Material Name: Firetemp庐 Pillow Material Safety Data
Sheet ID: 2011
Section 1 - Chemical Product and Company Identification
Product Name Firetemp庐 PIllow
CAS# Not Assigned
Generic Name Fire and Smoke Stop Pillow
Formula NA
Chemical Name: NA
Manufacturer Information
Johns Manville Insulation Group Telephone: 303-978-2000 8:00AM-5:00PM M-F
Fire Protection Systems Internet Address: http://www.jm.com
P.O. Box 5108 Emergency: 800-424-9300 (Chemtrec, In English)
Denver, CO 80127
Trade Names: Firetemp庐 Pillow
Section 2 - Composition / Information on Ingredients
CAS # Component Percent
65997-17-3 Mineral Wool Fiber 40-50
1317-65-3 Calcium carbonate 15-24
9003-29-6 Polybutene homopolymer 15-24
7782-42-5 Graphite 10-18
14807-96-6 Talc 5-12
7664-93-9 Sulfuric Acid 0-6
25104-55-6 Urea extended phenol-formaldehyde resin (cured) 0.4-3.0
7697-37-2 Nitric Acid 0-3
Additional Component Information
Note: The acid components of this product are encapsulated within the natural graphite matrix. They do not pose a hazard
during normal use or handling.
This product is a pliable brick shape pillow used as a firestop in medium to large through-penetrations. When exposed to fire
or high temperatures above 150掳C, the intumescent part of this product will expand to seal around the penetrant(s) forming a
solid barrier to prevent the passage of smoke, fire, and fumes.
Section 3 - Hazards Identification
APPEARANCE AND ODOR: Gray/brown board with black intumescent strip. Slight resin odor.
Inhalation
Irritation of the nose and throat may occur.
Skin
This product may cause irritation to the skin.
Ingestion
Product is not intended to be ingested or eaten. If this product is ingested, severe irritation of the gastrointestinal tract may
occur, and should be treated symptomatically. Seek medical attention.
Eyes
This product may cause irritation to the eyes.
Primary Routes of Entry (Exposure)
Inhalation, skin, and eye contact
Target Organs
____________________________________________________________
Page 1 of 6 Issue Date: 06/29/2006 Revision: 1.0000
Material Name: Firetemp庐 Pillow Material Safety Data
Sheet ID: 2011
Section 4 - First Aid Measures
First Aid: Inhalation
Remove to fresh air. If symptoms persist contact a physician.
First Aid: Skin
Wash exposed skin with soap and water. If irritation develops or persists, seek medical attention.
First Aid: Ingestion
Product is not intended to be ingested or eaten. If the material is swallowed, get immediate medical attention or advice -- Do
not induce vomiting.
First Aid: Eyes
Flush eyes with large amounts of water for 5-20 minutes. Contact a medical professional.
Section 5 - Fire Fighting Measures
Flash Point: Intumescent Strip = 214掳C Method Used: PMCC
General Fire Hazards
There is no potential for spontaneous fire or explosion.
Hazardous Combustion Products
Carbon dioxide, carbon monoxide, and trace gases. Intumescent Strip: Thermal decomposition or combustion may produce
dense smoke, oxides of carbon, sulfur, nitrogen, and low molecular weight organic compounds. Material volume will increase
up to 200 times when exposed to intense heat, >150掳C.
Extinguishing Media
Water, foam, carbon dioxide, or dry powder
Fire Fighting Equipment/Instructions
Firefighters should wear full-face, self-contained breathing apparatus and impervious protective clothing. Firefighters should
avoid inhalation of combustion products.
Section 6 - Accidental Release Measures
Containment Procedures
Pick up large pieces. Vacuum dusts.
Clean-Up Procedures
Comply with state and local regulations for disposal of these products. If you are unsure of the regulations, contact your local
Public Health Department, or the local office of the Environmental Protection Agency (EPA).
Section 7 - Handling and Storage
Handling Procedures
Use protective equipment as described in Section 8 of this material safety data sheet when handling uncontained material.
Storage Procedures
Warehouse storage should be in accordance with package directions, if any. Material should be kept dry, and protected from
moisture.
Section 8 - Exposure Controls / Personal Protection
A: Component Exposure Limits
Mineral Wool Fiber (65997-17-3)
ACGIH: 1 fiber/cm3 TWA (respirable fibers, length >5 碌m, aspect ratio >=3:1, as determined by the
membrane filter method at 400-450X magnification [4-mm objective], using phase-contrast
illumination)
Calcium carbonate (1317-65-3)
OSHA: 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction)
Graphite (7782-42-5)
ACGIH: 2 mg/m3 TWA (respirable fraction, all forms except graphite fibers)
OSHA: 2.5 mg/m3 TWA (respirable dust)
____________________________________________________________
Page 2 of 6 Issue Date: 06/29/2006 Revision: 1.0000
Material Name: Firetemp庐 Pillow Material Safety Data
Sheet ID: 2011
Talc (14807-96-6)
ACGIH: 2 mg/m3 TWA (respirable fraction, particulate matter containing no asbestos and < 1%
crystalline silica)
OSHA: 2 mg/m3 TWA (respirable dust, less than 1% crystalline silica)
Sulfuric Acid (7664-93-9)
ACGIH: 0.2 mg/m3 TWA (thoracic fraction)
OSHA: 1 mg/m3 TWA
Nitric Acid (7697-37-2)
ACGIH: 2 ppm TWA
4 ppm STEL
OSHA: 2 ppm TWA; 5 mg/m3 TWA
4 ppm STEL; 10 mg/m3 STEL
PERSONAL PROTECTIVE EQUIPMENT
Personal Protective Equipment: Eyes/Face
Wear safety glasses with side shields.
Personal Protective Equipment: Skin
Neoprene rubber or nitrile rubber gloves should be used to help prevent excessive skin contact.
Personal Protective Equipment: Respiratory
Respiratory protection is recommended if the product is handled in poorly ventilated areas.
Ventilation
Local exhaust or general dilution ventilation should be provided to keep exposure levels below the applicable exposure limits.
Section 9 - Physical & Chemical Properties
Appearance: Odor:
Gray/brown board with black intumescent strip Slight resin odor
Physical State: pH:
Solid NA
Vapor Pressure: Vapor Density:
NA NA
Boiling Point: Melting Point:
NA NA
Solubility (H2O): Specific Gravity:
NA Intumescent Strip = 1.5-1.7
VOC: NA
Section 10 - Chemical Stability & Reactivity Information
Chemical Stability
This is a stable material.
Incompatibility
This product reacts with hydrofluoric acid, concentrated acids, or bases.
Hazardous Decomposition
Carbon dioxide, carbon monoxide, oxides of sulfur, nitrogen, low molecular organic compounds, and trace amounts of
formaldehyde when heated above 200掳C.
Hazardous Polymerization
Will not occur.
Section 11 - Toxicological Information
Acute Toxicity
A: General Product Information
Skin, eye, and upper respiratory irritation may occur after contact with product.
B: Component Analysis - LD50/LC50
Sulfuric Acid (7664-93-9)
Inhalation LC50 Mouse: 320 mg/m3/2H; Inhalation LC50 Rat: 510 mg/m3/2H; Oral LD50 Rat: 2140 mg/kg
Urea extended phenol-formaldehyde resin (cured) (25104-55-6)
Oral LD50 Rat: 7 g/kg
____________________________________________________________
Page 3 of 6 Issue Date: 06/29/2006 Revision: 1.0000
Material Name: Firetemp庐 Pillow Material Safety Data
Sheet ID: 2011
Nitric Acid (7697-37-2)
Inhalation LC50 Rat: 7 mg/L/4H
Carcinogenicity
A: General Product Information
No additional information available.
B: Component Carcinogenicity
Mineral Wool Fiber (65997-17-3)
ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to humans
NTP: Reasonably Anticipated To Be A Carcinogen (respirable size)
IARC: Group 3 - Not Classifiable (IARC Monograph 81, 2002, listed under Man-made mineral fibres,
Monograph 43, 1988).
Talc (14807-96-6)
ACGIH: A4 - Not Classifiable as a Human Carcinogen (containing no asbestos fibers); A1 - Confirmed
Human Carcinogen (containing asbestos fibers)
IARC: Group 3 - Not Classifiable (IARC Supplement 7, 1987; Monograph 42, 1987)
Sulfuric Acid (7664-93-9)
ACGIH: A2 - Suspected Human Carcinogen (contained in strong inorganic acid mists)
IARC: Group 1 - Known Human Carcinogen (IARC Monograph 54, 1992, listed under Occupational
exposures to mists and vapours from sulfuric acid and other strong inorganic acids)
Section 12 - Ecological Information
Ecotoxicity
A: General Product Information
No additional information available.
B: Component Analysis - Ecotoxicity - Aquatic Toxicity
Talc (14807-96-6)
96 Hr LC50 Brachydanio rerio: >100 g/L [semi-static]
Sulfuric Acid (7664-93-9)
96 Hr LC50 Brachydanio rerio: >500 mg/L [static]
24 Hr EC50 Daphnia magna: 29 mg/L
Nitric Acid (7697-37-2)
96 Hr LC50 Gambusia affinis: 72 mg/L
Section 13 - Disposal Considerations
US EPA Waste Number & Descriptions
A: General Product Information
Comply with state and local regulations for disposal. If you are unsure of the regulations, contact your local Public Health
Department, or the local office of the EPA.
B: Component Waste Numbers
No EPA Waste Numbers are applicable for this product's components.
Section 14 - Transportation Information
International Transportation Regulations
This product is not classified as a hazardous material for transport.
Section 15 - Regulatory Information
US Federal Regulations
A: General Product Information
SARA 311/312: This product is not classified as hazardous under SARA 311/312.
____________________________________________________________
Page 4 of 6 Issue Date: 06/29/2006 Revision: 1.0000
Material Name: Firetemp庐 Pillow Material Safety Data
Sheet ID: 2011
B: Component Analysis
This material contains one or more of the following chemicals required to be identified under SARA Section 302 (40 CFR 355
Appendix A), SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4).
Sulfuric Acid (7664-93-9)
SARA 302: 1000 lb TPQ
SARA 313: 1.0 % de minimis concentration (acid aerosols including mists, vapors, gas, fog, and other
airborne forms of any particle size)
CERCLA: 1000 lb final RQ; 454 kg final RQ
Nitric Acid (7697-37-2)
SARA 302: 1000 lb TPQ
SARA 313: 1.0 % de minimis concentration
CERCLA: 1000 lb final RQ; 454 kg final RQ
State Regulations
A: General Product Information
Other state regulations may apply. Check individual state requirements.
B: Component Analysis - State
The following components appear on one or more of the following state hazardous substances lists:
Component CAS # CA FL MA MN NJ PA
Mineral Wool Fiber (鹿related to Mineral wool fiber) 65997-17-3 Yes鹿 No Yes鹿 Yes No Yes鹿
Calcium carbonate 1317-65-3 No No Yes Yes No Yes
Graphite 7782-42-5 Yes No Yes Yes No Yes
Talc 14807-96-6 Yes No Yes Yes Yes Yes
Sulfuric Acid 7664-93-9 Yes No Yes Yes Yes Yes
Nitric Acid 7697-37-2 Yes No Yes Yes Yes Yes
The following statement(s) are provided under the California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65):
WARNING! This product contains a chemical known to the state of California to cause cancer.
Mineral Wool Fiber CAS# 65997-17-3
A: TSCA Status
This product and its components are listed on the TSCA 8(b) inventory.
None of the components listed in this product are listed on the TSCA Export Notification 12(b) list.
B: Component Analysis - Inventory
Component CAS # TSCA DSL EINECS
Mineral Wool Fiber 65997-17-3 Yes Yes Yes
Calcium carbonate 1317-65-3 Yes No Yes
Polybutene homopolymer 9003-29-6 Yes Yes No
Graphite 7782-42-5 Yes Yes Yes
Talc 14807-96-6 Yes Yes Yes
Sulfuric Acid 7664-93-9 Yes Yes Yes
Urea extended phenol-formaldehyde resin (cured) 25104-55-6 Yes Yes No
Nitric Acid 7697-37-2 Yes Yes Yes
Component Analysis - WHMIS IDL
The following components are identified under the Canadian Hazardous Products Act Ingredient Disclosure List:
Component CAS # Minimum Concentration
Sulfuric Acid 7664-93-9 1%
Nitric Acid 7697-37-2 1%
Section 16 - Other Information
Other Information
Prepared for:
Johns Manville Insulation Group
____________________________________________________________
Page 5 of 6 Issue Date: 06/29/2006 Revision: 1.0000
Material Name: Firetemp庐 Pillow Material Safety Data
Sheet ID: 2011
Fire Protection Systems
P.O. Box 5108
Denver, CO 80217-5108
Prepared by:
Johns Manville Technical Center
P.O. Box 625005
Littleton, CO USA 80162-5005
The information herein is presented in good faith and believed to be accurate as of the effective date given. However, no
warranty, expressed or implied, is given. It is the buyer's responsibility to ensure that its activities comply with Federal, State or
provincial, and local laws.
Date MSDS # Reason
03/16/06 2011-1.0000 New MSDS for new product
This is the end of MSDS # 2011
____________________________________________________________
Page 6 of 6 Issue Date: 06/29/2006 Revision: 1.0000
|