Creation Date: 08-16-2007
Revision Date: 09-21-2007
Material Safety Data Sheet
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1. Chemical Product and Company Identification
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Material Name Surrogate Standard for Method 524.2
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01
Version #
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Mixture
CAS #
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N9331051
Item #
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Methanol solution containing trace elements
Synonym(s)
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PerkinElmer Life and Analytical Sciences
Identification Of The
710 Bridgeport Avenue
Company/Undertaking
Shelton, CT 06484
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Technical Support 800-762-4000
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CHEMTREC 800-424-9300
Emergency Telephone
Emergency Phone 800-762-4000
Number
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2. Composition / Information on Ingredients
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Hazardous component(s) CAS # Percent PEL TLV
METHANOL (METHYL ALCOHOL) 67-56-1 > 90 200 ppm 200
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Non-hazardous component(s) CAS # Percent
4-Bromofluorobenzene 460-00-4 0.01 - 0.1
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1,2-Dichlorobenzene-d4 2199-69-1 0.01 - 0.1
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3. Hazards Identification
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Health: 2*
HMIS RATINGS
Flammability: 3
Physical hazard: 0
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Health: 2
NFPA RATINGS
Flammability: 3
Instability: 0
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4. First Aid Measures
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First Aid
Skin contact
If skin irritation persists, call a physician. Wash off immediately with soap and plenty of water
removing all contaminated clothes and shoes.
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Eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
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Inhalation
Oxygen or artificial respiration if needed. Move to fresh air. Call a physician or Poison Control
Centre immediately.
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Ingestion
If swallowed, seek medical advice immediately and show this container or label. If a person
vomits when lying on his back, place him in the recovery position.
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Material ID 17408 Material Name Surrogate Standard for Method 524.2
1/ 5
MSDS US
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5. Fire Fighting Measures
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Specific methods
In the event of fire, cool tanks with water spray.
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6. Accidental Release Measures
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Personal precautions
Use personal protective equipment. Keep people away from and upwind of spill/leak.
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Environmental precautions
Prevent further leakage or spillage if safe to do so.
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Methods for cleaning up
Dam up. Soak up with inert absorbent material. Shovel into suitable container for disposal.
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7. Handling and Storage
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Handling
Keep away from heat and sources of ignition.
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8. Exposure Controls / Personal Protection
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Exposure Limit Values
Material TWA STEL
Surrogate Standard for Method 524.2 200 ppm 250 ppm
ACGIH - Threshold Limits Values - Time Weighted Averages (TLV-TWA)
METHANOL (METHYL 67-56-1 200 ppm TWA
ALCOHOL)
OSHA - Final PELs - Time Weighted Averages (TWAs)
METHANOL (METHYL 67-56-1 200 ppm TWA; 260 mg/m3 TWA
ALCOHOL)
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Exposure Controls
Engineering measures to reduce exposure
Provide adequate ventilation.
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Respiratory protection
In the case of respirable dust and/or fumes, use self-contained breathing apparatus. Wear a
positive-pressure supplied-air respirator.
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Hand protection
gloves
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Eye protection
goggles If splashes are likely to occur, wear:
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9. Physical & Chemical Properties
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Important health, safety and environmental information
51.8 掳F (11 掳C) estimated
Flash Point
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867.2 掳F (464 掳C) estimated
Auto Ignition
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Flammable IB
Flammability Class
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148.1 掳F (64.5 掳C) estimated
Boiling Point
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2.1 (butyl acetate = 1)
Evaporation Rate
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-144.4 掳F (-98 掳C) estimated
Melting Point
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Characteristic pungent odor
Odor Threshold
Material ID 17408 Material Name Surrogate Standard for Method 524.2
2/ 5
MSDS US
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0.79 g/l 1.1 (air = 1)
Vapor Density
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129.9691 hPa estimated
Vapor Pressure
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99.8 % estimated
Volatile Organic
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10. Chemical Stability & Reactivity Information
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Further information
Stable at normal conditions
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11. Toxicological Information
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Dermal LD50 (Rabbit): 15800 mg/kg
Other Toxicological
Inhalation LC50 (Rat): 64000 mg/kg/4h
Information
Oral LD50 (Mouse): 7300 mg/kg
Oral LD50 (Rat): 5628 mg/kg
Potential Dermal Absorption
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Acute Toxicity
NIOSH - Selected LD50s and LC50s
METHANOL (METHYL 67-56-1 Inhalation LC50 Rat: 64000 mg/kg/4H; Oral LD50
ALCOHOL) Rat: 5628 mg/kg; Oral LD50 Mouse: 7300 mg/kg;
Dermal LD50 Rabbit: 15800 mg/kg
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Symptoms and Target Organs
NIOSH - Pocket Guide - Target Organs
METHANOL (METHYL 67-56-1 skin, eyes, CNS, GI tract, respiratory system
ALCOHOL)
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12. Ecological Information
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Ecotoxicity
Ecotoxicity - Freshwater Fish Species Data
METHANOL (METHYL 67-56-1 96 Hr LC50 fathead minnow (28 days old):29400
ALCOHOL) mg/L (flow-through);96 Hr LC50 rainbow trout
(fingerling):13 mg/L;48 Hr LC50 trout: 8000 mg/L
Ecotoxicity - Microtox Data
METHANOL (METHYL 67-56-1 5 min EC50 Photobacterium phosphoreum: 43000
ALCOHOL) mg/L; 15 min EC50 Photobacterium phosphoreum:
40000 mg/L; 25 min EC50 Photobacterium
phosphoreum: 39000 mg/L
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13. Disposal Considerations
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Disposal Instructions
In accordance with local and national regulations.
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Material ID 17408 Material Name Surrogate Standard for Method 524.2
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MSDS US
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14. Transportation Information
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US DOT
Methanol
Proper shipping name DOT
3
Hazard class
UN1230
UN number
II
Packaging group
IB2, T7, TP2
Special provisions
150
Packaging exceptions
202
Packaging non bulk
242
Packaging bulk
1L
Quantity limits
DOT
passenger
60 L
Quantity limits cargo
B
Vessel stowage
location
40
Vessel stowage other
3
Labels required
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Other Information
DOT regulated, small quantity provisions apply (see 49CFR173.4) According to IATA respectively
ICAO exempt from regulations up to 1 per each inner packaging and 14 per each outer packaging.
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15. Regulatory Information
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CERCLA/SARA Section 313
Surrogate Standard for Method 524.2
Material
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METHANOL (METHYL ALCOHOL)
Ingredient(s)
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US Federal Regulations
CERCLA/SARA - Hazardous Substances and their Reportable Quantities
METHANOL (METHYL 67-56-1 5000 lb final RQ; 2270 kg final RQ
ALCOHOL)
CERCLA/SARA - Section 313 - Emission Reporting
METHANOL (METHYL 67-56-1 1.0 % de minimis concentration
ALCOHOL)
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State Regulations
Massachusetts - Right To Know List
METHANOL (METHYL 67-56-1 Present
ALCOHOL)
Massachusetts - Toxics Use Reduction Act
METHANOL (METHYL 67-56-1 CERCLA and 313 chemical
ALCOHOL)
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International Regulations
Canada - WHMIS - Ingredient Disclosure List
METHANOL (METHYL 67-56-1 1 % (English Item 1012, French Item 183)
ALCOHOL)
Material ID 17408 Material Name Surrogate Standard for Method 524.2
4/ 5
MSDS US
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16. Other Information
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Disclaimer
The information provided in this Material Safety Data Sheet is based on our present knowledge,
and believed to be correct at the date of publication. However, no representation is made
concerning its accuracy and completeness. It is intended as guidance only, and is not to be
considered a warranty or quality specification. All materials may present unknown hazards, and
should be used with caution. Although certain hazards are described, we cannot guarantee that
these are the only hazards which exist. PerkinElmer Life and Analytical Sciences shall not be held
liable for any damage resulting from handling or from contact with the product.
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Material ID 17408 Material Name Surrogate Standard for Method 524.2
5/ 5
MSDS US
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