXIDIZABLE MATERIALS.
SECTION 7: SPILL AND DISPOSAL INFORMATION
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
DANGER! OXIDIZING AND CORROSIVE MATERIAL. DUST EXPLOSION HAZARD. DO NOT GET IN EYES OR ON SKIN.
DO NOT BREATH DUST. FOR SPILLS, WEAR APPROPRIAITE PROTECTIVE GEAR, AND RESPIRATORY PROTECTION.
WHERE DUST MAY BE GENERATED, WEAR FULL FACE RESPIRATORY PROTECTION, AND REMOVE ALL SOURCES
OF IGNITION. FOR LARGE SPILLS, OR WHEN SPILLED MATERIAL COMES IN CONTACT WITH WATER,
SELF-CONTAINED BREATHING APPARATUS IS PERFERRED.
CAREFULLY SWEEP UP SPILLED MATERIALS (AVOID GENERATING DUST) AND PLCE IN AN APPROPRIATE CONTAINER
FOR DISPOSAL. DO NOT CONTAMINATE WITH OXIDIZABLE MATERIALS. NEUTRALIZE ANY RESIDUE WITH DILUTE, ALKALINE
SODIUM BISULFITE OR THIOSULFATE SOLUTION; ABSORB WITH SAND OR VERMICULITE AND PLACE IN A COMPATIBLE
CONTAINER FOR DISPOSAL. IF SPILLED MATERIAL IS WET, NEUTRALIZE AND PROCEED AS STATED ABOVE.
MATERIAL IS TOXIC TO FISH. DO NOT DISCHARGE INTO LAKES, STREAMS, PONDS OR PUBLIC WATER UNLESS IN ACCORDANCE
WITH AN NPDES PERMIT.
WASTE DISPOSAL METHODS
DISPOSE OF IN COMPLIANCE WITH ALL FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS. INCINERATION IS THE
PREFERRED METHOD. RELATIVELY SMALL QUANTITIES OF PRODUCT MAY BE NEUTRALIZED AS STATED ABOVE, AND IF IN
ACCORDANCE WITH LOCAL LAWS AND OPERATORS OF THE LOCAL SEWERAGE TREATMENT PLANTS, THE NEUTRALIZED
MATERIALS MAY BE DISCHARGED IN SEWER SYSTEMS.
SECTION 8: PERSONAL PROTECTION INFORMATION
VENTILATION TYPE
IN PROCESSES WHERE DUST OR AIRBORNE PARTICULATES MAY BE GENERATED, PROPER VENTILATION MUST BE
PROVIDED IN ACCORDANCE WITH GOOD VENTILATION PRACTICES.
RESPIRATORY PROTECTION
IN PROCESSES WHERE DUST OR AIRBORNE PARTICULATES MAY BE GENERATED.A NIOSHA/MSHA JOINTLY
APPROVED RESPIRATOR IS ADVISED IN THE ABSENCE OF PROPER ENVIRONMENTAL CONTROLS.
PROTECTIVE GLOVES
RUBBER OR NEOPRENE, TO PREVENT SKIN CONTACT.
EYE PROTECTION
WEAR CHEMICAL GOGGLES WHERE THERE IS A POTENTIAL FOR EYE CONTACT. USE SAFETY GLASSES WITH
SIDE SHIELDS UNDER NORMAL USE CONDITIONS.
OTHER PROTECTIVE EQUIPMENT
EYE WASH; SAFETY SHOWER; PROTECTIVE CLOTHING (LONG SLEEVES, COVERALLS OR OTHER AS APPROPRIATE),
WHEN NEEDED, TO PREVENT SKIN CONTACT.
SECTION 9: STORAGE AND HANDLING
PRECAUTIONS FOR STORAGE AND HANDLING:
DO NOT BREATH DUST. AVOID GENERATING DUST. STORE IN A COOL, DRY PLACE, ISOLATED FROM ALL ORGANIC MATERIAL.
PRODUCT IS A STRONG OXIDIZER AND IS CORROSIVE. AVOID HEAT AND DIRECT SUNLIGHT. DO NOT ALLOW PRODUCT
TO COME IN CONTACT WITH OXIDIZABLE MATERIAL. KEEP CONTAINER CLOSED.
SECTION 10: TOXICOLOGY INFORMATION
ORAL LD50 (RAT): 468 mg/kg
EYE IRRITATION (RABBIT): SEVERE IRRITANT AND CORROSIVE
(PRODUCED TISSUE DISTRUCTION TO BOTH ABRADED AND UNABRADED SKIN-PRIMARY IRRITATION INDEX=110)
SKIN IRRITATION (RABBIT-DRAIZE TEST): CORROSIVE TO BOTH ABRADED AND UNABRADED SKIN.
SKIN CORROSIVE (RABBIT-US DOT TEST): NOT CORROSIVE
SEVERELY IRRITATING TO LUNG UPON INHALATION WITH POTENTIAL SYSTEMIC ABSORPTION AND TISSUE DAMAGE.
LC50 (RAINBOW TROUT-96 HOURS): 0.5 mg/L
LC50 (BLUEGILL SUNFISH-96 HOURS): 1.2 mg/L
LC50 (DAPHNIA MAGNA-48 HOURS): 0.4 mg/L
LC50 (MYSID SHRIMP-96 HOURS): 0.93 mg/L
LC50 (SHEEPHEAD MINNOW-96HOURS): 1.4 mg/L (AS BR2)
EC 50 (EASTERN OYSTERS-96 HOURS): 0.84 mg/L (AS BR2)
FOR 1,3-DICHLORO-5, 5-DIMETHYLHYDANTOIN:
SKIN SENSITIZATION (GUINEA PIG-BUEHLER TEST): SKIN SENSITIZER
SECTION 11: MISCELLANEOUS AND REGULATORY INFORMATION
FEDERAL LEVEL REGULATIONS:
THIS IS AN EPA REGISTERED PESTICIDE (EPA REGISTRATION NO. 6836-115). THIS MATERIAL MAY ONLY BE USED IN THE EPA
REGISTERED APPLICATION(S) STATED ON THE PRODUCT LABEL.
TOXIC SUBSTANCE CONTROL ACT (TSCA INVENTORY) STATUS:
FOUND ON U.S. EPA TSCA INVENTORY.
CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION AND LIABILITY ACT OF 1980 REQUIRES NOTIFICATION
OF THE NATIONAL RESPONSE CENTER) (TELEPHONE 800-424-8802) IN THE EVENT OF A RELEASE OF QUANTITIES OF THE FOLLOWING
HAZARDOUS MATERIALS CONTAINED IN THIS PRODUCT, IF THE RELEASE IS EQUAL TO OR GREATER THAN THE REPORTABLE
QUANTITIES (RQ'S) LISTED IN 40 CFR 302.4:
CHEMICAL NAME CAS NUMBER TYPICAL MAXIMUM CONCENTRATION
NONE KNOWN
SARA TITLE III, SECTION 302/304 (SUPERFUND AMENDMENT AND REAUTHORIZATION ACT OF 1986)-THIS ACT REQUIRES EMERGENCY
PLANNING, INCLUDING AGENCY NOTIFICATION, FOR POSSIBLE RELEASE OF THE FOLLOWING COMPONENTS OF THIS MATERIAL,
BASED UPON THE THRESHOLD PLANNING QUANTITIES (TPQs) AND RELEASE REPORTABLE QUANTITIES (RQs) LISTED FOR THE
COMPONENTS IN 40 CFR 355:
CHEMICAL NAME CAS NUMBER TYPICAL MAXIMUM CONCENTRATION
NONE KNOWN
SARA TITLE III SECTION 311/312-THIS ACT REQUIRES REPORTING UNDER THE COMMUNITY RIGHT-TO -KNOW PROVISION DUE TO THE
INCLUSION OF THE FOLLOWING COMPONENTS OF THIS MATERIAL IN ONE OR MORE OF THE FIVE HAZARD CATEGORIES LISTED
IN 40 CFR 370:
CHEMICAL NAME CAS NAME HAZARD *) CATEGORIES
BROMOCHLORO-5, 5-DIMETHYLHYDANTOIN 126-06-7 A,R
1, 3-DICHLORO-5, 5-DIMETHYLHYDANTOIN 118-52-5 A,R
1, 3-DICHLORO-5-ETHYL-5-METHYHYDANTOIN 89415-87-2 A,R
*) THE FIVE HAZARD CATEGORIES ARE AS FOLLOWS: F=FIRE HAZARD; S=SUDDEN RELEASE OF PRESSURE;
R=REACTIVE; A=IMMEDIATE (ACUTE) HEALTH HAZARD; C=DELAYED (CHRONIC HEALTH HAZARD)
SARA TITLE III SECTION 313-THIS ACT REQUIRES SUBMISSION OF ANNUAL REPORTS OFF THE RELEASES OF THE FOLLOWING
COMPONENTS OF THE MATERIAL IF THIS THRESHOLD REPORTING QUANTITIES AS LISTED IN 40 CFR 372, ARE MET OR EXCEEDED:
CHEMICAL NAME CAS NUMBER TYPICAL MAXIMUM CONCENTRATION
NONE KNOWN
THE INFORMATION PROVIDED HEREIN IS COMPILED FROM INTERNAL REPORTS AND DATA FROM PROFESSIONAL PUBLICATIONS.
IT IS FURNISHED WITHOUT WARRANTY OF ANY KIND, EXPRESS OR IMPLIED. IT IS INTENDED TO ASSIST IN EVALUATING THE
SUITABILITY AND PROPER USE OF THE MATERIAL IN MANUFACTURING AND IN THE DEVELOPMENT AND IMPLEMENTATION
OF SAFETY PRECAUTIONS AND PROCEDURES.
Phone: (262) 781-1350
SAFETY DATA SHEET
SUPPLEMENTAL OXYGEN, IF AVAILABLE. GET IMMEDIATE MEDICAL ATTENTION.
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