Material Safety Data Sheet CS: 1.4.20
1 of 6
Page:
LPUBC Issue Date :January 2008
Infosafe No鈩? DRAFT by BARNES CS: 1.4.20
Product Name :ULTRASIL庐 PART B
Classified as hazardous
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
ULTRASIL庐 PART B
Product Name
Barnes Products Pty Ltd (ABN 004 011 456)
Company Name
Address 6 Homedale Road Bankstown
NSW 2200
(02) 9793 7555
Emergency Tel.
Tel: (02) 9793 7555
Telephone/Fax
Fax: (02) 9793 7091
Number
Curing agent/catalyst for RTV silicone compounds.
Recommended Use
Name Product Code
Other Names
GELSIL庐 PART B
MAXIMOULD庐 PART B
Other Information Information provided has been prepared in good faith and believed to be
correct. Barnes Products Pty Limited make no warranty either express or
implied as to completeness, accuracy thereof, misuse or misinterpretation of
this information.
2. HAZARDS IDENTIFICATION
Classified as hazardous
Hazard
HAZARDOUS SUBSTANCE.
Classification
NON-DANGEROUS GOODS.
Hazard classification according to the criteria of NOHSC.
Dangerous goods classification according to the Australia Dangerous Goods
Code.
Risk Phrase(s) Classified as hazardous
R36/38 Irritating to eyes and skin.
R48/22 Harmful: danger of serious damage to health by prolonged exposure if
swallowed.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
Safety Phrase(s) S2 Keep out of reach of children.
S23(2) Do not breathe vapour.
S24/25 Avoid contact with skin and eyes.
S35 This material and its container must be disposed of in a safe way.
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
S45 In case of accident or if you feel unwell seek medical advice immediately
S61 Avoid release to the environment. Refer to special instructions/safety
data sheet.
Other Information CONTAINS AN ORGANOTIN COMPOUND WHICH MAY BE TOXIC BY INGESTION, INHALATION AND
ABSORPTION, IS A SKIN IRRITANT AND SEVERE EYE IRRITANT AND CAN POSSIBLY CAUSE
CHRONIC EFFECTS. If moisture is present, methanol may be emitted before and
during curing and is irritating to eyes, skin and respiratory tract. Methanol,
at high concentrations, can have central nervous system effects and may cause
blindness if swallowed (unlikely route for exposure in this form).
3. COMPOSITION/INFORMATION ON INGREDIENTS
METHANOL [CAS No. 67-56-1]EMITTED WHEN CONTACTED WITH MOISTURE <13%
Information on
Composition
Name CAS Proportion
Ingredients
2996-92-1 15-40 %
Phenyltrimethoxys
ilane
77-58-7 1-5 %
Dibutyltin
dilaurate
Balance
Other ingredients
determined not be
hazardous
4. FIRST AID MEASURES
Inhalation If respiratory irritation or distress occurs remove victim to fresh air. Seek
Print Date: 8/01/2008 CS: 1.4.20
Material Safety Data Sheet CS: 1.4.20
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Page:
LPUBC Issue Date :January 2008
Infosafe No鈩? DRAFT by BARNES CS: 1.4.20
Product Name :ULTRASIL庐 PART B
Classified as hazardous
medical attention if respiratory irritation or distress continues.
Ingestion If swallowed, DO NOT induce vomiting. If conscious, rinse out mouth with
water. If sickness persists, seek medical attention. Do not leave victim
unattended.
Skin Immediately wipe excess material off skin with a dry cloth; then wash skin
with plenty of soap and water. Seek medical attention if irritation develops
or persists.
Eye In case of contact, immediately absorb excess with clean absorbent cloth or
cotton. Then, hold eyelids open and flush with a steady, gentle stream of
water for at least 15 minutes. Remove contact lenses, if present and easy to
do so. Seek medical attention if irritation develops or persists or if visual
changes occur.
Eye wash and normal washroom facilities.
First Aid Facilities
Advice to Doctor All treatments should be based on observed signs and symptoms of distress of
the patient. Consideration
should be given to the possibility that overexposure to materials other than
this product may have occurred. Treat symptomatically. No specific antidote
available.
Other Information For advice, contact a Poisons Information Centre (Phone e.g. Australia 13
1126; New Zealand 0800 764
766) or a doctor (at once).
5. FIRE FIGHTING MEASURES
Do not use water in a jet. Keep containers cool with water spray.
Suitable
Use foam, carbon dioxide or dry chemical to extinguish fire.
Extinguishing Media
Under fire conditions, toxic and highly flammable gases are released
Hazards from
(explosion hazard).
Combustion
On combustion or on thermal decomposition (pyrolysis), releases formaldehyde,
Products
oxides of carbon, silica
(crystalline).
Specific Hazards Classified as a Class C1 (COMBUSTIBLE LIQUID) for the purpose of storage and
handling, in accordance with the requirements of AS1940. This product should
be stored and used in a well-ventilated area away from naked flames, sparks
and other sources of ignition.
On contact with humidity, releases methanol. (Quantity potentially released: 1
- 5% of product weight).
Fire-fighters should wear full protective clothing and self contained
Precautions in
breathing apparatus (SCBA) operated in positive pressure mode.
connection with Fire
6. ACCIDENTAL RELEASE MEASURES
Wear appropriate personal protective equipment and clothing to minimise
Emergency
exposure. Extinguish or remove all sources of ignition and stop leak if safe
Procedures
to do so. Increase ventilation. Evacuate all unnecessary personnel. If
possible contain the spill. Place inert absorbent material onto spillage. Use
clean non-sparking tools to collect the material and place into a suitable
labelled container. Do not dilute material but contain. Dispose of waste
according to federal, Environmental Protection Authority and state
regulations. If large quantities of this material enter the waterways contact
the Environmental Protection Authority, or your local Waste Management
Authority.
7. HANDLING AND STORAGE
Avoid breathing vapors and mists. Avoid direct or prolonged contact with skin
Precautions for Safe
and eyes. Use nonsparking
Handling
tools and grounded/bonded equipment and containers when transferring. DO NOT
ALLOW TO FREEZE.
Store, transfer and handle under a blanket of nitrogen.
Store in a cool, dry well-ventilated area away from heat, sources of ignition,
Conditions for Safe
oxidising agents, foodstuffs, and clothing and out of direct sunlight. Keep
Storage
containers closed when not in use and securely sealed and protected against
physical damage. Inspect regularly for deficiencies such as damage or leaks.
Do NOT pressurise, cut, heat or weld containers as they may contain hazardous
residues. For information on the design of the storeroom, reference should be
made to Australian Standard AS1940 - The storage and handling of flammable and
Print Date: 8/01/2008 CS: 1.4.20
Material Safety Data Sheet CS: 1.4.20
3 of 6
Page:
LPUBC Issue Date :January 2008
Infosafe No鈩? DRAFT by BARNES CS: 1.4.20
Product Name :ULTRASIL庐 PART B
Classified as hazardous
combustible liquids. Reference should also be made to all State and Federal
regulations.
<32掳C
Storage
Temperatures
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
No exposure standards assigned to this specific material by the ASCC/NOHSC,
National Exposure
however, the following exposure standards have been assigned to the following
Standards
components of the product:
Methanol (CAS 67-56-1) (Released product during curing)
(NOHSC)
[TWA] 200 ppm; 262 mg/m鲁
[STEL] 250 ppm; 328 mg/m鲁
Notices: Sk
Tin, organic compounds (as Sn)
[TWA] - ppm; 0.1 mg/m鲁
[STEL] - ppm; 0.2 mg/m鲁
Notices: Sk
Exposure Determinant Sampling Time BEI
Biological Limit
Methyl alcohol Methyl alcohol in urine End of shift 15mg/L
Values
(Ref: ACGIH 2006)
TWA - the Time-Weighted Average airborne concentration over an eight-hour
Other Exposure
working day, for a five-day working week over an entire working life.
Information
STEL (Short Term Exposure Limit) - the average airborne concentration over a
15 minute period which should not be exceeded at any time during a normal
eight-hour workday.
According to current knowledge these concentrations should neither impair the
health of, nor cause undue discomfort to, nearly all workers.
'Sk' notice - absorption through the skin may be a significant source of
exposure. The exposure standard is invalidated if such contact should occur.
These Exposure Standards are guides to be used in the control of occupational
health hazards. All atmospheric contamination should be kept to as low a level
as is workable. Exposure Standards should not be used as fine dividing lines
between safe and dangerous concentrations of chemicals, they are not a measure
of relative toxicity.
Provide sufficient ventilation to keep airborne levels below the exposure
Engineering
limit. Where vapours or mists are generated, particularly in enclosed areas,
Controls
and natural ventilation is inadequate, a local exhaust ventilation system is
required. Refer to AS1940 - The storage and handling of flammable and
combustible liquids and AS2430 - Explosive gas atmospheres for further
information concerning ventilation requirements.
If engineering controls are not effective in controlling airborne exposure
Respiratory
then respiratory protective equipment with a gas filter, suitable for
Protection
protecting against airborne contaminants, should be used. Final choice of
appropriate breathing protection is dependant upon actual airborne
concentrations and the type of breathing protection required will vary
according to individual circumstances. Expert advice may be required to make
this decision. Reference should be made to Australian Standards AS/NZS 1715,
Selection, Use and maintenance of Respiratory Protective Devices; and AS/NZS
1716, Respiratory Protective Devices.
Eye Protection Safety glasses with side shields, goggles or full-face shield as appropriate
recommended. Final choice of appropriate eye/face protection will vary
according to individual circumstances i.e. methods of handling or engineering
controls and according to risk assessments undertaken. Eye protection should
conform with Australian/New Zealand Standard AS/NZS 1337 - Eye Protectors for
Industrial Applications.
Hand Protection Skin contact should be minimized through use of gloves of impervious material
(e.g. PVC or Nitrile) and
suitable long-sleeved clothing (i.e., shirts and pants). Consideration must be
given both to durability as well as permeation resistance. NOTE: Under normal
conditions of use, in which the product is extruded from its container using
an appropriate dispenser, skin contact is unlikely.
Body Protection Wear appropriate clothing including chemical resistant apron where clothing is
likely to be contaminated. It is advisable that a local supplier of personal
protective clothing is consulted regarding the choice of material.
Print Date: 8/01/2008 CS: 1.4.20
Material Safety Data Sheet CS: 1.4.20
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Page:
LPUBC Issue Date :January 2008
Infosafe No鈩? DRAFT by BARNES CS: 1.4.20
Product Name :ULTRASIL庐 PART B
Classified as hazardous
9. PHYSICAL AND CHEMICAL PROPERTIES
Blue, viscous liquid
Appearance
Alcohol-like odour
Odour
Not available
Melting Point
> 211掳C (@ 760 mmHg)
Boiling Point
Slowly hydrolyses
Solubility in Water
1.0 @ 25掳C
Specific Gravity
Not applicable
pH Value
< 20 mmHg @ 107掳C
Vapour Pressure
Not available
Vapour Density
(Air=1)
90掳C AFNOR T 60103 (EEC closed cup)
Flash Point
Flammability Classified as a Class C1 (COMBUSTIBLE LIQUID) for the purposes of storage and
handling, in accordance with the requirements of AS1940. This product should
be stored and used in a well ventilated area away from naked flames, sparks
and other sources of ignition.
Not available
Auto-Ignition
Temperature
6%
Flammable Limits -
Lower
36%
Flammable Limits -
Upper
10. STABILITY AND REACTIVITY
Stable under normal conditions of storage and handling.
Chemical Stability
Conditions to Avoid Heat, direct sunlight, open flames or other sources of ignition.
Avoid contact with water and extreme humidity.
Avoid contact with water, strong oxidising agents, strong acids and strong
Incompatible
bases.
Materials
Thermal decomposition may result in the release of toxic and/or irritating
Hazardous
fumes including carbon monoxide, carbon dioxide, dimethylcyclosiloxanes,
Decomposition
methylphenylcyclosiloxanes and formaldehyde.
Products
Contact with water will cause decomposition by hydrolysis to produce methanol.
Hazardous Reactions May react with strong oxidising agents, strong acids and strong bases. Will
react with water to produce methanol.
Will not occur.
Hazardous
Polymerization
11. TOXICOLOGICAL INFORMATION
No toxicity data is available for this specific product.
Toxicology
Information
Inhalation Inhalation of product vapours may cause irritation of the nose, throat and
respiratory system.
Ingestion Ingestion of this product will irritate the gastric tract causing nausea and
vomiting. Harmful: danger of serious damage to health by prolonged exposure if
swallowed.
Irritating to skin resulting in redness and itching.
Skin
May cause eye irritation, tearing, stinging, blurred vision, and redness.
Eye
Chronic Effects This product does not contain any substances that are considered by OSHA, NTP,
IARC or ACGIH to be
'probable' or 'suspected' human carcinogens.
Other Information CAUTION! CONTAINS AN ORGANOTIN COMPOUND WHICH MAY BE TOXIC BY INGESTION,
INHALATION AND ABSORPTION, IS A SKIN IRRITANT AND SEVERE EYE IRRITANT AND CAN
POSSIBLY CAUSE CHRONIC EFFECTS. If moisture is present, methanol may be
emitted before and during curing and is irritating to eyes, skin and
Print Date: 8/01/2008 CS: 1.4.20
Material Safety Data Sheet CS: 1.4.20
5 of 6
Page:
LPUBC Issue Date :January 2008
Infosafe No鈩? DRAFT by BARNES CS: 1.4.20
Product Name :ULTRASIL庐 PART B
Classified as hazardous
respiratory tract. Methanol, at high concentrations, can have central nervous
system effects and may cause blindness if swallowed (unlikely route for
exposure in this form).
This product contains methylpolysiloxanes which can generate formaldehyde when
heated above 150掳C in the presence of air. Formaldehyde is a known animal
carcinogen and is listed as a probable human carcinogen by the IARC.
Formaldehyde is irritating to the eyes, nose, throat and skin and is a dermal
sensitiser.
12. ECOLOGICAL INFORMATION
No data is available for this material.
Ecotoxicity
No data is available for this material.
Persistence /
Degradability
No data is available for this material.
Mobility
No data is available for this material.
Environmental Fate
No data is available for this material.
Bioaccumulative
Potential
Do not allow product to enter drains, waterways or sewers.
Environ. Protection
13. DISPOSAL CONSIDERATIONS
Dispose of waste according to federal, EPA and state regulations. Labels
Disposal
should not be removed from containers until they have been cleaned. Do not
Considerations
cut, puncture or weld on or near containers. Empty containers may contain
hazardous residues. Contaminated containers must not be treated as household
waste. Containers should be cleaned by appropriate methods and then re-used or
disposed of by landfill or incineration as appropriate. Do not incinerate
closed containers. Advise combustible nature.
Container Disposal Separate the different packaging components and treat them separately.
Incinerate plastic plastic packaging at a licensed installation. Entrust the
uncontaminated packaging to a licensed waste contractor. Following
decomatination, re-use or recycle metal packaging. Disposable containers.
Incinerate at a licensed installation.
14. TRANSPORT INFORMATION
Not classified as Dangerous Goods according to the Australian Code for the
Transport
Transport of Dangerous Goods by Road and Rail.
Information
IMDG UN No Sea Transport
UN Number: 3082
Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(Contains: ORGANOTIN CARBOXYLATE)
Dangerous Goods Class: 9
Packing Group: III
Label: None allocated
Marine Transport:
Classified as Dangerous Goods Class 9 according to the International Maritime
Organization Rules (Maritime Dangerous Goods Code - IMDG Code) for transport
by sea.
This material is a MARINE POLLUTANT according to the IMDG Code.
15. REGULATORY INFORMATION
S7
Poisons Schedule
Harmful,Irritant,Dangerous for the environment
Hazard Category
16. OTHER INFORMATION
MSDS Revised: January 2008
Date of preparation
Supersedes: April 2005
or last revision of
MSDS
Contact Person/Point
...End Of MSDS...
Print Date: 8/01/2008 CS: 1.4.20
Material Safety Data Sheet CS: 1.4.20
6 of 6
Page:
LPUBC Issue Date :January 2008
Infosafe No鈩? DRAFT by BARNES CS: 1.4.20
Product Name :ULTRASIL庐 PART B
Classified as hazardous
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Print Date: 8/01/2008 CS: 1.4.20
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