Material Safety Data Sheet
Revision Date: 05/31/2006 Issue date: 05/31/2006
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product name: Loctite(R) Fixmaster(R) Poxy Pak(TM) Fast Cure Item No. : 81120_HARDENER
Epo xy
Product type: Epoxy Hardener Region: United States
Company address: Contact Information:
Henkel Corporation Telephone: 860.571.5100
1001 Trout Brook Crossing Emergency telephone: 860.571.5100
Rocky Hill, Connecticut 06067 Internet: www.loctite.com
2. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components % ACGIH TLV OSHA PEL OTHER
Polymercaptan hardener 60-100 None None None
Proprietary
N-(2-Aminoethyl)piperazine 10-30 None None None
140-31-8
Triethylenetetramine 5-10 None None 1 ppm, skin TWA, (WEEL)
112-24-3
Phenol, 2,4,6- 5-10 None None None
tris[(dimethylamino)methyl]
90-72-2
6 mg/m3 TWA 10 mg/m3 TWA 3 mg/m3 TWA respirable dust
Silica, amorphous, fumed, 1-5
crystalline-free
112945-52-5
Aminoethylethanolamine 1-5 None None None
111-41-1
Heptakis(dipropyleneglycol)- 1-5 None None None
triphosphate
13474-96-9
Hydroxyethylpiperazine 1-5 None None None
103-76-4
Diethylene triamine 1-5 1 ppm TWA None None
111-40-0 (skin)
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
HMIS:
Physical state: Liquid HEALTH: 3*
Color: Opaque FLAMMABILITY: 1
Odor: None PHYSICAL HAZARD: 1
Personal Protection: See Section 8
DANGER:
Item No. : 81120_HARDENER Product name: Loctite(R) Fixmaster(R) Poxy Pak(TM) Fast Cure Epo xy
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CAUSES EYE AND SKIN BURNS.
MAY CAUSE ALLERGIC SKIN AND RESPIRATORY REACTION.
MAY CAUSE RESPIRATORY TRACT IRRITATION.
MAY BE HARMFUL IF ABSORBED THROUGH SKIN.
Relevant routes of exposure: Eye contact, Ingestion, Inhalation, Skin contact
Potential Health Effects
Inhalation: Allergic respiratory reaction. May cause respiratory tract irritation. May cause irritation to nose and
throat. Lung damage. Respiratory tract burns.
Skin contact: May cause skin burns. Allergic skin reaction. Harmful if absorbed through skin. Rash. Redness. Tissue
damage.
Eye contact: Burns. Severe eye irritation. Redness. Tissue damage.
Ingestion: May be harmful if swallowed. May cause burns of mouth and throat if swallowed.
Existing conditions aggravated by Skin disorders. Skin allergies. Respiratory disorders. Eye disorders. Asthma.
exposure:
See Section 11 for additional toxicological information.
4. FIRST AID MEASURES
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get
medical attention.
Skin contact: Immediately flush skin with plenty of water (using soap, if available). Remove contaminated clothing
and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention if
symptoms occur.
Eye contact: Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention.
Ingestion: DO NOT induce vomiting unless directed to do so by medical personnel. Keep individual calm. Get
medical attention immediately.
Notes to physician: None.
5. FIRE-FIGHTING MEASURES
Flash point: Greater than 93潞C (200潞F) Tagliabue closed cup
Autoignition temperature: Not available
Flammable/Explosive limits-lower %: Not available
Flammable/Explosive limits-upper %: Not available
Extinguishing media: Water spray (fog), foam, dry chemical or carbon dioxide.
Special fire fighting procedures: Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear.
Unusual fire or explosion hazards: In the event of fire, cool tanks with water spray.
Hazardous combustion products: Oxides of carbon. Oxides of nitrogen. Ammonia. Amines. Nitric acid. Nitrosamines. Irritating organic
fragments.
6. ACCIDENTAL RELEASE MEASURES
Environmental precautions: Prevent product from entering drains or open waters.
Item No. : 81120_HARDENER Product name: Loctite(R) Fixmaster(R) Poxy Pak(TM) Fast Cure Epo xy
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Clean-up methods: Remove all ignition sources. Immediately contact emergency personnel. Scrape up as much material
as possible. Clean residue with soap and water. Store in a closed container until ready for disposal.
7. HANDLING AND STORAGE
Handling: Keep away from heat, spark and flame. Do not breathe mist or vapors. Keep container closed. Avoid
contact with eyes, skin and clothing. Wash thoroughly after handling.
Storage: Store at or below 37.8掳C (100掳F). Store in original container until ready to use. Keep in a cool, well
ventilated area away from heat, sparks and open flame. Keep container tightly closed until ready for
use.
Incompatible products: Refer to Section 10.
For information on product shelf life contact Henkel Customer Service at (800) 243-4874.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering controls: Use local exhaust ventilation to maintain airborne concentrations below established exposure limits.
Respiratory protection: Use a NIOSH approved air-purifying respirator if the potential to exceed established exposure limits
exists.
Skin protection: Chemical resistant, impermeable gloves. Use chemical resistant, impermeable clothing including
gloves and either an apron or body suit to prevent skin contact.
Eye/face protection: Chemical splash goggles or safety glasses with side shields.
See Section 2 for exposure limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state: Liquid
Color: Opaque
Odor: None
Vapor pressure: Less than 5 mm Hg at 20潞C (68潞F)
pH: Not applicable
Boiling point/range: Greater than 149掳C (300掳F)
Melting point/range: Not available
Specific gravity: 1.04
Vapor density: Not available
Evaporation rate: Not available
Solubility in water: Slightly soluble
Partition coefficient (n-octanol/water): Not available
VOC content: 0.098% (value for resin and hardener together)
10. STABILITY AND REACTIVITY
Stability: Stable
Hazardous polymerization: Will not occur.
Hazardous decomposition products: None
Incompatability: Strong acids. Strong oxidizers. Halogenated compounds. Strong mineral acids. Reactive metals.
Calcium hypochlorite. Sodium hypochlorite. Nitrous acid and other nitrosating agents.
Conditions to avoid: Excessive heat. Storage with incompatible materials.
11. TOXICOLOGICAL INFORMATION
Carcinogen Status
Item No. : 81120_HARDENER Product name: Loctite(R) Fixmaster(R) Poxy Pak(TM) Fast Cure Epo xy
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Hazardous components NTP Carcinogen IARC Carcinogen OSHA Carcinogen
Polymercaptan hardener No No No
Proprietary
N-(2-Aminoethyl)piperazine No No No
140-31-8
Triethylenetetramine No No No
112-24-3
Phenol, 2,4,6- No No No
tris[(dimethylamino)methyl]
90-72-2
Silica, amorphous, fumed, No No No
crystalline-free
112945-52-5
Aminoethylethanolamine No No No
111-41-1
Heptakis(dipropyleneglycol)- No No No
triphosphate
13474-96-9
Hydroxyethylpiperazine No No No
103-76-4
Diethylene triamine No No No
111-40-0
Literature Referenced Target Organ & Other Health Effects
Hazardous components Health Effects/Target Organs
Polymercaptan hardener No data
Proprietary
N-(2-Aminoethyl)piperazine Irritant, Corrosive, Allergen
140-31-8
Triethylenetetramine Allergen, Developmental, Irritant, Mutagen, Corrosive
112-24-3
Phenol, 2,4,6- Allergen, Irritant
tris[(dimethylamino)methyl]
90-72-2
Silica, amorphous, fumed, Nuisance dust
crystalline-free
112945-52-5
Aminoethylethanolamine Allergen, Irritant
111-41-1
Heptakis(dipropyleneglycol)- No data
triphosphate
13474-96-9
Hydroxyethylpiperazine Allergen, Central nervous system, Irritant
103-76-4
Diethylene triamine Allergen, Eyes, Irritant
111-40-0
12. ECOLOGICAL INFORMATION
Ecological information: Not available
13. DISPOSAL CONSIDERATIONS
Information provided is for unused product only.
Recommended method of disposal: Dispose according to EPA and local governmental regulations.
EPA hazardous waste number: Not a RCRA hazardous waste.
14. TRANSPORT INFORMATION
The shipping classifications in this section are for non-bulk packaging only (unless otherwise specified). Shipping classification may be
different for bulk packaging.
U.S. Department of Transportation Ground (49 CFR):
Item No. : 81120_HARDENER Product name: Loctite(R) Fixmaster(R) Poxy Pak(TM) Fast Cure Epo xy
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Proper shipping name: Corrosive liquid, basic, organic, n.o.s. ( Triethylenetetramine / Aminoethylpiperazine )
Hazard class or division: 8
Identification number: UN 3267
Packing group: II
Exceptions: (Not more than 1L) Consumer Commodity ORM-D
International Air Transportation (ICAO/IATA):
Proper shipping name: Corrosive liquid, basic, organic, n.o.s. ( Triethylenetetramine / Aminoethylpiperazine )
Hazard class or division: 8
Identification number: UN3267
Packing group: II
WaterTransportation (IMO/IMDG):
Proper shipping name: Corrosive liquid, basic, organic, n.o.s. ( Triethylenetetramine / Aminoethylpiperazine )
Hazard class or division: 8
Identification number: UN3267
Packing group: II
15. REGULATORY INFORMATION
United States Regulatory Information
TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory.
TSCA 12 (b) Export Notification: None.
CERCLA/SARA Section 302 EHS: None above reporting de minimus.
CERCLA/SARA Section 311/312: Immediate Health Hazard
CERCLA/SARA 313: None above reporting de minimus.
California Proposition 65: This product contains a chemical known to the State of California to cause cancer.
Canada Regulatory Information
CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Domestic Substances List.
WHMIS hazard class: E, D.2.A, D.2.B
16. OTHER INFORMATION
This material safety data sheet contains changes from the previous version in sections: Corrected information in Section(s) 2, 14.
Prepared by: Gary Pierson, Sr. Product Safety and Regulatory Affairs Specialist
DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation
does not assume responsibility for any results obtained by persons over whose methods Henkel Corporation has no control. It is the
user's responsibility to determine the suitability of Henkel's products or any production methods mentioned herein for a particular
purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be
involved in the handling and use of any of Henkel Corporation's products. In light of the foregoing, Henkel Corporation specifically
disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale
or use of Henkel Corporation's products. Henkel Corporation further disclaims any liability for consequential or incidental damages of
any kind, including lost profits.
Item No. : 81120_HARDENER Product name: Loctite(R) Fixmaster(R) Poxy Pak(TM) Fast Cure Epo xy
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