SAFETY DATA SHEET (EC REGULATION No 1907/2006 ) Date: 24/09/2007 Page 1/5
Version: N掳2 (07/05/2007) Revision: N掳7 (02/05/2007)
Name: ATM 007 - ATM01 Company: DURIEU S.A.
SAFETY DATA SHEET
1 - IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
Identification of the substance or preparation:
Name: ATM 007.
Product code: ATM01.
Company/undertaking identification:
Registered company name: DURIEU S.A..
Address: Z.A.I. "La Marini猫re" 2,bis rue Charles de Gaulle.91070.BONDOUFLE.FRANCE.
Telephone: + 33 (0)1.60.86.48.70. Fax:+ 33 (0)1.60.86.84.84. Telex:.
sp.auger@durieu.com
www.durieu.com
Emergency telephone: + 33 (0)1.45.42.59.59.
Association/Organisation: ORFILA / INRS http://www.centres-antipoison.net.
Use of the substance/preparation:
Water-borne concentrate. Fungicide and Mildewcide against lichen, moss and mildew.
2 - HAZARDS IDENTIFICATION
This product is not classed as flammable. Refer to the recommendations regarding the other products present on the site
Possibility of corrosive effects.
Possibility of skin sensitisation. The preparation may also irritate the skin and prolonged contact may aggravate this effect.
Possibility of noxious effects with symptoms of slight poisoning by contact with the skin and swallowing.
Harmful to aquatic organisms, may cause long-termadverse effects in the aquatic environment.
Preparation classification:
Corrosive.
R 52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R 43 May cause sensitisation by skin contact.
R 21/22 Harmful in contact with skin and if swallowed.
R 34 Causes burns.
Other data:
This product is for use as a biocide.
3 - COMPOSITION/INFORMATION ON INGREDIENTS
Full text of risk phrases appearing in section 3: see section 16.
Hazardous substances present on their own:
(present in the preparation at a sufficient concentration to give it the toxicological characteristics it would have in a 100% pure
state)
INDEX CAS EC Name Symb. R: %
612-140-00-5 63449-41-2 264-151-6 QUATERNARY AMMONIUM C N 34 50 21/22 10 <= x % < 25
COMPOUNDS, BENZYL-C 8-18
-ALKYLDIMETHYL, CHLORIDES
Other substances representing a hazard:
INDEX CAS EC Name Symb. R: %
68439-45-2 ALCOOL ETHOXYLE Xn 41 22 2.5 <= x % < 10
603-140-00-6 111-46-6 203-872-2 2,2'-OXYBISETHANOL Xn 22 10 <= x % < 25
613-112-00-5 26530-20-1 247-761-7 2-OCTYL-2H-ISOTHIAZOL-3-ONE TN 34 43 50/53 23/24 22 0 <= x % < 2.5
- Made under licence of European Label System庐 MSDS software from InfoDyne - http://www.infodyne.fr -
SAFETY DATA SHEET (EC REGULATION No 1907/2006 ) Date: 24/09/2007 Page 2/5
Version: N掳2 (07/05/2007) Revision: N掳7 (02/05/2007)
Name: ATM 007 - ATM01 Company: DURIEU S.A.
Substances present at a concentration below the minimum danger threshold:
No known substance in this category present.
Other substances with occupational exposure limits:
No known substance in this category present.
4 - FIRST AID MEASURES
As a general rule, in case of doubt or if symptoms persist, always call a doctor.
NEVER induce swallowing in an unconscious person.
In the event of splashes or contact with eyes:
Wash thoroughly with soft, clean water for 15 minutes holding the eyelids open.
If there is any redness, pain or visual impairment, consult an ophthalmologist.
In the event of splashes or contact with skin:
Remove all contaminated or stained clothing immediately. Do not use them again until they have been decontamined.
Wash the skin thoroughly with soap and water or a recognised cleaner.
DO NOT use solvents or thinners.
If the contaminated area is widespread and/or there is damage to the skin, a doctor must be consulted or the patient transferred
to hospital
In the event of swallowing:
In the event of swallowing, if the quantity is small (no more than one mouthful), rinse the mouth with water, administer
activated medical charcoal and consult a doctor.
Consult a doctor and show him the label.
If swallowed accidentally, do not allow to drink, do not induce vomiting and transfer to hospital immediately by ambulance.
Show the label to the doctor.
5 - FIRE-FIGHTING MEASURES
Not relevant.
Special protective equipment for fire-fighters:
Due to the toxicity of the gas emitted on thermal decomposition of the products, fire-fighting personnel are to be equipped
with autonomous insulating breathing apparatus.
6 - ACCIDENTAL RELEASE MEASURES
Personal precautions:
Avoid any contact with the skin and eyes.
Consult the safety measures listed under headings 7 and 8.
Environmental precautions:
Contain and control the leaks or spills with non-combustible absorbent materials such as sand, earth, vermiculite,
diatomaceous earth in drums for waste disposal.
Prevent any material from entering drains or waterways.
Use drums to dispose of waste recovered in accordance with applicable regulations (see heading 13).
If the product contaminates waterways, rivers or drains, alert the relevant authorities in accordance with statutory procedures
Methods for cleaning up:
If the ground is contaminated, once the product has been recovered by sponging with an inert and non-combustible absorbent
material, wash the contaminated area in plenty of water.
If a large amount has been spilt, evacuate all personnel and only allow intervention by trained operators equipped with safety
apparatus.
Clean preferably with a detergent, do not use solvents.
7 - HANDLING AND STORAGE
The regulations relating to storage premises apply to workshops where the product is handled.
Anyone with a history of skin sensitisation must on no account handle such products
Fire prevention:
Prevent access by unauthorised personnel.
- Made under licence of European Label System庐 MSDS software from InfoDyne - http://www.infodyne.fr -
SAFETY DATA SHEET (EC REGULATION No 1907/2006 ) Date: 24/09/2007 Page 3/5
Version: N掳2 (07/05/2007) Revision: N掳7 (02/05/2007)
Name: ATM 007 - ATM01 Company: DURIEU S.A.
Recommended equipment and procedures:
For personal safety, see 搂8.
Observe precautions stated on label and also industrial safety regulations
Product must not come into contact with the skin and eyes
Provide safety showers and eye washes in workshops where the product is handled constantly
Prohibited equipment and procedures:
Smoking, eating and drinking are prohibited in premises where the preparation is used
Never open the packages under pressure
Storage:
Keep the container tightly closed in a dry, well-ventilated place
Keep away from food and drink, including those for animals.
8 - EXPOSURE CONTROLS/PERSONAL PROTECTION
Use personal protection equipment as per Directive 89/686/EEC.
Anyone with a history of skin sensitisation must on no account handle such products.
Exposure limit values (2003-2006):
Germany/AGW AGW: AGW: Faktor: Bemerkungen:
26530-20-1 - 0,05 mg/m3 E 2(I) DFG, H, Y
111-46-6 10 ml/m3 44 mg/m3 4(I) DFG, Y
UK/WELs TWA: STEL: Ceiling: Definition: Criterion:
111-46-6 23 ppm - - - -
UK/OES TWA: STEL: Ceiling: Definition: Criterion:
111-46-6 23 ppm - - - -
Hand protection:
Protective creams may be used for exposed skin, but they should not be applied after contact with the product.
Where there is a risk of contact with the hands, suitable gloves must be used
Eye and face protection:
Avoid contact with the skin and eyes
Provide personnel with gloves, face masks and safety goggles.
Provide eye washes in workshops where the product is constantly handled
Skin protection:
Wear suitable protective clothing, in particular an apron and boots. These items must be kept in good condition and cleaned
after use.
For further information, see 搂 11 of S.D.S. - Toxicological information.
9 - PHYSICAL AND CHEMICAL PROPERTIES
General information:
Physical state: fluid liquid
Important health, safety and environmental information:
pH of the substance or preparation: neutral.
When a pH measure is possible, it has a value of: not stated.
pH (aqueous solution): 7.00 +/-0.2
Boiling point/boiling range: not specified.
Flash point interval: not relevant.
vapour pressure: not relevant.
Density: >1
water solubility: Dilutable.
- Made under licence of European Label System庐 MSDS software from InfoDyne - http://www.infodyne.fr -
SAFETY DATA SHEET (EC REGULATION No 1907/2006 ) Date: 24/09/2007 Page 4/5
Version: N掳2 (07/05/2007) Revision: N掳7 (02/05/2007)
Name: ATM 007 - ATM01 Company: DURIEU S.A.
Other information:
melting point/melting range: not specified.
Self-ignition temperature: not specified.
Decomposition point/decomposition range : not specified.
% VOC: 0
10 - STABILITY AND REACTIVITY
The preparation is stable at the handling and storage conditions recommended per 搂 7 of the safety data sheet,
11 - TOXICOLOGICAL INFORMATION
No data is available regarding the preparation itself.
It is generally agreed that substances contained are likely to cause tissue damage in less than four hours after application to the
healthy, unbroken skin of an animal.
It is generally agreed that substances contained are likely to cause, among certain predisposed subjects, a sensitisation reaction
by cutaneous route
12 - ECOLOGICAL INFORMATION
No ecological data on the product itself is available.
The product must not be allowed to run into drains or waterways.
Ecotoxicity:
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
13 - DISPOSAL CONSIDERATIONS
Do not pour into drains or waterways.
Waste:
Recycle or dispose of waste in compliance with current legislation, preferably via a certified collector or company.
Do not contaminate the ground or water with waste, do not dispose of waste into the environment.
Soiled packaging:
Empty container completely. Keep label(s) on container.
Give to a certified disposal contractor.
14 - TRANSPORT INFORMATION
Transport product in compliance with provisions of the ADR for road, RID for rail, IMDG for sea and ICAO/IATA for air
transport (ADR 2007 - IMDG 2006 - ICAO/IATA 2007).
UN1760=CORROSIVE LIQUID, N.O.S.
ADR/RID Class Code Pack gr. Label Ident. LQ Provis.
8 C9 III 8 80 LQ7 274
IMDG Class 2掳Label Pack gr. LQ EMS Provis.
8 - III 5L F-A,S-B 223 274 944
IATA Class 2掳Label Pack gr. Passager Passager Cargo Cargo note
8 - III 818 5L 820 60 L A3
8 - III Y818 1L - - -
15 - REGULATORY INFORMATION
This preparation was classified in compliance with the directive known as 1999/45/EC and its adaptations
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SAFETY DATA SHEET (EC REGULATION No 1907/2006 ) Date: 24/09/2007 Page 5/5
Version: N掳2 (07/05/2007) Revision: N掳7 (02/05/2007)
Name: ATM 007 - ATM01 Company: DURIEU S.A.
In addition directive 2004/73/EC with the 29掳 adaptation of directive 67/548/EEC (Hazardous substances) have been taken
into account.
This product is not classed as flammable.
This product is for use as a biocide.
Preparation classification:
Corrosive.
Contains:
612-140-00-5 QUATERNARY AMMONIUM COMPOUNDS, BENZYL-C 8-18 -ALKYLDIMETHYL, CHLORIDES
613-112-00-5 2-OCTYL-2H-ISOTHIAZOL-3-ONE
Particular hazards associated with the preparation and safety recommendations:
R 52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R 43 May cause sensitisation by skin contact.
R 21/22 Harmful in contact with skin and if swallowed.
R 34 Causes burns.
S 23 Ne pas respirer les gaz/fum茅es/vapeurs/a茅rosols.
S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical
advice.
S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label
where possible).
S 60 This material and its container must be disposed of as hazardous waste.
16 - OTHER INFORMATION
Since the user's working conditions are not known by us, the information supplied on this safety data sheet is based on our
current level of knowledge and on national and community regulations.
The product must not be used for any purposes other than those specified under heading 1 without first obtaining written
handling instructions.
It is at all times the responsibility of the user to take all necessary measures to comply with legal requirements and local
regulations.
The information given on this safety data sheet must be regarded as a description of the safety requirements relating to our
product and not a guarantee of its properties
Full text of risk phrases appearing in section 3:
R 21/22 Harmful in contact with skin and if swallowed.
R 22 Harmful if swallowed.
R 23/24 Toxic by inhalation and in contact with skin.
R 34 Causes burns.
R 41 Risk of serious damage to eyes.
R 43 May cause sensitisation by skin contact.
R 50 Very toxic to aquatic organisms.
R 50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
Labelling for contents (REGULATION (EC) No 648/2004 - 907/2006):
- 5 % or over but less than 15 % : nonionic surfactants
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