Johnson Matthey
RUTHENIUM NITROSYL NITRATE IN AQUEOUS SOLN
194000 2.00 EC Current 03.11.1999
1. PRODUCT AND COMPANY IDENTIFICATION
194000
Product Code
RUTHENIUM NITROSYL NITRATE IN AQUEOUS SOLN
Trade Name
Substance
Product Type
Johnson Matthey PLC
Manufacturer/Supplier
Precious Metals Division, Chemicals
Address
Orchard Road
ROYSTON, Hertfordshire
SG8 5HE
+(44) 1763 253000
Phone Number
+(44) 1763 253155
Fax Number
Ruthenium nitrosylnitrate, Ru(NO)(NO ) , in aqueous solution, which contains
Composition
30% Nitric acid.
1
JM Version Number
24/08/93
Date of First Issue
2. COMPOSITION/INFORMATION ON THE COMPONENTS
RUTHENIUM NITROSYL NITRATE IN AQUEOUS SOLN
Product Formal Name
Product Chemical Family .Not Specified
34513-98-9
CAS Number
3. HAZARD IDENTIFICATION
The hazards of this material are essentially those of 30% Nitric acid, it is
therefore classified as oxidizing and corrosive. Any contact with this material
may lead to tissue damage.
There is no toxicological data available for the Ruthenium compound, but it is
not thought to present a significant hazard in comparison to those of the Nitric
acid component.
4. FIRST AID MEASURES
Over-exposure may produce the following symptoms -
First Aid
Inhalation - irritating to the eyes, nose, throat and respiratory tract, producing
coughing.
Ingestion - nausea and vomiting.
Eye contact - redness, irritation, blurred vision and pain.
Skin - redness and irritation with possible tissue damage. 聽 聽
remove from exposure and allow to rest in fresh air. Seek medical advice. 聽
First Aid - Inhalation
rinse mouth with clean water and give water or milk to drink. Seek medical
First Aid - Ingestion
attention.
irrigate with water or isotonic saline solution for 15 minutes. Seek medical
First Aid - Eyes
attention.
remove contaminated clothing and wash skin with soap and water. If
First Aid - Skin
symptoms persist or tissue damage is evident, seek medical attention.
Launder clothing before re-use. 聽
5. FIRE FIGHTING MEASURES
Although the material is not flammable, it will assist a fire, producing toxic
fumes of oxides of nitrogen. The reside, ash or char left after a fire may have
catalytic properties and may promote the re-ignition of flammable materials
and vapours. Firefighters should wear protective equipment and self-
contained breathing apparatus. Use any extinguisher suitable for the
surrounding fire. 聽
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Johnson Matthey
RUTHENIUM NITROSYL NITRATE IN AQUEOUS SOLN
194000 2.00 EC Current 03.11.1999
6. ACCIDENTAL RELEASE MEASURES
Wearing suitable protective equipment, absorb the spillage in a suitable inert
absorbant (NOT sawdust or similar). Store absorbed material in a suitable
plastic container.
Wash site of spillage with large amounts of water. Do not allow wash water to
enter natural watercourses. 聽
7. HANDLING AND STORAGE
Good industrial hygiene practices should be observed. Use only under
Handling (JM)
conditions of a good level of ventilation. Avoid contact with skin and eyes. Do
not eat, drink, smoke or apply cosmetics whilst handling this material. 聽
Keep in a secure store. 聽
Storage (JM)
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
The following exposure standards have been established for the components
of this material -
UK Occupational Exposure Standard, Nitric acid - 5 mg/m鈥?
USA ACGIH TLV, Nitric acid - 5.2 mg/m鈥?
Germany MAK, Nitric acid - 5 mg/m鈥?
USSR, Nitric acid - 2 mg/m鈥?
France VME, Nitric acid - 5 mg/m鈥?
Sweden Occupational Exposure Limit, Nitric acid - 5 mg/m鈥?
Use only in well ventilated conditions. Users should wear eye protection and
chemically resistant gloves. 聽 聽 聽 聽 聽 聽 聽 聽 聽 聽 聽 聽 聽
9. PHYSICAL AND CHEMICAL PROPERTIES
Dark red solution.
Appearance
Nitric acid.
Odour
1
pH
no data.
Boiling Range/Point
-18掳C approx.
Melting Point
Flash Point not applicable.
not flammable.
Flammability
not applicable.
Auto-flammability
not explosive.
Explosive Properties
strong oxidisier.
Oxidising Properties
no data.
Vapour Pressure
>1.5
Density
Water - very soluble
Solubility in Water
Fat - no data.
no data.
Partition Coefficient
10. STABILITY AND REACTIVITY
This material is supplied in a stable condition. The Nitric acid content may
present a reactive hazard following contact with combustible materials,
reducing agents, metals and many organic materials.
Users should note that the use of borohydride solutions to reduce Ruthenium
salt solutions to the metal is reported as producing solids which are explosive
when dry. 聽
11. TOXICOLOGICAL INFORMATION
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Johnson Matthey
RUTHENIUM NITROSYL NITRATE IN AQUEOUS SOLN
194000 2.00 EC Current 03.11.1999
11. TOXICOLOGICAL INFORMATION (continued)
There is no toxicological data available for the Ruthenium component, the
following data refers to the Nitric acid component -
LDLo (oral human) 430 mg/kg, LDLo (unreported man) 110 mg/kg.
Users should note that Nitric acid is reported as producing reproductive
effects in laboratory animals.
聽
12. ECOLOGICAL INFORMATION
The effect of ruthenium compounds on the environment has not been
investigated but the hazard is thought to be low. Ruthenium is not
concentrated by plants or animals. Natural processes will tend to produce
insoluble compounds.
However, the nitrate content of this material is such as to present a serious
ecological hazard. Do not allow this material to enter natural watercourses. 聽 聽
13. DISPOSAL
Return accumulated waste material to the refinery for metal recovery, or
dispose of in accordance with local and national regulations. 聽
14. TRANSPORT INFORMATION
U.N. No. 3264, Class 8, Packing Group II
ADR 2801 2(b)
Proper shipping name "Corrosive liquid n.o.s. -----------" 聽 聽
15. REGULATORY INFORMATION
Oxidizing
Labelling Information
Corrosive
R8 Contact with combustible material may cause fire.
R phrases
R35 Causes severe burns.
S23 Do not breathe gas/fumes/vapour/spray.
S phrases
S26 In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
S36 Wear suitable protective clothing.
S45 In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
2520688
EINECS Number
O - Oxidizing
EC Annex I Classification
C - Corrosive
16. OTHER INFORMATION
30 July 1999
MSDS first issued
3 November 1999
MSDS data revised
This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is given in good faith, being based on the latest information
available to Johnson Matthey PLC and is to the best of Johnson Matthey PLC's knowledge and belief, accurate and reliable at
the time of preparation. However, no representation, warranty or guarantee is made as to the accuracy, liability or
completness and Johnson Matthey PLC assumes no responsibility therefore, and disclaims any liability for any loss, damage
or injury howsoever arising (including in respect of any claim brought by any third party) incurred using this information. The
product is supplied on thecondition that the user accepts responsibility to satisfy himself as to the suitability and completness
of such information for his own particular use. Freedom from patent or any other proprietary rights of any third party must not
be assumed. 聽
Reference Sources
REFERENCE SOURCES
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Johnson Matthey
RUTHENIUM NITROSYL NITRATE IN AQUEOUS SOLN
194000 2.00 EC Current 03.11.1999
16. OTHER INFORMATION (continued)
Registry of Toxic Effects of Chemical Substances. Published by the National Institute of Occupational Safety and Health. USA.
Oil and Hazardous Materials Technical Assistance Data System. Published by The Office of Water and Waste Management.
Environmental Protection Agency USA.
Chemical Hazard Response Information System. Published by US Coast Guard.
NIOSHTIC Occupational Safety and Health database. Published by the National Institute of Occupational Safety and Health.
USA.
HSELINE Health and Safety Executive Library and Information Service. Published by the Health and Safety Executive. UK.
CISDOC International Occupational Safety and Health Database. Published by the International Labour Organisation. Geneva.
RISKLINE. Published by the National Chemical Inspectorate. Sweden.
TOXLINE. Published by the Chemical Abstracts Service. USA.
Developmental and Reproductive Toxicology. The National Library of Medicine. USA.
Toxicity, Bibliography. The National Library of Medicine. USA.
Environmental Mutagen Information. Oak Ridge National Laboratory. USA.
Environmental Teratology Information. Oak Ridge National Laboratory. USA
BIOSIS. Published by Biological Abstracts Inc. USA.
Epidemiology Information. The Food and Drug Administration. USA
International Pharmaceutical Abstracts. The American Society of Hospital Pharmacists. USA.
Hazardous Materials Technical Center Abstracts. Department of the Army, Hazardous Materials Technical Center. USA.
Toxicology Document and Data Depository. National Technical Information Service. USA.
Federal Research in Progress. National Technical Information Service. USA.
Toxicology Research Projects. National Institutes of Health. USA
Toxic Substances Control Act Test Submissions. The Environmental Protection Agency. USA.
Patty's Industrial Hygiene and Toxicology 3rd edition.
Handbook on the Toxicology of Metals. Friberg, Nordberg and Vouk 2nd edition.
Bretherick's Handbook of Reactive Chemical Hazards. 5th edition.
Grant's Toxicology of the Eye. 3rd edition.
Merck Index 10th edition.
Handbook on Toxicology of Inorganic Compounds. Seiler, Sigel and Sigel.
Catalog of Teratogenic Agents. Shepard. 4th edition
Reproductive Hazards of Industrial Chemicals. Barlow and Sullivan.
Royal Society of Chemistry, Chemical Safety Data Sheets. JMAC Approved applications -
National Sales Offices
Johnson Matthey PLC,33 Jeffreys Road, Brimsdown, ENFIELD, Middlesex EN3 7PW, United Kingdom, Tel:- 0181 8048111,
Fax:- 0181 8041918
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Johnson Matthey S.A., Vallespir, 193-195, 08014 BARCELONA, Espa帽a, Tel:- (93) 490 86 86, Fax:- (93) 490 68 98
Johnson Matthey A/S, Frederikssundsvej 274 D, Br垄nsh垄j 2700, Denmark, Tel:- 38 89 62 00, Fax:- 38 89 62 01
Johnson Matthey PLC, Unit 1 - 2, Blanchardstown Business Centre, Clonsilla Road, Blanchardstown, Dublin 15, Republic of
Ireland, Tel:- 1 820 7722, Fax:- 1 820 7733
Johnson Matthey GmbH, Alfa Products, Zeppelinstrasse 7, Postfach 6540, D-7500 KARLSRUHE 1, Deutschland, Tel:- 721
840070, Fax:- 721 849674
Johnson Matthey SA, 13 Rue de la Perdrix, Z1 PARIS Nord II, BP 50240, 95996 Roissy, CDG Cedix France, Tel:- 1 48 63 22
99, Fax:- 1 48 63 27 02
Oy Johnson Matthey A.B, Kielotie 7A 4KRS, 01300 BANTAA, Soumi, Tel:- 08574 800, Fax:- 08574 807
Johnson Matthey A.B., Victor Hasselblads gata 8, S-421 31 V盲stra Fr枚lunda, Sverige, Tel:- 031 891390, Fax:- 31 477795
Johnson Matthey & Co G.m.b.H, Steckhovengasse 12, 1132 WIEN, 脰sterreich, Tel:- 877 98 90, Fax:- 877 98 933
Johnson Matthey & Brandenberger A.G., Glattalstrasse 18, CH-8052 ZURICH, Switzerland, Tel:- 01 302 4488, Fax:- 01 302
4701
Johnson Matthey GmbH, Otto-Volger-Stra脽e 9B, D-65843 Sulzbach/Ts, Deutschland, Tel:- (0 61 96)70 38-21, Fax:- (0 61 96)
70 38 12
17. 000000000
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Johnson Matthey
RUTHENIUM NITROSYL NITRATE IN AQUEOUS SOLN
194000 2.00 EC Current 03.11.1999
17. 000000000 (continued)
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