MATERIAL SAFETY DATA SHEET UPDATES AVAILABLE AT WWW.GREENBOOK.NET 1
Dow AgroSc iences
UFL: 14.5% @ 80掳C approved positive-pressure self-contained breathing
TELONE* E.C. SOIL apparatus or positive-pressure air line with auxiliary
EXTINGUISHING MEDIA: Water spray, foam, alco-
FUMIGANT self-contained air supply. In confined or poorly venti-
hol foam, CO2, dry chemical.
lated areas, use a NIOSH approved self-contained
FIRE AND EXPLOSION HAZARDS: Toxic, irritating
Emergency Phone: 800-992-5994 breathing apparatus or positive pressure airline with
vapors may occur under fire conditions. Keep vapors
Dow AgroSciences LLC auxiliary self- contained air supply.
away from possible ignition sources.
Indianapolis, IN 46268 APPLICATORS AND ALL OTHER HANDLERS:
FIRE-FIGHTING EQUIPMENT: Use positive-pres-
Effective Date: 16-Mar-07 Refer to the product label for personal protective
sure, self-contained breathing apparatus and special
Product Code: 46005 clothing and equipment.
protective clothing, including heavy neoprene or rub-
MSDS: 005615 ber boots and neoprene gloves.
9. PHYSICAL AND CHEMICAL PROPERTIES:
1. PRODUCT AND COMPANY IDENTIFICATION: 6. ACCIDENTAL RELEASE MEASURES: BOILING POINT: Approximately 220掳F, 104掳C
PRODUCT: Telone* E.C. Soil Fumigant SOLUBILITY IN WATER: Approximately 0.1%
ACTION TO TAKE FOR SPILLS/LEAKS: If it can be
COMPANY IDENTIFICATION: SPECIFIC GRAVITY: 1.20 @ 25掳C, 77掳F
done safely, invert or reposition the leaking container
Dow AgroSciences LLC VAPOR PRESSURE: 28 mm/Hg @ 20掳C, 68掳F
of Telone EC so that the area with the leak is up and
9330 Zionsville Road the flow is reduced. If possible, put the container into APPEARANCE: Light to straw-amber colored liquid
Indianapolis, IN 46268-1189 an overpak. Cover or confine the leakage with an ODOR: Pungent, sweet penetrating odor
absorbent such as diatomaceous earth, clay, sand, or
2. HAZARDOUS IDENTIFICATIONS: 10. STABILITY AND REACTIVITY:
other non-combustible absorbent material. Collect
EMERGENCY OVERVIEW the spent absorbent material in a disposal drum. If STABILITY (CONDITIONS TO AVOID): May form
Light to straw-amber colored liquid with a pungent the spill is on the ground, dig up enough of the soil to explosive mixtures with air when confined.
odor. May cause severe eye irritation with cor neal eliminate the contamination and place the soil in a INCOMPATIBILITY (SPECIFIC MATERIALS TO
injury. May cause skin irritation, even a burn. Toxic to disposal drum. Report large spills to Dow AVOID): Corrosive to some metals. Do not use con-
aquatic organisms. Regulated under PMN 88-608. AgroSciences at 800-992-5994. tainers or equipment containing aluminum, magne-
EMERGENCY PHONE NUMBER: 800-992-5994 sium, zinc, cadmium, or their alloys. Avoid strong
7. HANDLING AND STORAGE:
bases.
3. COMPOSITION/INFORMATION ON
PRECAUTIONS TO BE TAKEN IN HANDLING AND HAZARDOUS DECOMPOSITION PRODUCTS:
INGREDIENTS:
STORAGE: Hydrogen chloride and other toxic, irritating gases
HANDLING: Keep out of reach of children. The use of
Component CAS Number W/W% may be formed if product is involved in fire.
this product may be hazardous to your health. This
1,3-Dichloropropylene 542-75-6 93.6 HAZARDOUS POLYMERIZATION: Not known to
product contains 1,3-dichloropropene, which has
CIS Isomer 10061-01-5 occur.
been deter mined to cause tumors in laboratory ani-
TRANS Isomer 10061-02-6
11. TOXICOLOGICAL INFORMATION:
mals. Risks can be reduced by exactly following
Balance 6.4
directions for use, precautionary statements, and by POTENTIAL HEALTH EFFECTS: This section
4. FIRST AID: wearing the personal protective equipment specified includes possible adverse effects, which could occur
on the label.
EYE: Wash immediately and continuously with flow- if this material is not handled in the recommended
STORAGE: Store in tightly closed original container
ing water for at least 30 minutes. Remove contact manner.
in a cool place away from dwellings. Do not allow con-
lenses after the first 5 minutes and continue washing. EYE: May cause severe eye irritation with cor neal
tamination of seeds, plants, fer tilizers or other pesti-
Obtain prompt medical consultation, preferably from injury, which may result in per manent impair ment of
cide chemicals. Do not contaminate food, feedstuffs,
an ophthalmologist. vision, even blindness. Chemical burns may occur.
drugs, or domestic water supplies.
SKIN: Take off contaminated clothing. Wash skin with Vapor may cause lacrimation (tears). Vapor may
soap and plenty of water for 15-20 minutes. Call a poi- cause eye irritation experienced as mild discomfort
8. EXPOSURE CONTROLS/PERSONAL
son control center or doctor for treatment advice. and redness.
PROTECTION:
Wash clothing before reuse. Shoes and other leather SKIN: Brief contact may cause skin irritation with
These precautions are suggested for conditions
items which cannot be decontaminated should be local redness. Prolonged or repeated exposure may
where a potential for exposure exists. Emergency
disposed of properly. cause skin irritation, even a burn. Prolonged or wide-
conditions may require additional precautions.
INGESTION: Call a poison control center or doctor spread skin contact may result in absorption of harm-
EXPOSURE GUIDELINES:
immediately for treatment advice. Have person sip a ful amounts. The LD50 for skin absorption in rabbits
1,3-Dichloropropene: ACGIH TLV is 1 ppm, Skin, A3.
glass of water if able to swallow. Do not induce vomit- for similar material is 333 mg/kg. Animal data indicate
A 鈥榮kin鈥? notation following the exposure guideline
ing unless told to do so by the poison control center or that 1,3-Dichloropropene is a potential skin
refers to the potential for der mal absorption of the
doctor. Never give anything by mouth to an uncon- sensitizer.
material including mucous membranes and the eyes
scious person. INGESTION: Moderate toxicity if swallowed. Based
either by contact with vapors or by direct skin contact.
INHALATION: Move person to fresh air. If person is on infor mation for a similar material, the oral LD50 for
It is intended to alert the reader that inhalation may
not breathing, call an emergency responder or ambu- rats is expected to be >224 mg/kg. Small amounts
not be the only route of exposure and that measues
lance, and then give artificial respiration; if by mouth swallowed incidental to nor mal handling operations is
to minimize der mal exposures should be considered.
to mouth use rescuer protection (pocket mask, etc.). not likely to cause injury; however, swallowing larger
ENGINEERING CONTROLS: Provide general and/
If breathing is difficult, oxygen should be adminis- amounts may cause serious injury, even death. Aspi-
or local exhaust ventilation to control airborne levels
tered by qualified personnel. ration into the lungs may occur during ingestion or
below the exposure guidelines. Lethal concentrations
NOTE TO PHYSICIAN: Because rapid absorption vomiting, resulting in rapid absorption and injury to
may exist in areas with poor ventilation.
may occur through the lungs if aspirated and cause other body systems.
systemic effects, the decision of whether to induce RECOMMENDATIONS FOR MANUFACTURING, INHALATION: Easily attainable vapor concentra-
vomiting or not should be made by a physician. If COMMERCIAL BLENDING, AND PACKAGING tions may cause serious adverse effects, even death.
lavage is performed, suggest endotracheal and/or Excessive exposure may cause headache, dizziness,
WORKERS:
esophageal control. Danger from lung aspiration anesthesia, drowsiness, unconsciousness, and other
EYE/FACE PROTECTION: Use chemical goggles.
must be weighed against toxicity when considering central ner vous system effects, including death.
Eye wash fountain should be located in the immedi-
emptying the stomach. Respiratory symptoms, Excessive exposure may cause irritation to upper
ate work area. If exposure causes eye discomfort,
including pulmonary edema, may be delayed. Per- respiratory tract (nose and throat) and lungs.
use a NIOSH approved full-face respirator.
sons receiving significant exposure should be SYSTEMIC (OTHER TARGET ORGAN) EFFECTS:
SKIN PROTECTION: Use protective clothing chemi-
observed 24-48 hours for signs of respiratory dis- Effects have been reported on the following organs:
cally resistant to this material. Selection of specific
tress. Maintain adequate ventilation and oxygenation bladder, blood, kidney, liver, respiratory tract and
items such as faceshield, gloves, boots, apron, or full
of the patient. Excessive exposure may aggravate stomach.
body suit will depend on operation. Safety shower
pre-existing lung, liver, and kidney disease. No spe- CANCER INFORMATION: 1,3-Dichloropropene is
should be located in the immediate work area.
cific antidote. Treatment of exposure should be listed as a potential carcinogen for hazard communi-
Remove contaminated clothing immediately, wash
directed at the control of symptoms and the clinical cation pur poses under OSHA Standard 29 CFR
skin area with soap and water, and launder clothing
condition of the patient. Have the MSDS, and if avail- 1910.1200. 1,3-Dichloropropene has been shown to
before reuse. Items, which cannot be decontami-
able, the product container or label with you when cause cancer in laboratory animals by the oral route.
nated, such as shoes, belts, and watchbands, should
calling a poison control center or doctor, or going for Inhalation exposure resulted in an increase in the
be removed and disposed of properly.
treatment. nor mal occurrence of benign lung tumors in male
RESPIRATORY PROTECTION: Atmospheric levels
mice.
should be maintained below the exposure guideline.
5. FIRE FIGHTING MEASURES:
(BIRTH DEFECTS): 1,3-
TERATOLOGY
When respiratory protection is required use a NIOSH
FLASH POINT: 83掳F (28掳C) Dichloropropene did not cause birth defects or any
approved self-contained breathing apparatus or posi-
METHOD USED: TCC other fetal effects in laboratory animals.
tive pressure airline with auxiliary self-contained air
FLAMMABLE LIMITS: supply. For emergency and conditions where the REPRODUCTIVE EFFECTS: 1,3-Dichloropropene
LFL: 5.3% @ 80掳C exposure guideline may be exceeded, use a NIOSH did not interfere with reproduction in animal studies.
Database and format copyright 漏 by Vance Communication Corporation. All rights reserved.
MATERIAL SAFETY DATA SHEET UPDATES AVAILABLE AT WWW.GREENBOOK.NET 2
A fire hazard
MUTAGENICITY (EFFECTS ON GENETIC MATE-
CALIFORNIA PROPOSITION 65: The following
For the active ingredient, 1,3-
RIAL):
statement is made in order to comply with the Califor -
Dichloropropene, in-vitro genetic toxicity studies
nia Safe Drinking Water and Toxic Enforcement Act of
were negative in some cases and positive in other
1986: This product contains a chemical(s) known to
cases. Animal genetic toxicity studies were negative.
the State of Califor nia to cause cancer. The chemical
12. ECOLOGICAL INFORMATION: is 1,3-Dichloropropene (CAS # 542-75-6)
CONSENT ORDER FOR PMN (UNITED STATES)
ENVIRONMENTAL FATE:
In the United States, a component of this material,
MOVEMENT & PARTITIONING:
cis-1,3-dichloro-propene (DR-0019-3180), was
Based largely or completely on data for major compo-
reviewed by the Environmental Protection Agency
nent(s).
under PMN 88-608. There was no resulting consent
Potential for mobility in soil is very high (Koc is
order. However, EPA is concerned that, based on an
between 0 and 50).
analogous chemical structure, this PMN material
Bioconcentration potential is low (BCF <100 or
may cause oncogenicity, mutagenicity, neurotoxicity,
Log Pow <3).
and developmental toxicity and may result in unrea-
DEGRADATION & PERSISTENCE:
sonable risk to unprotected workers. The EPA
Based largely or completely on data for a similar
strongly recommends that, to mitigate inhalation
material.
exposure, workers should wear a NIOSH approved
Degradation is expected in the atmospheric envi-
respirator and to mitigate der mal exposure, should
ronment within days to weeks.
wear adequate protective clothing which covers any
ECOTOXICOLOGY:
exposed parts of the body, imper vious gloves, and
Based largely or completely on data for a similar
chemical safety goggles or equivalent.
material.
TOXIC SUBSTANCES CONTROL ACT (TSCA): All
Material is highly toxic to aquatic organisms on an
ingredients are on the TSCA inventory or are not
acute basis (LC50 or EC50 is between 0.1 and 1
required to be listed on the TSCA inventory.
mg/L in the most sensitive species tested).
STATE RIGHT-TO-KNOW: The following product
components are cited on cer tain state lists as men-
13. DISPOSAL CONSIDERATIONS:
tioned. Non-listed components may be shown in the
DISPOSAL METHOD: If wastes and/or containers
composition section of the MSDS.
cannot be disposed of according to the product label
directions, disposal of this material must be in accor- CHEMICAL NAME CAS NUMBER LIST
dance with your local or area regulatory authorities. 1,3-Dichloropropylene 542-75-6 NJ1 NJ2 NJ3
PA1 PA2 PA3
This infor mation presented below only applies to the
material as supplied. The identification based on NJ1=New Jersey Special Health Hazard Substance
character istic(s) or listing may not apply if the mate- (present at greater than or equal to 0.1%).
rial has been used or otherwise contaminated. It is NJ2=New Jersey Environmental Hazardous Sub-
the responsibility of the waste generator to deter mine stance (present at greater than or equal to 1.0%).
the toxicity and physical proper ties of the material NJ3=New Jersey Workplace Hazardous Substance
generated to deter mine the proper waste identifica- (present at greater than or equal to 1.0%).
tion and disposal methods in compliance with PA1=Pennsylvania Hazardous Substance (present at
applicable regulations. greater than or equal to 1.0%).
If the material as supplied becomes a waste, follow all PA2=Pennsylvania Special Hazardous Substance
applicable regional, national and local laws and regu- (present at greater than or equal to 0.01%).
lations. PA3=Pennsylvania Environmental Hazardous Sub-
stance (present at greater than or equal to 1.0%).
14. TRANSPORT INFORMATION:
OSHA HAZARD COMMUNICATION STANDARD:
U.S. DEPARTMENT OF TRANSPORTATION (DOT) This product is a 鈥淗azardous Chemical鈥? as defined by
INFORMAITON: the OSHA Hazard Communication Standard, 29 CFR
FOR ALL PACKAGE SIZES: DO NOT SHIP BY AIR 1910.1200.
For package sizes shipped by land or water: NATIONAL FIRE PROTECTION ASSOCIATION
PESTICIDES, LIQUID, TOXIC, FLAMMABLE, N.O.S. (NFPA) RATINGS:
(1,3-DICHLOROPROPENE)/6.1(3)/UN2903/PGII/
Health 3
RQ (1,3-DICHLOROPROPENE).
Flammability 3
Reactivity 0
15. REGULATORY INFORMATION:
NOTICE: The infor mation herein is presented in good COMPREHENSIVE ENVIRONMENTAL
faith and believed to be accurate as of the effective RESPONSE COMPENSATION AND LIABILITY
date shown above. However, no warranty, express or ACT (CERCLA, or SUPERFUND): This product con-
implied, is given. Regulatory requirements are sub- tains the following substance(s) listed as 鈥淗azardous
ject to change and may differ from one location to Substances鈥? under CERCLA, which may require
another; it is the buyer鈥檚 responsibility to ensure that reporting of releases:
its activities comply with federal, state or provincial,
Chemical Name CAS# RQ % in Product
and local laws. The following specific infor mation is
1,3-Dicloropropene 542-75-6 100 lb. 93.6
made for the pur pose of complying with numerous
federal, state or provincial, and local laws and
16. OTHER INFORMATION:
regulations.
MSDS STATUS:
U.S. REGULATIONS
Revised Sections: 2 & 3
SARA 313 INFORMATION: This product contains
Reference: DR-0354-7420
the following substances subject to the reporting
Replaces MSDS Dated: 3/30/04
requirements of Section 313 of Title III of the
Document Code: D03-017-008
Superfund Amendments and Reauthorization Act of
Replaces Document Code: D03-017-007
1986 and 40 CFR Part 372:
The Infor mation Herein Is Given In Good Faith, But
CHEMICAL NAME CAS NUMBER CONCENTRATION No Warranty, Express or Implied, Is Made. Consult
1,3-Dichloropropene 542-75-6 93.6% Dow AgroSciences for Fur ther Infor mation.
TRANS-1,3-D 10061-02-6 藴43.0% *Trademark of Dow AgroSciences LLC VID 3.20.07
SARA HAZARD CATEGORY: This product has been
reviewed according to the EPA 鈥淗azard Categories鈥?
promulgated under Sections 311 and 312 of the
Superfund Amendment and Reauthorization Act of
1986 (SARA Title III) and is considered, under appli-
cable definitions, to meet the following categories:
An immediate health hazard
A delayed health hazard
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