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MATERIAL SAFETY DATA SHEET
(MSDS)
1. MATERIAL IDENTIFICATION
PRODUCT NAME : AVIATION GASOLINE, AVGAS 100
OTHER NAME : GASOLINE 100
PRODUCER : PERTAMINA
Jalan Perwira No.4
Jakarta Pusat Post Code 10110
Phone Number : 021 鈥? 3815509, Facsimile : 3455344
Emergency Telephone Number within 24 hours : 021 鈥? 3816732
MSDS Information Telephone Number : 021 鈥? 3815578 / 3815504
2. MATERIAL COMPOSITION / IDENTITY INFORMATION
Composition : Hydrocarbon and Additive
3. HAZARD IDENTIFICATION
Hazard Communication Standard : OSHA 29 CFR 1910, 1200 (hazardous)
Exposure Effects : Irritation to the eyes, respiratory tracts and skin, dizziness,
nausea and becoming unconscious. Its misuse(inhaling /
swallowing) or other misuses(as solvent, or washing materials)
for a long time can cause variable neurological effects, sudden
death due to cardiac arrest, hematological changes and
leukemia. These effects must be prevented from occurring
in the place of or the environment of distribution, for examples
in Depots, DPPU, and others
: Green liquid and is flammable
Emergency Response Data
4. FIRST AID METHODS
Eye Contact : Flush the eyes continuously with copious amount of. water. If irritation
persists seek medical advice.
Skin Contact : Wash the contacted part with water and soap. Wash the contaminated clothes
before being worn again.
Inhaled : Stop/Avoid further exposure. If there is occurrence of irritation in the
respiratory tract, dizziness, unconsciousness, seek medical advice. When
BREATHING STOPS, GIVE RESUSCITATION FROM MOUTH TO
MOUTH.
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Swallowed : When more than 0.5 liter of the substance is swallowed, give one or two glasses
of water and ask him/her to drink at once prior to the seeking of medical help in
the Emergency Installation or other Emergency Centers.
CAUTION : Never stimulate the victims to vomit or to swallow anything
when they are unconscious.
Note for Doctors : The swallowed substance can be absorbed into the lungs that may cause
chemical pneumonitis that needs urgent treatment.
5. FIRE FIGHTING METHODS
Fire Fighting Media : Carbon dioxide, dry chemical powder and foam
Specific Procedure in Fire Fighting :
a. Carbon dioxide : Spray it to the front fire from upwind.
b. Dry Chemical Powder : Spray it to the front fire from upwind
c. Foam : When the fire is in a container, spray the foam into the inner
wall of the container, not to the burning liquid, and from
upwind.
When the fire is caused by spill of liquid, spray it to the
front fire until the spill is covered thoroughly, and from
upwind
Personal Protective Equipment : For fires in relatively closed areas, the fire fighters must be
equipped with Self Contained Breathing Apparatus (SCBA).
Explosion and Fire Hazards : These hazards occur in unprotected storage tanks near the
fire location.
Flash Point : - 45掳 F or 鈥? 43掳 C
Flammable Limits : LEL 1.4%, UEL 7.6%
NFPA Hazard ID : Flammability : 3, Instability : 1
Hazardous Material Decomposition : Carbon Monoxide
6. SPILL AND LEAK HANDLING METHODS
Notification Procedure : Notify the authority promptly about the occurrence of the spills, in
accordance with the determined local authorization when the spills are
suspected to contaminate the water channel.
Spill or Leakage Procedure : Put away all conditions that can enable the occurrence of ignition. Adsorb
the spill by using sorbent, sawdust mixed with clay and other fire inhibitor
materials Clean and dispose it at the determined place of disposal
according to the local regulation
Environmental Prevention : Prevent the entrance of the spill into the water ditches, disposal channels, or
its seepage into the earth.
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7. PRECAUTIONS FOR HANDLING AND STORAGE
Handling : NEVER SUCK AVGAS 100 WITH YOUR MOUTH. AVGAS 100 CANNOT
BE USED AS SOLVENT OR AS WASHING MATERIAL Explosion proof equipment must
be used and do not do any spraying. On handling the open areas, prevent the possibility of the
occurrence of ignition. Portable containers must undergo proper tests. On being filled, the
containers must be placed on the surface of the ground, whereas their caps must be kept
attached to the containers to anticipate static electricity
Storage : The storage tanks must be grounded and bonded and must be equipped with self closing
valves, pressure vacuum bungs and flame traps. Avoid from flammable substance, fire,
electrics or other hot source
8. CONTROL MEASURES/PERSONAL PROTECTIVE EQUIPMENT
Ventilation : When Avgas 100 is used in a relatively closed room, a local exhaust
ventilation must be provided. Ventilation and the equipment used must
be explosion proof
Breathing Protection : Use breathing apparatus when the polluted concentration in the air is
higher than the permissible threshold limit value.
Eye Protection : Use chemical type goggles
Skin Protection : Use leather or PVC gloves. Apply Good Personal Hygiene Practices
Threshold Limit : Value 300 ppm
9. PHYSICAL AND CHEMICAL PROPERTIES
No. PROPERTIES UNITS LIMITS TEST METHOD
Appearance Clear, bright and visually free from solid Visual examination
matter and undissolved water at
ambient temperature.
1. Colour, Visual (Note 1) Green -
2. Corrosion, Copper Strip Max 1 ASTM D 130/IP 154
Density at 150C Kg/m3
3. Report ASTM D 1298 / IP 160
4. Total Sulfur % m/m Max 0.05 ASTM D 1266 / IP 107
5. Existent Gum mg/100ml Max 3 ASTM D 381 / IP 131
0C
6. Freezing Point Max Minus 60 ASTM D 2386 / IP 16
7. Specific Energy MJ/kg Min 43.5 IP 12
Reid Vapour Pressure at 37,80C
8. kPa Min 38.0 ASTM D 323 / IP 69
Max 49.0
9. Knock Rating ;
10. Lean Mixture Motor Method Octane Number Min 99,5 ASTM D 2700/IP 236
(see Note 2)
11. Rich Mixture Octane Number - -
12. Performance Number Min 130 ASTM D 909/IP 119
(see Note 2 )
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13. Distillation : ASTM D 86 / IP 123
0C
14. Initial Boiling Point Report Group 2
Fuel Evaporated
0C
15. 10 vol % Max 75
0C
16. 40 vol % Min 75
0C
17. 50 vol % Max 105
0C
18. 90 vol % Max 135
0C
19. Final Boiling Point Max 170
0C
20. Sum of 10% + 50% Evaporated Temperatures Min 135
21. Residue % v/v Max 1.5
22. Loss % v/v Max 1.5
23. Oxidation Stability, 16 hours : ASTM D 873 / IP 138
24. Potential Gum mg/100ml Max 6 -
25 Precipitate mg/100ml Max 2 -
26. Tetraethyl Lead Content g Pb/l Max 1.12 ASTM D 3341/ IP 270
27. Water Reaction : ASTM D 1094 / IP 289
28. Interface Rating Max 2 -
29. Volume Change ml Max 2 -
30. Electrical Conductivity pS/m See Note 3 ASTM D 2624 / IP 274
31. Colour IP 17
32. Lovibond Min 1.7
33. Blue Max 2,9
Min 1.5
Yellow Max 2.7
*) Complies with Def. Stan 91-90 / issue 1 (DERD 2485), 8 May 1996 Except TEL Content follow to ASTM D 910-94
E1 : The visual colour must comply with test 16 of this table and test method IP 17 (Method A) using a 50.8 mm cell.
E2 : Knock rating shall be reported to the nearest 0.1 for Octane Number and nearest whole number for Performance Number
E3 : When a Static Dessipator Additive has been added to the fuel the conductivity at the point, time and temperature of delivery to the purchase shall
be in range 50 to 600 pS/m.
Note : The above mentioned specifications are in accordance with the Letter of Decision of
DirectorateGeneral of Oil and Gas, No. 27.K/34/DDJM/1999 dated Mei 5,1999.
10. REACTIVITY
Thermal Stability and Light : stable
Conditions that should be avoided : heat, flame, ignition or conditions that can
cause static electricity
Inappropriate materials that should : halogen, strong acid, base, and strong
be avoided oxidations. Decomposition of hazardous
materials : carbon monoxide
Polymerization of hazardous material : does not exist formation
11. TOXICOLOGY DATA
-----------------------------------------ACUTE TOXICOLOGY ---------------------------------
Acute Toxicity Data : Vapor or mist can cause irritation to the Respiratory tracts
HAZARDS OF COMBUSTION RESULTS : Combustion can result in exposure of high carbon
monoxide in the air which in turn can cause loss of consciousness,
heart disorder, brain disorder or even death. Exposure to, high
carbon monoxide can cause breathing difficulties caused by
competitive reaction between carbon monoxide and oxygen
-----------------------------CHRONIC TOXICOLOGY -----------------------
Experiments with animals with concentration of > 3000 ppm show an increase incidents of kidney
. and liver tumors. However, these effects do not exist in human being
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-----------------------------OTHER TOXICOLOGY DATA --------------------
Laboratory experiments (API = American Petroleum Institute) using experiment animals show that
exposure to high concentration of gasoline vapor in a long period can cause kidney disorder and
cancer, and liver cancer. Effects to reproduction system cannot be proved yet. Repeated exposure to
benzene with low concentration can cause abnormalities in human blood, such as anemia and
leukemia. Exposure to hexane in a long period can cause disorder in nerve system, such as being
numb and paralyzed
12. WATER POLLUTION
Environmental effects and damage : Seepage of this substance to the soil can contaminate soil
water or aquifer.
13. DISPOSAL CONSIDERATION
Effluent Disposal : can be burned in the incinerator or according to Govermental Regulation
Regulation Information : Sludge this product can be categorized as B3, and its disposal must
accord with the regulation on effluent disposal of B3.
14. TRANSPORTATION INFORMATION
USA DOT :
SHIPPING NAME : GASOLINE
HAZARD CLAS & DIV :3
ID NUMBER : UN 1203
ERG NUMBER : 128
PACKING GROUP : PG II
: Unknown
STCC
DANGEROUS WHEN WET : None.
POISON : None.
LABEL(s) : Flammable Liquid
PLACARD (s) : Flammable
: Unknown
PRODUCT RQ
RID / ADR :
HAZARD CLASS :3
HAZARD SUB CLASS : 3(b)
LABEL :3
DANGER NUMBER : 33
UN NUMBER : 1203
SHIPPING NAME : GASOLINE
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IMO :
HAZARD CLASS & DIV :3
ID/UN NUMBER : 1203
PACKING GROUP : PG 11
SHIPPING NAME : GASOLINE
ICAO / IATA:
HAZARD CLASS & DIV :3
ID/UN NUMBER : 1203
PACKING GROUP : PG II
SHIPPING NAME : GASOLINE
LAISEL(s) : Flammable liquid
15. REGULATION INFORMATION
Inventory Status : Registered in TSCA and EINECS/ELINCS.
EEC Labeling : None
Symbol : F+ = Highly flammable, T = toxic
Risk Phrase(s) : R12-45-38-22. Highly flammable. It can cause cancer skin irritation,
and dangerous when swallowed.
Safety Phrase(s) : S53-45-2-23-24-29-43-62. Avoid exposure. Read the instructions before
Use In case of accidents or inconvenience, seek medical help. Keep it away
From children鈥檚 reach. Avoid contact it with skin. In the occurrence of fire,
use CO2, dry chemical or foam.
16. OTHER INFORMATION
WARNING LABEL
Content oil fuel AVGAS 100 DANGEROUS
Highly flammable. The vapor can cause fires. They can cause health disorder, that is irritation to the
eyes, skins, noses, throats, lungs, headaches, queasiness and loss of consciousness. When swallowed,
it can block respiratory tract which in turn can cause death. Long time exposure with this substance
can cause malign tumor in the kidney and
liver. Keep a distance from heat, sparks or jet of sparks. Avoid contacting it with any part of your
body. Avoid inhaling the vapor produced in a long period. Keep the containers
closed. Handle it in a well ventilated room. Its misuse can cause accidents or sickness. Use it only for
mechanical purposes. Do not use it as solvent or skin cleaner. Do not suck it with your mouth.
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FIRST AID : When inhaled, the victim should be moved away to an open fresh area. If he/she does
not breathe, resuscitation from mouth to mouth should be given promptly. When it is still difficult for
him/her to breathe, add oxygen. Call the doctor immediately.
When it contacts with the skin, wash it with soap and copious amount of water. Wash the
contaminated clothes before being worn again. When swallowed, seek medical advice. Never try to
make the victims to vomit without the doctor鈥檚 supervision. Never give the victims something to be
swallowed when they are unconscious, as it can be fatal.
ATTENTION
The remnant of residue in a container can cause fire or explosion. Do not do any cutting, hitting or welding
near the container. All warning labels must be kept being checked for their existence, so that the container will
be really safe. The warning label should at least include the following : This material is toxic and dangerous, it
can cause malign tumor, death of babies when born, and disturbance for reproduction system
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