World Headquarters Page 1
Hach Company Date Printed 1/12/06
P.O.Box 389 MSDS No: M00106
Loveland, CO USA 80539
(970) 669-3050
SAFETY DATA SHEET
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1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name: CUP-1
Catalog Number: 2493749
HACH LANGE GmbH Emergency Telephone Numbers:
Willst盲tterstrasse 11 (Poison Information Center Main)
40549 D眉sseldorf, Germany (+49 (0) 6131 19240) 24 HR
+49-(0)211-52880
SDS Number: M00106
Chemical Name: Not applicable
Chemical Formula: Not applicable
Chemical Family: Not applicable
Use of the substance/preparation: Low range copper determination.
CAS No.: Not applicable
Hazard: May cause irritation.
Date of MSDS Preparation:
Day: 12
Month: 01
Year: 2006
Additional Emergency Response Numbers: Austria: +49 (0)6131 19240, Belgium: +32-(0)70-245245, France: +33-
(0)1-40370404, Italy: +39-02-66101029, Netherlands: +31-(0)30-2748888, Switzerland: +41-(0)1-2515151
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2. COMPOSITION / INFORMATION ON INGREDIENTS
Ascorbic Acid
EEC Number: 2000662
CAS No.: 50-81-7
Percent Range: 10,0 - 20,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
Sodium Ascorbate
EEC Number: 2051261
CAS No.: 134-03-2
Percent Range: 80,0 - 90,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
Other components, each
EEC Number: Not applicable
CAS No.: Not applicable
Percent Range: < 1,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
World Headquarters Page 2
Hach Company Date Printed 1/12/06
P.O.Box 389 MSDS No: M00106
Loveland, CO USA 80539
(970) 669-3050
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: Not established
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3. HAZARDS IDENTIFICATION
Emergency Overview:
Appearance: Light yellow to tan powder
Odor: None
EU Symbols: Not applicable
R PHRASES: Not applicable
Protective Equipment:
Potential Health Effects:
Eye Contact (EC): May cause irritation
Skin Contact (EC): No effects are anticipated
Skin Absorption (EC): No effects anticipated
Target Organs (SA E): Not applicable
Ingestion (EC): May cause: gastrointestinal tract irritation diarrhea
Target Organs (Ing E): None Reported
Inhalation: May cause: irritation of nose and throat
Target Organs (Inh E): None Reported
Medical Conditions Aggravated: None reported
Chronic Effects: No effects anticipated
Cancer / Reproductive Toxicity Information:
This product does NOT contain any IARC listed chemicals.
Additional Cancer / Reproductive Toxicity Information: Contains: an experimental mutagen.
Toxicologically Synergistic Products: None reported
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4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.
Skin Contact (First Aid): Wash skin with plenty of water for 15 minutes. Call physician if irritation develops.
Ingestion (First Aid): Give large quantities of water. Call physician immediately.
Inhalation: Remove to fresh air.
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5. FIRE FIGHTING MEASURES
Flammable Properties: Can burn in fire, releasing toxic vapors. Dusts at sufficient concentrations can form explosive
mixtures with air.
Hazardous Combustion Products: Toxic fumes of: carbon monoxide, carbon dioxide. sodium monoxide
Fire / Explosion Hazards: High concentrations of dust may form an explosive mixture with air.
Static Discharge: None reported.
Mechanical Impact: None reported
Extinguishing Media: Dry chemical. Carbon dioxide Water spray to cool containers
Extinguishing Media NOT To Be Used: Not applicable Not applicable Not applicable
Fire Fighting Instruction: As in any fire, wear self-contained breathing apparatus pressure-demand and full protective
gear.
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6. ACCIDENTAL RELEASE MEASURES
Spill Response Notice:
Only persons properly qualified to respond to an emergency involving hazardous substances should respond to a spill
involving chemicals. See Section 13, Special Instructions for disposal assistance.
World Headquarters Page 3
Hach Company Date Printed 1/12/06
P.O.Box 389 MSDS No: M00106
Loveland, CO USA 80539
(970) 669-3050
Containment Technique: Stop spilled material from being released to the environment. Cover spilled solid material with
sand or other inert material.
Clean-up Technique: Scoop up spilled material into a large beaker and dissolve with water. Adjust to a pH between 6 and
9 with an alkali, such as soda ash or sodium bicarbonate. Filter to remove solids. Flush reacted material to the drain with a
large excess of water. Decontaminate the area of the spill with a soap solution.
Evacuation Procedure: Evacuate as needed to perform spill clean-up. If conditions warrant, increase the size of the
evacuation.
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7. HANDLING AND STORAGE
Handling: Avoid contact with eyes Do not breathe dust. Wash thoroughly after handling. Maintain general industrial
hygiene practices when using this product.
Storage: Protect from: light heat moisture
Special Packaging Instructions: Not applicable
Use of the substance/preparation: Low range copper determination.
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8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT
Engineering Controls: Have an eyewash station nearby. Maintain general industrial hygiene practices when using this
product.
Personal Protective Equipment:
Eye Protection: safety glasses with top and side shields
Skin / Hand Protection: disposable latex gloves lab coat
Inhalation Protection: adequate ventilation
Precautionary Measures: Avoid contact with: eyes Do not breathe: dust Protect from: light heat moisture
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m3, Inhalable dust
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9. PHYSICAL / CHEMICAL PROPERTIES
Appearance: Light yellow to tan powder
Physical State: Solid
Odor: None
pH: 5% solution = 4,9
Vapor Pressure: Not applicable
Vapor Density (air = 1): Not applicable
Boiling Point: Not applicable
Melting Point: 155掳-165掳C
Flash Point: Not applicable
Method: Not applicable
Autoignition Temperature: Not determined
Flammability Limits:
Lower Explosion Limits: Not applicable
Upper Explosion Limits: Not applicable
Specific Gravity (water = 1): 2,511
Evaporation Rate (water = 1): Not applicable
Volatile Organic Compounds Content: Not applicable
Partition Coefficient (n-octanol / water): Not applicable
Solubility:
Water: Soluble
Acid: Not determined
Other: Not determined
Metal Corrosivity:
Steel: Not determined
Aluminum: Not determined
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10. STABILITY / REACTIVITY
World Headquarters Page 4
Hach Company Date Printed 1/12/06
P.O.Box 389 MSDS No: M00106
Loveland, CO USA 80539
(970) 669-3050
Chemical Stability: Stable when stored under proper conditions.
Conditions to Avoid: Exposure to air. Excess moisture Exposure to light.
Reactivity / Incompatibility: Incompatible with: alkalies copper dyes iron oxidizers
Hazardous Decomposition: Heating to decomposition releases toxic fumes of carbon monoxide and carbon dioxide.
Hazardous Polymerization: Will not occur.
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11. TOXICOLOGICAL INFORMATION
Product Toxicological Data:
LD50: None reported
LC50: None reported
Dermal Toxicity Data: None reported
Skin and Eye Irritation Data: None reported
Mutation Data: None reported
Reproductive Effects Data: None reported
--
Ingredient Toxicological Data: Ascorbic acid: Oral rat LD50 = 11900 mg/kg
This product does NOT contain any IARC listed chemicals.
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12. ECOLOGICAL INFORMATION
Product Ecological Information: --
No ecological data available for this product.
Ingredient Ecological Information: --
No ecological data available for the ingredients of this product.
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13. DISPOSAL CONSIDERATIONS
NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stringent
state or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemical
and analysis solutions must be disposed of in compliance with the respective national regulations. Product packaging must
be disposed of in compliance with the country-specific regulations or must be passed to a packaging return system.
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14. TRANSPORT INFORMATION
I.C.A.O.:
I.C.A.O. Proper Shipping Name: Not Currently Regulated
--
ICAO Hazard Class: NA
ICAO Subsidiary Risk: NA
ICAO UN/ID Number: NA
ICAO Packing Group: NA
I.M.O.:
I.M.O. Proper Shipping Name: Not Currently Regulated
--
I.M.O. Hazard Class: NA
I.M.O. Subsidiary Risk: NA
I.M.O. UN Number: NA
I.M.O. Packing Group: NA
A.D.R.:
A.D.R. Proper Shipping Name: Not Currently Regulated
--
A.D.R Hazard Class: NA
A.D.R. Subsidiary Risk: NA
A.D.R. UN-Number:: NA
World Headquarters Page 5
Hach Company Date Printed 1/12/06
P.O.Box 389 MSDS No: M00106
Loveland, CO USA 80539
(970) 669-3050
A.D.R. Packing Group: NA
Additional Information: This product may be shipped as part of a chemical kit composed of various compatible
dangerous goods for analytical or testing purposes. This kit would have the following classification: Proper Shipping
Name: Chemical Kit Hazard Class: 9 UN Number 3316
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15. REGULATORY INFORMATION
National Inventories:
EEC Inventory Status: All ingredients used to make this product are listed on EINECS / ELINCS.
EEC Number: Not applicable
EEC LABEL COPY:
EU Symbols: Not applicable
R PHRASES: Not applicable
S PHRASES: Not applicable
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16. OTHER INFORMATION
References: Vendor Information. Technical Judgment. Sax, N. Irving. Dangerous Properties of Industrial Materials, 7th
Ed. New York: Van Nostrand Reinhold Co., 1989. Gosselin, R. E. et al. Clinical Toxicology of Commercial Products,
5th Ed. Baltimore: The Williams and Wilkins Co., 1984. In-house information. Air Contaminants, Federal Register, Vol.
54, No. 12. Thursday, January 19, 1989. pp. 2332-2983. TLV's Threshold Limit Values and Biological Exposure Indices
for 1992-1993. American Conference of Governmental Industrial Hygienists, 1992.
R PHRASES: Not applicable
Use of the substance/preparation: Low range copper determination.
Revision Summary: Updates in Section(s) 14,
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Legend:
NA - Not Applicable w/w - weight/weight
ND - Not Determined w/v - weight/volume
NV - Not Available v/v - volume/volume
USER RESPONSIBILITY: Each user should read and understand this information and incorporate it in individual site safety
programs in accordance with applicable hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA
OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
HACH COMPANY 漏2006
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