Creation Date: 06-26-2007
Revision Date: 09-21-2007
Material Safety Data Sheet
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1. Chemical Product and Company Identification
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Material Name Blend -Volatile Organics Combination
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01
Version #
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Mixture
CAS #
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N9331047
Item #
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Methanol, Carbinol, Methyl Alcohol solution containing trace constituents.
Synonym(s)
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PerkinElmer Life and Analytical Sciences
Identification Of The
710 Bridgeport Avenue
Company/Undertaking
Shelton, CT 06484
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Technical Support 800-762-4000
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CHEMTREC 800-424-9300
Emergency Telephone
Emergency Phone 800-762-4000
Number
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2. Composition / Information on Ingredients
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Hazardous component(s) CAS # Percent TWA TLV
Methanol 67-56-1 > 60
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Non-hazardous component(s) CAS # Percent
1,2-DICHLOROBENZENE, ANHYDROUS, 95-50-1 < 0.1
99%
BENZENE 71-43-2 < 0.1
BROMOBENZENE 108-86-1 < 0.1
BROMOFORM 75-25-2 < 0.1
CARBON TETRACHLORIDE, 99.9% 56-23-5 < 0.1
CHLOROBENZENE 108-90-7 < 0.1
CHLOROBROMOMETHANE 74-97-5 < 0.1
CHLOROFORM 67-66-3 < 0.1
DICHLOROBROMOMETHANE 75-27-4 < 0.1
n-butylbenzene 104-51-8 < 0.1
SEC-BUTYLBENZENE 135-98-8 < 0.1
TERT-BUTYLBENZENE 98-06-6 < 0.1
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1,1-DICHLOROETHANE 75-34-3 < 0.1
1,2-DIBROMO-3-CHLOROPROPANE 96-12-8 < 0.1
1,2-Dibromomethane No Data < 0.1
1,2-DICHLOROETHANE, ANHYDROUS, 107-06-2 < 0.1
99.8%
1,3-DICHLOROBENZENE 541-73-1 < 0.1
CHLORODIBROMOMETHANE 124-48-1 < 0.1
CIS-1,2-DICHLOROETHYLENE 156-59-2 < 0.1
METHYLENE BROMIDE 74-95-3 < 0.1
O-CHLOROTOLUENE 95-49-8 < 0.1
P-CHLOROTOLUENE 106-43-4 < 0.1
P-DICHLOROBENZENE 106-46-7 < 0.1
VINYLIDENE CHLORIDE 75-35-4 < 0.1
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1,1-DICHLOROPROPENE 563-58-6 < 0.1
1,2-DICHLOROPROPANE 78-87-5 < 0.1
1,3-DICHLOROPROPANE 142-28-9 < 0.1
CIS-1,3-DICHLOROPROPENE 10061-01-5 < 0.1
CUMENE 98-82-8 < 0.1
ETHYLBENZENE 100-41-4 < 0.1
HEXACHLOROBUTADIENE 87-68-3 < 0.1
P-CYMENE 99-87-6 < 0.1
PROPANE, 2,2-DICHLORO- 594-20-7 < 0.1
trans-1,2-Dichloroethene 156-60-5 < 0.1
TRANS-1,3-DICHLOROPROPENE 10061-02-6 < 0.1
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3. Hazards Identification
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Emergency Overview
Highly flammable.
Toxic by inhalation, ingestion and in contact with the skin.
Danger of very serious irreversible effects.
Irritating to eyes, respiratory system and skin.
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Health: 1
NFPA RATINGS
Flammability: 3
Instability: 0
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4. First Aid Measures
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General advice
Immediate medical attention is required
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First Aid
Skin contact
Wash off immediately with soap and plenty of water removing all contaminated clothes and
shoes. Consult a physician.
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Eye contact
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Consult a
physician.
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Inhalation
Move to fresh air. Oxygen or artificial respiration if needed.
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Ingestion
Rinse mouth. Never give anything by mouth to an unconscious person. Call a physician
immediately.
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5. Fire Fighting Measures
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Suitable extinguishing media
water spray.
carbon dioxide (CO2), dry powder or foam
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Specific hazards
In the event of fire toxic fumes may be formed.
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Special protective equipment for firefighters
Wear suitable protective equipment
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6. Accidental Release Measures
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Evacuation Procedures
Evacuate personnel to safe areas.
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Personal precautions
Remove all sources of ignition. Ensure adequate ventilation. Use personal protective equipment.
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Methods for cleaning up
Neutralise with dry-lime, sand, or soda ash. Clean contaminated surface thoroughly. Keep in
suitable and closed containers for disposal.
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7. Handling and Storage
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Handling
Use only in area provided with appropriate exhaust ventilation. Wear personal protective
equipment. Keep away from heat and sources of ignition. Do not breathe vapours or spray mist.
Avoid contact with skin and eyes.
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Storage
Keep tightly closed. Keep away from heat. Keep in a dry, cool place.
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8. Exposure Controls / Personal Protection
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Exposure Limit Values
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Exposure Controls
Engineering measures to reduce exposure
Provide adequate ventilation.
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Hygiene measures
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin,
eyes and clothing. Keep away from food and drink. Wash hands before breaks and immediately
after handling the product.
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Respiratory protection
No personal respiratory protective equipment normally required.
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Hand protection
solvent-resistant gloves
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Eye protection
safety glasses with side-shields
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Skin and body protection
lab coat.
Remove and wash contaminated clothing before re-use. Discard contaminated shoes.
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9. Physical & Chemical Properties
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General Information
Form
liquid
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Color
colorless
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Odor
slight
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Important health, safety and environmental information
0 estimated
Specific Gravity
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0 % estimated
Volatile Organic
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10. Chemical Stability & Reactivity Information
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Stability
Stable
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Hazardous decomposition products
carbon oxides
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Incompatibility
acids; acid chlorides; acid anhydrides; alkaline metals; reducing agents
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11. Toxicological Information
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Acute Toxicity
Irritating to eyes, respiratory system and skin.
Toxic by inhalation, in contact with skin and if swallowed.
Methyl Alcohol may be fatal or cause blindness if swallowed.
Cannot be made non-poisonous.
Ingestion may provoke the following symptoms:
nausea, headache, and vomiting
gastrointestinal disturbance, dizziness, weakness, and
unconsciousness
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Carcinogenicity Data
BENZENE
Ingredient(s)
- OSHA Select Carcinogen
- OSHA Possible Select Carcinogen
- ACGIH Confirmed Carcinogen
- IARC Group 1 Carcinogen - Humans
- NTP Known Carcinogen
- NTP Suspected Carcinogen
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12. Ecological Information
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Mobility
Not available
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Ecological Information
Not available
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13. Disposal Considerations
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Disposal Instructions
In accordance with local and national regulations.
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Waste from residues / unused products
In accordance with local and national regulations.
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14. Transportation Information
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US DOT
Methanol
Proper shipping name DOT
3
Hazard class
UN1230
UN number
II
Packaging group
IB2, T7, TP2
Special provisions
150
Packaging exceptions
202
Packaging non bulk
242
Packaging bulk
1L
Quantity limits
DOT
passenger
60 L
Quantity limits cargo
B
Vessel stowage
location
40
Vessel stowage other
3
Labels required
131
ERG number
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CTDG
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15. Regulatory Information
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CERCLA/SARA Section 313
Blend -Volatile Organics Combination
Material
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Methanol
Ingredient(s)
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International Regulations
Canada - CEPA - Schedule I - List of Toxic Substances
BENZENE 71-43-2 Present
Canada - WHMIS - Classifications of Substances
BENZENE 71-43-2 B2, D2A, D2B
Methanol 67-56-1 B2, D1B, D2A, D2B
Canada - WHMIS - Ingredient Disclosure List
BENZENE 71-43-2 0.1 % (English Item 153, French Item 277)
Methanol 67-56-1 1 % (English Item 1012, French Item 183)
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Canada Regulations
Canada - CEPA - Schedule I - List of Toxic Substances
BENZENE 71-43-2 Present
Canada - WHMIS - Classifications of Substances
BENZENE 71-43-2 B2, D2A, D2B
Methanol 67-56-1 B2, D1B, D2A, D2B
Canada - WHMIS - Ingredient Disclosure List
BENZENE 71-43-2 0.1 % (English Item 153, French Item 277)
Methanol 67-56-1 1 % (English Item 1012, French Item 183)
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16. Other Information
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Recommended use
For research use only.
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Disclaimer
The information provided in this Material Safety Data Sheet is based on our present knowledge,
and believed to be correct at the date of publication. However, no representation is made
concerning its accuracy and completeness. It is intended as guidance only, and is not to be
considered a warranty or quality specification. All materials may present unknown hazards, and
should be used with caution. Although certain hazards are described, we cannot guarantee that
these are the only hazards which exist. PerkinElmer Life and Analytical Sciences shall not be held
liable for any damage resulting from handling or from contact with the product.
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