World Headquarters Page 1
Hach Company Date Printed 1/12/06
P.O.Box 389 MSDS No: M00309
Loveland, CO USA 80539
(970) 669-3050
SAFETY DATA SHEET
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1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name: Calmagite
Catalog Number: 82522
HACH LANGE GmbH Emergency Telephone Numbers:
Willst盲tterstrasse 11 (Poison Information Center Main)
40549 D眉sseldorf, Germany (+49 (0) 6131 19240) 24 HR
+49-(0)211-52880
SDS Number: M00309
Chemical Name: 3-Hydroxy-4((2-hydroxy-5-methyl-phenyl)azo)-1-naphthalenesulfonic Acid, Monohydrate
Chemical Formula: C17H14N2O5S.H2O
Chemical Family: Organic Acid
Use of the substance/preparation: Indicator for calcium Indicator for Magnesium.
CAS No.: 3147-14-6
Hazard: May cause irritation.
Date of MSDS Preparation:
Day: 12
Month: 01
Year: 2006
Additional Emergency Response Numbers: Austria: +49 (0)6131 19240, Belgium: +32-(0)70-245245, France: +33-
(0)1-40370404, Italy: +39-02-66101029, Netherlands: +31-(0)30-2748888, Switzerland: +41-(0)1-2515151
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2. COMPOSITION / INFORMATION ON INGREDIENTS
Impurities
EEC Number: Not applicable
CAS No.: Not applicable
Percent Range: <40
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established.
PEL: Not established.
EU Occupational Exposure Limits: Not established
Calmagite
EEC Number: 2215630
CAS No.: 3147-14-6
Percent Range: >60
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
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3. HAZARDS IDENTIFICATION
Emergency Overview:
Appearance: Black powder
Odor: Not determined
World Headquarters Page 2
Hach Company Date Printed 1/12/06
P.O.Box 389 MSDS No: M00309
Loveland, CO USA 80539
(970) 669-3050
EU Symbols: Not applicable
R PHRASES: Not applicable
Protective Equipment:
Potential Health Effects:
Eye Contact (EC): None reported
Skin Contact (EC): No effects are anticipated
Skin Absorption (EC): None Reported
Target Organs (SA E): None Reported
Ingestion (EC): None reported
Target Organs (Ing E): None Reported
Inhalation: May cause: irritation of nose and throat
Target Organs (Inh E): None Reported
Medical Conditions Aggravated: None reported
Chronic Effects: None reported
Cancer / Reproductive Toxicity Information:
This product does NOT contain any IARC listed chemicals.
Additional Cancer / Reproductive Toxicity Information: an experimental carcinogen. Azo dye compounds have
produced tumors in laboratory animals. Azo dye exposure has produced no known cases of cancer in humans.
Casarett and Doull's Toxicology, 2nd ed. page 96-97.
Toxicologically Synergistic Products: None reported
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4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.
Skin Contact (First Aid): Wash skin with soap and plenty of water.
Ingestion (First Aid): Give large quantities of water. Call physician immediately.
Inhalation: Remove to fresh air.
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5. FIRE FIGHTING MEASURES
Flammable Properties: Can burn in fire, releasing toxic vapors.
Hazardous Combustion Products: Toxic fumes of: carbon monoxide, carbon dioxide. nitrogen oxides. sulfur oxides.
Fire / Explosion Hazards: May react violently with: oxidizers
Static Discharge: None reported.
Mechanical Impact: None reported
Extinguishing Media: Use media appropriate to surrounding fire conditions
Extinguishing Media NOT To Be Used: Not applicable
Fire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand and full protective
gear.
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6. ACCIDENTAL RELEASE MEASURES
Spill Response Notice:
Only persons properly qualified to respond to an emergency involving hazardous substances should respond to a spill
involving chemicals. See Section 13, Special Instructions for disposal assistance.
Containment Technique: Stop spilled material from being released to the environment.
Clean-up Technique: Never put unreacted azides down the drain! Work in an approved fume hood. Sweep up material.
Dilute material with excess water making a weaker than 5% solution. Add an excess of aqueous sodium nitrate. Slowly
acidify the solution with sulfuric acid. Nitrogen oxide gas will evolve until the reaction is complete. Test for complete
reaction with starch-iodine paper, it should turn blue. Flush reacted material to the drain with a large excess of water.
Decontaminate the area of the spill with a soap solution.
Evacuation Procedure: Evacuate as needed to perform spill clean-up. If conditions warrant, increase the size of the
evacuation.
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7. HANDLING AND STORAGE
World Headquarters Page 3
Hach Company Date Printed 1/12/06
P.O.Box 389 MSDS No: M00309
Loveland, CO USA 80539
(970) 669-3050
Handling: Avoid contact with eyes clothing Do not breathe dust. Wash thoroughly after handling. Maintain general
industrial hygiene practices when using this product.
Storage: Protect from: heat Store away from: oxidizers
Special Packaging Instructions: Not applicable
Use of the substance/preparation: Indicator for calcium Indicator for Magnesium.
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8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT
Engineering Controls: Maintain general industrial hygiene practices when using this product.
Personal Protective Equipment:
Eye Protection: safety glasses with top and side shields
Skin / Hand Protection: disposable latex gloves lab coat
Inhalation Protection: adequate ventilation
Precautionary Measures: Avoid contact with: eyes clothing Do not breathe: dust Wash thoroughly after handling.
Protect from: heat
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
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9. PHYSICAL / CHEMICAL PROPERTIES
Appearance: Black powder
Physical State: Solid
Odor: Not determined
pH: Not determined
Vapor Pressure: Not applicable
Vapor Density (air = 1): Not applicable
Boiling Point: Not applicable
Melting Point: 330 掳C (626 掳F)
Flash Point: Not applicable
Method: Not applicable
Autoignition Temperature: Not determined
Flammability Limits:
Lower Explosion Limits: Not applicable
Upper Explosion Limits: Not applicable
Specific Gravity (water = 1): Not determined
Evaporation Rate (water = 1): Not applicable
Volatile Organic Compounds Content: Not determined
Partition Coefficient (n-octanol / water): 2,24
Solubility:
Water: Soluble
Acid: Soluble
Other: Not determined
Metal Corrosivity:
Steel: Not determined
Aluminum: Not determined
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10. STABILITY / REACTIVITY
Chemical Stability: Stable when stored under proper conditions.
Conditions to Avoid: Extreme temperatures
Reactivity / Incompatibility: May react violently in contact with: oxidizers
Hazardous Decomposition: Heating to decomposition releases: carbon dioxide carbon monoxide nitrogen oxides sulfur
oxides
Hazardous Polymerization: Will not occur.
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11. TOXICOLOGICAL INFORMATION
World Headquarters Page 4
Hach Company Date Printed 1/12/06
P.O.Box 389 MSDS No: M00309
Loveland, CO USA 80539
(970) 669-3050
Product Toxicological Data:
LD50: Oral rat LD50> 5000 mg/kg
LC50: None reported
Dermal Toxicity Data: None reported
Skin and Eye Irritation Data: None reported
Mutation Data: None reported
Reproductive Effects Data: None reported
--
Ingredient Toxicological Data: Not applicable
This product does NOT contain any IARC listed chemicals.
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12. ECOLOGICAL INFORMATION
Product Ecological Information: No information available on this product.
Ingredient Ecological Information: Not applicable
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13. DISPOSAL CONSIDERATIONS
NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stringent
state or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemical
and analysis solutions must be disposed of in compliance with the respective national regulations. Product packaging must
be disposed of in compliance with the country-specific regulations or must be passed to a packaging return system.
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14. TRANSPORT INFORMATION
I.C.A.O.:
I.C.A.O. Proper Shipping Name: Not Currently Regulated
--
ICAO Hazard Class: NA
ICAO Subsidiary Risk: NA
ICAO UN/ID Number: NA
ICAO Packing Group: NA
I.M.O.:
I.M.O. Proper Shipping Name: Not Currently Regulated
--
I.M.O. Hazard Class: NA
I.M.O. Subsidiary Risk: NA
I.M.O. UN Number: NA
I.M.O. Packing Group: NA
A.D.R.:
A.D.R. Proper Shipping Name: Not Currently Regulated
--
A.D.R Hazard Class: NA
A.D.R. Subsidiary Risk: NA
A.D.R. UN-Number:: NA
A.D.R. Packing Group: NA
Additional Information: This product may be shipped as part of a chemical kit composed of various compatible
dangerous goods for analytical or testing purposes. This kit would have the following classification: Proper Shipping
Name: Chemical Kit Hazard Class: 9 UN Number 3316
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15. REGULATORY INFORMATION
National Inventories:
EEC Inventory Status: EINECS Listed: Yes
World Headquarters Page 5
Hach Company Date Printed 1/12/06
P.O.Box 389 MSDS No: M00309
Loveland, CO USA 80539
(970) 669-3050
EEC Number: 2215630
EEC LABEL COPY:
EU Symbols: Not applicable
R PHRASES: Not applicable
S PHRASES: Not applicable
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16. OTHER INFORMATION
References: TLV's Threshold Limit Values and Biological Exposure Indices for 1992-1993. American Conference of
Governmental Industrial Hygienists, 1992. The Merck Index, 11th Ed. Rahway, New Jersey: Merck and Co., Inc., 1989.
In-house information. Technical Judgment. Air Contaminants, Federal Register, Vol. 54, No. 12. Thursday, January 19,
1989. pp. 2332-2983. Outside Testing.
R PHRASES: Not applicable
Use of the substance/preparation: Indicator for calcium Indicator for Magnesium.
Revision Summary: Updates in Section(s) 14,
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Legend:
NA - Not Applicable w/w - weight/weight
ND - Not Determined w/v - weight/volume
NV - Not Available v/v - volume/volume
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site safety
programs in accordance with applicable hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA
OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
HACH COMPANY 漏2006
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