Thunder Sky Battery Limited
MATERIAL SAFETY DATA SHEET
(form according to EEC Directive 93/112/EC)
NAME: LITHIUM-ION RECHARGABLE BATTERIES
1- IDENTIFICATION (of the product and the supplier)
1.1 Product: Rechargeable battery
Yes X
No
Trade name and model: LITHIUM-ION RECHARGABLE BATTERIES
IEC designation: ______________________________________________
Models: TS-LCP all sizes
Electrochemical system: Lithium Cobalt Di-Oxide
Electrodes Negative electrode Positive electrode
Carbon/Graphite Lithium cobaltite (LiCoO2)*
Solution of Lithium hexafluorophosphate (LiPF6)
Electrolyte
In a mixture of organic solvents**
3.6 Volts
Nominal voltage
*Equivalent name: lithiated cobalt oxide.
** Ethylene Carbonate (EC) + DiEthyl Carbonate (DMC) + DiEthyl Carbonate (DEC) + Ethyl
Acetate (EA).
1.2 Supplier:
Name: Thunder Sky Battery Ltd.
Lanshan 2nd Road (South)
Address:
High-Tech Industrial Park (North), Shenzhen PRC
Phone: + 86 755 86026789
Fax: +86 755 86026678
1.3 Emergency contact:
CHEMTREC Phone: 1-800-424-9300
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2 - COMPOSITION (typical weight percentages of basic material)
Metals % Plastics % Others %
- Steel, Copper, 31 - Polypropylene, 11 Lithium Cobaltite 21
-
Aluminum Polyethylene Carbon 17
-
Organic solvents 14
-
Salts 2
-
LiMn2O4 4
-
3 鈥? HAZARDS IDENTIFICATION
3.1 Physical:
The Lithium-Ion rechargeable batteries described in this Material Safety Data Sheet are sealed units
which are not hazardous when used according to the recommendations of the manufacturer.
Under normal conditions of use, the solid electrode materials and liquid electrolyte they contain are non-
reactive provided the battery integrity is maintained and seals remain intact. There is Risk of exposure
only in cases of abuse (mechanical, thermal, electrical), which leads to the activation of the safety valve
and/or the rupture of the battery container. Electrolyte leakage, electrode materials reaction with
moisture/water or battery vent/explosion/fire may follow, depending upon the circumstances.
In case of excessive internal pressure and/or temperature Thunder Sky batteries are fitted with a safety
vent for protection and/or rupture of the cell case.
3.2 Chemical
Classification of dangerous substances contained into the product
as per directive 67/548/EEC
Substance Melting Boiling Classification
point point
CAS N0 Chemical Exposure Indication Special Safety
Symbol limit of danger risk (1) advices (2)
> 1000oC
12190-79-3 LiCoO2 N/A 0.1 mg/m3 R 22 S2 S22
OSHA R43 S24 S26 S36
S37 S43 S45
EC: 96-49-1 Organic None Flammable R21 R22 R41 S2 S24
EC: 38掳C EC: 243掳C
DMC: 616-38-6 solvents established R42/43 S26 S36
DMC: 4掳C DMC: 90掳C
DEC: 105-58-8 (DC-DMC OSHA S37 S45
DEC:-43掳C DEC: 127掳C
EA: 141-78-6 DEC-EA) EA: -84掳C EA: 77掳C
21324-40-3 LiPF6 N/A N/A None Irritant R14 S2 S8 S22
(decomposes established Corrosive R21 R22 S24 S26 S36
OSHA R41 R43 S37 S45
at 160掳C)
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1 鈥? Nature of Special risks:
R14 Reacts with water.
R 21 Harmful in contact with skin.
R22 Harmful if swallowed.
R41 Risk of serious damage to the eye.
R42/43 May cause sensitization by inhalation and skin contact.
R43 May cause sensitization by skin contact.
2 鈥? Safety advices:
S2 Keep out of reach from children.
S8 Keep away from moisture.
S 22 Do not breathe dust.
S 24 Avoid contact with skin.
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical attention.
S36 Wear suitable gloves.
S 45 In case of incident, seek medical attention
4- FIRST AID MEASURES
In case of battery rupture or explosion, evacuate personnel from contaminated area and provide maximum
ventilation to clean out fumes/gases.
In all cases, seek medical attention.
Eye contact: Flush with plenty of water (eyelids held open) for at least 15 minutes.
Skin contact: Remove all contaminated clothing and flush affected areas with plenty of
Water and soap for at least 15 minutes
Do not apply greases or ointments.
Ingestion: Dilute by giving plenty of water and get immediate medical attention.
Assure that the victim does not aspirate vomited material by use of positional drainage.
Assure that mucus does not obstruct the airway.
Do not give anything by mouth to an unconscious person.
Inhalation: Remove to fresh air and ventilate he contaminated area.
Give oxygen or artificial respiration if needed.
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5鈥? FIRE-FIGHTING MEASURES
Fire and exposion hazard: The batteries can leak and/or spout vaporized or decomposed and
combustible electrolyte fumes in case of exposure above 80掳C
resulting from inappropriate use, abuse, or from the environment.
Possible formation of hydrogen fluoride (HF) and phosphorous oxides
during fire. LiPF6 salt contained in the electrolyte releases hydrogen
fluoride (HF) in contact with water.
Extinguishing media: Suitable: 鈥︹?? Spray or immerse in water
Not to be used:鈥︹?︹?︹?? Type D extinguishers, Co2, Dry chemical or Foam extinguishers
Special exposure hazards: Following cell overheating due to external source or due to improper
use, electrolyte leakage or battery container rupture may occur and
release inner component/material in the environment.
Eye contact: The electrolyte solution contained in the battery is irritant to ocular
tissues.
Skin contact: The electrolyte solution contained in the battery causes skin irritation.
Ingestion: The ingestion of electrolyte solution causes tissue damage to
throat and gastro/respiratory tract.
Inhalation: Contents of a leaking or ruptures battery can cause respiratory tract,
mucus, membrane irritation and edema.
Special protective equipment: Use self-contained breathing apparatus to avoid breathing irritant
fumes.
Wear protective clothing and equipment to prevent body contact with
electrolyte solution.
6- ACCIDENTAL RELEASE MEASURES
The material contained within the batteries would only be expelled under abusive conditions.
Soak under water or spray with copious amounts of water, place in approved container (after cooling if
necessary) and dispose in accordance with local regulations.
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7- HANDLING AND STORAGE
The batteries should not be opened, destroyed nor incinerate since they may leak or rupture and
release in the environment the ingredients they contain.
Handling: Do not crush, pierce, short (+) and (-) battery terminals with conductive (i.e. metal)
goods. Do not directly heat or solder. Do not throw into fire. Do not mix batteries of
different types and brands. Do not mix new and used batteries. Keep batteries in non-
conductive (i.e. plastic) trays.
Storage: Store in a cool (preferably below 30掳C) and ventilated area away from moisture,
sources of heat, open flames, food and drink. Keep adequate clearance between walls
and batteries. Temperature above 70掳C may result in battery leakage and rupture.
Since short circuit can cause burn, leakage and rupture hazard, keep batteries in
original packaging until use and do not jumble them.
Other: Follow manufacturer recommendations regarding maximum recommended currents
and operating temperature range.
Applying pressure or deforming the battery may lead to disassembly followed by eye,
skin and throat irritation.
8- EXPOSURE CONTROLS/PERSONAL PROTECTION
Respiratory protection: Not necessary under normal use. In case of battery rupture, use self-
contained full-face respiratory equipment.
Hand protection: Not necessary under normal use. Use Viton rubber gloves if handling a
leaking battery.
Eye protection: Not necessary under normal use. Wear safety goggles or glasses with
side shields if handling a leaking or ruptured battery.
Skin protection: Not necessary under normal use. Use rubber apron and protective
working in case of handling of a ruptured battery.
9- PHYSICAL AND CHEMICAL PROPERTIES
9.1 Appearance: (Physical shape and color as supplied)
White Plastic Prismatic cases with ribs, hermetically sealed and fitted
with a metallic terminals/connections.
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9.2 Temperature range:
Continuous Occasional
In storage during + 30掳C max -40/+ 70掳C
discharge during - 30/+ 70掳C -40/+ 70掳C
during charge 0/+ 50掳C 0/+ 50掳C
鈮? 120 鈥? 200whr/kg depending upon size
9.3 Specific energy:
(Note: Wh = Normal voltage x Rated Ah)
kg = Average battery weight)
9.4 Specific pulse power: 600w-1200w/kg Varies depending upon size
9.5 Mechanical resistance: As defined in relevant IEC standard
9.6 Other:
10 - STABILITY AND REACTIVITY
Conditions to avoid: Heat above 70掳C or incinerate.
Deform, mutilate, crush, pierce, disassemble.
Short circuit.
Prolonged exposure to humid conditions.
Materials to avoid: N/A
Hazardous decomposition products: Corrosive/Irritant Hydrogen fluoride (HF) is produced in case of
reaction of lithium hexafluorophosphate (LiPF6) with water.
Combustible vapors and formation of Hydrogen fluoride (HF)
and phosphorous oxides during fire.
11 - TOXOLOGICAL INFORMATION
Thunder Sky Battery Ltd. Lithium-Ion rechargeable batteries do not contain toxic materials.
12 - ECOLOGICAL INFORMATION
When properly used or disposed, Thunder Sky Battery Ltd Lithium-Ion rechargeable batteries do not
present environmental hazard.
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13 - DISPOSAL CONSIDERATIONS
Dispose in accordance with applicable regulations, which vary from country to country.
Lithium-Ion batteries should have their terminals insulated and be preferably wrapped in individual
plastic bags prior to disposal.
13.1 Incineration: Incineration should never be performed by battery users but eventually be
trained professionals in authorized facilities with proper gas and fumes
treatment.
13.2 Recycling: Send to authorized recycling facilities.
14 - TRANSPORT INFORMATION
14.2 United Nations: UN掳 3090
Classification 9
Packaging ICAO 903 for Air Transport
IMDG 903 for Sea Transport
14.2 Internations conventions: Air IATA Yes
Sea IMDG Yes
Land ADR (road) Yes
RID (rail) Yes
14.3 Other: In the USA: Code of Federal Regulations
(49 CFR Ch. 1 搂 173-185)
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15 - REGULATION INFORMATION
The transport of rechargeable lithium-ion batteries is regulated by various bodies (IATA, IMO, ADR, US-
DOT) that follow the United Nations 鈥淩ecommendations on the Transport of Dangerous Goods, Model
Regulations, 13th Revised edition 鈥? 2003 鈥? Ref. STSG/AC.10/1 Rev. 13鈥?.
Depending on their lithium metal equivalent weight content, design, and ability to pass safety tests
defined by the UN in the 鈥淩ecommendations on the Transport of Dangerous Goods 鈥? Manual of Tests
and Criteria 鈥? 3rd Revised edition 鈥? 2002 鈥? Ref. Ref. STSG/AC.10/11 Rev. 3 Amendment 1 <
Batteries>>鈥?, the lithium-ion cells and the battery packs may or may not be assigned to the UN N潞 3090
Class-9, that is restricted for transport.
Individual lithium-ion cells and battery packs with respectively less than 1.5 and 8 grams of equivalent
Lithium metal content that pass the UN-defined safety tests, are not restricted for transport (1.0 Ah of
declared nominal capacity = 0.3 gram of Li equivalent weight content).
16 鈥? OTHER INFORMATION/DISCLAIMER
This information has been compiled from sources considered to be dependable and is to the best of our
knowledge and belief, accurate and reliable as of the date compiled. However, no representation,
warranty (either expressed or implied) or guarantee is made to the accuracy, reliability or completeness
of the information contained herein.
This information relates to the specific materials designated and may not be valid for such material
used in combination with any other materials or in any process. It is the user鈥檚 responsibility to satisfy
himself as to the suitability and completeness of this information for his particular use.
Thunder Sky does not accept liability for any loss or damage that may occur whether direct, indirect,
incidental or consequential, from the use of this information. Thunder Sky does not offer warranty
against patent infringement. Additional information is available by calling the telephone number above
designated purpose.
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