Material Safety Data Sheet
according to 91/155/EEC
Product name : MASTERTOP P 605, COMP B (CONIPOX 605)
605_B
Revision : 07.07.2006 Version : 6.0.0
Print date : 24.07.2006
01. Identification of substance, preparation and company
Product name
MASTERTOP P 605, COMP B (CONIPOX 605) (630-0605-5299) (605_B)
Manufacturer/Supplier
BASF Construction Chemicals
(Schweiz) AG Division CONICA Technik
Street/P.O.Box
Industriestrasse 26 /
Country code/Postal code/Town/City
CH-8207 Schaffhausen
Telephone / Telefax
+41-58-958-2525 / +41-58-958-3525
Emergency information
Schweizer Toxzentrum +0041-1-2515151 (CH)
Centre Anti - Poison +0033 01 40 37 04 04 (FR)
Toxikologick茅 informa-n铆 st-edisko +00420 224 919 293 (CZ)
Myrkytystietokeskus puh.(suora) +358 (0) 9 471 977 (vaihde) 094711 (FIN)
02. Composition/information on ingredients
Chemical characterization
Modified cycloaliphatic polyamine mixture
Hazardous components
BENZYL ALCOHOL ; EC-No. : 202-859-9 ; CAS-No. : 100-51-6
Percentage : 10 - 25 %
Classification : Xn ; R 20/22
M-PHENYLENEBIS(METHYLAMINE) ; EC-No. : 216-032-5 ; CAS-No. : 1477-55-0
Percentage : 10 - 25 %
Classification : C ; R 34 Xn ; R 20/21/22
CYCLOHEX-1,2-YLENEDIAMINE ; EC-No. : 211-776-7 ; CAS-No. : 694-83-7
Percentage : 10 - 25 %
Classification : C ; R 34 R 43
3-AMINOMETHYL-3,5,5-TRIMETHYLCYCLOHEXYLAMINE ; EC-No. : 220-666-8 ; CAS-No. : 2855-13-2
Percentage : 2,5 - 10 %
Classification : C ; R 34 R 43 R 52/53 Xn ; R 21/22
POLYOXYPROPYLEN DIAMINE ; CAS-No. : 9046-10-0
Percentage : 2,5 - 10 %
Classification : C ; R 34 Xn ; R 21/22
2,4,6-TRIS(DIMETHYLAMINOMETHYL)PHENOL ; EC-No. : 202-013-9 ; CAS-No. : 90-72-2
Percentage : 2,5 - 10 %
Classification : Xn ; R 22 Xi ; R 36/38
2-METHYL-1,5-PENTAMETHYLENDIAMINE ; EC-No. : 239-556-6 ; CAS-No. : 15520-10-2
Page : 1 / 8
Material Safety Data Sheet
according to 91/155/EEC
Product name : MASTERTOP P 605, COMP B (CONIPOX 605)
605_B
Revision : 07.07.2006 Version : 6.0.0
Print date : 24.07.2006
Percentage : 0,5 - 2,5 %
Classification : C ; R 34 Xn ; R 20/22
For the wording of the listed risk phrases refer to section 16.
03. Hazards identification
Hazard designation
Causes burns. 路 May cause sensitisation by skin contact. 路 Harmful by inhalation, in contact with skin and if swallowed.
Classification : C ; R 34 路 R 43 路 Xn ; R 20/21/22
Additional information
Danger of irritation to eyes, nose, throat and the air passages.
04. First-aid measures
After inhalation
Take the casualty into the fresh air and keep warm. Keep at rest. Irregular breathing/no breathing: artificial respiration.
Unconsciousness: lateral position - call a physician.
After skin contact
Immediately remove all contaminated clothing. Wash away with soap and water and rinse. Do NOT use solvents or thinners.
After eye contact
Remove contact lenses, keep eyelids open. Flush with plenty of water (10 - 15 min.). Call a physician.
After ingestion
Contact a doctor immediately. Keep at rest. Do not induce vomiting.
05. Fire-fighting measures
Suitable extinguishing media
Alcohol resistant foam, CO2, powders, water spray.
Unsuitable extinguishing media
Waterjet.
Special risk posed by the substance or by the actual preparation, its combustion
products or gases discharged
Fire will produce dense black smoke. Exposure to decomposition products may cause a health hazard.
Special protective equipment
Appropriate breathing apparatus may be required.
Additional information
Cool endangered containers with water in case of fire. Do not allow the quenching water into the sewage system.
06. Accidental release measures
Personal precautions
Provide for sufficient ventilation. Do not inhale the vapour. Refer to protective measures listed in sections 7 and 8.
Environmental precautions
Do not empty into drains. If the product contaminates lakes, rivers or sewages, inform appropriate authorities in accordance
with local regulations.
Page : 2 / 8
Material Safety Data Sheet
according to 91/155/EEC
Product name : MASTERTOP P 605, COMP B (CONIPOX 605)
605_B
Revision : 07.07.2006 Version : 6.0.0
Print date : 24.07.2006
Methods for cleaning up/collecting
Contain and collect spillage with non-combustible absorbent materials, e.g. sand, earth, vermiculite, diatomaceous earth and
place in container for disposal according to local regulations (see section 13). Clean preferabily with a detergent; avoid use of
solvents. Provide for sufficient ventilation.
07. Handling and storage
Information for safe handling
Avoid contact with skin and eyes. Do not inhale the vapour. Do not eat or drink during work - no smoking. Comply with the
health and safety at work laws. Provide for fresh air ventilation.
Requirements to be met by storerooms and containers
Containers should be kept dry and sealed. Containers which are opened must be carefully resealed and kept upright to prevent
leakage.
Information about separation of incompatible products
Keep away from oxidizing agents, from strongly alkaline and strongly acid materials.
Further information about storage conditions
Always keep in containers of same material as the original one. See also instructions on the label. Avoid heating and direct
sunlight.
Storage class (VCI) : 8
08. Exposure controls and personal protection
Additional information about engineering measures
Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and
good general extraction. If these are not sufficient to maintain concentrations of particulates and solvent vapour below the
OEL (=Occupational Exposure Limit) , suitable respiratory protection must be worn.
Personal protective equipment
Respiratory protection
If workplace limits are exceeded, a gas mask approved for this purpose must be worn. Provide for fresh air ventilation.
Hand protection
Butylrubber >= 0,5mm >= 480 min. After washing hands replace lost skin fat by fat containing skin creams. By using other
gloves with a lower endurance, change them more often.
Eye protection
Use safety glasses.
Body protection
Light protective clothing.
09. Physical and chemical properties
Image
Form : Liquid.
Colour : Colourless.
Odour : Like amine. Ammonia
Relevant safety data
Boiling point / range : ( 1013 hPa ) no data available
Flash point : > 100 掳C DIN 53213
Page : 3 / 8
Material Safety Data Sheet
according to 91/155/EEC
Product name : MASTERTOP P 605, COMP B (CONIPOX 605)
605_B
Revision : 07.07.2006 Version : 6.0.0
Print date : 24.07.2006
Vapour pressure : ( 50 掳C ) no data available
g/cm3
Density : ( 20 掳C ) 1,01
Solvent-separation test : ( 20 掳C ) inapplicable
Viscosity : ( 20 掳C ) 310 mPa.s
10. Stability and reactivity
Conditions to avoid
Stable under recommended storage and handling conditions(See section 7).
Materials to avoid
Keep away from oxidizing agents, strongly alkaline and strongly acid materials in order to avoid exothermic reactions.
Exothermic reactions with isocyanates and epoxide resin.
Hazardous decomposition products
Corrosive gases / vapours. Ammonia When exposed to high temperatures may produce hazardous decomposition products
such as carbon monoxide and dioxide, smoke, oxides of nitrogen.
11. Toxicological information
Experience on practice
Prolonged inhalation of vapours in high concentrations may lead to headache, giddiness and nausea. The product causes skin
corrosions,and it causes serious damage to eyes.
Additional toxicological information
The product was classified in toxicological terms on the basis of the results of the calculation procedure outlined within General
Directive on Preparations (1999/45/EC). Danger of irritation to eyes, nose, throat and the air passages.
12. Ecological information
Details on elimination (persistance / degradibility)
Biological degradiation / elimination
Specification : Biodegradadtion ( 3-AMINOMETHYL-3,5,5-TRIMETHYLCYCLOHEXYLAMINE ; CAS-No. :
2855-13-2 )
Value / dosage : 8%
Testing method : EEC C.4-A(DOC)
Ecotoxical effects
Aquatic toxicity
Specification : Toxicity to fish ( BENZYL ALCOHOL ; CAS-No. : 100-51-6 )
Parameters : LC 50
Pimephales promelas
Value / dosage : 460 mg/l
Test-period : 96 h
Specification : Toxicity to fish ( BENZYL ALCOHOL ; CAS-No. : 100-51-6 )
Parameters : LC 50
Lepomis macrochirus
Value / dosage : 27 mg/l
Test-period : 96 h
Specification : Toxicity to daphnia ( BENZYL ALCOHOL ; CAS-No. : 100-51-6 )
Parameters : EC50
Species: Daphnia magna Straus 1820
Page : 4 / 8
Material Safety Data Sheet
according to 91/155/EEC
Product name : MASTERTOP P 605, COMP B (CONIPOX 605)
605_B
Revision : 07.07.2006 Version : 6.0.0
Print date : 24.07.2006
Value / dosage : 400 mg/l
Test-period : 24 h
Specification : Toxicity to algae ( BENZYL ALCOHOL ; CAS-No. : 100-51-6 )
Parameters : EC50
Scenedesmus subspicatus
Value / dosage : 640 mg/l
Test-period : 96 h
Specification : Toxicity to fish ( 3-AMINOMETHYL-3,5,5-TRIMETHYLCYCLOHEXYLAMINE ; CAS-No. :
2855-13-2 )
Parameters : LC 50
Brachydanio rerio
Value / dosage : 70 mg/l
Test-period : 96 h
Testing method : EC 84/449
Specification : Toxicity to daphnia ( 3-AMINOMETHYL-3,5,5-TRIMETHYLCYCLOHEXYLAMINE ; CAS-No.
: 2855-13-2 )
Parameters : EC50
Species: Daphnia magna Straus 1820
Value / dosage : 44 mg/l
Test-period : 24 h
Specification : Toxicity to daphnia ( 3-AMINOMETHYL-3,5,5-TRIMETHYLCYCLOHEXYLAMINE ; CAS-No.
: 2855-13-2 )
Parameters : NOEC
Species: Daphnia magna Straus 1820
Value / dosage : 3 mg/l
Test-period : 504 h
Testing method : OECD 202 part 2
Specification : Toxicity to algae ( 3-AMINOMETHYL-3,5,5-TRIMETHYLCYCLOHEXYLAMINE ; CAS-No. :
2855-13-2 )
Parameters : EC50
Scenedesmus subspicatus
Value / dosage : 37 mg/l
Test-period : 72 h
Testing method : EC 88/302
Specification : Toxicity to algae ( 3-AMINOMETHYL-3,5,5-TRIMETHYLCYCLOHEXYLAMINE ; CAS-No. :
2855-13-2 )
Parameters : NOEC
Scenedesmus subspicatus
Value / dosage : 1,5 mg/l
Test-period : 72 h
Testing method : EC 88/302
Specification : Toxicity to fish ( 2,4,6-TRIS(DIMETHYLAMINOMETHYL)PHENOL ; CAS-No. : 90-72-2 )
Parameters : LC 50
Species: Trout
Value / dosage : 222 mg/l
Test-period : 24 h
Toxicity to bacteria
Specification : Toxicity to bacteria ( 3-AMINOMETHYL-3,5,5-TRIMETHYLCYCLOHEXYLAMINE ; CAS-No.
: 2855-13-2 )
Page : 5 / 8
Material Safety Data Sheet
according to 91/155/EEC
Product name : MASTERTOP P 605, COMP B (CONIPOX 605)
605_B
Revision : 07.07.2006 Version : 6.0.0
Print date : 24.07.2006
Parameters : EC10
Pseudomonas putida
Value / dosage : 1120 mg/l
Test-period : 18 h
Additional ecological information
General ecological information
Do not empty into waters or drains.
13. Disposal considerations
Contaminated packaging must be emptied of all residues and, following appropriate cleaning, may be sent to a recycling plant.
Uncleaned packaging must be disposed of in the same manner as the medium.
Product
Waste key
According to the actual waste legislation it is not possible for us to give the waste code because it depends on the application
of the product that we do not know here. If you need some help to determine this code, please ask your executives. Disposal
Code according to European Waste Catalog (EWC) please specify according to the use of product, e.g.: 080111* Waste from
production, formulation, sales and application of paints and varnishes. Old paints and varnishes, containing organic solvents or
some other dangerous product.
14. Transport information
Land transport ADR/RID
Classification
Class : 8 Kemlercode : 80
Substance number : 2735 Classification-Code : C7
LQ19
Proper shipping name
AMINE, LIQUID, CORROSIVE, N.O.S.
Hazardous components
M-PHENYLENEBIS(METHYLAMINE)
Packaging
Packaging group : III
Label : 8
Maritime transport IMDG/GGVSea
Classification
IMDG-Code : 8 EmS number : F-A / S-B
UN number : 2735 Marine Poll. : -
LQ 5 l
Proper shipping name
AMINE, LIQUID, CORROSIVE, N.O.S.
Hazardous components
M-PHENYLENEBIS(METHYLAMINE)
Packaging
Packaging group : III
Label : 8
Page : 6 / 8
Material Safety Data Sheet
according to 91/155/EEC
Product name : MASTERTOP P 605, COMP B (CONIPOX 605)
605_B
Revision : 07.07.2006 Version : 6.0.0
Print date : 24.07.2006
Air transport ICAO-TI and IATA-DGR
Classification
Class : 8
UN number : 2735
Proper shipping name
AMINE, LIQUID, CORROSIVE, N.O.S.
Hazardous components
M-PHENYLENEBIS(METHYLAMINE)
Packaging
Packaging group : III
Label : 8
15. Regulatory information
Classification according to EC directives
Danger symbol and danger designation
C ; Corrosive
Hazard-determining components of labelling
M-PHENYLENEBIS(METHYLAMINE) ; CAS-No. : 1477-55-0
CYCLOHEX-1,2-YLENEDIAMINE ; CAS-No. : 694-83-7
3-AMINOMETHYL-3,5,5-TRIMETHYLCYCLOHEXYLAMINE ; CAS-No. : 2855-13-2
POLYOXYPROPYLEN DIAMINE ; CAS-No. : 9046-10-0
R-phrases
34 Causes burns.
43 May cause sensitisation by skin contact.
20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
S-phrases
1/2 Keep locked up and out of the reach of children.
35 This material and its container must be disposed of in a safe way.
51 Use only in well-ventilated areas.
36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
46 If swallowed, seek medical advice immediately and show this container or lable.
64 If swallowed, rinse mouth with water (only if the person is conscious).
28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer).
45 In case of accident or if you feel unwell, seek medical advice immediately (show the lable where
possible).
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
National regulatory information
Germany: Safety Instruction Code of german occupational safety and health organisation. Berufsgenossenschaften der
Bauwirtschaft: GISCODE RE 1
Regulation on inflammable liquids (VbF)
VbF-Class : Not dangerous according to VbF
Emission control act ("TA-Luft")
Page : 7 / 8
Material Safety Data Sheet
according to 91/155/EEC
Product name : MASTERTOP P 605, COMP B (CONIPOX 605)
605_B
Revision : 07.07.2006 Version : 6.0.0
Print date : 24.07.2006
Sum organic substances class I : 10 - 15 %
Water pollution classification
Class : 2 according VwVwS
Other regulations
Please refer to guidline M 004 "Irritant/Corrosive Chemicals" BG Chemie! (DE)
16. Other information
Further information
We have no knowledge or control over the user麓s working conditions however. The product may not be used for any purpose
other than that specified in chapter 16 unless written consent has been obtained. The user is responsible for the observance of
all required statutory provisions.
Relevant changes
08. Components with critical values that require monitoring at the workplace (exposure limits) 路 14. Land transport ADR/RID
and GGVS/GGVE 路 14. Classification (ADR) 路 14. Proper shipping name (ADR) 路 14. Substance releasing the danger (ADR) 路 14.
Maritime transport IMDG/GGVSea 路 14. Classification (IMDG) 路 14. Proper shipping name (IMDG) 路 14. Substance releasing the
danger (IMDG) 路 14. Air transport ICAO-TI and IATA-DGR 路 14. Proper shipping name (ICAO) 路 14. Substance releasing the
danger (ICAO) 路 15. Hazard-determining components of labelling 路 15. R-phrases
R-Phrases of components
20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
20/22 Harmful by inhalation and if swallowed.
21/22 Harmful in contact with skin and if swallowed.
22 Harmful if swallowed.
34 Causes burns.
36/38 Irritating to eyes and skin.
43 May cause sensitisation by skin contact.
52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Department issuing data sheet
BASF Construction Chemicals Bussiness Line Performance Flooring.
Contact
R. Burgos / C. Schmidt
These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and
shall not establish a legally valid contractual relationship.
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