MSDS-UP873358
Phenol : chlorophorm
MATERIAL SAFETY AND DATA SHEET
Section 1 Chemical Product and Company Identification
Name nom Phenol chlorophorm Cat.# UP873358
Not available
Synonyms
(CAS, chemical names,
tradename, abbreviates鈥?)
UPTIMA-INTERCHIM 213 J.F.Kennedy, 03100 Montlucon
Company identification
(FRANCE)
Tel. :+33 (0)4 70 03 88 55
Fax: +33 (0)4 70 03 82 60
e-mail: uptima@interchim.com
In Europe: Call UPTIMA-INTERCHIM Tel.: +33 4 70 03 88 55
In case of Emergency
out of office: Centre anti Poisons de Lyon Tel.: +33 4 72 11 69 11
In US: call CHEMTREC Tel.: 800;424;9300
Section 2 Composition, Information on Ingredients
Component Hazardous ingredients Information
CAS % weight
Phenol 108-95-2, 55-61%
Chlorophorm 67-66-3 40-50%
Isoamyl Alcohol 123-51-3 <1%
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MSDS-UP873358
Section 3 Hazards Identification
Physical State and Liquid.
Appearance
Label precautionary Not available
statement
Emergency overview DANGER!
CAUSES SEVERE EYE AND SKIN IRRITATION.
CAUSES DAMAGE TO THE FOLLOWING ORGANS: KIDNEYS, NERVOUS SYSTEM,
LIVER, HEART,
SPLEEN, RESPIRATORY TRACT, SKIN, EYES, CENTRAL NERVOUS SYSTEM.
FLAMMABLE LIQUID AND VAPOR.
VAPOR MAY CAUSE FLASH FIRE.
MAY BE HARMFUL IF SWALLOWED.
POSSIBLE CANCER HAZARD
CONTAINS MATERIAL WHICH MAY CAUSE CANCER BASED ON ANIMAL DATA.
Risk of cancer depends on duration and level of exposure. Keep away from heat, sparks and
flame.
Avoid contact with eyes, skin and clothing. Do not ingest. Avoid breathing vapor or mist. Keep
container closed. Use only with adequate ventilation. Wash thoroughly after handling.
Accute health effects Very hazardous in case of eye contact (irritant). Hazardous in case of eye contact (corrosive).
Inflammation of the eye is characterized by redness, watering, and itching.
(Eye, Skin, Ingestion, Inhalation,
Chronic)
Sensitization of the product: Not available.
Very hazardous in case of skin contact (irritant, permeator). Hazardous in case of skin contact
(corrosive). Skin contact may produce burns. Severe over-exposure can result in death. Skin
inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering.
Inhalation of the spray mist may produce severe irritation of respiratory tract, characterized by
coughing, choking, or shortness of breath. Over-exposure by inhalation may cause respiratory
irritation. May be fatal if inhaled.
May be fatal if swallowed. May cause burns to mouth, throat, and stomach.
Other information See section 11
(over-exposure, toxicity鈥?)
Precautionnary guidelines Wear suitable protective clothing, gloves and eye/face when handling to avoid contact
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MSDS-UP873358
Section 4 First aid Measures
General measures Remove contaminated clothing promptly.
Allow the victim to rest in a well ventilated area, Seek medical attention
Emergency first measures Check for and remove any contact lenses. In case of contact, immediately flush eyes with
(Eyes, Skin, Ingestion, plenty of water for at least 15 minutes. Cold water may be used. Get medical attention
Inhalation鈥?) immediately.
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Cover the irritated skin with an emollient. Cold
water may be used.Wash clothing before reuse. Thoroughly clean shoes before reuse. Get
medical attention immediately.
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. Get medical attention immediately.
If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never
give anything by mouth to an unconscious person. Loosen tight clothing such as a collar, tie,
belt or waistband. Get medical attention immediately.
Notes to physicians Not available
Section 5 Fire Fighting Measures
Physical Information Flammable. The lowest known value is 349.9掳C (661.8掳F) (Isoamyl Alcohol).
The lowest known value is CLOSED CUP: 41.9掳C (107.4掳F). (Isoamyl Alcohol)
(Flammability, auto-ignition,
flash point鈥?) The greatest known range is LOWER: 1.2% UPPER: 9% (Isoamyl Alcohol)
These products are carbon oxides (CO, CO2), halogenated compounds.
Fire Hazards in Presence of Not available.
Various Substances
Explosion Hazards in Risks of explosion of the product in presence of mechanical impact: Not available.
Presence of Various Risks of explosion of the product in presence of static discharge: Not available.
Substances
Fire Fighting Media Be sure to use an approved/certified respirator or equivalent.
and Instructions
Protective Clothing (Fire) Be sure to use an approved/certified respirator or equivalent.
Special Remarks on Fire Combustible material: may burn but does not ignite readily.
Hazards When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers
explosion
hazards.
Some may polymerize (P) explosively when heated or involved in a fire.
Contact with metals may evolve flammable hydrogen gas.
Containers may explode when heated.
Runoff may pollute waterways.
Substance may be transported in a molten form. (Phenol)
Special Remarks on Not available.
Explosion Hazards
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MSDS-UP873358
Section 6 Accidental Release Measures
Small Spill and Leak Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate
waste disposal container. If necessary: Neutralize the residue with a dilute solution of sodium
carbonate.
Large Spills and Leaks Flammable liquid. Corrosive liquid. Poisonous liquid.
Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. Absorb
with DRY earth, sand or other non-combustible material. Do not get water inside container. Do
not touch spilled material. Use water spray curtain to divert vapor drift. Use water spray to
reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Call for
assistance on disposal. Neutralize the res idue with a dilute solution of sodium
carbonate. Be careful that the product is not present at a concentration level above TLV.
Check TLV on the MSDS and with local authorities.
Section 7 Handling and Storage
Handling Keep away from heat, sparks and flame. Keep container closed. Use only with adequate
ventilation. To avoid fire or explosion, dissipate static electricity during transfer by grounding
and bonding containers and equipment before transferring material. Use explosion-proof
electrical (ventilating, lighting and material handling) equipment.
Storage Store in a segregated and approved area. Keep container in a cool, well-ventilated area. Keep
container tightly closed and sealed until ready for use. Avoid all possible sources of ignition
(spark or flame).
Section 8 Exposure Controls, Personal Protection
Engineering controls Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of
vapors below their respective threshold limit value. Ensure that eyewash stations and safety
showers are proximal to the work-station location.
Personal protection Eyes : Face shield.
Body : Full suit.
(eyes, hands, body,
respiratory鈥?) Respiratory: Vapor respirator. Be sure to use an approved/certified respirator or equivalent.
Wear appropriate respirator when ventilation is inadequate.
Hands : Gloves.
Feet : Boots.
consult local authorities
Exposure limits
Section 9 Physical and Chemical Properties
Liquid
Physical state /
Appearance
Not available.
Odor
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MSDS-UP873358
Other
Molecular Weight : Not applicable.
(pH, Melting/Freezing Point,
Molecular Formula: Not applicable.
Vapor Pressure, Vapor Density,
Volatility, Boiling Point, pH (1% Soln/Water): Acidic.
Viscosity, Flash point, Auto- Boiling/Condensation Point: The lowest known value is 60.55掳C (141掳F) (Chloroform).
ignition temperature, Explosion Weighted average: 122.16掳C (251.9掳F)
limits (low.Upp.), Specific
Melting/Freezing Point: May start to solidify at 40.9掳C (105.6掳F) based on data for:
Gravity / Density, Molecular
Phenol. Weighted average: -13.17掳C(8.3掳F)
Formula /MW
Critical Temperature : The lowest known value is 263.3掳C (505.9掳F) (Chloroform).
Specific Gravity : Weighted average: 1.23 (Water = 1)
Vapor Pressure : The highest known value is 21.3 kPa (@ 20掳C) (Chloroform).
Weighted average: 10.37 kPa (@ 20掳C)
Vapor Density : The highest known value is 4.1 (Air = 1) (Chloroform). Weighted
average: 3.65 (Air = 1)
Volatility : Not available.
Odor Threshold : Not available.
Evaporation Rate : 10.2 (Chloroform) compared to Butyl acetate.
VOC : Not available.
Viscosity : Not available.
LogKow : Not available.
Ionicity (in Water): Not available.
Dispersion Properties : See solubility in water.
Solubility : Partially soluble in cold water, hot water.
Physical Chemical Comments: Not available.
Section 10 Stability and Reactivity
The product is stable.
Chemical Stability
Chemical Reactivity
(conditions, by -products鈥?)
Reactive with oxidizing agents, metals, acids, alkalis.
Incompatibilities
(conditions, materials鈥?)
These products are halogenated compounds.
Decomposition
Hazardous Polymerization Will not occur.
polymerisation
(conditions, materials鈥?)
Section 11 Toxicological Information
Acute oral toxicity (LD50): 36 mg/kg [mouse]. (Chloroform).
Toxicity in animals
Acute dermal toxicity (LD50): 630 mg/kg [rabbit]. (Phenol).
in human
CARCINOGENIC EFFECTS : Classified A4 (Not classifiable for human or animal.) by
ACGIH, 3 (Not classifiable for human.) by IARC [Phenol]. Classified A3 (Proven for animal.)
by ACGIH, 2B (Possible for human.) by IARC, 3 (Possible for human.) by European Union
[Chloroform].
Very hazardous in case of skin contact (irritant, permeator).
Slightly hazardous in case of ingestion, of inhalation (lung irritant).
MAY CAUSE CANCER
Chronic effects
TARGET ORGAN(S):
(carcinogenicity, teratogenicity,
reproductive toxicity, mutagenesis) CENTRAL NERVOUS SYSTEM
KIDNEYS
LIVER
PANCREAS
SPLEEN
TO THE BEST OF OUR KNOWLEDGE, THE CHEMICAL, PHYSICAL, AND
TOXICOLOGICAL PROPERTIES HAVE NOT BEEN THOROUGHLY INVESTIGATED.
Not available.
Remarks
(RTECS鈥?)
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MSDS-UP873358
Section 12 Ecological Information
Not available.
Ecotoxicity (BOD5, COD鈥?)
Not available.
Biodegradation
Not available.
Mobility
The products of degradation are as toxic as the product itself.
Remarks
Section 13 Disposal Considerations
THIS COMBUSTIBLE MATERIAL MAY BE BURNED IN A CHEMICAL INCINERATOR
Waste
EQUIPPED WITH AN AFTERBURNER AND SCRUBBER..
Consult your local or regional authority or a licensed professional waste service
Remarks
Section 14 Transport Information
CLASS 6.1: Poisonous material.
Classifications
TOXIC LIQUID, ORGANIC, N.O.S., 6.1, 8, UN2922,
(Other classifications)
Shipping
Hazards Class
UN # 2810
UN Class
packing group III
Packing Group
Not available.
Comments
( marine polluants鈥?)
Section 15 Regulatory Information
TOXIC
Classification Europe
CAUSE BURNS R34
VERY TOXIC BY INHALATION R 26/27/28
MAY CAUSE CANCER R 45 S 36/37/39
WEAR SUITABLE PROTECTIVE CLOTHING, GLOVES AND EYE/FACE PROTECTION
US information
Other classifications
This product is subject to sara section 313 reporting requirements
Section 16 Additional Information
UPTIMA-INTERCHIM, C08F
MSDS validation
The information above is believed to be accurate and represents the best information currently availabl e to us. However,
Comment
we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and
we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be liable for any claims, losses, or damages of any
third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising,
even if the company has been advised of the possibility of such damages
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