Creation Date: 09-25-2007
Revision Date: 09-25-2007
Material Safety Data Sheet
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1. Chemical Product and Company Identification
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Material Name Polynuclear Aromatic Hydrocarbons Method 625
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01
Version #
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Mixture
CAS #
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N9331044
Item #
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Methylene chloride and benzene solution containing trace elements
Synonym(s)
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PerkinElmer Life and Analytical Sciences
Identification Of The
710 Bridgeport Avenue
Company/Undertaking
Shelton, CT 06484
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Technical Support 800-762-4000
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CHEMTREC 800-424-9300
Emergency Telephone
Emergency Phone 800-762-4000
Number
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2. Composition / Information on Ingredients
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Hazardous component(s) CAS # Percent TWA TLV
BENZ[A]ANTHRACENE 56-55-3 0.1 - 1 10 ppm 0.5
BENZO(B)FLUORANTHENE 205-99-2 0.1 - 1 10 ppm 0.5
BENZO[A]PYRENE 50-32-8 0.1 - 1 10 ppm 0.5
NAPHTHALENE 91-20-3 0.1 - 1 10 ppm 0.5
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DICHLOROMETHANE 75-09-2 40 - 70 10 ppm 0.5
BENZO(K)FLUORANTHENE 207-08-9 0.1 - 1 10 ppm 0.5
DIBENZO(A,H)ANTHRACENE 53-70-3 0.1 - 1 10 ppm 0.5
INDENO(1,2,3-CD)PYRENE 193-39-5 0.1 - 1 10 ppm 0.5
(2,3-O-PHENYLENEPYRENE)
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BENZENE 71-43-2 40 - 70 10 ppm 0.5
CHRYSENE 218-01-9 0.1 - 1 10 ppm 0.5
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Non-hazardous component(s) CAS # Percent
ACENAPHTHENE 83-32-9 0.1 - 1
ACENAPHTHYLENE 208-96-8 0.1 - 1
ANTHRACENE 120-12-7 0.1 - 1
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BENZO(GHI)PERYLENE 191-24-2 0.1 - 1
FLUORANTHENE 206-44-0 0.1 - 1
FLUORENE 86-73-7 0.1 - 1
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PHENANTHRENE 85-01-8 0.1 - 1
PYRENE 129-00-0 0.1 - 1
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3. Hazards Identification
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Specific hazards
Avoid contact with the skin. Irritating to eyes. Irritating to skin. Highly flammable.
Material ID 17764 Material Name Polynuclear Aromatic Hydrocarbons Method 625
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Health: 3
HMIS RATINGS
Flammability: 2
Physical hazard: 1
Personal protection: I
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Health: 3
NFPA RATINGS
Flammability: 2
Instability: 0
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4. First Aid Measures
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General advice
Consult a physician.
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First Aid
Skin contact
If skin irritation persists, call a physician. Wash off immediately with soap and plenty of water
removing all contaminated clothes and shoes.If skin irritation persists, call a physician and
Wash off immediately with soap and plenty of water removing all contaminated clothes and
shoes.
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Eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.Rinse
thoroughly with plenty of water for at least 15 minutes and consult a physician.
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Inhalation
Oxygen or artificial respiration if needed. Move to fresh air. Call a physician or Poison Control
Centre immediately.
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Ingestion
If swallowed, seek medical advice immediately and show this container or label. If a person
vomits when lying on his back, place him in the recovery position.
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5. Fire Fighting Measures
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1043.6 掳F (562 掳C) estimated
Auto Ignition
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Flammable IB
Flammability Class
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12.2 掳F (-11 掳C) estimated
Flash Point
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Suitable extinguishing media
Do not use a solid water stream as it may scatter and spread fire. Use extinguishing measures that
are appropriate to local circumstances and the surrounding environment.
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Specific methods
In the event of fire, cool tanks with water spray.
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6. Accidental Release Measures
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Personal precautions
Use personal protective equipment. Keep people away from and upwind of spill/leak.
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Environmental precautions
Prevent further leakage or spillage if safe to do so.
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Methods for cleaning up
Dam up. Soak up with inert absorbent material. Shovel into suitable container for disposal.
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7. Handling and Storage
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Handling
Keep away from heat and sources of ignition.
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Material ID 17764 Material Name Polynuclear Aromatic Hydrocarbons Method 625
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8. Exposure Controls / Personal Protection
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Exposure Limit Values
Material TWA STEL
Polynuclear Aromatic Hydrocarbons Method 0.5 ppm 2.5 ppm
625
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Exposure Controls
Engineering measures to reduce exposure
Provide adequate ventilation.
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Respiratory protection
In the case of respirable dust and/or fumes, use self-contained breathing apparatus. Wear a
positive-pressure supplied-air respirator.
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Hand protection
gloves
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Eye protection
goggles If splashes are likely to occur, wear:
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9. Physical & Chemical Properties
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Important health, safety and environmental information
12.2 掳F (-11 掳C) estimated
Flash Point
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1043.6 掳F (562 掳C) estimated
Auto Ignition
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Flammable IB
Flammability Class
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103.6 掳F (39.8 掳C) estimated
Boiling Point
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-142.1 掳F (-96.7 掳C) estimated
Melting Point
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1.83
Octanol Water
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1.8 mg/L
Solubility in Water
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1.1736 estimated
Specific Gravity
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275.9941 hPa estimated
Vapor Pressure
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96.8 % estimated
Volatile Organic
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10. Chemical Stability & Reactivity Information
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Further information
Stable at normal conditions
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11. Toxicological Information
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Dermal LD50 (Rabbit): 9400 l/kg
Other Toxicological
Inhalation LC50 (Rat): 10000 ppm/7h
Information
Oral LD50 (Mouse): 4700 mg/kg
Oral LD50 (Rat): 930 mg/kg
Occupational Carcinogen
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Carcinogenicity Data
OSHA Select Carcinogen
Material
ACGIH Confirmed Carcinogen
IARC Group 1 Carcinogen - Humans
NTP Known Carcinogen
Material ID 17764 Material Name Polynuclear Aromatic Hydrocarbons Method 625
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MSDS CANADA
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Material ID 17764 Material Name Polynuclear Aromatic Hydrocarbons Method 625
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ACENAPHTHENE
Ingredient(s)
- OSHA Select Carcinogen
- NTP Suspected Carcinogen
ACENAPHTHYLENE
- OSHA Select Carcinogen
- NTP Suspected Carcinogen
ANTHRACENE
- OSHA Select Carcinogen
- OSHA Possible Select Carcinogen
- ACGIH Confirmed Carcinogen
- IARC Group 1 Carcinogen - Humans
- NTP Known Carcinogen
- NTP Suspected Carcinogen
BENZO(B)FLUORANTHENE
- OSHA Select Carcinogen
- ACGIH Suspected Carcinogen
- NTP Suspected Carcinogen
BENZO(GHI)PERYLENE
- OSHA Select Carcinogen
- NTP Suspected Carcinogen
BENZO(K)FLUORANTHENE
- OSHA Select Carcinogen
- NTP Suspected Carcinogen
BENZO[A]PYRENE
- OSHA Select Carcinogen
- ACGIH Suspected Carcinogen
- IARC Group 1 Carcinogen - Humans
- NTP Known Carcinogen
- NTP Suspected Carcinogen
BENZ[A]ANTHRACENE
- OSHA Select Carcinogen
- ACGIH Suspected Carcinogen
- NTP Suspected Carcinogen
DIBENZO(A,H)ANTHRACENE
- OSHA Select Carcinogen
- NTP Suspected Carcinogen
DICHLOROMETHANE
- OSHA Select Carcinogen
- OSHA Possible Select Carcinogen
- ACGIH Animal Carcinogen
- NTP Suspected Carcinogen
FLUORANTHENE
- OSHA Select Carcinogen
- NTP Suspected Carcinogen
FLUORENE
- OSHA Select Carcinogen
- NTP Suspected Carcinogen
INDENO(1,2,3-CD)PYRENE (2,3-O-PHENYLENEPYRENE)
- OSHA Select Carcinogen
- NTP Suspected Carcinogen
NAPHTHALENE
- OSHA Select Carcinogen
- ACGIH Not Classified Carcinogen
- NTP Suspected Carcinogen
PHENANTHRENE
- OSHA Select Carcinogen
- ACGIH Confirmed Carcinogen
- IARC Group 1 Carcinogen - Humans
- NTP Known Carcinogen
- NTP Suspected Carcinogen
Material ID 17764 Material Name Polynuclear Aromatic Hydrocarbons Method 625
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MSDS CANADA
- NTP Suspected Carcinogen
PYRENE
- OSHA Select Carcinogen
- ACGIH Confirmed Carcinogen
- IARC Group 1 Carcinogen - Humans
- NTP Known Carcinogen
- NTP Suspected Carcinogen
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12. Ecological Information
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13. Disposal Considerations
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Disposal Instructions
In accordance with local and national regulations.
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14. Transportation Information
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US DOT
Flammable liquids, toxic, n.o.s.
Proper shipping name DOT
3
Hazard class
UN1992
UN number
II
Packaging group
IB2, T7, TP2, TP13
Special provisions
None
Packaging exceptions
202
Packaging non bulk
243
Packaging bulk
1L
Quantity limits
DOT
passenger
60 L
Quantity limits cargo
B
Vessel stowage
location
40
Vessel stowage other
3, 6.1
Labels required
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CTDG
Flammable liquids, toxic, n.o.s.
Proper shipping name CTDG
3
Hazard class
UN1992
UN number
II
Packaging group
IB2, T7, TP2, TP13
Special provisions
None
Packaging exceptions
202
Packaging non bulk
243
Packaging bulk
1L
Quantity limits
CTDG
passenger
60 L
Quantity limits cargo
B
Vessel stowage
location
40
Vessel stowage other
3, 6.1
Labels required
Material ID 17764 Material Name Polynuclear Aromatic Hydrocarbons Method 625
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Other Information
According to IATA respectively ICAO exempt from regulations up to 1 per each inner packaging and
15 per each outer packaging. DOT regulated, small quantity provisions apply (see 49CFR173.4)
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15. Regulatory Information
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CERCLA/SARA Section 313
Polynuclear Aromatic Hydrocarbons Method 625
Material
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BENZENE
Ingredient(s)
Material ID 17764 Material Name Polynuclear Aromatic Hydrocarbons Method 625
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MSDS CANADA
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Material ID 17764 Material Name Polynuclear Aromatic Hydrocarbons Method 625
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International Regulations
Canada - CEPA - Schedule I - List of Toxic Substances
ACENAPHTHENE 83-32-9 [SOR/2000-109]
ACENAPHTHYLENE 208-96-8 [SOR/2000-109]
ANTHRACENE 120-12-7 [SOR/2000-109]
BENZ[A]ANTHRACENE56-55-3 [SOR/2000-109]
BENZO(B)FLUORANTHENE 205-99-2 [SOR/2000-109]
BENZO(GHI)PERYLENE91-24-2
1 [SOR/2000-109]
BENZO(K)FLUORANTHENE 207-08-9 [SOR/2000-109]
BENZO[A]PYRENE 50-32-8 [SOR/2000-109]
DIBENZO(A,H)ANTHRACENE53-70-3 [SOR/2000-109]
DICHLOROMETHANE 75-09-2 Present
FLUORANTHENE 206-44-0 [SOR/2000-109]
FLUORENE 86-73-7 [SOR/2000-109]
INDENO(1,2,3-CD)PYRENE193-39-5 [SOR/2000-109]
(2,3-O-PHENYLENEPYRENE)
NAPHTHALENE 91-20-3 [SOR/2000-109]
PHENANTHRENE 85-01-8 [SOR/2000-109]
PYRENE 129-00-0 [SOR/2000-109]
Canada - WHMIS - Classifications of Substances
ACENAPHTHENE 83-32-9 Uncontrolled product according to WHMIS
classification criteria
ACENAPHTHYLENE 208-96-8 Uncontrolled product according to WHMIS
classification criteria
ANTHRACENE 120-12-7 Uncontrolled product according to WHMIS
classification criteria
BENZ[A]ANTHRACENE56-55-3 D2A, D2B
BENZO(B)FLUORANTHENE 205-99-2 D2A, D2B
BENZO(GHI)PERYLENE91-24-2
1 Uncontrolled product according to WHMIS
classification criteria
BENZO(K)FLUORANTHENE 207-08-9 D2A
BENZO[A]PYRENE 50-32-8 D2A
DIBENZO(A,H)ANTHRACENE53-70-3 D2A, D2B
DICHLOROMETHANE 75-09-2 D1B, D2A, D2B
FLUORANTHENE 206-44-0 D2B
FLUORENE 86-73-7 D2B
INDENO(1,2,3-CD)PYRENE193-39-5 D2A
(2,3-O-PHENYLENEPYRENE)
NAPHTHALENE 91-20-3 B4, D2A
PHENANTHRENE 85-01-8 Uncontrolled product according to WHMIS
classification criteria
PYRENE 129-00-0 Uncontrolled product according to WHMIS
classification criteria
Canada - WHMIS - Ingredient Disclosure List
ACENAPHTHENE 83-32-9 1 % (English Item 3, French Item 2)
ANTHRACENE 120-12-7 1 % (English Item 120, French Item 249)
BENZ[A]ANTHRACENE56-55-3 0.1 % (English Item 151, French Item 281)
BENZO(B)FLUORANTHENE 205-99-2 0.1 % (English Item 159, French Item 284)
BENZO[A]PYRENE 50-32-8 0.1 % (English Item 163, French Item 287)
DIBENZO(A,H)ANTHRACENE53-70-3 0.1 % (English Item 501, French Item 636)
DICHLOROMETHANE 75-09-2 0.1 % (English Item 1044, French Item 508)
FLUORANTHENE 206-44-0 1 % (English Item 770, French Item 892)
INDENO(1,2,3-CD)PYRENE193-39-5 0.1 % (English Item 871, French Item 1017)
(2,3-O-PHENYLENEPYRENE)
Material ID 17764 Material Name Polynuclear Aromatic Hydrocarbons Method 625
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NAPHTHALENE 91-20-3 1 % (English Item 1108, French Item 1181)
PHENANTHRENE 85-01-8 1 % (English Item 1257, French Item 1371)
PYRENE 129-00-0 1 % (English Item 1373, French Item 1458)
Material ID 17764 Material Name Polynuclear Aromatic Hydrocarbons Method 625
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Material ID 17764 Material Name Polynuclear Aromatic Hydrocarbons Method 625
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Canada Regulations
Canada - CEPA - Schedule I - List of Toxic Substances
ACENAPHTHENE 83-32-9 [SOR/2000-109]
ACENAPHTHYLENE 208-96-8 [SOR/2000-109]
ANTHRACENE 120-12-7 [SOR/2000-109]
BENZ[A]ANTHRACENE56-55-3 [SOR/2000-109]
BENZO(B)FLUORANTHENE 205-99-2 [SOR/2000-109]
BENZO(GHI)PERYLENE91-24-2
1 [SOR/2000-109]
BENZO(K)FLUORANTHENE 207-08-9 [SOR/2000-109]
BENZO[A]PYRENE 50-32-8 [SOR/2000-109]
DIBENZO(A,H)ANTHRACENE53-70-3 [SOR/2000-109]
DICHLOROMETHANE 75-09-2 Present
FLUORANTHENE 206-44-0 [SOR/2000-109]
FLUORENE 86-73-7 [SOR/2000-109]
INDENO(1,2,3-CD)PYRENE193-39-5 [SOR/2000-109]
(2,3-O-PHENYLENEPYRENE)
NAPHTHALENE 91-20-3 [SOR/2000-109]
PHENANTHRENE 85-01-8 [SOR/2000-109]
PYRENE 129-00-0 [SOR/2000-109]
Canada - WHMIS - Classifications of Substances
ACENAPHTHENE 83-32-9 Uncontrolled product according to WHMIS
classification criteria
ACENAPHTHYLENE 208-96-8 Uncontrolled product according to WHMIS
classification criteria
ANTHRACENE 120-12-7 Uncontrolled product according to WHMIS
classification criteria
BENZ[A]ANTHRACENE56-55-3 D2A, D2B
BENZO(B)FLUORANTHENE 205-99-2 D2A, D2B
BENZO(GHI)PERYLENE91-24-2
1 Uncontrolled product according to WHMIS
classification criteria
BENZO(K)FLUORANTHENE 207-08-9 D2A
BENZO[A]PYRENE 50-32-8 D2A
DIBENZO(A,H)ANTHRACENE53-70-3 D2A, D2B
DICHLOROMETHANE 75-09-2 D1B, D2A, D2B
FLUORANTHENE 206-44-0 D2B
FLUORENE 86-73-7 D2B
INDENO(1,2,3-CD)PYRENE193-39-5 D2A
(2,3-O-PHENYLENEPYRENE)
NAPHTHALENE 91-20-3 B4, D2A
PHENANTHRENE 85-01-8 Uncontrolled product according to WHMIS
classification criteria
PYRENE 129-00-0 Uncontrolled product according to WHMIS
classification criteria
Canada - WHMIS - Ingredient Disclosure List
ACENAPHTHENE 83-32-9 1 % (English Item 3, French Item 2)
ANTHRACENE 120-12-7 1 % (English Item 120, French Item 249)
BENZ[A]ANTHRACENE56-55-3 0.1 % (English Item 151, French Item 281)
BENZO(B)FLUORANTHENE 205-99-2 0.1 % (English Item 159, French Item 284)
BENZO[A]PYRENE 50-32-8 0.1 % (English Item 163, French Item 287)
DIBENZO(A,H)ANTHRACENE53-70-3 0.1 % (English Item 501, French Item 636)
DICHLOROMETHANE 75-09-2 0.1 % (English Item 1044, French Item 508)
FLUORANTHENE 206-44-0 1 % (English Item 770, French Item 892)
INDENO(1,2,3-CD)PYRENE193-39-5 0.1 % (English Item 871, French Item 1017)
(2,3-O-PHENYLENEPYRENE)
Material ID 17764 Material Name Polynuclear Aromatic Hydrocarbons Method 625
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NAPHTHALENE 91-20-3 1 % (English Item 1108, French Item 1181)
PHENANTHRENE 85-01-8 1 % (English Item 1257, French Item 1371)
PYRENE 129-00-0 1 % (English Item 1373, French Item 1458)
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16. Other Information
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Disclaimer
The information provided in this Material Safety Data Sheet is based on our present knowledge,
and believed to be correct at the date of publication. However, no representation is made
concerning its accuracy and completeness. It is intended as guidance only, and is not to be
considered a warranty or quality specification. All materials may present unknown hazards, and
should be used with caution. Although certain hazards are described, we cannot guarantee that
these are the only hazards which exist. PerkinElmer Life and Analytical Sciences shall not be held
liable for any damage resulting from handling or from contact with the product.
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Material ID 17764 Material Name Polynuclear Aromatic Hydrocarbons Method 625
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