Sartomer Company
Material Safety Data Sheet
Product: ESACURE TZM Revised Date: 01-17-2005
MSDS ID: S-000906 Replaces Date: 03-06-2000
01. GENERAL INFORMATION
Sartomer Company, Inc.
Oaklands Corporate Center
502 Thomas Jones Way
Exton, Pennsylvania 19341
Emergency phone numbers:
800/424-9300 (CHEMTREC)
610/692-8401 (Sartomer Co., Inc.)
Product information:
610/363-4100
GENERIC NAME
Blend of 4-methylbenzophenone and benzophenone
DOT PROPER SHIPPING NAME UN/NA NUMBER
N/AP N/AP
DOT HAZARD CLASS
Not regulated
02. SUMMARY OF HAZARDS
WARNING
PHYSICAL HAZARDS: No significant hazards expected
ACUTE HEALTH EFFECTS: Suspect slight eye irritation hazard
(SHORT-TERM) Susect slight to moderate skin irritation hazard
Suspect slight inhalation/respiratory tract
irritation hazard
Suspect slight ingestion hazard
Suspect slight skin absorption hazard
CHRONIC HEALTH EFFECTS: See Supplement section of MSDS for chronic health
(LONG-TERM) effects information.
03. COMPONENTS
COMPONENT NAME CAS NUMBER % COMPOSITION (BY WT.)
4-Methylbenzophenone 134-84-9 40-60
Benzophenone 119-61-9 40-60
04. PHYSICAL AND CHEMICAL DATA
BOILING POINT pH
GT 100C/212F N/DA
FREEZING POINT POUR POINT
N/DA May crystallize below 5C/41F
SPECIFIC GRAVITY (H20=1 AT 39.2F) VOLATILE CHARACTERISTICS
Date Printed: 01-17-2005 Page: 1 of 6
Sartomer Company
Material Safety Data Sheet
Product: ESACURE TZM Revised Date: 01-17-2005
MSDS ID: S-000906 Replaces Date: 03-06-2000
AP 1.09 AT 20C/68F Negligible
VISCOSITY UNITS, TEMP. (Brookfield) SOLUBILITY IN WATER
N/DA Insoluble
VAPOR PRESSURE STABILITY
N/DA Stable
VAPOR SP GR (AIR=1 AT 60 - 90F) HAZARDOUS POLYMERIZATION
N/AP Not expected to occur
APPEARANCE AND ODOR
Clear, colorless to light straw colored liquid with faint characteristic
odor.
CONDITIONS AND MATERIALS TO AVOID
High temperatures, direct sunlight, ultraviolet raditation;
Strong oxidizers
HAZARDOUS DECOMPOSITION PRODUCTS
Acrid smoke-fumes/carbon monoxide/carbon dioxide and perhaps other toxic
vapors may be released during a fire involving this product.
05. OCCUPATIONAL EXPOSURE LIMITS
SUBSTANCE SOURCE DATE TYPE VALUE TIME
A PEL or TLV has not been established
06. FIRE AND EXPLOSION
FLASH POINT METHOD=(PMCC) AUTOIGNITION TEMP. METHOD=
GT 212F/100C N/DA
FLAMMABLE LIMITS (% VOLUME IN AIR)
LOWER: N/DA UPPER: N/DA
FIRE AND EXPLOSION HAZARDS
High temperatures, accidental impurities, or exposure to radiation or
oxidizers may cause spontaneous polymerizing reaction generating heat/
pressure. Closed containers may rupture or explode during runaway
polymerization.
EXTINGUISHING MEDIA
Dry chemical
CO2
Foam
Water fog and spray for cooling fire exposed containers
SPECIAL FIREFIGHTING PROCEDURES
Do not enter fire area without proper protection. See Section 5 -
decomposition products possible. Fight fire from safe distance/protected
location. Heat may build pressure/rupture closed containers, spreading fire,
increasing risk of burns/injuries. Do not use solid water stream/may spread
fire. Use water spray/fog for cooling. Avoid frothing/steam explosion.
Date Printed: 01-17-2005 Page: 2 of 6
Sartomer Company
Material Safety Data Sheet
Product: ESACURE TZM Revised Date: 01-17-2005
MSDS ID: S-000906 Replaces Date: 03-06-2000
Burning liquid will float on water. Notify authorities if liquid enters
sewer/public waters.
Do not direct water jets directly into storage containers due to danger of
boilover.
07. HEALTH HAZARDS
ROUTES OF EXPOSURE
INHALATION
No significant signs or symptoms indicative of any adverse health hazard are
expected to occur at standard conditions due to the low volatility of this
material. However, aerosols, or vapors which may be generated at elevated
processing temperatures, may cause respiratory tract irritation. Symptoms of
irritation may include coughing, mucous production and shortness of breath.
Although no appropriate human or animal health effects data are known to
exist,excessive concentrations of this material may cause nervous system
depression, headache and weakness leading to unconsciousness.
EYE CONTACT -- PRIMARY ROUTE
May cause minor eye irritation. Symptoms may include excessive tearing,
blinking and redness.
SKIN ABSORPTION -- PRIMARY ROUTE
Although no appropriate human or animal health effects data are known to
exist, this material is expected to be a slight skin absorption hazard.
SKIN IRRITATION -- PRIMARY ROUTE
May cause minor skin irritation.
Symptoms of irritation may include a slight localized redness or rash and
swelling.
May cause delayed skin irritation and blistering.
Prolonged or repeated contact may cause skin to become dry or cracked.
INGESTION
This material may be a slight health hazard if ingested in large quantities.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
No additional medical information found.
08. PROTECTIVE EQUIPMENT / CONTROL MEASURES
RESPIRATORY PROTECTION
No occupational exposure standards have been developed for this material.
Where exposure through inhalation may occur from use, NIOSH/MSHA approved
respiratory protection equipment is recommended.
EYE PROTECTION
Eye protection such as chemical splash goggles and/or face shield must be
worn when possibility exists for eye contact due to splashing or spraying
liquid, airborne particles, or vapor. Contact lenses should not be worn.
Date Printed: 01-17-2005 Page: 3 of 6
Sartomer Company
Material Safety Data Sheet
Product: ESACURE TZM Revised Date: 01-17-2005
MSDS ID: S-000906 Replaces Date: 03-06-2000
SKIN PROTECTION
When skin contact is possible, protective clothing including gloves, apron,
sleeves, boots, head and face protection should be worn. This equipment must
be cleaned thoroughly after each use.
ENGINEERING CONTROLS
If handling results in aerosol or vapor generation, local exhaust ventilation
is recommended.
OTHER HYGIENIC PRACTICES
Emergency eye wash fountains and safety showers should be available in the
immediate vicinity of any potential exposure.
OTHER WORK PRACTICES
Use good personal hygiene practices. Wash hands before eating, drinking,
smoking, or using toilet facilities. Promptly remove soiled clothing/wash
thoroughly before reuse. Shower after work using plenty of soap and water.
09. EMERGENCY AND FIRST AID
INHALATION
If overcome by exposure, remove victim to fresh air immediately. Give oxygen
or artificial respiration as needed. Obtain emergency medical attention.
Prompt action is essential.
EYE CONTACT
In case of eye contact, immediately rinse with clean water for 20-30 minutes.
Retract eyelids often. Obtain emergency medical attention if pain, blinking,
tears or redness persist.
SKIN CONTACT
Immediately remove contaminated clothing. Wash skin thoroughly with mild
soap/water. Flush w/lukewarm water for 15 minutes. If sticky, use waterless
cleaner first. Seek medical attention if ill effect or irritation develops.
INGESTION
If large quantity swallowed, administer lukewarm water (pint) if victim
completely conscious/alert. Do not induce vomiting/aspiration risk exceeds
systemic poisoning risk. Obtain emergency medical treatment.
EMERGENCY MEDICAL TREATMENT PROCEDURES
Treat symptomatically.
10. SPILL AND DISPOSAL
PRECAUTIONS IF MATERIAL IS SPILLED OR RELEASED
Extinguish all ignition sources. Limit access to spill area. Impound/
recover large land spill; soak up small spill with inert solids. On water,
contain/minimize dispersion/collect. Report per regulatory requirements.
If the product has escaped into a water course, into the drainage system, or
has contaminated the ground or vegetation, notify authorities. Residues can
be flushed away with plenty of water to water treatment plants.
Date Printed: 01-17-2005 Page: 4 of 6
Sartomer Company
Material Safety Data Sheet
Product: ESACURE TZM Revised Date: 01-17-2005
MSDS ID: S-000906 Replaces Date: 03-06-2000
WASTE DISPOSAL METHODS
This product is not a listed hazardous waste, and to the best of our
knowledge is not a characteristic hazardous waste if discarded in its
purchased form (see 40 CFR 261). However, under RCRA it is the
responsibility of the user of a product to determine at the time of disposal
whether the product meets any of the criteria of a hazardous waste.
Comply with local/state/federal regulations for solid waste disposal.
Landfill solids at permitted sites. Use registered transporters.
11. ADDITIONAL PRECAUTIONS
HANDLING AND STORAGE PROCEDURES
Store containers in a dark, dry, well-ventilated location. Keep containers
tightly closed and away from strong oxidizers and radiation. Product
containers should be plastic (opaque), not transparent. Prevent
contamination by foreign materials. Product may crystallize at storage
temperatures below 5C/41F. Bond and ground containers before beginning
transfer. Electrical equipment should conform to the National Electric Code.
DECONTAMINATION PROCEDURES
Follow standard plant procedures or supervisor's instructions for
decontamination operations.
12. LABEL INFORMATION
USE STATEMENT
FOR INDUSTRIAL USE ONLY
SIGNAL WORD
WARNING
HEALTH HAZARDS
MAY CAUSE SKIN IRRITATION
PRECAUTIONARY MEASURES
AVOID HEAT, HIGH TEMPERATURE.
AVOID CONTACT WITH EYES, SKIN AND CLOTHING.
AVOID BREATHING VAPORS/MIST.
KEEP CONTAINER CLOSED WHEN NOT IN USE.
WASH THOROUGHLY AFTER HANDLING.
BEFORE USING PRODUCT, READ MATERIAL SAFETY DATA SHEET(MSDS).
13. SUPPLEMENT
NPCA - HMIS RATING
Health 2
Flammability 1
Reactivity 1
Personal protection** B
**Consider application/conditions of use when assigning personal protective
equipment.
CHRONIC HEALTH EFFECTS INFORMATION:
Date Printed: 01-17-2005 Page: 5 of 6
Sartomer Company
Material Safety Data Sheet
Product: ESACURE TZM Revised Date: 01-17-2005
MSDS ID: S-000906 Replaces Date: 03-06-2000
Chronic exposure to some ketones has been associated with neurotoxic effects
such as brain and central nervous system damage.
REGULATORY INFORMATION
TSCA STATUS
TSCA status: All components of this product are listed, or excluded from
listing, on the United States Environmental Protection Agency Toxic Substances
Control Act (TSCA) inventory.
INTERNATIONAL INVENTORY STATUS
Australia (AICS): included on inventory
Canada (DSL): included on inventory
Europe (EINECS): included on inventory
Japan (ENCS): included on inventory
Korea (ECL): included on inventory
Philippines (PICCS): not included on inventory
*Note - qualifiers and codes used in this MSDS
EQ = Equal; AP = Approximately; LT = Less Than; GT = Greater Than;
TR = Trace; UK = Unknown; N/AP = Not Applicable; N/P = No Applicable
Information Found; N/DA = No Data Available
14. DISCLAIMERS
Some of the information presented and conclusions drawn herein are from
sources other than direct test data on the product itself. The information in
this MSDS was obtained from sources which we believe are reliable. However,
the information is provided without any warranty, express or implied,
regarding its correctness. The conditions or methods of handling, storage, use
and disposal of the product are beyond our control and may be beyond our
knowledge. For this and other reasons, we do not assume responsibility and
expressly disclaim liability for loss, damage or expense arising out of or in
any way connected with the handling, storage, use or disposal of the product.
This MSDS was prepared and is to be used only for this product. If the
product is used as a component in another product, this MSDS information may
not be applicable. This MSDS has been prepared in accordance with the
requirements of the OSHA Hazard Communication Standard (29 CFR 1910.1200).
Date Printed: 01-17-2005 Page: 6 of 6
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